SAFETY DATA SHEET KAESER

high performance oil for

1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 1 of 10
Modified: Pa/AW V01

1. Identity of substance, preparation, and supplying company

1.1 Product identifier
Product trade name: KAESER high performance oil for nitrogen reciprocating compressors Iso 320 N
9.4659.0, 9.4659.00010, 9.4659.00020

1.2 Relevant identified uses of the substance or mixture and uses advised against:
Not applicable.
Usage of the substance/mixture: Lubricant, cooling oil
Recommended limitations of use: Only for professional users

1.3 Supplier providing the safety data sheet

Supplier: Kaeser Compressors Canada Inc.
3760 La Vérendrye
Boisbriand, QC J7H 1R5
CANADA
Tel.: +1/450-971-1414
Email: msds.ca@kaeser.com
Technical information: Phone: +1/450-971-1414

1.4 Emergency telephone number: +1/514-895-3176

2. Possible Hazards/Effects on Health

2.1 Classification of the substance or mixture
Classification (Regulation) EC No. 1272/2008 (CLP)
Sensitiser via skin contact, category 1: H317: May cause an allergic skin reaction.
Chronic aquatic toxicity, category 3: H412: Harmful to aquatic life with long lasting effects
Classification (67/548/EEC, 1999/45/EC)
Sensitising, environmentally harmful R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.

2.2 Label elements

Classification (Regulation EC No. 1272/2008)
Hazard Pictograms

Signal word: Warning

Hazard statements: H317: May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects
Safety Instructions: Prevention:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective clothing.
Response:
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Disposal:
P501 Dispose of contents/container to an approved waste disposal plant.

Risk-determining component(s) for labelling: long chain alkyl polyamide

90-30-2 N-1-naphthylaniline

2.3 Other hazards

Do not handle until all safety precautions have been read and understood.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 2 of 10
Modified: Pa/AW V01

3. Composition/Information on Ingredients
3.2 Mixtures
Chemical characterization: high performance oil for nitrogen reciprocating compressors Iso 320 N
Hazardous components

Chemical description CAS No. /EC Classification Classification Concentrat

No./Register (67/548/EEC) Regulation EC No. ion [%]
No. 1272/2008
Long chain alkyl - Xi; R43-R36/38 Eye irritation. 2; H319 > 1 < 10
polyamide R52/53 Skin irritation. 2; H315
Sensitises skin 1; H317
Aquatic Chronic 3; H412
Benzenamine, N- 68411-46-1 R52/53 Aquatic Chronic 3; H412 > 1 < 10
phenyl-, reaction 270-128-1
products with 2,4,4-
trimethylpentene
Triphenyl phosphate 115-86-6 N; R50/53 Aquatic Acute 1; H400 > 0,25 < 1
204-112-2 Aquatic Chronic 1; H410
N-1-naphthylaniline 90-30-2 Xn; R22 Acute Tox. 4; H302 > 0,25 < 1
201-983-0 Xi; R43 Skin Sens. 1A; H317
N; R50/53 STOT RE 2; H373
Aquatic Acute 1; H400
Aquatic Chronic 1; H410

For the full text of the R phrases and H-statements mentioned in this section, see section 16.

4. First-aid Measures
4.1 Description of first-aid measures
General instructions
Remove the affected person from the danger area. Obtain medical advice. Provide the physician with this
safety data sheet.

Inhalation:
Remove to fresh air upon inhalation of combustion gases, decomposition products or dust. Seek medical
advice if breathing remains difficult.

Skin contact:
Remove contaminated clothing and shoes. Wash with soap and plenty of water. Seek medical advice if
breathing remains difficult.

Eye contact:
As a precaution, rinse thoroughly with water. Remove contact lenses. Protect unaffected eye. Keep eye
wide open during rinsing. Seek specialist medical advice if eye irritation persists.

Ingestion:
Rinse the mouth with water and drink plenty of water. Do not administer milk or alcoholic beverages. Never
orally infuse a liquid to an unconscious person. Seek medical aid.

4.2 Important symptoms and effects, both acute and delayed

Symptoms: sensitising effects

4.3 Indication of any immediate medical attention and special treatment needed
Treatment: The physician should contact the poisons information centre to obtain specialist advice.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 3 of 10
Modified: Pa/AW V01

5. Fire-fighting Measures
5.1 Extinguishing media
Suitable extinguishing media:
Adjust the fire-fighting measures to the actual environment.

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire fighting:
Burning produces noxious and toxic fumes.

5.3 Advice for firefighters

Special protective equipment for fire-fighting:
Wear self-contained breathing apparatus.
Further information:
Collect contaminated extinguishing water separately – it must not escape into the sewage system.
Combustion residue and contaminated water must be disposed of according to local regulations.

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Ensure adequate ventilation.

6.2 Environmental precautions

Prevent the escape of material into the sewage system or water. Inform the appropriate authority of any
spillage of product into surface water or sewage systems.

6.3 Methods and materials for containment and cleaning up

Cleaning:
Soak up with a binding substance (e.g., sand, silica gel, acid biding agent, universal binding agent, saw
dust). For disposal, fill into suitable and sealable containers.

6.4 Reference to other sections

For protective measures, see section 7 and 8.

7. Handling and Storage

7.1 Precautions for safe handling:

Notes on safe handling:

For smoking protection see section 8. Smoking, eating and drinking should be prohibited in the application
area. Dispose of rinse water in accordance with local and national regulations.

Instructions on fire and explosion prevention

Common measures for preventative fire protection.

7.2 Conditions for safe storage, including any incompatibilities:

Storage room and container requirements
Store containers tightly sealed in a dry and well ventilated room.

Other Information:
No decomposition under correct storage and use.

7.3 Specific applications:

Specific application(s): Industrial raw material

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 4 of 10
Modified: Pa/AW V01

8. Exposure control and personal protection

8.1 Parameters to be monitored

Contents CAS number Value Parameters to be Issue: Base:

monitored
triphenyl 115-86-6 TWA 3 mg/m³ 2005-04-06 GB EH40
phosphate
STEL 6 mg/m³ 2005-04-06 GB EH40

DNEL

Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene

End Use: Workers

Exposure routes: Skin contact
Potential health effects: Chronic Effects, Systemic Effects
Value: 0.62 mg/kg

End Use: Workers

Exposure routes: Inhalation
Potential health effects: Chronic Effects, Systemic Effects
Value: 4.37 mg/m³

End Use: General exposures

Exposure routes: Skin contact
Potential health effects: Chronic Effects, Systemic Effects
Value: 0.31 mg/kg

End Use: General exposures

Exposure routes: Inhalation
Potential health effects: Chronic Effects, Systemic Effects
Value: 1.09 mg/m³

End Use: General exposures

Exposure routes: Ingestion
Potential health effects: Chronic Effects, Systemic Effects
Value: 0.31 mg/m³

PNEC

Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene

Fresh water
Value: 0.051 mg/l

Marine water
Value: 0.0051 mg/l

Fresh water sediment

Value: 9320 mg/kg

Marine sediment
Wert: 932 mg/kg

Soil
Value: 1860 mg/kg

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 5 of 10
Modified: Pa/AW V01

STP
Value: 1 mg/l

8.2 Exposure controls

Personal protective equipment
Respiratory protection:
If vapours are produced, use a breathing apparatus with a recognised filter type.
Hand protection:
Wear protective gloves from polyvinyl alcohol or nitrile butyl rubber. The protective gloves must meet the
specifications of EC Directive 89/686/EEC and the resulting standard EN 374. Prior to removing the gloves,
clean with water and soap.
Eye protection:
Eyewash bottle containing pure water. Tightly sealed protective glasses.
Body protection
Impermeable protective clothing: Select the body protection according to the quantity and concentration of
the hazardous substance in the workplace.
Specific hygiene measures:
Observe normal procedures for handling chemicals. Do not smoke, drink or eat while working with the
substance. Wash hands before breaks and at the end of working day.
Environmental exposure controls
General instructions
Prevent the escape of material into the sewage system or water. Inform the appropriate authority of any
spillage of product into surface water or sewage systems.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state: Liquid
Colour: Yellow
Odour: No data available.
Odour threshold: No data available.
Flash point 290°C
Ignition point: No data available.
Lower explosion threshold: No data available.
Upper explosion threshold: No data available.
Flammability (solid, gaseous) No data available.
Auto-ignition temperature No data available.
pH value No data available.
Pour point - 36°C
Vapour pressure No data available.
Density 0.94 g/cm³
Water solubility: No data available.
Partition coefficient n-octonol/water: No data available.
Solubility in other solvents: No data available.
Kinematic viscosity (40℃) 293 mm²/s [ASTM D 445]
Kinematic viscosity (100℃) 25.4 mm²/s [ASTM D 445]
Relative vapour density No data available.
Evaporation rate: No data available.

9. 2 Further information
Oxidising potential: No data available.

10. Stability and reactivity

10.1 Reactivity:
Stable when stored as specified.
10.2 Chemical stability:
No decomposition under correct storage and use.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 6 of 10
Modified: Pa/AW V01

10.3 Potential of dangerous reactions:

No decomposition when correctly used
10.4 Conditions to avoid:
Exposure to humidity, contamination
10.5 Incompatible materials:
Substances to avoid: Acids, bases, oxidising agents.
10.6 Hazardous decomposition products:
Carbon oxides, metal oxides, nitrogen oxides (NO x).

11. Toxicological information

11.1 Information on toxicological effects
Acute toxicity:
Acute oral toxicity: Estimated value 35.176 mg/kg (calculation method).
Note: Not classified due to lack of data.

Acute oral toxicity

Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: LD50: > 2,000 mg/kg, species: rat,
method: OECD Test Guideline 401
triphenyl phosphate: LD50: > 2,000 mg/kg, species: rat
N-1-naphthylaniline: LD50: 1,625 mg/kg, species: rat

Acute inhalative toxicity

Remarks: Not classified due to lack of data.

Acute inhalative toxicity

triphenyl phosphate: LC50: > 200 mg/l, exposure time: 1 h; species: rat

Acute dermal toxicity:

Remarks: Not classified due to lack of data.

Acute dermal toxicity

Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: LD50: > 2,000 mg/kg, species: rat
triphenyl phosphate LD50 > 7,900 mg/kg, species: rabbit
N-1-naphthylaniline: LD50 dermal: > 5,000 mg/kg, species: rabbit

Skin corrosion/irritation
Skin irritation: Remarks: Not classified due to lack of data.

Skin irritation:
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: Species: rabbit, result: No skin
irritation, method: OECD Test Guideline 404
triphenyl phosphate: Species: rabbit, result: no skin irritation, method: OECD Test Guideline 404, Exposure
time: 4 h
N-1-naphthylaniline: Species: rabbit, result: no skin irritation, method: Draize test
MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN
 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 7 of 10
Modified: Pa/AW V01

Severe eye damage/irritation

Eye irritation: Remarks: Not classified due to lack of data.

Eye irritation
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: Species: rabbit, result: No eye
irritation, method: OECD Test Guideline 405
triphenyl phosphate: Species: Rabbit, result: no eye irritation, method: OECD Test Guideline 405
N-1-naphthylaniline: Species: Rabbit, result: no eye irritation, method: OECD Test Guideline 405

Respiratory or skin sensitisation

Sensitisation: Classification: May cause sensitisation by skin contact.

Sensitisation:
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: Species: guinea pig, classification:
Did not cause sensitization on laboratory animals, method: OECD Test Guideline 406
triphenyl phosphate: Maximisation test (GPMT), Species: guinea pig, classification: Did not cause
sensitisation on laboratory animals. Method: OECD Test Guideline 406
N-1-naphthylaniline: Maximisation test (GPMT), Species: guinea pig, classification: may cause sensitisation
by skin contact. Result: may cause sensitisation by skin contact.
Patch test, Species: human, classification: May cause sensitisation by skin contact. Result: The product is
a skin sensitizer, sub-category 1A.

Germ cell mutagenicity:

triphenyl phosphate: Ames test, result: negative. In-vitro assay, result: negative, unscheduled DNA
synthesis (UDS), result: Negative
N-1-naphthylaniline: Ames test, result: negative. Chinese hamster ovary (CHO), result: negative

Genotoxicity in vivo
N-1-naphthylaniline: In-vivo assay, species: mouse, result: Negative

Mutagenicity – assessment:
Remarks: Not classified due to lack of data.

Carcinogenicity – assessment:
Remarks: Not classified due to lack of data.

Reproductive toxicity – assessment:

Remarks: Not classified due to lack of data.

Target organ systemic – single exposure

Remarks: Not classified due to lack of data.

Target organ systemic toxicant – repeated exposure

Remarks: Not classified due to lack of data.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 8 of 10
Modified: Pa/AW V01

Aspiration hazard
Aspiration toxicity: No classification in respect to aspiration toxicity.

Toxicology assessment
More information: No data available for the product itself.

12. Ecological information

12.1 Toxicity
Toxicity to fish: Remarks: No data available.

Toxicity to fish:
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: LC50: > 71 mg/l, exposure time:
96 h, species: Danio rerio (zebra fish), method: OECD Test Guideline 203
triphenyl phosphate LC50: 0.78 mg/l, exposure time: 96 h, species: Lepomis macrochirus (bluegill sunfish),
static test, LC50: 1.2 mg/l, exposure time: 96 h
N-1-naphthylaniline: species: Oryzias lapites (Orange-red killifish), static test, LC50: 0.44 mg/l, exposure
time: 96 h
Species: Oncorhynchus mykiss (rainbow trout), semi-static test, analytical monitoring: yes

Chronic toxicity to fish

triphenyl phosphate: NOEC: 0.037 mg/l, exposure time: 30 d, species: Oncorhynchus mykiss (rainbow
trout)

Toxicity to daphnia and other aquatic invertebrates (chronic toxicity)

N-1-naphthylaniline: NOEC: 0.02 mg/l, exposure time: 21 d, species: Daphnia magna (freshwater flea),
analytical monitoring: yes

12.2 Persistence and degradability

Bio-degradability: Result: No data available.

Bio-degradability:
Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: Result: According to the results of
tests of biodegradability this product is not readily biodegradable. Method: CO2 Evolution Test
triphenyl phosphate: aerobic, result: Readily biodegradable. 83 - 94%, method: OECD Test Guideline 301
N-1-naphthylaniline: aerobic, result: According to the results of tests of biodegradability this product is not
readily biodegradable. 0%, method: OECD Test Guideline 301

12.3 Bioaccumulative potential

Bioaccumulation: Remarks: No data available.

Bioaccumulation:
triphenyl phosphate: species: Oryzias lapites (Orange-red killifish), exposure time: 18 d, temperature: 25°C,
concentration: 0.01 mg/l, bio concentration factor (BCF): 144
N-1-naphthylaniline: species: Cyprinus carpio (common carp), exposure time: 56 d, temperature: 25°C,
concentration: 0.1 mg/l, bio concentration factor (BCF): 427 – 2.730

12.4 Mobility in soil

Mobility: Remarks: No data available.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 9 of 10
Modified: Pa/AW V01

12.5 Results of PBT and vPvB assessment

This mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT),
or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

Additional ecological information: The product itself has not been tested. An environmental hazard cannot
be excluded in the event of unprofessional handling and disposal. Harmful to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.

Additional ecological information:

Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene: Harmful to aquatic organisms, may
cause long-term adverse effects in the aquatic environment. Do not allow material to contaminate ground
water system. Do not flush into surface water or sanitary sewer system.

13. Disposal considerations

13.1 Waste treatment methods
Product:
The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds,
waterways or ditches with chemical or used container. Offer surplus and non-recyclable solutions to a
licensed disposal company.

Waste disposal code as per EWC (European Waste Catalogue): 130206* synthetic machine,
gear, and lubricating oils.

Contaminated packaging:
Recommendation: Empty remaining contents. Dispose of as unused product. Do not reuse empty
containers.

14. Transport Information

Not classified as dangerous in the meaning of the following transport regulations: ADR/RID, IMO/IMDG and
IATA/ICAO codes.

Special precautions for user: none

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate list of substances of very high concern for authorisation (Article 59):
This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH),
Article 57).

Major Accident Hazard Legislation 96/82/EC, issue 2003:

Petroleum products: a) gasoline and naphtha, b) kerosenes (including aeroplane fuel), c) gas oils (including
diesel fuels, home heating oil and gas oil blending streams)
13, quantity 1: 2,500 t, quantity 2: 25,000 t

Water hazard class (Germany): WGK 1 slightly water hazardous , self-classification

Notification status
US.TSCA: On TSCA Inventory
DSL: All components of this products are on the Canadian DSL.
AICS: On the inventory, or in compliance with the inventory.
NZloC: Not in compliance with the inventory.
ENCS: On the inventory, or in compliance with the inventory.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN

 SAFETY DATA SHEET KAESER
high performance oil for
1907/2006/EC nitrogen reciprocating
compressors Iso 320 N
Normal.dotm Created by: Pa/UT QEM Created on: 18.05.2011 Modified: 11th Mar. 2015 Released by: QESM Page 10 of 10
Modified: Pa/AW V01

KECI: On the inventory, or in compliance with the inventory.

PICCS: On the inventory, or in compliance with the inventory.
IECSC: Not in compliance with the inventory.

15.2 Chemical Safety Assessment

No information available.

16. Further information

Full text of R phrases referred to under sections 2 and 3
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of H-statements referred to under sections 2 and 3

H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Further information:

Safety data sheet directive: Regulation 1907/2006/EC (REACH).

The information in this safety data sheet is based on current knowledge and experience and is intended to
describe the product for the purposes of health, safety and environmental requirements only. It should not,
therefore, be construed as a guarantee of any specific property of the product.

MSDS-reciprocating compressor oil Iso 320 N-CAE-CAN