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Admixture

The document summarizes the measurement of uncertainty for testing the pH and relative density of an admixture. It identifies sources of uncertainty including repeatability, calibration buffers/hydrometer, and thermometer. It calculates the standard uncertainty from each source, combines them, and determines the expanded uncertainty of 1.0887 or ±0.14 at a 95% confidence level for pH testing and 0.0086 or ±0.0086 for relative density testing.

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Mishra dtu
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36 views5 pages

Admixture

The document summarizes the measurement of uncertainty for testing the pH and relative density of an admixture. It identifies sources of uncertainty including repeatability, calibration buffers/hydrometer, and thermometer. It calculates the standard uncertainty from each source, combines them, and determines the expanded uncertainty of 1.0887 or ±0.14 at a 95% confidence level for pH testing and 0.0086 or ±0.0086 for relative density testing.

Uploaded by

Mishra dtu
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Global Test House Pvt. Ltd.

Plot No.87/2&9 , Opp. Metro Pillar No.617, Industrial Area


Rohtak Road Mundka, New Delhi- 110041

Measurement of Uncertainty
(As per NABL 141 Guideline)

Item: Admixture Date of Test: 16-26/10/2022


Test Parameter: pH Temperature: 31 ± 2°C

Source of Uncertainty:
U1 Repeatability Type A Normal Distribution Normal Distribution
U2 pH Buffer 4 Type B Uncertainty from Calibration ………...Do…………….
Certificate at 95% CL
2
U3 pH Buffer 7 Type B ………...Do……………. ………...Do…………….
U4 pH Buffer 9 Type B ………...Do……………. ………...Do…………….
U5 Thermometer Type B ………...Do……………. ………...Do…………….

Standard Deviation
S.No. I (Test Observation/Readings) (I-A) Deviation (I-A)²
√∑ (I-A)²/N-1
1 6.50 -0.098 0.009604
√0.093280/4
2 6.52 -0.078 0.006084
3 6.80 0.202 0.040804
4 6.72 0.122 0.014884
0.1527
5 6.45 -0.148 0.021904
Avg (A) 6.60 0.093280

Std. Uncertainty= Standard Deviation/√n 0.0683

Relative Uncertainty %

Std. Uncertainty at Average test value


Relative Uncertainty %
S.No. Source of Uncertainty Std.Uncertainty/Max. value of machine/equipment X Avg.
Std. Uncertainty/AverageX100
test value
1 Repeatabilty 0.0683 0.0683/6.60X100 1.0351
2 pH Buffer 4 0.005X4/4 0.0050 0.005/4X100 0.1250
3 pH Buffer 7 0.005X7/7 0.0050 0.005/7X100 0.0714
4 pH Buffer 9 0.005X9/9 0.0050 0.005/9X100 0.0556
5 Thermometer 0.1500X25/50 0.0750 0.075/25X100 0.3000

Uncertainty Budget

Probable Relative Unc.


S.No. Sources of Uncertainty Type Value (X) Divisor Std. Unc. Degree of Freedom
Distribution %
U1 Repeatabilty A Normal 0.0683 1 0.0683 1.0351 4
U2 pH Buffer 4 B Normal 0.0050 2 0.0100 0.1250 α
U3 pH Buffer 7 B Normal 0.0050 2 0.0100 0.0714 α
U4 pH Buffer 9 B Normal 0.0050 2 0.0100 0.0556 α
U5 Thermometer B Normal 0.1500 2 0.3000 0.3000 α

Combined Uncertainty = √(UI)² + (U2)² + (U3)² + (U4)² + (U5)²


Combined Uncertainty = √(1.0351)² + (0.1250)² + (0.0714)² + (0.0556)² + (0.3000)²
= 1.0887
Expanded Uncertainty = 2X1.0887 = 2.177
(At 95% Confidence level) ±2.177
K=2

Expanded Uncertainty ±2.177% @ 6.60

± Mµ = 0.14 @ 6.60

Approved by

Global Test House Pvt. Ltd. Document:GTHPLQR-24: Measurement of Uncertainty


Issue No.: 01 Issue Date: 25/08/2021 Rev. No.: 00 Rev. Date: Page No.: 01 of 01
Prepared By: QM Issued By: QM Approved By: TM Controlled Copy
Global Test House Pvt. Ltd.
Plot No.87/2&9 , Opp. Metro Pillar No.617, Industrial Area
Rohtak Road Mundka, New Delhi- 110041

Measurement of Uncertainty
(As per NABL 141 Guideline)

Item: Admixture Date of Test: 16-26/10/2022


Test Parameter: Relative Density Temperature: 31 ± 2°C

Source of Uncertainty:
U1 Repeatability Type A Normal Distribution Normal Distribution
U2 Hydrometer Type B Uncertainty from Calibration ………...Do…………….
Certificate at 95% CL
2

Standard Deviation
S.No. I (Test Observation/Readings) (I-A) Deviation (I-A)²
√∑ (I-A)²/N-1
1 1.10 -0.008 0.000064
√0.001480/4
2 1.13 0.022 0.000484
3 1.08 -0.028 0.000784
4 1.12 0.012 0.000144
0.0192
5 1.11 0.002 0.000004
Avg (A) 1.108 0.001480

Std. Uncertainty= Standard Deviation/√n 0.0086

Relative Uncertainty %

Std. Uncertainty at Average test value


Relative Uncertainty %
S.No. Source of Uncertainty Std.Uncertainty/Max. value of machine/equipment X Avg.
Std. Uncertainty/AverageX100
test value
1 Repeatabilty 0.0086 0.0086/1.108X100 0.7764
B Hydrometer 0.0006X1.166/2 0.00032 0.0032/1.166X100 0.0275

Uncertainty Budget

Probable Relative Unc.


S.No. Sources of Uncertainty Type Value (X) Divisor Std. Unc. Degree of Freedom
Distribution %
U1 Repeatabilty A Normal 0.0086 1 0.0086 0.7764 4
U2 Hydrometer B Normal 0.0006 2 0.0011 0.0275 α

Combined Uncertainty = √(UI)² + (U2)²


Combined Uncertainty = √(0.0086)² + (0.0275)²
= 0.7769
Expanded Uncertainty = 2X0.7769 = 1.554
(At 95% Confidence level) ±1.554
K=2

Expanded Uncertainty ±1.554% @ 1.108

± Mµ = 0.02 @ 1.108

Approved by

Global Test House Pvt. Ltd. Document:GTHPLQR-24: Measurement of Uncertainty


Issue No.: 01 Issue Date: 25/08/2021 Rev. No.: 00 Rev. Date: Page No.: 01 of 01
Prepared By: QM Issued By: QM Approved By: TM Controlled Copy
Global Test House Pvt. Ltd.
Plot No.87/2&9 , Opp. Metro Pillar No.617, Industrial Area
Rohtak Road Mundka, New Delhi- 110041

Measurement of Uncertainty
(As per NABL 141 Guideline)

Item: Admixture Date of Test: 16-26/10/2022


Test Parameter: Dry Material Content, % Temperature: 31 ± 2°C

Source of Uncertainty:
U1 Repeatability Type A Normal Distribution Normal Distribution
U2 Weighing Balance 200 g Type B Uncertainty from Calibration ………...Do…………….
Certificate at 95% CL
2
U3 Oven Type B ………...Do……………. ………...Do…………….

Standard Deviation
S.No. I (Test Observation/Readings), % (I-A) Deviation (I-A)²
√∑ (I-A)²/N-1
1 34.65 -0.682 0.465124
√9.067480/4
2 36.05 0.718 0.515524
3 37.60 2.268 5.143824
4 34.56 -0.772 0.595984
1.5056
5 33.80 -1.532 2.347024
Avg (A) 35.33 9.067480

Std. Uncertainty= Standard Deviation/√n 0.6733

Relative Uncertainty %

Std. Uncertainty at Average test value


Relative Uncertainty %
S.No. Source of Uncertainty Std.Uncertainty/Max. value of machine/equipment X Avg.
Std. Uncertainty/AverageX100
test value
1 Repeatabilty 0.6733 0.6733/35.33X100 1.9057
2 Weighing Balance 200 g 0.0018X170/200 0.001530 0.001530/170X100 0.0009
3 Oven 0.1500X105/250 0.0630 0.0630/105X100 0.0600

Uncertainty Budget

Probable Relative Unc.


S.No. Sources of Uncertainty Type Value (X) Divisor Std. Unc. Degree of Freedom
Distribution %
U1 Repeatabilty A Normal 0.6733 1 0.6733 1.9057 4
U2 Weighing Balance 200 g B Normal 0.0018 2 0.0036 0.0009 α
U3 Oven B Normal 0.1500 2 0.3000 0.0600 α

Combined Uncertainty = √(UI)² + (U2)² + (U3)²


Combined Uncertainty = √(1.9057)² + (0.0009)² + (0.0600)²
= 1.907
Expanded Uncertainty = 2X1.907 = 3.813
(At 95% Confidence level) ±3.813
K=2

Expanded Uncertainty ± 3.813% @ 35.33 %

± Mµ = 1.35 % @ 35.33 %

Approved by

Global Test House Pvt. Ltd. Document:GTHPLQR-24: Measurement of Uncertainty


Issue No.: 01 Issue Date: 25/08/2021 Rev. No.: 00 Rev. Date: Page No.: 01 of 01
Prepared By: QM Issued By: QM Approved By: TM Controlled Copy
Global Test House Pvt. Ltd.
Plot No.87/2&9 , Opp. Metro Pillar No.617, Industrial Area
Rohtak Road Mundka, New Delhi- 110041

Measurement of Uncertainty
(As per NABL 141 Guideline)

Item: Admixture Date of Test: 16-26/10/2022


Test Parameter: Ash Content, % Temperature: 31 ± 2°C

Source of Uncertainty:
U1 Repeatability Type A Normal Distribution Normal Distribution
U2 Weighing Balance 200 g Type B Uncertainty from Calibration ………...Do…………….
Certificate at 95% CL
2
U3 Oven Type B ………...Do……………. ………...Do…………….
U4 Muffle Furnace Type B ………...Do……………. ………...Do…………….

Standard Deviation
S.No. I (Test Observation/Readings), % (I-A) Deviation (I-A)²
√∑ (I-A)²/N-1
1 2.56 0.068 0.004624
√0.019880/4
2 2.50 0.008 0.000064
3 2.41 -0.082 0.006724
4 2.56 0.068 0.004624
0.0705
5 2.43 -0.062 0.003844
Avg (A) 2.49 0.019880

Std. Uncertainty= Standard Deviation/√n 0.0315

Relative Uncertainty %

Std. Uncertainty at Average test value


Relative Uncertainty %
S.No. Source of Uncertainty Std.Uncertainty/Max. value of machine/equipment X Avg.
Std. Uncertainty/AverageX100
test value
1 Repeatabilty 0.0315 0.3729/10.252X100 1.2652
2 Weighing Balance 200 g 0.0018X50/200 0.000450 0.000450/50X100 0.00090
3 Oven 0.1500X105/250 0.0630 0.0630/105X100 0.0600
4 Muffle Furnace 1.6X600/1200 0.8000 0.8000/600X100 0.1333

Uncertainty Budget

Probable Relative Unc.


S.No. Sources of Uncertainty Type Value (X) Divisor Std. Unc. Degree of Freedom
Distribution %
U1 Repeatabilty A Normal 0.0315 1 0.0315 1.2652 4
U2 Weighing Balance 200 g B Normal 0.0018 2 0.0036 0.00090 α
U3 Oven B Normal 0.1500 2 0.3000 0.0600 α
U4 Muffle Furnace B Normal 1.6000 2 3.2000 0.1333 α

Combined Uncertainty = √(UI)² + (U2)² + (U3)² + (U4)²


Combined Uncertainty = √(1.2652)² + (0.00090)² + (0.0600)² + (0.1333)²
= 1.274
Expanded Uncertainty = 2X1.274 = 2.547
(At 95% Confidence level) ± 2.547
K=2

Expanded Uncertainty ± 2.547% @ 2.49%

± Mµ = 0.063 % @ 2.49 %
Approved by

Global Test House Pvt. Ltd. Document:GTHPLQR-24: Measurement of Uncertainty


Issue No.: 01 Issue Date: 25/08/2021 Rev. No.: 00 Rev. Date: Page No.: 01 of 01
Prepared By: QM Issued By: QM Approved By: TM Controlled Copy
Global Test House Pvt. Ltd.
Plot No.87/2&9 , Opp. Metro Pillar No.617, Industrial Area
Rohtak Road Mundka, New Delhi- 110041

Measurement of Uncertainty
(As per NABL 141 Guideline)

Item: Admixture Date of Test: 16-26/10/2022


Test Parameter: Chloride, % Temperature: 31 ± 2°C

Source of Uncertainty:
U1 Repeatability Type A Normal Distribution Normal Distribution
U2 Weighing Balance 200 g Type B Uncertainty from Calibration ………...Do…………….
Certificate at 95% CL
2
U3 Oven Type B ………...Do……………. ………...Do…………….

Standard Deviation
S.No. I (Test Observation/Readings), % (I-A) Deviation (I-A)²
√∑ (I-A)²/N-1
1 0.017 -0.001 0.000001
√0.000014/4
2 0.017 -0.001 0.000001
3 0.016 -0.002 0.000004
4 0.020 0.002 0.000004
0.0019
5 0.020 0.002 0.000004
Avg (A) 0.018 0.000014

Std. Uncertainty= Standard Deviation/√n 0.0008

Relative Uncertainty %

Std. Uncertainty at Average test value


Relative Uncertainty %
S.No. Source of Uncertainty Std.Uncertainty/Max. value of machine/equipment X Avg.
Std. Uncertainty/AverageX100
test value
1 Repeatabilty 0.0008 0.0008/0.018X100 4.6481
2 Weighing Balance 200 g 0.0018X50/200 0.00045 0.00045/50X100 0.00090
3 Oven 0.1500X150/250 0.0900 0.0900/150X100 0.0600

Uncertainty Budget

Probable Relative Unc.


S.No. Sources of Uncertainty Type Value (X) Divisor Std. Unc. Degree of Freedom
Distribution %
U1 Repeatabilty A Normal 0.0008 1 0.0008 4.6481 4
U2 Weighing Balance 200 g B Normal 0.00180 2 0.0036 0.00090 α
U3 Oven B Normal 0.1500 2 0.3000 0.0600 α

Combined Uncertainty = √(UI)² + (U2)² + (U3)²


Combined Uncertainty = √(4.6481)² + (0.00090)² + (0.0600)²
= 4.648
Expanded Uncertainty = 2X4.648 = 9.297
(At 95% Confidence level) ±9.297
K=2

Expanded Uncertainty ± 9.297% @ 0.0018%

± Mµ = 0.002 % @ 0.018 %

Approved by

Global Test House Pvt. Ltd. Document:GTHPLQR-24: Measurement of Uncertainty


Issue No.: 01 Issue Date: 25/08/2021 Rev. No.: 00 Rev. Date: Page No.: 01 of 01
Prepared By: QM Issued By: QM Approved By: TM Controlled Copy

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