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Test Bank-CH-6 Final +

The document contains 18 multiple choice questions regarding thermochemistry concepts such as: 1) Calculating heat of combustion/formation from calorimetry experiments. 2) Identifying properties such as specific heat, enthalpy, and their relation to exothermic/endothermic processes. 3) Applying Hess's law to calculate enthalpy changes from standard heats of formation. The questions cover a range of thermochemistry topics including calorimetry, state functions, heat of reaction, and Hess's law.

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miku nakano
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210 views4 pages

Test Bank-CH-6 Final +

The document contains 18 multiple choice questions regarding thermochemistry concepts such as: 1) Calculating heat of combustion/formation from calorimetry experiments. 2) Identifying properties such as specific heat, enthalpy, and their relation to exothermic/endothermic processes. 3) Applying Hess's law to calculate enthalpy changes from standard heats of formation. The questions cover a range of thermochemistry topics including calorimetry, state functions, heat of reaction, and Hess's law.

Uploaded by

miku nakano
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Thermochemistry

1. I 0.315 moles of hexane (C6H14) burn in a bomb calorimeter containing 5.65 liters of
water, what’s the molar heat of combustion of hexane (the water temperature rises 55.4
0
C)? The heat capacity of water is 4.184 J/g0C.
a) 4150 kJ/mol
b) 1310 kJ/mol
c) 4150 J/mol
d) 1310 J/mol

2. If I burn 22.0 grams of propane (C3H8) in a bomb calorimeter containing 3.25 liters of
water, what’s the molar heat of combustion of propane if the water temperature rises
88.5 0C?
a) 1.20 x 103 kJ
b) 2.40 x 103 kJ/mol.
c) 1.20 x 103 J
d) 2.40 x 103 J/mol.

3. What units of energy are commonly used in chemistry?


a) Joules
b) Liters
c) Kilogram
d) Calories

Which
e) 1of the following statements correctly describes the signs of q and w
for the6following exothermic process at P = 1 atm and T = 370 K?
- H 2O( g )  H 2O(l )

A) q and w are negative


B) q is positive, w is negative
C) q is negative, w is positive
D) q and w are both zero

4. What is the units for heat capacity?


a) J
b) g /°C
c) J /g .°C
d) J / °C
5. A piece of silver of mass 362 g has a heat capacity of 85.7 J.°C-1. What is the specific
heat of silver?
a) 0.237 J / °C
b) 237 J / °C
c) 23 J / °C
d) 47 J / °C

6. Calculate the amount of heat liberated (in kJ) from 366 g of mercury (specific heat of
mercury 0.139 J /g .°C) when it cools from 77.0 to 12.0 °C.
a) 33.1 kJ
b) -3.31 kJ
c) 3.31 J
d) 1000 J

7. A 6.22 kg piece of copper metal (specific heat of copper 0.385 J /g .°C) is heated from
20.5 °C to 324.3 °C. Calculate the heat absorbed (in kJ) by the metal.
a) 728 J
b) 728 kJ
c) 72J
d) 27kJ

8. SI unit of work is
a) Atmosphere
b) Joule
c) Calories
d) Second

9. A chemical reaction that absorbs heat from the surroundings is said to be __________
and has a __________ ΔH at constant pressure
a) endothermic, positive
b) endothermic, negative
c) exothermic, negative
d) exothermic, positive

10. Which one of the following statements is true?


a) Enthalpy is an intensive property.
b) The enthalpy is not a state function
c) Enthalpy is a state function.
d) H is the value of q measured under conditions of constant volume.
11.ΔH for an endothermic process is _______ while ΔH for an exothermic process is ____.
a) zero, positive
b) zero, negative
c) positive, negative
d) negative, positive

12.Of the following, which one is a state function?


a) E
b) q
c) w
d) All of the above

13.When a system ________ ΔE is always negative.


a) absorbs heat and does work
b) gives off heat and does work
c) absorbs heat and has work done on it
d) none of the above is always negative

14.Consider the following standard heats of formation:


P4O10(s) = –3110 kJ/mol , H2O(l) = –286 kJ/mol , H3PO4(s) = –1279 kJ/mol
Calculate the change in enthalpy for the following process:
P4O10(s) + 6H2O(l) → 4H3PO4(s)
a) 290 kJ
b) 2117 kJ
c) 1720 kJ
d) 0 kJ

15. Calculate the work for the expansion of CO2 from 1.0 to 2.5 liters against a pressure of
1.0 atm at constant temperature.
a) 1.5 liter ⋅ atm
b) 2.5 liter ⋅ atm
c) –1.5 liter ⋅ atm
d) –2.5 liter ⋅ atm

16. One mole of an ideal gas is expanded from a volume of 1.00 liter to a volume of 10.00
liters against a constant external pressure of 1.00 atm. How much work (in joules) is
performed on the surroundings? (T = 300 K; 1 L atm = 101.3 J)
a) 456 J
b) 912 J
c) 2740 J
d) 2870 J

17.A 25.0 g piece of aluminum (which has a molar heat capacity of 24.03J/°C mol) is
heated to 82.4°C and dropped into a calorimeter containing water (specific heat
capacity of water is 4.18J/g°C) initially at 22.3°C. The final temperature of the water
is 24.9°C. Calculate the mass of water in the calorimeter.
a) 187 g
b) 6.57 g
c) 3180 g
d) 2120 g

18 Consider the following data:


Ca(s) + 2C (graphite) → CaC2(s) ΔH (kJ)= –62.8
Ca(s) + ½ O2(g) → CaO(s) ΔH (kJ)= –635.5
CaO(s) + H2O(l) → Ca(OH)2(aq) ΔH (kJ)= –653.1
C2H2(g) + 5/2 O2(g) → 2CO2 + H2O(l) ΔH (kJ)= –1300
C(graphite) + O2(g) → CO2(g) ΔH (kJ)= –393.51

Use Hess’s law to find the change in enthalpy at 25°C for the following equation:
CaC2(s) + 2H2O(l) → Ca(OH)2(aq) + C2H2(g)
a) –713 kJ
b) 713 kJ
c) –318.8 kJ
d) –3045 kJ

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