Klass.-Nr. /Class. No.

51322 May 2006

Norm vor Anwendung auf Aktualität prüfen / Check standard for current issue prior to usage.
Alloyed Quenched and Tempered Steel 22MnB5 TL
Uncoated or Pre-Coated
The English translation is believed to be accurate .In case of discrepancies the German version shall govern.

Material Requirements for Semi-Finished Products and Components

4225
Konzernnorm
Descriptors: quenched and tempered steel, 22MnB5, press-quenching, induction-
hardening, pre-coated, AlSi hot-dip coated, sheet, cold-rolled, hot-rolled, tube

Changes
The following changes have been made as compared to Technical Supply Specification TL 4225,
1995-09:
─ Standard completely revised
Numerical notation according to ISO practice (see VW 01000).

Previous issues
1995-09

1 Scope
This TL standard specifies the requirements for uncoated or pre-coated, hot-rolled or cold-rolled
sheets or welded tubes made of steels, based on 22MnB5 for press quenching or induction
hardening, with thicknesses between 0,65 and 6,00 mm.

2 Description
Description example for press-quenched sheet metals with a thickness of 1,5 mm made of cold-
rolled, uncoated raw material:
Material: TL 4225 +C
Semi-finished product: EN 10131-1,5
Description example for a press-quenched AlSi hot-dip coated sheet with a thickness of 2,0 mm
with a coating weight of 150 g/m2 (standard coating) according to DIN EN 10292:
Material: TL 4225 +AS 150
Semi-finished product: EN 10143-2,0
Description example for a welded tube with an outer diameter of 30 mm and an uncoated,
induction-hardened (water quenching) wall, thickness 3,0 mm:
Material: TL 4225
Tube 30 x 3,0 – EN 10305-3
QUELLE: NOLIS
Form FE 41 - 01.06

Page 1 of 11
Fachverantwortung/Responsibility Normung/Standards (E2TC, 1733)

K-GQL-2/3 Dr. Lachmann Tel: +49-5361-9-33994 Dr. Eisenberg Ute Hager-Süß Tel: +49-5361-9-49035 Terlinden
Vertraulich. Alle Rechte vorbehalten. Weitergabe oder Vervielfältigung ohne vorherige Zustimmung einer Normenabteilung des Volkswagen Konzerns nicht gestattet.
Vertragspartner erhalten die Norm nur über die B2B Lieferantenplattform „www.vwgroupsupply.com“.
Confidential. All rights reserved. No part of this document may be transmitted or reproduced without prior permission of a Standards Department of the Volkswagen Group.
Parties to a contract can only obtain this standard via the B2B supplier platform “www.vwgroupsupply.com”.
 VOLKSWAGEN AG
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TL 4225: 2006-05

3 Manufacturing method
See Table 1.
Table 1
Raw material cold or hot-rolled, uncoated or pre-coated
Profiles and shells, press- Depending on the sheet thickness, austenitizing 5 to 10 minutes at
quenched 900 °C to 950 °C. Quenching in tool, cooling rate at least 30 K/s.1)
Tubes, induction-hardened Austenitizing at 930 °C to 1 050 °C with subsequent water
(water quenching) quenching, cooling rate at least 30 K/s1).
1) Longer austenitizing times or different austenitizing temperatures require the approval of the responsible quality assurance
department.

4 Requirements

4.1 General requirements

Approval of first supply and changes according to Volkswagen standard VW 01155.
Avoidance of hazardous substances according to VW 91101.

4.2 Chemical composition in weight percent

See Table 2.
Table 2
C C Si Mn Cr Mo P S Ti Al B
(Profiles, (Tubes)
shells)
0,20 0,23 0,15 1,10  0,35  0,35  0,025  0,005 0,020 0,020 0,002
to to to to to to to
0,25 0,27 0,40 1,40 0,050 0,060 0,005

4.3 Requirements for unhardened sheets and tubes

4.3.1 Mechanical properties

Determination of the mechanical-technological properties perpendicular to the rolling direction
according to DIN EN 10002-1, specimen shape H 20 x 80 according to DIN 50125, related to
specimen cross sections without coatings. See Table 3 – Mechanical properties of the raw material
for sheets.
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TL 4225: 2006-05

Table 3 – Mechanical properties of the raw material for sheets

Codes Condition 0,2% offset proof Tensile strength Elongation at break

stress Rp0,2 Rm A80 mm
MPa MPa %
min.
not pre-coated
+C cold-rolled 310 to 400 480 to 560 20
+H hot-rolled  320  500 10
inorganically/organically coil-coated
+XT cold-rolled 310 to 430 480 to 560 19
AlSi hot-dip coated
+AS cold- or hot-rolled 350 to 550 500 to 700 10

4.3.2 Matrix
In cold-rolled condition, the matrix is ferrite/pearlite with carbide precipitates and can occasionally
contain small portions of bainite.
Typical grain size > 10 ASTM (informative), see Fig. 1.
Unless otherwise agreed, manganese sulfides with sharp boundaries and oriented in longitudinal
direction to the rolling direction with a length of > 50 µm are not permissible, see Fig. 2 .
Deviating matrix requirements need the approval of the responsible quality assurance department.

Fig. 1 – Matrix in unhardened condition (transverse microsection, OE1 = 500:1)

1
Original enlargement on the microscope
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TL 4225: 2006-05

Rolling direction

Fig. 2 – Elongated manganese sulfides > 50 µm

(transverse microsection, unetched, OE = 500:1)

4.3.3 Requirements for surfaces and coatings

4.3.3.1 Unetched sheets

Surface type of cold-rolled products in initial condition A according to DIN EN 10268.
Specifications for roughness and peak count of cold-rolled products for cold forming before press-
quenching must be agreed upon with the processing party. Unless otherwise agreed, during test
procedure, the following applies according to SEP 1940:
Ra [µm]: 1,1 to 1,7
RPC [1/cm]: > 50.
Surface type in hot-rolled condition according to DIN EN 10111.

4.3.3.2 Inorganically/organically coil-coated sheets (+XT)

An inorganic/organic coil coating (sol-gel-varnish system) can be applied as a forming aid and as a
protection against scaling. The burning-in process at approx. 200°C to 250°C, slightly influences
the mechanical-technological characteristic values (see Table 3 – Mechanical properties of the raw
material for sheets).
Specification of the layer properties according to special agreement.

4.3.3.3 AlSi pre-coated sheets (+AS)

Specification of the aluminum-silicon coating and test of the coating weight according to DIN EN
10292. A normal coating weight is 150 g/m2 (+AS 150), coating weight according to Table 4 –
Coating weight of the AlSi coating AS 150 (coating weight 150 g/m2). Deviating coating weights
need special agreement.
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TL 4225: 2006-05

Table 4 – Coating weight of the AlSi coating AS 150 (coating weight 150 g/m2)
Characteristic Minimum coating weight in g/m2 on Reference values for layer Density
value one side thicknesses per side in µm g/cm3
Three-surface Single-surface Typical value Area
specimen specimen
AS 150 70 to 90 60 to 100 25 20 to 30 approx. 3.0

Layers shown in transverse microsection, see Fig. 3 – AlSi layer (+AS) in unhardened condition,
informative (OE = 1000:1) (informative).

AlSi-Schicht,
AlSi ca. 6060HV
layer, approx. HV

Diffusionszone,
Diffusion ca. 600600
zone, approx. HV HV

Grundgefüge
Matrix

Fig. 3 – AlSi layer (+AS) in unhardened condition, informative (OE = 1000:1)

4.3.3.4 Tubes
Surface characteristics and inner characteristics of welded tubes according to DIN EN 10305-3, for
seamless tubes according to DIN EN 10305-1.

4.3.4 Limit deviations and tolerances of form

DIN EN 10131 applies to cold-rolled flat products, DIN EN 10051 to hot-rolled flat products, and
DIN EN 10143 to hot-dip coated sheets.
Dimensions and limit deviations of welded tubes according to DIN EN 10305-3, for seamless tubes
according to DIN EN 10305-1.

4.4 Requirements for press-quenched components and induction-hardened tubes

The processing party is responsible for the requirements for the press-quenched or induction-
hardened condition.

4.4.1 Mechanical properties

See Table 5– Mechanical properties in hardened condition.
Determination according to DIN EN 10002-1.
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TL 4225: 2006-05

Specimen shapes for press-quenched components shape H 12,5 x 50 according to DIN 50125 or
small specimens with k= 5,65 (e.g. a  b  L0 = 2,0  6  20 or 2,0 x 20 x 35).
For induction hardened tubes oriented in longitudinal direction to the tube axis, trouser test piece or
round test piece according to DIN EN 10002-1 (Appendix E).
Table 5– Mechanical properties in hardened condition
Condition 0,2% offset Tensile strength Elongation at break Hardness
proof stress Rm A80 mm A50 mm A HV 10 / HV 30
Rp0,2 MPa % % %
MPa min. min. min.
press- 1 000 to 1 250 1 300 to 1 650 4,5 5 6 400 to 520
quenched
(profiles,
shells)
induction 1 100 to 1 400 1 400 to 1 900 6 7 8 435 to 575
hardened
(tubes)

When designing the component, an increase in the yield point of approx. 100 MPa due to bake
hardening during burning-in of the cathodic electrocoating must be considered in hardened
condition.
Estimation of tensile strength on the component based on the hardness according to
DIN EN ISO 18265 – A.1. After agreement with the responsible quality assurance department, for
process monitoring, non-destructive test methods for determining the hardness on the component
are permissible (e.g. micromagnetic methods).

4.4.2 Matrix
The matrix shows self-tempered martensite with residues of bainite.
The manganese sulfides, normally not permitted and oriented in longitudinal direction to the rolling
direction (see Section 4.3.2) are especially well visible in hardened condition on the etched
microsection, see Fig. 4.
When loaded perpendicularly to the rolling direction, these inclusions lead, in the case of a
breakdown, to a so-called wood-fiber structure (Fig. 5) and a significant decrease of the impact
resistance. By decreasing the sulfur content using a very fine desulphurization or a respective
metallurgical treatment for spheroidization, manganese sulfides forming this structure can be
avoided as far as possible.
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TL 4225: 2006-05

Rolling direction

Fig. 4 – Elongated manganese sulfides > 50 µm in hardened condition

(transverse microsection, etched, OE = 500:1)

Fig. 5 – Fracture face with wood fiber structure due to long manganese sulfides
(stereo microscope, OE = 32:1)

4.4.3 Requirements for surfaces and coatings in hardened condition

4.4.3.1 Uncoated components

After press-quenching, these products are delivered in completely descaled condition. Upon
special agreement, the products can also be delivered in untreated condition.
For descaling, blast cleaning with metallic blast material (chill casting and steel casting according to
DIN EN ISO 11124, Part 1 to 4) is recommended.
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TL 4225: 2006-05

Alternative descaling procedures (e.g. ultrasonic cleaning) need the approval of the responsible
quality assurance department.

4.4.3.2 Surface decarburization

Maximum permissible surface decarburization according to DIN EN ISO 3887: DD = 0,1 mm.
A total decarburization is not permissible.

4.4.3.3 AlSi-pre-coated components (+AS)

Layers in transverse microsection, see Fig. 6 (informative). The extreme hardness of the layer
thickness near the surface must be taken into consideration concerning design and wear of the
tools.
Layer thickness: 30 µm to 40 µm (see also Section 4.6.1).
The layer thickness in hardened condition shall be determined preferably visually on the transverse
microsection. For this purpose, the microsection must be etched with nital solution and the bright
alloy layer in the microsection must be used for determining the total layer thickness. Since the
layer thickness varies due to the manufacturing method, a sufficient number of specimens from
different component areas is needed for evaluation.
Alternative procedures for determining the layer thickness on the press-quenched component shall
be agreed upon with the responsible quality assurance department. Comparison of the alternative
layer thickness measuring procedures with the metallographically determined layer thickness must
be documented.

Partly brittlespröde
Teilweise intermetallic Fe-Al-Si phases,
intermetallische
approx. 450 to 1 100 HV
Fe-Al-Si-Phasen, ca. 450 bis 1100 HV
Diffusion zone, approx.
Diffusionszone, 250bis
ca. 250 to 450
450 HV
HV

Matrix
Grundgefüge

Fig. 6 – AlSi layer (+AS) after press-quenching, informative (OE = 500:1)

Spheroidizations of the AlSi layer (Fig. 7) resulting from forming processes are not permissible.
Unless otherwise agreed, a cold pre-forming of AlSi-coated components is not permissible. From a
certain degree of deformation on, this leads to large areas of flaking of the layer and/or significant
accumulations of scale residues resulting from oxidation of the AlSi layer and the base material
(Fig. 8).
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TL 4225: 2006-05

Fig. 7 – Non-permissible spheroidizations of the AlSi layer on the press-quenched

component (OE = 100:1)

Fig. 8 – Non-permissible large areas of flaking of the AlSi layer with scale residues
(OE = 200:1)

4.5 Surface treatment, phosphating and painting

Oiling according to Table 6. The oiling process must be matched with the subsequent processes
(oven process, joining, cleaning, painting). When transporting the goods by ship, a seaworthy
packaging is recommended.
Table 6 - Oiling
Initial condition hardened hardened and blasted
Uncoated according to QP A001 Optional according to QP A001
Inorganically/organically optional optional according to QP A001
coil-coated (+XT)
AlSi-coated (+AS) optional optional -

A phosphatability according to QP A020 must be guaranteed.

For blast-cleaned press-quenched components (+C, +H, +XT), it may become necessary to adapt
the phosphating parameters (e.g. “free acid”).
When phosphating AlSi-coated press-quenched components (+AS), this leads to an increase of the
aluminum content in the bath. A limit value of 50 mg/l must be adhered to. If the aluminum ions are
not sufficiently precipitated from the phosphating bath, a precipitation in the form of cryolite (sodium
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TL 4225: 2006-05

hexafluoroaluminate Na3AlF6) is required and the precipitation must be ensured with a system for
sludge removal. Otherwise, there is the danger of precipitation of cryolite sludge on horizontal
surfaces of the components or bodies to be phosphated.
Properties after painting according to TL 260.

4.6 Joining press-quenched components

Generally, the joining concept of assemblies with press-quenched components must be agreed
upon in early state with the responsible experts.

4.6.1 Welding
Due to their special properties, press-quenched and induction-hardened steels are considered as
conditionally suitable for welding. Discontinuities in hardness in the heat-affected zone must be
considered when designing the joint. Normally, the welded joint does not reach the strength of the
base material in this zone.
During welding of AlSi-coated sheets, intermetallic Fe-Al phases can occur near the fusion line
(marked brightly in the etched microsection), depending on the welding procedure and the type of
joint (cf. PV 6702).
When the maximum permissible layer thickness of 40 µm after press-quenching is exceeded,
spattering can occur and the required spot welding diameter may be fallen below during resistance
spot welding of AlSi-coated sheets (+AS, cf. Section 4.4.3.3)
The welding suitability of an inorganic/organic coil coating (+XT) in blasted and non-blasted
condition must be tested for each layer system.

4.6.2 Bonding with high-strength structural adhesives

Determination of the tensile shear strength in hardened condition on lap joint according to
DIN EN 1465.
The required minimum values of the tensile shear strengths of non-aged and aged specimens must
be agreed upon with the respective quality assurance and process departments.
For AlSi-coated, press-quenched sheets, shear strengths of > 20 MPa can be reached when using
respective adhesives. Normally, the coating fails between the softer alloy coating and the brittle
upper coating components.

5 Referenced standards2
PV 6702 Spot Weld Joints; Strength Testing of Steel Materials
QP A001 Prelubes, Slushing Oils (General), Blank Washing Oils, Drawing Oils and
Drawing Agents; Quality Requirements (currently only available in German)
QP A002 Metal Surfaces Pretreatment before Painting; Quality Requirements
TL 260 Paint Coating of Metal Surfaces; Requirements for Surface Protection
VW 01155 Vehicle Supply Parts; Approval of First Supply and Changes
VW 91101 Environmental Standard for Vehicles; Vehicle Parts, Materials, Operating
Fluids; Avoidance of Hazardous Substances
DIN 50125 Testing of Metallic Materials; Tensile Test Pieces

2
In this section terminological inconsistencies may occur as the original titles are used.
 Page 11
TL 4225: 2006-05

DIN EN 1465 Adhesives – Determination of Tensile Lap-Shear Strength of Rigid-to-Rigid

Bonded Assemblies
DIN EN 10002-1 Metallic Materials; Tensile Testing, Part 1: Method of Testing at Ambient
Temperature
DIN EN 10051 Continuously Hot-Rolled Uncoated Plate, Sheet and Strip of Non-Alloy and
Alloy Steels - Tolerances of Dimensions and Shape
DIN EN 10111 Continuously Hot-Rolled Low Carbon Steel Sheet and Strip for Cold
Forming - Technical Delivery Conditions
DIN EN 10131 Cold-Rolled Uncoated Low Carbon and High-Yield Strength Steel Flats for
Cold Forming; Tolerances on Size and Geometrical Tolerances
DIN EN 10143 Continuously Hot-Dip Metal Coated Steel Sheet and Strip;
Tolerances on Dimensions and Shape
DIN EN 10268 Cold-Rolled Flat Products made of High Yield Strength Micro-Alloyed Steels
for Cold Forming – General Delivery Conditions
DIN EN 10292 Continuously Hot-Dip Coated Strip and Sheet of Steels with Higher Yield
Strength for Cold Forming – Technical Delivery Conditions
DIN EN 10305-1 Steel Tubes for Precision Applications – Technical Delivery Conditions –
Part 1: Seamless Cold Drawn Tubes
DIN EN 10305-3 Steel Tubes for Precision Applications – Technical Delivery Conditions –
Part 3: Welded Cold Sized Tubes
DIN EN ISO 3887 Steels – Determination of Depth of Decarburization
DIN EN ISO 11124-1 Preparation of Steel Substrates Before Application of Paints and Related
Products - Specifications for Metallic Blast-Cleaning Abrasives - Part 1:
General Introduction and Classification
DIN EN ISO 11124-2 Preparation of Steel Substrates Before Application of Paints and Related
Products - Specifications for Metallic Blast-Cleaning Abrasives - Part 2:
Chilled-Iron Grit
DIN EN ISO 11124-3 Preparation of Steel Substrates Before Application of Paints and Related
Products - Specifications for Metallic Blast-Cleaning Abrasives - Part 3:
High-Carbon Cast-Steel Shot and Grit
DIN EN ISO 11124-4 Preparation of Steel Substrates Before Application of Paints and Related
Products - Specifications for Metallic Blast-Cleaning Abrasives - Part 4:
Low-Carbon Cast-Steel Shot
DIN EN ISO 18265 Metallic Materials – Conversion of Hardness Values
SEP 1940 Measurement of Roughness Average Ra and Peak Count RPc on Cold-
Rolled Flat Steel Products