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HOW TO PASSIVATE STAINLESS STEEL PARTS

October 2003

By Terry A. Debold and James W. Martin

Carpenter Technology Corporation
Reading, Pa., USA

Passivation remains a critical step in maximizing the

essential corrosion resistance of parts and components
machined from stainless steels. It can make the
difference between satisfactory performance and
premature failure. Incorrectly performed, passivation can
actually induce corrosion.

The process of passivation is sometimes misunderstood.

It is a post-fabrication method of maximizing the inherent
corrosion resistance of the stainless alloy from which the
workpiece was produced. It is not a scale removal
treatment, nor anything like a coat of paint.

There is no universal agreement on the precise

mechanics of how passivation works. But it is certain that
a protective oxide film is present on the surface of
passive stainless steel before it is fabricated. This
invisible film is considered to be extremely thin, almost
0.0000001-inch thick – which is about 100,000 times
thinner than a human hair!

A clean, freshly machined, polished or pickled stainless

steel part automatically acquires this oxide film from
exposure to oxygen in the atmosphere. Under ideal
conditions, this protective oxide film completely covers all
surfaces of the part. Passivation is designed to maximize the
inherent corrosion resistance of stainless
steel parts after machining.

In actual practice, however, contaminants such as shop dirt or particles of iron from cutting tools may be
transferred to the surface of the stainless steel parts during machining. If not removed, these foreign
particles can reduce effectiveness of the original protective film. When this happens, corrosive attack may
begin.

During the machining process, a microscopic amount of free iron may be worn off the cutting tool and
transferred to the surface of the stainless steel workpiece. Under certain conditions, a thin coating of rust
may appear on the part. This is actually corrosion of the tool steel and not the parent metal. Sometimes
the crevice at the embedded tool steel particle or its corrosion products may cause attack of the part
itself.

Similarly, small particles of iron-containing shop dirt may adhere to the stainless part surface. Although
the metal may appear shiny in the as-machined condition, the invisible particles of free iron can lead to
rusting on the surface after exposure to the atmosphere.

Exposed sulfides also can be a problem, if not taken into consideration. They come from the addition of
sulfur to stainless steels to improve machinability. Sulfides improve the alloy’s ability to form chips that
break away cleanly from the cutting tool during the machining process. Unless the part is properly
passivated, sulfides can act as initiation sites for corrosion on the surface of the fabricated product.

In both cases, passivation is needed to maximize the natural corrosion resistance of the stainless steel. It
can remove surface contamination, such as particles of iron-containing shop dirt and iron particles from
cutting tools that can form rust or act as initiation sites for corrosion. In addition, passivation also can
remove sulfides exposed on the surface of free-machining stainless alloys, which also may act as

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initiation sites for corrosion.

A two-step procedure can provide the best possible corrosion resistance – (1) cleaning, a fundamental,
but sometimes overlooked procedure and (2) an acid bath, or passivating treatment.

Cleaning First

Cleaning should always come first. Grease, coolant or other shop debris must be thoroughly cleaned from
the surface to obtain the best possible corrosion resistance. Machining chips or other shop dirt can be
wiped carefully off the part. A commercial degreaser or cleanser may be used to clean off machining oils
or coolants. Foreign matter such as thermal oxides may have to be removed by grinding, or by methods
such as acid pickling.

Sometimes a machine operator might skip the basic cleaning, assuming erroneously that by simply
immersing the grease-laden part in an acid bath, both cleaning and passivating will take place
simultaneously. That doesn’t happen. Instead, the contaminating grease reacts with the acid to form gas
bubbles. These bubbles collect on the surface of the workpiece and interfere with passivation.

Even worse, contamination of the passivating solution,

sometimes with high levels of chlorides, can cause "flash
attack" as shown in Fig. 1. Instead of obtaining the
desired oxide film with a shiny, clean, corrosion-resisting
surface, the flash attack causes a heavily etched or
darkened surface - a deterioration of the very surface that
passivation is designed to optimize.

Parts made from martensitic stainless steels (which are

magnetic, with moderate corrosion resistance and
capable of yield strengths up to about 280 ksi [1930 Fig. 1 - The parts on the left have clean,
MPa]) are hardened at a high temperature and then shiny, corrosion-resistant surfaces after
tempered to secure the hardness and mechanical proper passivating. The parts on the right
properties desired. Precipitation hardenable alloys (which exhibit "flash attack" after treatment in a
offer a better combination of strength and corrosion contaminated passivating solution.
resistance than the martensitic grades) may be solution
treated, partially machined, aged at lower temperatures,
followed by finish machining.

In such cases, the parts must be thoroughly cleaned with a degreaser or cleanser to remove any traces of
cutting fluid before heat treating. Otherwise, cutting fluid remaining on the parts will cause excessive
oxidation. This condition can result in undersize parts with a pitted finish after the scale is removed by
acid or abrasive methods. If cutting fluids are allowed to remain on parts that are bright hardened, as in a
vacuum furnace or protective atmosphere, surface carburization may occur, leading to a loss of corrosion
resistance.

Passivating Baths

After thorough cleaning, the stainless steel part or component is ready for immersion in a passivating acid
bath. In current practice, any one of three approaches can be used – nitric acid passivation, nitric acid
with sodium dichromate passivation and citric acid passivation. Which bath and composition to use
depends on the grade of stainless steel and prescribed acceptance criteria.

More resistant chromium-nickel grades can be passivated in a 20% by vol. nitric acid bath (Fig. 2). As
indicated in the same table, less resistant stainless grades can be passivated by adding sodium
dichromate to the nitric acid bath to make the solution more oxidizing and capable of forming a passive
film on the surface. Another option, used in place of nitric acid plus sodium dichromate, is to increase the
concentration of nitric acid to 50% by vol. The sodium dichromate addition and the higher nitric acid
concentration both reduce the chance of undesirable flash attack.

Figure 2 - Procedures for passivating stainless steel parts in nitric acid baths. Methods vary according to
chromium content of the non-free-machining alloys treated, and according to the free-machinability
characteristics of the alloys specifically identified.

Nitric Acid Passivation of Stainless Steels

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Grades Passivation Practice

- Chromium-Nickel Grades (300 Series) 20% by vol. nitric acid at 120/140°F (49/60°C) for
- Grades with 17% Chromium or more (except 440 30 minutes
Series)

- Straight Chromium Grades (12-14% Chromium) 20% by vol. nitric acid + 3 oz. per gallon (22 g/liter)
- High Carbon-High Chromium Grades (440 sodium dichromate at 120/140°F (49/60°C) for 30
Series) minutes
- Precipitation Hardening Stainless OR
50% by vol. nitric acid at 120/140°F (49/60°C) for
30 minutes

Passivation for Free-Machining Stainless Steels Including

AISI Types 420F, 430F, 440F, 203, 182-FM and
Carpenter Project 70+® Types 303 and 416

1. 5% by wt. sodium hydroxide at 160/180°F (71/82°C) for 30 minutes.

2. Water rinse.
3. 20% by vol. nitric acid + 3 oz. per gallon (22 g/liter) sodium dichromate at 120/140°F (49/60°C) for
30 minutes.
4. Water rinse.
5. 5% by wt. Sodium hydroxide at 160/180°F (71/82°C) for 30 minutes.
6. Water rinse.

The procedure for passivating free-machining stainless steels (also shown in Fig. 2) is somewhat
different from that used with the non-free-machining stainless grades. That is because the sulfides of
sulfur-containing free-machining grades are partially or totally removed during passivation in a typical
nitric acid bath, creating microscopic discontinuities in the surface of the machined part.

Even normally efficient water rinses can leave residual acid trapped in these discontinuities after
passivation. This acid can then attack the surface of the part unless it is neutralized or removed.

Free-Machining Stainless Grades

To effectively passivate the free-machining stainless steels, Carpenter has developed the A-A-A (alkaline-
acid-alkaline) process, which neutralizes trapped acid. This method of passivation can be accomplished
in less than two hours. Here is the step-by-step procedure:

After degreasing, soak the parts for 30 minutes in a 5% solution of sodium hydroxide at 160°F to
180°F (71°C to 82°C).

Then rinse the part thoroughly in water.

Next, immerse the part for 30 minutes in a 20% by vol. nitric acid solution containing 3 ounces per
gallon (22 g/liter) of sodium dichromate at 120°F to 140°F (49°C to 60°C).

After removing the part from this bath, flush it with water, then immerse it in the sodium hydroxide
solution for another 30 minutes.

Rinse the part again with water and dry it, completing the A-A-A method of passivation.

The benefits of using the alkaline-acid-alkaline method

are demonstrated in Fig. 3. The left test cone clearly Fig. 3 -
shows the improved surface and resistance of free- Test cone
machining stainless steel when passivated by the A-A-A on left
method. The visible result of conventional passivation can shows a
be seen in the right test cone. bright
finish with
improved
Citric acid passivation has become increasingly popular
resistance
with fabricators who want to avoid the use of mineral
of free-
acids or solutions containing sodium dichromate, along
machining
with the disposal problems and greater safety concerns
stainless
associated with their use. Citric acid is considered
steel when passivated using the A-A-A
environmentally friendly in every respect. It is on the
method. Result of conventional passivation
GRAS (Generally Regarded as Safe) list compiled by the
is visible on the right. Both samples were
FDA as a material that is safe for people to handle.

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exposed to salt spray.

Although citric acid passivation offers attractive environmental advantages, shops having success with
mineral acid passivation, and suffering no safety issues, might want to stay the course. There may be no
real need to change if those fabricators have a clean shop, well-maintained and clean equipment, coolant
free of iron-containing shop dirt, and a process that yields good results.

Passivation treatment in citric acid baths has been found useful for a large number of stainless steel
families, including several individual stainless grades, as summarized in Fig. 4. The conventional nitric
acid passivation methods from Fig. 3 are included for convenience. Note that the older nitric acid
formulations are in volume percent, while newer citric acid concentrations are in weight percent. It is
important to note, in implementing these procedures, that a careful balance of immersion time, bath
temperature and concentration is critical to avoid the "flash attack" described earlier.

Figure 4 - Passivation with Citric or Nitric Acids

Stainless Example % Cr 10% by weight Citric Acid Percent Nitric Acid -

Family Stainless Steels - passivated 30 minutes at
passivated 30 minutes as 120°F/140°F
below

ºF pH(a) Process Volume %(c) Process

(b) (b)

Austenitic Type 304/304L 15.0 - 150 1 20% 1

Type 316/316L 23.5
Custom Flo 302HQ
Type 305
Nitrogen strengthened

Martensitic- Custom 630 (17Cr-4Ni) 11.0 150 1 1

20% + Na2Cr2O7
17.5
PH Custom 450® stainless
Custom 455® stainless
Custom 465® stainless
15Cr-5Ni

Ferritic Type 430 >16 150 1 1

20% + Na2Cr2O7

Ferritic Type 409Cb <12 180-200 2 1

20% + Na2Cr2O7
Use care: low Cr

Martensitic Type 410 <15 120-130 2 1

20% + Na2Cr2O7
Type 420
TrimRite® stainless

Austenitic- Type 303 17-19 150 2 2

20% + Na2Cr2O7
FM

Ferritic-FM Types 430F& 430FR >16 NA NA NA 2

20% + Na2Cr2O7

Ferritic-FM >16 100 2 NA NA

Chrome Core® 18-FM

Ferritic-FM Type 409Cb-FM <13 110 5 2 2

20% + Na2Cr2O7
Use care: low Cr

Martensitic- Type 416 <13 110 5 2 Preferred vs. citric 2

FM 20% + Na2Cr2O7

(a) pH adjusted with sodium hydroxide.

(b) See Figure 5
(c) Na2Cr2O7 means add 3 oz/gal (22 g/l) of sodium dichromate to the 20% nitric acid. An alternative to this mixture is 50% nitric acid
without sodium dichromate.

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The passivation treatment varies depending on chrome content and machinability characteristics of the
grades in each family. Note the columns referring to Process 1 or Process 2. As shown in Fig. 5, Process
1 includes five steps – clean and degrease, rinse, passivate, rinse and dry. Process 2 includes seven
steps – clean and degrease, rinse, passivate, rinse, neutralize, rinse and dry.

Figure 5 - Process Line-Ups Using Passivation Treatments from Figure 4 (above).

Process 1 Process 2

Clean/degrease.
Clean/degrease in 5% by weight sodium hydroxide at

Water rinse. 160/180ºF (71/82ºC) for 30 minutes.

Passivate as in Figure 4.
Water rinse.

Water rinse.
Passivate as in Figure 4.

Dry.
Water rinse.

Neutralize in 5% by weight sodium hydroxide at
160/180ºF (71/82ºC) for 30 minutes.

Water Rinse.

Dry.

Laboratory tests have indicated that citric acid passivation procedures were more prone to "flash attack"
than nitric acid procedures. Factors causing this attack included excessive bath temperature, excessive
immersion time and bath contamination. Citric acid products containing corrosion inhibitors and other
additives (e.g., wetting agents) that reportedly reduce sensitivity to "flash attack" are commercially
available.

Special procedures have been found necessary for the passivation of stainless steel beverage fittings.
ASTM A967 criteria may not be applicable to free-machining stainless steels for such applications. A
shop needing free-machining stainless bar for beverage fittings may seek technical assistance from his
stainless steel supplier.

The ultimate choice of passivation will depend on the acceptance criteria imposed by the manufacturer for
whom the parts or components are to be made. For more information, refer to ASTM A967 "Standard
Specification of Chemical Passivation Treatments for Stainless Steel Parts." The specification can be
accessed at www.astm.org.

Testing Passivated Parts

Tests are often performed to evaluate the surface of passivated parts. The question to be answered is,
"Did passivation remove free iron and optimize the corrosion resistance of the free-machining grades?"

It is important that the test method be matched to the grade under evaluation. A test that is too severe will
fail perfectly good material, while one that is too lenient will allow unsatisfactory parts to pass.

The 400 series precipitation-hardening and free-machining stainless steels are best evaluated in a
cabinet capable of maintaining 100% humidity (samples wet) at 95°F (35°C) for 24 hours. The cross
section is usually the most critical surface, particularly for free-machining grades. One reason for this is
that the sulfides, elongated in the direction of working, intersect this surface.

Critical surfaces should be positioned upward, but at 15 to 20 degrees from the vertical to allow any
moisture to run off. Material that has been properly passivated will be virtually free of rust, although it may
show some light staining.

Austenitic non-free-machining stainless grades also may be evaluated by means of a humidity test.

When so tested, liquid droplets of water should be present on the surface of samples, revealing free iron
by the presence of rust formation.

A faster method is available using a solution from ASTM A380, "Standard Recommended Practice for
Cleaning and Descaling Stainless Steel Parts, Equipment and Systems." This test consists of swabbing
the part with a copper sulfate/sulfuric acid solution, maintaining wetness for six minutes and observing
whether there is any plating of copper. As an alternative, the part may be immersed in the solution for six

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minutes. Copper plating occurs if iron is dissolved. This test should not be applied to surfaces of parts for
use in food processing. Also, it should not be used for the martensitic or lower-chromium ferritic stainless
steels of the 400 series because false-positive results are likely.

Historically, the 5% salt spray test at 95°F (35°C) also has been used to evaluate passivated samples.
This test, too severe for some grades, generally is not necessary to confirm that passivation has been
effective.

Do’s and Don’ts

Here are some do’s and don’ts that may help you passivate successfully:

DO clean first, removing all particles of oxide or heat tint before passivating.

DO avoid chlorides that, in excess, can cause harmful flash attack. When possible, use only a good
grade of water containing less than about 50 parts per million (ppm) of chlorides. Tap water is usually
adequate, and in some cases up to several hundred ppm chlorides can be tolerated.

DO replace baths on a regular schedule to avoid a loss in passivation potential that can result in flash
attack and ruined parts. Baths should be maintained at proper temperature because out-of-control
temperature may allow localized attack.

DO maintain very specific schedules for solution replacement during high production runs to minimize the
possibility of contamination. Use a control sample to test the bath’s effectiveness. If the sample is
attacked, it is time to change the bath.

DO assign certain machines to fabricate stainless steels only; stay with the same preferred coolant to cut
stainless steels, to the exclusion of all other metals.

DO rack parts individually for treatment to avoid metal-to-metal contact. This is especially important with
free-machining stainless steels where free flow of passivating and rinse solutions is needed to diffuse
away corrosion products from sulfides and avoid pockets of acid.

DON’T passivate stainless steel parts that have been carburized or nitrided. Parts so treated may have
their corrosion resistance lowered to the point where they are subject to attack in the passivating tank.

DON’T use tooling with iron content in a shop environment (floor, equipment, coolant, etc.) that is not
exceptionally clean. Steel grit can be avoided by using carbide or ceramic tools.

DON’T forget that attack can occur in a passivating bath if parts are improperly heat treated. High-
carbon, high-chromium martensitic grades must be hardened to become corrosion-resistant. Passivation
is frequently performed after a subsequent temper using a temperature that maintains the corrosion
resistance.

DON’T overlook the nitric acid concentration in the passivating bath. It should be checked periodically
using a simple titration procedure in Figure 6.

DON’T passivate more than one stainless steel at a time. This discipline can prevent costly mixups and
avoid galvanic reactions.

Figure 6. Simple titration test for checking nitric acid concentration of passivating bath. This test should be performed at regular
intervals.
TITRATION PROCEDURE
Concentration of nitric acid (percent) in a passivating bath can be
determined with this method of titration, assuming excessive iron
contamination has not occurred.

SUPPLIES

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1. 0.5N standard sodium hydroxide solution (has limited shelf
life).
2. Phenolphthalein indicator solution.
3. 1.0-ml pipettes, Class A.
4. 25-ml Schellbach burette with Teflon stopcock.
5. Burette support and clamp.
6. Casserole for acid sampling.
7. 250-ml Erlenmeyer flasks.
8. 4-ounce sample bottles.

PROCEDURE

1. Use casserole to transfer acid from tank to sample bottle.

2. Measure 1.0 ml of nitric acid solution into a 250-ml flask
containing 100 to 150 ml of a good grade of water (drinking
water will suffice) and a few drops of the phenolphthalein
indicator.
3. Swirl flask and add sodium hydroxide slowly from a burette
until the solution remains pink at least one-half minute.

CALCULATION

ml titration X 3.24 = volume percent of nitric acid

NOTE: If the passivating solution contains sodium dichromate, the

phenolphthalein indicator should be eliminated and the titration
continuously monitored (pH meter) until a pH of 7.0 is obtained.

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