INDIAN SCHOOL MUSCAT
SENIOR SECTION
DEPARTMENT OF CHEMISTRY
CLASS XII
SOLUTIONS
The
1. values of Van’tHoff factors for KCl, NaCl and K2SO4 respectively are-----------
a) 2,2 and 1 b)2, 2 and 3 c)1, 1 and 2 d)1, 1 and1
If2.the molality of the solution is doubled,The value of molal depression constant (Kf) will be
a)Halved b)tripled c)unchanged d)doubled
Which
3. of the following liquid pairs show positive deviation from Raoult’slaw.
a) Water and HCl b)Benzene and Methanol c)water and nitric acid
d)Acetone and Chloroform
Assertion
4. –Reason type questions:
In the following questions a statement of assertion followed by a statement of reason is given,Choose the correc
choices.
(a) Both assertion and reason are correct statements and the reason is a correct explanation for assertion.
(b) Both assertion and reason are correct but reason is not a correct explanation for assertion.
(c) Assertion is correct but reason is incorrect.
(d) Assertion is wrong but reason is correct.
i. Assertion:Lowering of vapour pressure is directly proportional to osmotic pressure of the solution.
Reason : Osmotic pressure is a colligative property
ii. Assertion:The solubility of a gas in a liquid increases with increase in pressure
Reason: The solubility of a gas in a liquid is directly proportional to the pressure of the
gas
Why
5. do gases always tend to be less soluble in liquids as the temperature israised?
Define
6. the following terms:
a) Van’t Hoff factor
b) Ebullioscopic constant
c) Cryoscopic constant
d) Isotonic solutions
e) Ideal solutions
Give
7. reasons for the following :
a) Measurement of osmotic pressure method is preferred for the determination of molar masses of macromole
b) Elevation of boiling point of 1 M KCl solution is nearly double than that of 1 M sugar solution
‘The
8. osmotic pressure measured when benzoic acid is dissolved in benzene is less thanthe expected value’.Com
-1
18gofglucose,C
9. 6H12O6(molarmass=180gmol )isdissolvedin1kgofwaterinasauce pan. At what temperature will
(Kb for water = 0.52 k kg mol-1, boiling point of pure water = 373.15K)
Define
10. an ideal solution and write one of itscharacteristics.
What
11. are azeotropic mixtures? What are itstypes?
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a)12.Why are aquatic species more comfortable in cold water than in warmwater?
b) What happens when we place the blood cell in saline water solution (hypertonicsolution)?Give reason.
Calculate
13. the amount of KCl which must be added to 1 kg of water so that the freezing pointisdepressed by 2K.
Determine
14. the osmotic pressure of a solution prepared by dissolving 2.5 x 10-2g of K2SO4in 2L of water at 250C
completelydissociated.
(R = 0.0821 L atm K-1mol-1, molar mass of K2SO4= 174 gmol-1)
Asolutionofglucoseinwaterislabelledas10%w/w,whatwouldbethemolalityandmole
15. fraction of each component i
-1
solution is 1.2 g mL , thenwhat shall be the molarity of thesolution?
A16.
solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapourpressure
of2.8kPaat298K.Further,18gofwateristhenaddedtothesolutionandthenewvapour pressure becomes 2.9 kPa at 29
the solute (ii)Vapourpressure of water at 298K.
Calculatethedepressioninthefreezingpointofwaterwhen10gofCH
17. 3CH2CHClCOOHisadded to 250 g of water. Ka=
Two18. elements A and B form compounds having formula AB2 and AB4. When dissolved in 20
gofbenzene(C6H6),1gofAB2lowersthefreezingpointby2.3Kwhereas1.0gofAB4lowersitby1.3K.Themolardepressi
1
.Calculate atomic masses of A andB.
o
Vapourpressureofwaterat20
19. Cis17.5mmHg.Calculatethevapourpressureofwaterat20o C when 15 g of glucose (M
dissolved in 150 g of water.
a)20.Explain thefollowing:
i. Henry’s law about dissolution of a gas in aliquid.
ii. Molal boiling point elevation constant for asolvent.
b) A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerolin 500 g of water. This s
100.42oC. What mass ofglycerol was dissolved to make this solution? (Kb for water = 0.512 K kg mol-1)
a)21.Onmixingacetonewithchloroform,areductionoccursintotalvolume.
Whattypeof deviations from ideal behavior for solutions is shown in this case andwhy?
b) Phenol associates in benzene to certain extent to form a dimer. A solution containing
20g of phenol in 1.0 kg of benzene has its freezing point lowered by 0.69 K. Calculatethe fraction of pheno
(Given Kffor benzene = 5.1 KKgmol-1)
What is Van’t Hoff factor? What is the value of Van’t Hoff factor if the solute undergoes
a)22.
i. Dissociation ii. Association
a) How many mL of a 0.1 M HCl solution are required to react completely with 1g ofa mixture of Na2CO3and
equimolar amounts of both?
a)23.How can direction of osmosis be reversed? Give one use of reverse osmosis
b) Blood cells are isotonic with 0.9% solution of NaCl
solution. What happens when if we place blood cells ina solution containing :
(i) 0.4% of NaCl solution. (ii) 1.2% of NaCl solution
Derive
24. the relation between relative lowering of vapour pressure and mole fraction of anon volatile solute.
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