Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Special Cleaner for Glass and Plastic GR1N
Article No.: G9904571 Revision date: 01.12.2017 EN
Print date: 04.12.2017 Issue date: 01.12.2017 Page: 1|6
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifiers
Article No. (manufacturer/supplier) G9904571
Identification of the substance or mixture: GR1N aqueous cleaner
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
cleaning agent
1.3. Details of the supplier of the safety data sheet
supplier (manufacturer/importer/downstream user/distributor):
CESB GmbH
Bennostraße 2 Telefon: +49(0)30 2100522-70
13053 Berlin Telefax: +49(0)30 2100522-75
Germany
Dept. responsible for information:
E-mail: [email protected]
1.4. Emergency telephone number
Emergency telephone number: UK: Tel: 111 or 0344 892 111 (NHS professionals only)
Ireland: Members of Public: 01 809 2166. (8.00 a.m. to
10.00 p.m. 7 days a week)
Ireland: Healthcare Professionals: 01 809 2566 (24 hour service)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms
Hazard statements:
n.a
Precautionary statements
n.a.
contains:
n.a
Besondere Kennzeichnung bestimmter Gemische
EUH210 Safety data sheet available on request
2.3. Other hazards
SECTION 3: Composition / information on ingredients
3.1. Mixtures
Product description / chemical characterization
Description: water based cleaner, pH neutral
Hazardous ingredients:
Classification according to Regulation (EC) No. 1272/2008 [CLP].
EC-No. REACH No.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Special Cleaner for Glass and Plastic GR1N
Article No.: G9904571 Revision date: 01.12.2017 EN
Print date: 04.12.2017 Issue date: 01.12.2017 Page: 2|6
CAS-No. Chemical name Wt.-%
INDEX-No. classification Remark
n.a.
.
Additional information
*Full text of classification: see section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures:
General information:
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth, place
in recovery position and seek medical advice.
Following inhalation
Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial
respiration.
Following skin contact:
Remove contaminated, saturated clothing immediately. After contact with skin, wash immediately with plenty of water and
soap. Do not use solvents or thinners.
After eye contact:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek
medical advice immediately.
After ingestion:
If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm.
Do NOT induce vomiting..
4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
alcohol resistant foam, carbon dioxide, Powder, spray mist, (water)
Extinguishing media which must not be used for safety reasons:
strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device.Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways. Treat runoff as hazardous.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate affected area. Do not breathe vapours. See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see chapter 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see chapter 7 and 8).
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Special Cleaner for Glass and Plastic GR1N
Article No.: G9904571 Revision date: 01.12.2017 EN
Print date: 04.12.2017 Issue date: 01.12.2017 Page: 3|6
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advices on safe handling
Avoid contact with skin, eyes and clothes. Avoid respiration of swarf. When using do not eat, drink or smoke. Personal
protection equipment: refer to chapter 8. Do not empty containers with pressure - no pressure vessel! Always keep in
containers that correspond to the material of the original container. Follow the legal protection and safety regulations.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks.
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Keep container tightly closed. Remove all
sources of ignition. Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to
prevent any leaks..
7.3. Specific end use(s)
Observe technical data sheet.Observe instructions for use.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limit values:
n.a.
8.2. Exposure controls
Provide good ventilation. This can be achieved with local or room suction.
Occupational exposure controls
Respiratory protection
n.a.
Hand protection
For prolonged or repeated handling the following glove material must be used: not necessary
Thickness of the glove material 0,4 mm Breakthrough time (maximum wearing time) 30 min
Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove
manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin: Recommended
glove articles DIN EN 374
Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye protection
Wear closely fitting protective glasses in case of splashes.
Protective clothing
Wear suitable protective clothing and gloves.
Protective measures
After contact clean skin thoroughly with water and soap or use appropriate cleanser.
Environmental exposure controls
Do not allow to enter into surface water or drains. See chapter 7. No additional measures necessary..
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Physical state liquid
Colour without
Odour perfumed
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Special Cleaner for Glass and Plastic GR1N
Article No.: G9904571 Revision date: 01.12.2017 EN
Print date: 04.12.2017 Issue date: 01.12.2017 Page: 4|6
Safety relevant basis data Unit Method Remark
Flash point (°C): Not applicable
Ignition temperature in °C: n.a.
Lower explosion limit: n.a.
Upper explosion limit: n.a.
Vapour pressure at 20 °C: 23,00 mbar
Density at 20 °C: 1,00 g/cm³ DIN 51757
Water solubility (g/L): soluble in water
pH at 20 °C: 7,00 1,0
Viscosity at 20 °C: < 12 s 4 m DIN 51562/1
9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
not reactive under normal use conditions
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
chapter 7.
10.3. Possibility of hazardous reactions
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
chapter 7. Hazardous decomposition byproducts may form with exposure to high temperatures..
10.5. Incompatible materials
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides. none at regular usenone at regular use..
SECTION 11: Toxicological information
Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 [CLP]
No data on preparation itself available.
11.1. Information on toxicological effects
Acute toxicity
Toxicological data are not available.
skin corrosion/irritation; Serious eye damage/eye irritation
Toxicological data are not available.
Respiratory or skin sensitisation
Toxicological data are not available.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Toxicological data are not available.
Specific target organ toxicity
Toxicological data are not available.
Aspiration hazard
Toxicological data are not available.
Practical experience/human evidence
Other observations:
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic
contact dermatitis and/or absorption through skin. Splashing may cause eye irritation and reversible damage.
Overall Assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
Remark
There is no information available on the preparation itself.
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Special Cleaner for Glass and Plastic GR1N
Article No.: G9904571 Revision date: 01.12.2017 EN
Print date: 04.12.2017 Issue date: 01.12.2017 Page: 5|6
SECTION 12: Ecological information
overall evaluation
Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 [CLP]There is no information
available on the preparation itself.
Do not allow to enter into surface water or drains.
12.1. Toxicity
No information available.
Long-term Ecotoxicity
Toxicological data are not available.
12.2. Persistence and degradability
Toxicological data are not available.
12.3. Bioaccumulative potential
Toxicological data are not available.
Bioconcentration factor (BCF)
Toxicological data are not available.
12.4. Mobility in soil
Toxicological data are not available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation:
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EWC
070799 wastes not otherwise specified
packaging
Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
SECTION 14: Transport information
This mixture is not classified as dangerous according to international transport regulations (ADR/RID, IMDG,
ICAO/IATA).
No dangerous good in sense of this transport regulation.
14.1. UN number n. a.
14.2. UN proper shipping name
14.3. Transport hazard class(es) n.a.
14.4. Packing group n.a.
14.5. Environmental hazards
Land transport (ADR/RID) n.a.
14.6. Special precautions for user
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Additional information
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) No 453/2010
Special Cleaner for Glass and Plastic GR1N
Article No.: G9904571 Revision date: 01.12.2017 EN
Print date: 04.12.2017 Issue date: 01.12.2017 Page: 6|6
Land transport (ADR/RID)
tunnel restriction code
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Information according to 1999/13/EC about limitation of emissions of volatile organic compounds (VOC-guideline).
VOC-value (in g/L) ISO 11890-2: 55,000
VOC-value (in g/L) ASTM D 2369: 55,000
National regulations
Restrictions of occupation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).
Other regulations, restrictions and prohibition regulations
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this preparation were not carried out.
SECTION 16: Other information
Full text of classification in section 3:
Abbreviations and acronyms
Not contained in the list of poisonous chemicals and precursor of the agreement governing chemical weapons (CWC)
Additional information
Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 [CLP]
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations. Without written approval, the product must not be used for purposes different from those mentioned in
chapter 1. It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules
and regulations. The details in this safety data sheet describe the safety requirements of our product and are not to be
regarded as guaranteed attributes of the product..
Annex
At present, data / information on exposure scenarios are not available, so that an evaluation of the preperation cannot yet be
made
