He a lt h 2
0 0
Fire
2 0
Re a c t iv it y 0
P e rs o n a l A
P ro t e c t io n
Material Safety Data Sheet
Buffer Solution, pH 4.01/CLEAR MSDS
Section 1: Chemical Product and Company Identification
Product Name: Buffer Solution, pH 4.01/CLEAR Contact Information:
Catalog Codes: SLB2821, SLB4321 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: Not applicable. US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Potassium biphthalate;
Hydrochloric acid; Methyl paraben; Propyl paraben; Water Order Online: ScienceLab.com
CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
Synonym:
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Not applicable.
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: Not applicable.
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Potassium biphthalate 877-24-7 1.02
Hydrogen chloride 7647-01-0 0.000192
Water 7732-18-5 99
Methyl paraben 99-76-3 0.01
Propyl paraben 94-13-3 0.0025
Toxicological Data on Ingredients: Potassium biphthalate LD50: Not available. LC50: Not available.
Section 3: Hazards Identification
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Non-
hazardous in case of inhalation.
Potential Chronic Health Effects: Non-corrosive for skin. Non-sensitizer for skin. Non-permeator by skin. CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged
exposure to the substance can produce target organs damage.
p. 1
Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation: Not available.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such
as a collar, tie, belt or waistband.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2). Some metallic oxides.
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks.
Non-flammable in presence of shocks, of heat, of oxidizing materials, of reducing materials, of combustible materials, of
organic materials, of metals, of acids, of alkalis.
Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical
impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or
foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal. If necessary:
Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize the residue
with a dilute solution of sodium carbonate. Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Section 7: Handling and Storage
Precautions: Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the
residue under a fume hood. Ground all equipment containing material. Do not breathe gas/fumes/ vapor/spray.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
p. 2
Section 8: Exposure Controls/Personal Protection
Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might
not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits: Not available.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid.
Odor: Odorless.
Taste: Not available.
Molecular Weight: Not applicable.
Color: Clear Colorless.
pH (1% soln/water): Acidic.
Boiling Point: The lowest known value is 100°C (212°F) (Water).
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: Weighted average: 1 (Water = 1)
Vapor Pressure: The highest known value is 2.3 kPa (@ 20°C) (Water).
Vapor Density: The highest known value is 0.62 (Air = 1) (Water).
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.
Solubility: Easily soluble in cold water, methanol. Soluble in diethyl ether, acetone. Very slightly soluble in hot water.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass, of stainless steel(304), of stainless steel(316).
Special Remarks on Reactivity: Reacts violently with water especially when water is added to the product. (Hydrogen
chloride)
Special Remarks on Corrosivity: Not available.
p. 3
Polymerization: Not available.
Section 11: Toxicological Information
Routes of Entry: Not available.
Toxicity to Animals: LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion. Non-hazardous in case of
inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Material is extremely destructive to tissue of the mucous membranes
and upper respiratory tract. (Hydrogen chloride)
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Decomposes and burns to form smoke, carbon monoxide and
carbon dioxide. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source ia s potential
dust explosion hazard. (Methyl paraben)
Section 13: Disposal Considerations
Waste Disposal:
Section 14: Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
Section 15: Other Regulatory Information
Federal and State Regulations: Pennsylvania RTK: Hydrochloric acid Massachusetts RTK: Hydrochloric acid TSCA
8(b) inventory: Potassium biphthalate; Hydrochloric acid; Methyl paraben; Propyl paraben; Water SARA 302/304/311/312
extremely hazardous substances: Hydrochloric acid CERCLA: Hazardous substances.: Hydrochloric acid;
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
p. 4
DSCL (EEC): This product is not classified according to the EU regulations.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment: Not applicable. Lab coat. Wear appropriate respirator when ventilation is inadequate. Safety glasses.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/10/2005 12:54 AM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5