Copper Analysis With EDTA
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Levent GüzelCopper Analysis With EDTA
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Levent GüzelLab Session 13, Experiment 12: Copper Analysis by
Complexometric Titration
A quantitative analysis of copper in a soluble copper salt will by performed by complexometric
titration. The complexing agent will be ethylenediaminetetraacetic acid (EDTA) in the form of
–1
its disodium dihydrate salt (Na2C10H18N2O10), with a molar mass of 372.24 g mol . Since
EDTA forms complexes with many metal ions, this particular method can only be used in the
2+ 2+
absence of such ions as Ca , Ni , etc. The reaction of complexation is:
2+ 2– 2– +
Cu (aq) + (EDTA) (aq) → Cu(EDTA) (aq) + 2H (aq)
2+
The stoichiometry is one metal cation to one EDTA anion. However, for Cu (since it has lost 2
–1 2–
electrons), the equivalent mass is 63.546/2 = 31.773 g eq , and since (EDTA) is a dianion its
–1
equivalent mass is 372.24/2 = 186.12 g eq (for the disodium dihydrate salt). The equation
above represents two equivalents reacting with two equivalents. The complex dianion is formed
+
with the release of two moles of H from EDTA, with the indicator being released from the
copper ion.
The complex dianion has the structure shown
in Figure 13.1. Note that the anion
completely surrounds the cation, forming six
coordinate covalent bonds to copper and a
very stable complex. The bonding to the
copper ion is nearly octahedral.
The indicator used for the titration is called
murexide. This indicator is highly colored
and will complex with the copper ion to give
a different colored species. During the
2–
titration, the EDTA forms a more stable
complex and frees the indicator, which then Figure 13.1
displays its original color. The appearance of Structure of Cu2+— EDTA dianion
the free indicator means that all metal ions
2–
have been complexed by EDTA , which
signals the end point. At the end point, the following equation applies:
NEDTAVEDTA = NCu(II)VCu(II) = #eq Cu(II), if V is given in L
= #meq Cu(II), if V is given in mL
The mass of Cu equals (#eq Cu(II)) × (equivalent mass of Cu(II)), and
mass Cu(II)
× 100 = % Cu
mass Cu(II) salt
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12A Experiment
1. Rinse your burette and fill it with standardized Na2EDTA•2H2O solution
(7.445 g Na2EDTA • 2 H2O per liter of water).
2. Weigh accurately three approximately 0.1 g samples of the copper salt.
3. Dissolve each sample in 50 mL of de-ionized water.
4. Add exactly the same amount of indicator to each sample, three drops to start off with. If the
indicator solution is not strong enough, add more but always the same for all samples. (The
indicator's concentration should be 100 mg/100 mL H2O)
5. Titrate each sample with the standardized EDTA. The light yellow solution turns green near
the end point, then suddenly purplish blue at the end point. This end point is fairly hard to
see, so put a white sheet of paper under your beaker and watch carefully. The distinctly
purplish hue, due to free murexide, is the key to observing the end point.
6. For each titration, calculate the number of equivalents or (milliequivalents) of Cu(II) found.
7. For each titrated sample, calculate the mass of copper in that sample.
8. For each titration, calculate the % copper content in the sample, then average them.
Sample 1 Sample 2 Sample 3
(a) Normality of EDTA
(b) grams of Cu(II) sample
(c) mL of EDTA solution Average
(d) eq (or meq) of Cu(II) % copper
(e) mass of copper content
(f) % copper content
12B Exercise
In the experiment on hydrates, we found that copper sulfate was a hydrate which contained
2–
36.1% by mass water. Since the only other component is the sulfate ion, SO4 , we can now
determine the complete formula of copper sulfate.
NOTE Solutions preparation:
Either weigh the EDTA analytically or standardize the solution. Label the bottles with the
normality of EDTA. Use deionized water. About 1 liter will be used by 20 students, 10 groups.
Make these solutions up fresh, including the murexide solution.
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Report Form 12: Copper Analysis Name ________________________________
by Complexometric Titration Partner___________________Section #_____
12A Experiment
Sample 1 Sample 2 Sample 3
(g) Normality of EDTA
(h) grams of Cu(II) sample
(i) mL of EDTA solution Average
(j) eq (or meq) of Cu(II) % copper
(k) mass of copper content
(l) % copper content
12B Exercise
Complete formula of copper sulfate.
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