(PANINI- eSANKALP2123AP1 TO eSANKALP2123AP6)

IIT – JEE, 2023

PAPER II (PHASE – I)
Time: 3 Hours Maximum Marks: 216

INSTRUCTIONS

A. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of two sections.
1. Section 1 contains 6 Integer Answer Type Questions ranging from 0 – 9.
2. Section 2: contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which One
Or More Than One are correct.
3. Section 3 contains 6 Numerical answer type questions with answer XXXXX.XX and each question carries +4 marks
for correct answer. There is no negative marking
B. Marking Scheme
4. For each questions in Section 1 and 3 : you will be awarded +4 marks for correct answer and no negative marking.
5. For each question Section 2: marks will be awarded in one of the following categories:
Full Marks : + 4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : + 1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : – 2 In all other cases.
For example, if [A], [C] and [D] are all the correct options for a question, darkening all these three will get +4 marks;
darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get -2 marks, as a wrong option is also
darkened.

Enrolment No. :

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Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

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IT-2022- eSANKALP2123AP1 TO eSANKALP2123AP6–PH-I-PCM-P2--2

PART I: PHYSICS
SECTION – 1: (Only Integer Value Correct Type)
This section contains 6 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).

1. Two balls are dropped from the same point after an interval of 1 s. If acceleration due to gravity is
2
10 m/s , what will be the separation between Balls 3 seconds after the release of first ball (in
meter) is (22+n). The value of n is ________________

2. A 40 kg slab rests on a frictionless floor. A 10 kg block rests on top of the slab as shown in the
figure. The coefficient of static friction between the block and slab is 0.60 and coefficient of kinetic
friction is 0.40. The 10 kg block is acted upon by a horizontal force of 100 N. The resulting
2 2
acceleration (m/s ) of slab will be : (Take g = 10 m/s )

3. A string is connected to block of mass  m=1.2kg placed

over rough table surface as shown in figure. Calculate
minimum vertical force F (in Newton) required to move the
block. Pulley string are ideal and coefficient of friction
between block and table surface is
1 2
 . Take g = 10 m/s
2

4. Find the mass (in kg) of the hanging block which will
prevent the smaller block from slipping over the
triangular block. All the surfaces are frictionless and the
strings and the pulleys are light.
Given m = M = 1kg; cot  = 2.

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5. An observer having a gun observes a remotely controlled balloon.

When he first notices the balloon, it was at an altitude of
800m and moving vertically upward at a constant velocity of
5m/s . The horizontal displacement of balloon from the observer
is 1600m. Shells fired from the gun have an initial velocity of
400m/s at a fixed angle θ.(sin θ = 3/5 and  cos θ 4/5). The
observer having gun waits (for some time after observing balloon)
2
and fires so as to destroy the balloon. Assume g=10m/s . Neglect
air resistance. The time (in sec) of flight of the shell before it
strikes the balloon is______
th th
6. The velocity (v) of water wave depend upon P power of their wavelength (), Q power of
th P Q R
density () of water & R power of acceleration due to gravity (g). v  g . Find the value of P +
Q+R
SECTION – 2: (One or More Than One Options Correct Type)
This section contains 5 multiple choice type questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE THAN ONE are correct.

7. A car moves with uniform acceleration along a straight line PQR its speed at P and R are 5 m/sec
and 25 m/s respectively. If PQ : QR = 1 : 2, then
(A) the ratio of the time taken by car to travel distance PQ and QR is 1 : 1
(B) the ratio of the time taken by car to travel distance PQ and QR is 1 : 2
(C) velocity at point Q is 10 m/sec
(D) the velocity at point Q is 15 m/sec

8. A man who can swim at a speed v relative to the water wants to cross a river of width d, flowing
with a speed u The point opposite him across the river is P.
d
(A) The minimum time in which he can cross the river is
v
d
(B) He can reach the point P in time
v
d
(C) He can reach the point P in time
v2  u2
(D) He cannot reach P if u > v
−1
9. Ship A is located 4 km north and 3 km east of ship B. Ship A has a velocity of 20kmh towards
−1
the south and ship B is moving at 40kmh in a direction 37 north of east.  X and Y-axes are
along east and north directions, respectively

(A) Velocity of A relative to B is 32iˆ  44 ˆj km / h 
(B) Position of  A relative to  B as a function of time is given by rAB    3  32 t  ˆi   4  44t  j km
 

(C) Velocity of  A relative to  B is   32iˆ  44ˆj km / h 

(D) Position of  A relative to  B as a function of time is given by 32tiˆ  44ˆj km 

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10. The speed of a train increases at a constant rate  α from zero to  v and then remains constant for
an interval and finally decreases to zero at a constant rate  β. The total distance travelled by the
train is l. The time taken to complete the journey is t. Then,
l     l v 1 1 
(A)   t  (B)   t   
,  v 2    
2l 2l
(C)  t is minimum when   v  (D)  t is minimum when v
   

11. A block of mass 15kg is resting on a rough inclined plane as shown in

figure. The block is tied up by a horizontal string which has a tension of
50N. The coefficient of friction between the surfaces of contact is
2
(g=10m/s )
(A)  1/2 (B)  2/3
(C)  3/4 (D)  1/4
2
12. Car is accelerating with acceleration =20m/s . A box of mass m=10kg
that is placed inside the car, it is put in contact with the vertical wall of
car as shown. The friction coefficient between the box and the wall is
 μ=0.6
2
(A) The acceleration of the box will be 20m/sec
(B) The friction force acting on the box will be 100N
(C) The contact force between the vertical wall and the box will be
100√5N
(D) The net contact force between the vertical wall and the box is only
of electromagnetic in nature

SECTION – 3: (Numerical Value Type)

This section contains 6 questions. The answer of each question is a numerical value in a decimal
notation, truncated/rounding off to the second decimal place e.g.

1. A block of mass  m at  t=0 moving to the left at a speed of

 0.5m/sec relative to ground is placed on a belt that is
moving at constant speed to the right at  1.6m/sec . If the
coefficient of friction is 0.3, how much time (in sec) does  m 1.6 m/s
2
take to stop slipping ? Take g = 10m/s

2. For the arrangement shown in figure, the strings are light &
inextensible, and pulleys are mass less frictionless. Pulley
P1 is fixed and pulleys P2 and P3 are moveable. Find
2 2
acceleration (m/s ) of  4kg block. g= lom/s

3. Two blocks  A and  B of masses  5kg and  3kg respectively rest on a smooth horizontal surface
with  B over  A . The coefficient of friction between A and  B is  0.5. Find the maximum horizontal
force (in Newton) that can be applied to A , so that there will be motion of  A and  B without
relative slipping?

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4. A given object takes 2 times as much time to slide down a  45 rough incline as it takes to slide
down a perfectly smooth  45 incline. Find the coefficient of kinetic friction between the object and
the incline?

2
5. A particle moves along a straight path ABC with a uniform acceleration of 0.5m/s . While it
crosses A its velocity is found to be 5m/s. It reaches C with a velocity 40m/s, 30 seconds after it
has crossed  B in its path. Find the distance (in metre)  AB?

6. A boat which has a speed of 5km/hr in still water crosses a river of width  1km along the shortest
possible path in 15 minutes. The velocity of the river water in kilometres per hour is

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IT-2022- eSANKALP2123AP1 TO eSANKALP2123AP6–PH-I-PCM-P2--6

PART II: CHEMISTRY

SECTION – 1: (Only Integer Value Correct Type)
This section contains 6 questions. Each question, when worked out will result in one integer
from 0 to 9 (both inclusive).

1. If number of nitrogen atoms present in 28 g N2 gas are yNA (where NA is Avogadro’s number),
then the value of ‘y’ is _______

2. The chloride of a metal (M), contains 65.5% of chlorine. 100 ml of the vapour of the chloride of
the metal at STP weight 0.72 gm. If the molecular formula of the metal chloride is MClx, then find
the value x.

3. 36 mL 0.5 M Br2 solution upon being made alkaline undergoes complete disproportionation into
Br  and BrO3 . The resulting solution requires 45 mL As(III) solution to reduce BrO3 to Br  .
Given that As(III) is oxidised to As(V), then ten times of the molarity of As(III) solution will be
______
4. The wave number of electromagnetic radiation emitted during the transition of electron in
2+
between two levels of Li ion whose principal quantum numbers sum is 4 and difference is 2 is
nRH, then the find value ‘n’ (where RH is Rydberg constant)
5. If the voltage with which an electron has to be accelerated so as to have its wavelength equal to
1Å is 50 x/3 volts, then the value of ‘x’ will be _____
rd
6. If the radius of first Bohr orbit of H-atom is x units and de Broglie wavelength of electron in 3
orbit of H-atom is found to be nx, then find the value of ‘n’.

SECTION – 2: (One or More Than One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE THAN ONE are correct.

7. Which of the following configurations do not violate pauli’s exclusion principle?

(A)   (B)    

(C)     (D)    

8. In a titration, 10 ml of H2O2 solution is treated with y milli-moles of KMnO 4 in acidic medium.

The left out KMnO 4 when treated with X in basic medium, oxidises X1 to X 6 and 0.2 M, x
ml of X was consumed. The normality of given H2O2 solution is (in acid medium MnO4
+2
changes to Mn while in basic medium MnO4 changes to MnO24 )

yx yx (5y  x) (5y  x)

(A) (B)   (C) (D)
5  2  10 5

9. The correct order of radii is

+3 +2 +4
(A) N < Be < B (B) F  O2  N3 (C) Na < Li < K (D) Fe < Fe < Fe

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10. Which of the following relation(s) between potential energy (PE), kinetic energy (KE) total
energy(E) of an electron in hydrogen atom is/are correct?

KE 1 E 1 KE 1 E
(A)  (B)  (C)  (D)  1
PE 2 PE 2 E 2 PE  KE

11. The number of electron (s) that can be filled in a d-orbital is/are :
(A) 1 (B) 2 (C) 5 (D) 10

12. Pick out the orbital(s) with equal number of nodal planes.

(A) 3dxy (B) 4s (C) 4dxy (D) 2px

SECTION – 3: (Numerical Value Type)

This section contains 6 questions. The answer of each question is a numerical value in a decimal
notation, truncated/rounding off to the second decimal place e.g.

1. Radiation corresponding to the transition n = 4 to n = 2 in hydrogen atoms falls on a certain metal

(work function=2.5 eV). The maximum kinetic energy (in eV) of the photo-electrons will be.

 
2. The atomic radius for Li and Li+ are 1.20 A and 0.80 A respectively. Assuming that the
difference in radii relates to the space occupied by 2s electron, calculate the percentage of
volume of Li – atom occupied by single valence electron.

3. A 2.0 g of mixture of Na2CO3 and NaHCO3 loses 0.248 g when heated to 300C, the temperature
at which NaHCO3 decomposes to Na2CO3(s), CO2(g) and H2O(g). What is the mass percentage
of Na2CO3 in the mixture?

4. The vapour density of a chloride of an element is 39.5. The equivalent weight of the element is
3.82g. The gram atomic weight of the element is.

5. 100 mL of 0.1 M oxalic acid dihydrate (H2C2O4.2H2O) required 50 mL acidified KMnO4 solution
upto the half equivalence point. Hence, the Molarity of KMnO4 solution will be:

6. 2 gm impure sample of CuSO4 was dissolved in excess KI solution and iodine thus produced
required 100 mL of 0.1 M Na2S2O3 solution upto the starch end-point. Hence mass percentage of
CuSO4 in the original sample is __________ [Atomic mass : Cu = 63.5, S = 32]

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IT-2022- eSANKALP2123AP1 TO eSANKALP2123AP6–PH-I-PCM-P2--8

PART III: MATHEMATICS

SECTION – 1: (Only Integer Value Correct Type)
This section contains 6 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).

x sin  bx  c 
1. If sin2  2x  5  dx 
   k, then a  b  c  d is equal to
a d

2. The simplified value of:

  
cos ec 90o    cot 450o     tan 180    sec 180   
o o

is:
cos ec  90 o
    tan 180 o
  tan  360     sec   
o

2
3.  | 1 x  | dx =
0

4. If , ,  are angles of a triangle, then sin2   sin2   sin2   2cos  cos  cos  is

5. The largest value of 2x3  3x 2  12x  5 for 2  x  4 occurs at x equal to

x 1 1
6. The number of integral solution of 2
 is
x 2 4

SECTION – 2: (One or More Than One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE THAN ONE are correct.

1
7. If  log0.1 x  2 , then
2
1 1 1
(A) maximum value of x is (B) x lies between and
10 100 10
1 1
(C) minimum value of x is (D) minimum value of x is
10 100

| x | 1
8. If  0, x  R, x  2, then x may belongs to
| x | 2

(A) (, 2) (B) [1, 1] (C) (2, ) (D) (1, 2)

9. If logx  8x  3   logx 4  2  0 then 2  x  1 

(A) 4 (B) 1
(C) -1 (D) -2

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10. If  denotes an empty set , then

(A)  is an empty set (B)  is a singleton set

(C)    (D)   

11. Which is/are true in a triangle………

(A) tan A  tanB  tanC  tan A.tanB.tanC (B) cot A  cot B  cot C  cot A.cot B.cot C
(C) sin A  sinBcosC  cosBsinC (D) cosC  sin A sinB  cos A cosB

12. For a positive integer n, let

 
 
fn      tan  1  sec 1  sec 2  1  sec 22  ........ 1  sec 2n  then
 2
 
     
(A) f2    1 (B) f5   1
 16   128 
      1
(C) f3    3 (D) f4   
 24   96  3
SECTION – 3: (Numerical Value Type)
This section contains 6 questions. The answer of each question is a numerical value in a decimal
notation, truncated/rounding off to the second decimal place e.g.

1. The sum of all values of ‘x’ satisfying the equation


log0.03  log2 x 
3
 4  log2 x 
2

3  log2 x  1 = 0, is

n
2. Suppose that sin 3 x sin 3x   cm cos mx is an identity in x, where c0 , c1 , c2 , ...., cn are
m 0

constants and cn  0, find the value of n.

3. Let A = {x, y, z} and B = {1, 2}, then the number of relations from A to B.

2
4. The solution of the equation 4log2 log x  log x   log x   1 is

5. If log 5
x  log51/ 3 x  log51/ 4 x  …. up to 7terms = 70, then the values of x is equal t0

6. Number of Solution of |4x + 3| + |3x – 4| = 12 is

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IT-2022- eSANKALP2123AP1 TO eSANKALP2123AP6–PH-I-PCM-P2--10

(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)

IIT – JEE, 2023

PAPER II (PHASE – I)
ANSWERS
PHYSICS (PART-I)
SECTION-1
1. 3
2. 1
3. 8
4. 2
5. 5
6. 1
SECTION-2
8. A, C, D
10. B, D
11. A, B, C
12. A, B, C, D

SECTION-3
1. 0.70
2. 2.41
3. 40.00
4. 0.50
5. 600.00
6. 3.00

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CHEMISTRY (PART-II)
SECTION-1
1. 2
2. 3
3. 4
4. 8
5. 9
6. 6
SECTION-2
7. A, B, D
8. B
9. B
10. A, B
11. A, B
12. A, C
SECTION-3
1. 0.05
2. 70.37
3. 66.40
4. 7.64
5. 0.04
6. 79.75

MATHEMATICS (PART-III)
SECTION – 1
1. 8
2. 2
3. 1
4. 2
5. 4
6. 5
SECTION – 2
7. A,B,D
8. A,B,C
9. B,C
10. B,C
11. A,C,D
12. A, B, C, D
SECTION – 3
1. 11.00
2. 6.00
4. 10.00
5. 25.00
6. 2.00

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