0 15.10.
2022 FIRST ISSUE JATIN P VEERU
Rev Date Description Checked Approved
DESIGN, SUPPLY, INSTALLATION, TESTING & COMMISSIONING OF 220 KV RUSUMO –
NYAKANAZI LINE UNDER REGIONAL RUSUMO FALLS HYDROPOWER PROJECT -
TRANSMISSION LINE COMPONENT.
CONTRACT NO. RUS-TZ/PA/001/2017-18/HQ/W/22
Tanzania Electric Supply Company Limited (TANESCO)
Umeme Park, Morogoro Road, Ubungo
CLIENT
P.O Box: 9024, Dar Es Salaam, Tanzania
Tel: +255 22 245 1130/9
CONSULTING ENGINEER WSP / INTEC GOPA
1600, Rene-Levesque West Blvd,
16th Floor, Montreal, Canada,
H3H 1P9
CONTRACTOR : STERLING AND WILSON PVT. LTD & ELECTROMONTAJ SA. UJV
Sterling & Wilson Pvt. Ltd,
Associates of SHAPOORJI PALLONJI & CO.PVT.LTD
1, Candiano Popescu Street, Bucharest, Romania
Universal Majestic, 9th Floor, P.L.Lokhande Marg,
Chembur, Mumbai, India
Title :
Fabrication Of Tower Member
Job no. E/18/0337 Date 15-10-2022
Prapared by Shubham Patel Checked Jatin Kumar Parikh
Design Approved Veeranjaneyulu Ravipati
Doc No. RUSTA-4SWE-TL-0390-015-00
STERLING AND WILSON METHOD STATEMENT DOC No. SW-T&D-MS-FABRICATION-01
REV No.: 00
PVT LTD DATE: 14-10-2022
FABRICATION Page 1
CONTENTS
S.NO DESCRIPTION PAGE NO
1) Purpose 2
2) Tools and Machine Required 2
3) Health Safety and Environment 2
4) Sequence of Work for Drilling and Trimming 2
i) Lifting and shifting of Structural Steel 3
ii) Marking and surface preparation. 3
iii) Cutting (Trimming), Drilling 3
iv) Fit Out of assembly/sub-assemblies 4
v) Cleaning and Painting. 4
5) Paint Specification 5
SHUBHAM PATEL JATIN KUMAR PARIKH VEERANJANEYELU RAVIPATI
(ENGINEER QUALITY) (HEAD QUALITY T&D) (PROJECT MANAGER)
PREPARED BY REVIEWED BY APPROVED BY
STERLING AND WILSON METHOD STATEMENT DOC No. SW-T&D-MS-FABRICATION-01
REV No.: 00
PVT LTD DATE: 14-10-2022
FABRICATION Page 2
1. PURPOSE:
To Establish Methodology for Drilling and Trimming of Tower components for construction of
220kV Rusumo- Nyakanazi Transmission Line. This procedure establishes Detailed description
and guidelines for Drilling and Trimming of tower components.
It explains the duties of each worker, machinery used, and methodology based on
international standards.
2. TOOLS & MACHINE REQUIRED:
Below is list of machinery and necessary equipment for doing the Drilling and Trimming of
steel structure and its elements.
• Grinding Machine
• Cutter
• Magnetic Drilling Machine
• Vernier caliper
• Sprit Level
• Measuring Tape
• Shop Sketch Drawings.
3. HEALTH, SAFETY, AND ENVIRONMENT:
• Standard PPE shall be worn by workers all times. PPE required for this activity includes
coverall, safety helmets, safety shoes, gloves, safety glass, etc
• First aid kit shall be made available at all working site.
• Equipment must be in good condition and all safety devices functional and active during
all the time.
• Tools must be in good shape and not damaged or modified
• Housekeeping and clean working area.
• Team members must be trained in different disciplines to perform in this activity.
• Ensure awareness about all works procedures and risk involve in it and all necessary
precautions has been taken before commencement of fabrication works.
• Fire extinguisher shall be provided near the workplace.
4. SEQUENCE OF WORK FOR DRILLING AND TRIMMING.
i) Lifting and shifting of Structural Steel
ii) Marking and surface preparation.
iii) Cutting (Trimming), Drilling
SHUBHAM PATEL JATIN KUMAR PARIKH VEERANJANEYELU RAVIPATI
(ENGINEER QUALITY) (HEAD QUALITY T&D) (PROJECT MANAGER)
PREPARED BY REVIEWED BY APPROVED BY
STERLING AND WILSON METHOD STATEMENT DOC No. SW-T&D-MS-FABRICATION-01
REV No.: 00
PVT LTD DATE: 14-10-2022
FABRICATION Page 3
iv) Fit Out of assembly/sub-assemblies
v) Cleaning and Painting.
I) LIFTING & STORAGE OF STRUCTURAL STEEL
• Structural Steel shall be placed over wooden/concrete blocks to avoid direct contact
with ground.
• The tower members shall not be dragged over the ground surfaces.
• Any foreign material that may tend to adhere permanently to the structures shall be
removed.
• Due care shall be taken to ensure no damages are caused to the galvanization of tower
parts during loading, transporting, and unloading.
II) MARKING AND SURFACE PREPARATION.
• Suitable Platform required for fabrication.
• Before start fabrication entire member is locked properly to avoid distortion.
• The fabrication of Structural steel works shall be carried out as per Shop sketch
Drawing provided by manufacturer.
• Marking shall be carried out as per approved Shop sketch Drawing subsequently
verified by the Engineer In charge prior to cutting & Trimming.
• Prior to marking the material shall be checked for its identification. Necessary items
shall be carefully and accurately marked in accordance with approved shop drawings.
III) CUTTING (TRIMMING) & DRILLING
A) CUTTING
• Structural steel shall be marked and cut to size by saw cutting.
• The edges of all member shall be perfectly straight and uniform throughout
• Cutting Allowances shall be follows
S.No Thickness Of Structural Steel in (MM) Tolerance in (MM)
1 6 2
2 6-25 3
3 25-63 4
4 75-150 6-8
SHUBHAM PATEL JATIN KUMAR PARIKH VEERANJANEYELU RAVIPATI
(ENGINEER QUALITY) (HEAD QUALITY T&D) (PROJECT MANAGER)
PREPARED BY REVIEWED BY APPROVED BY
STERLING AND WILSON METHOD STATEMENT DOC No. SW-T&D-MS-FABRICATION-01
REV No.: 00
PVT LTD DATE: 14-10-2022
FABRICATION Page 4
• Uneven edges shall be dressed by grinding.
• All corners shall be shaped so as to be notch free, sheared or cropped edges shall be
dressed so that they are free from distortion and burrs.
B) DRILLING
• Drilling of holes to be done on structural steel as per approved Shop sketch Drawing.
• Where several parts are to be connected to very close tolerances, such parts shall be first
assembled, tightly clamped together and drilled through.
• All holes shall be minimum 2+ mm larger than the size of the bolt.
IV) FIT OUT OF ASSEMBLY/SUB-ASSEMBLIES
• The fabricated steel structure shall be inspected in accordance with respective shop
sketch fabrication drawings and specification.
• Fitting shall be carried out after ensuring removal of burrs, notches, grinding, of edges
wherever required.
• Fittings shall be checked as per approved drawing.
• Overall length, orientation, diagonal measurement, and all other dimensions shall be
verified.
• 100% visual inspection shall be carried out for external defects
• All blank holes to be filled with required sized nut-bolts & Washers.
V) CLEANING AND PAINTING.
• All structural steel member shall be clean, dry and free of any constituent before painting.
• Surface preparation shall be in accordance with technical data sheet of specified paint.
• Paint shall be applied to dry, clean prepared surfaces under controlled favorable weather
conditions and in accordance with manufacturer data sheet.
• Dry film thickness shall be checked prior to sent to Locations.
• Application of one or two layers of the below mentioned paint (minimum dry coat
thickness: 100 microns) to be applied according to the supplier's instructions.
SHUBHAM PATEL JATIN KUMAR PARIKH VEERANJANEYELU RAVIPATI
(ENGINEER QUALITY) (HEAD QUALITY T&D) (PROJECT MANAGER)
PREPARED BY REVIEWED BY APPROVED BY
STERLING AND WILSON METHOD STATEMENT DOC No. SW-T&D-MS-FABRICATION-01
REV No.: 00
PVT LTD DATE: 14-10-2022
FABRICATION Page 5
5. PAINT SPECIFICATION
PROJECT: 220kV RUSUMO-NYAKANAZI TRANSMISSION LINE.
CONTRACT NO: RUS-TZ/PA/001/2017-18/HQ/W/22
Document Title: ZRC COLD GALVANIZING REPAIR COMPOUND (95% Zinc)
CSD No: RUSTA-1SWE-TL-0390-012-00
Product Name ZRC Cold Galvanizing Repair Compound 95% Zinc
Purpose Repair of Hot Dip galvanized Coatings
Reference CODE ASTM A780
Surface
Preparation As per Attached Technical Data Sheet
Application As per Attached Technical Data Sheet
Safety and Hazard As per Attached Safety Data Sheet
SHUBHAM PATEL JATIN KUMAR PARIKH VEERANJANEYELU RAVIPATI
(ENGINEER QUALITY) (HEAD QUALITY T&D) (PROJECT MANAGER)
PREPARED BY REVIEWED BY APPROVED BY
www.zrcworldwide.com
ZRC Cold Galvanizing Repair Compound
®
The original Cold Galvanizing Compound! Providing superior zinc coating protection for over 50 years!
Enjoy the following great benefits with ZRC Cold Galvanizing Compound:
• 95% zinc in the dry film using only Type III “ultra pure” ASTM-D-520 zinc
• Meets and exceeds Fed. Spec. DOD-P-21035A (Galvanizing Repair Spec);
MIL-P-26915A (USAF Zinc Dust Primer); ASTM Des. A-780 (Standard
Practice for Repair of Damaged Hot-Dip Galvanized Coatings; SSPC-Paint
20 (Specification for Zinc-Rich Primer)
• Passes 3,000 hours salt spray testing without failure (ASTM Des. B117)
• Passes Preece Test (ASTM Des. A239) for hot-dip galvanizing
• Passes 9-year subtropical testing
• Low VOC approved in all 50 states
• ISO 9001 registration assures the highest quality consistently
For specification assistance, application assistance, test reports and product
selection please contact our customer support at (800) 831-3275 or our
website www.zrcworldwide.com.
APPLICATIONS
Field applied galvanizing
Repairing hot-dip galvanizing
Rust proofing welds
Repairing inorganic zinc
THE ZRC DIFFERENCE Re-galvanizing of worn hot-dip
Metal fabrication
The ZRC difference is made possible by ZRC’s high zinc content (95% by weight in the
dried film) of “ultra pure” (ASTM D 520 Type III) zinc dust, ensuring that more metallic zinc Construction
is available for superior galvanic protection against corrosion. This high purity zinc dust is Manufacturing/OEM
compounded with a tenacious non-encapsulating binder using a highly controlled trade Antenna Towers
secret process in our state-of-the-art manufacturing facility.
Petrochemical Plants
Competitor
The result is a self-healing galvanic film that does not require sand- Roads & Bridges
blasting for most applications, providing both up-front labor savings Tanks
and extended longevity of corrosion protection. We offer a Certifi- Industrial Maintenance
cate of Compliance to these exacting material standards and a
Water Treatment
copy of our most recent ISO Registration Certificate.
Marine & Offshore
The Proof is in the Photos Cooling Towers
These scanning electron microscope photos Hundreds more!
illustrate the difference between the true galvanic
protection of ZRC and a competitor’s low
ZRC
percentage zinc coating.
TESTING & SPECIFICATION CONFORMANCE DATA Technical Data
• Meets and exceeds Fed. Spec. DOD-P-21035A, TYPE Single pack, premixed, ready to apply,
formerly MIL-P-21035 (Galvanizing Repair Spec.) liquid organic zinc compound
• Meets and exceeds Fed. Spec. MIL-P-26915A
THEORETICAL COVERAGE 400 ft²/gal @ 1.5 mil dry film thickness
(USAD Zinc Dust Primer)
• Passes 3,000 hours salt spray testing without failure** METALLIC ZINC CONTENT 95% by weight in dry film
(ASTM Des. B117) FLASH POINT 111°F (44°C) (SETA method, ASTM D3278)
• Passes Preece Test (ASTM Des. A239) for hot-dip galvanizing VOC CONTENT 3.3 lbs/gal (385 gms/ltr) (ASTM D3960)
• Resists intermittent dry-heat temperatures up to 750°F WEIGHT PER GALLON 24 lbs. (ASTM D1475)
• Meets and exceeds ASTM Des. A-780 (Standard Practice for
SOLIDS CONTENT 86% (by weight)/52% (by volume)
Repair of Damaged Hot-Dip Galvanized Coatings)
• Meets and exceeds SSPC-Paint 20 (Specification for Zinc-Rich VISCOSITY 1900 cps. Brookfield spindle #5 @ 100 RPM, @ 25°C
Primer), Type II (organic), Level I, Type III zinc dust MAXIMUM SERVICE TEMP - Intermittent 750°F (399)°C
MAXIMUM SERVICE TEMP - Constant 350°F (177)°C
AVAILABILITY/COST ELECTRICAL CONDUCTIVITY 73 million ohms per square @ 3 mils dry (resistivity)
Immediately available off the shelf, ZRC Cold Galvanizing
Compound is offered directly from the manufacturer, or through IMPACT RESISTANCE Greater than 30 inch-lbs. (extrusion) per ASTM-D2794
a worldwide distribution network. The initial cost of ZRC is more ABRASION RESISTANCE 11.5 liters per dry mil (tested @ 3 dry mils) per ASTM-D98-51
than offset by substantial maintenance savings and the POT LIFE At least 24 hrs.
increased service life of protected surfaces. Contact ZRC PACKAGING 3.5 gallon pails, gallon, quart, half-pint and aerosol cans
Worldwide for current pricing and further information.
DRY TIME Set to touch. When ambient air dried, 20-30 min.
@ 1.5 mil (38μ) thickness
MATERIALS/FINISHES
A unique formulation of 95% pure zinc metal as a liquid coating, RECOAT TIME (Second Coat) 12 hrs.
ZRC Cold Galvanizing Compound is manufactured to exacting
standards in our own state-of-the-art manufacturing facility. TOPCOATING After 24-48 hrs., topcoat with acrylic, epoxy, urethane or vinyl
type products. DO NOT USE alkyd, alkyd-modified acrylic, or
SUGGESTED SPECIFICATION lacquer type products. Consult our
Organic Zinc-Rich coating containing 95% metallic zinc, by Guide to Topcoating for detailed instructions.
weight in the dried film; as manufactured by ZRC Worldwide,
Marshfield, MA (www.zrcworldwide.com) or other facility having Surface Preparation
been registered to the International Organization for Standardization Dependant upon surface condition and intended service. Typical examples include:
ISO 9001 standard for quality. GREASE & OILS Solvent clean to SSPC-SP1
For areas and industries with more stringent VOC restrictions specify RUST SCALE Power tool clean to SSPC-SP3 or SSPC-SP11
ZRC 221. MILL SCALE Sandblast to SSPC-SP6 (commercial)
WATER IMMERSION (100°F maximum) Sandblast to SSPC-SP10 (near-white)
** Copy of reports available upon request
Application
BRUSH/ROLLER/AEROSOL Apply as received in container. For Brush Application, use 100%
Natural 100% Chinese bristle brushes. For Roller Application,
use 3/8" nap rollers, made of mohair or lambs wool (sheepskin).
SPRAY (low pressure compressor type)
Atomized air pressure 50 lbs/in² = 3.5 kg/cm²
Fluid pressure 15-20 lbs/in² = 1.1-1.4 kg/cm²
Orifice of tip 0.080 inches (0.20 cm)
Viscosity reduction 4:1 ZRC:Mineral Spirits -OR- 16:1 ZRC:Xylene
SPRAY (airless type)
Pump 30:1
Hose 1/2” (1.3 cm) (I.D.)
Orifice of tip 60°-0.026 inches (0.07 cm)
Type of tip Tungsten carbide, reversing
Filter screens Complete removal is recommended.
However, if screens are employed, use no less than 30 mesh.
Viscosity No reduction required
Recommended procedure Connect hose directly to pump, without filter assembly,
ensuring a hose length of 50 ft. max. Use in-pot agitator or
continuous recycling. Use least pressure possible. Start at
1500 lbs/in² = 105 kg/cm² and increase
as required for good spraying.
CLEAN UP Mineral spirits solvent or Xylene
ZRC Worldwide has been registered to the International Organization for Standardization
ISO 9000 Series Standards for Quality. The fact that ZRC is registered to ISO 9001 as-
145 Enterprise Drive, Marshfield, MA 02050-2132 sures our customers that the zinc-rich coatings manufactured in our facility are designed
Tel: 800.831.3275 or 781.319.0400 • Fax: 781.319.0404 and manufactured according to the most stringent quality control standards, so you can
www.zrcworldwide.com • E-mail: info@zrcworldwide.com rely on their consistency.
© 2019 ZRC Worldwide. All rights reserved.
SAFETY DATA SHEET
1. Identification
Product identifier ZRC Cold Galvanizing Compound
Other means of identification
Product number 10001 - 10004
Recommended use Corrosion protection of iron and steel.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Supplier/Manufacturer ZRC Worldwide
Address 145 Enterprise Drive, Marshfield, MA 02050
Telephone 781-319-0400
Emergency telephone 703-527-3887 CCN15781
(CHEMTREC)
Email info@zrcworldwide.com
2. Hazard(s) identification
Physical hazards Flammable liquids Category 3
Health hazards Skin corrosion/irritation Category 2
Carcinogenicity Category 2
Specific target organ toxicity, repeated Category 1 (central nervous system)
exposure
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment, Category 1
long-term hazard
OSHA defined hazards Not classified.
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. Causes skin irritation. Suspected of causing cancer. Causes
damage to organs (central nervous system) through prolonged or repeated exposure. Very toxic
to aquatic life with long lasting effects.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist/vapors. Wash thoroughly after handling.
Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear
protective gloves/protective clothing/eye protection/face protection. Observe good industrial
hygiene practices.
Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If
exposed or concerned: Get medical advice/attention. In case of fire: Use water fog, foam, dry
chemical powder, dry sand, carbon dioxide to extinguish. Collect spillage.
Storage Store in a well-ventilated place. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 1 / 10
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Zinc 7440-66-6 75 - 85
Solvent naphtha (petroleum), 64742-88-7 4-6
medium aliph.
Distillates (petroleum), 64742-47-8 4-5
hydrotreated light
Zinc oxide 1314-13-2 2-3
Ethylbenzene 100-41-4 0.1 - 1
Nonane 111-84-2 0.1 - 1
Composition comments All concentrations are in percent by weight unless otherwise indicated. Components not listed are
either non-health-hazardous or are below reportable limits.
4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important Narcosis. Behavioral changes. Decrease in motor functions. Direct contact with eyes may cause
symptoms/effects, acute and temporary irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause
delayed chronic effects.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Dry sand. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk. Cool containers exposed to flames with water until well after the fire is out.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Flammable liquid and vapor.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
protective equipment and ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
emergency procedures protective equipment and clothing during clean-up. Do not breathe mist/vapors. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 2 / 10
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material. Clean surface thoroughly to remove residual
contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation.
Take precautionary measures against static discharges. Use non-sparking tools and
explosion-proof equipment. Do not breathe mist/vapors. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Should be handled in
closed systems, if possible. Wear appropriate personal protective equipment. Wash hands
thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene
practices.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in an
area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the
SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form
Ethylbenzene (CAS PEL 435 mg/m3
100-41-4)
100 ppm
Solvent naphtha PEL 400 mg/m3
(petroleum), medium aliph.
(CAS 64742-88-7)
100 ppm
Zinc oxide (CAS 1314-13-2) PEL 5 mg/m3 Respirable fraction.
5 mg/m3 Fume.
15 mg/m3 Total dust.
US. ACGIH Threshold Limit Values
Components Type Value Form
Ethylbenzene (CAS TWA 20 ppm
100-41-4)
Nonane (CAS 111-84-2) TWA 200 ppm
Solvent naphtha TWA 200 mg/m3 Non-aerosol.
(petroleum), medium aliph.
(CAS 64742-88-7)
Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Respirable fraction.
TWA 2 mg/m3 Respirable fraction.
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 3 / 10
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form
Ethylbenzene (CAS STEL 545 mg/m3
100-41-4)
125 ppm
TWA 435 mg/m3
100 ppm
Nonane (CAS 111-84-2) TWA 1050 mg/m3
200 ppm
Zinc oxide (CAS 1314-13-2) Ceiling 15 mg/m3 Dust.
STEL 10 mg/m3 Fume.
TWA 5 mg/m3 Dust.
5 mg/m3 Fume.
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Ethylbenzene (CAS 0.15 g/g Sum of Creatinine in *
100-41-4) mandelic acid urine
and
phenylglyoxylic
acid
* - For sampling details, please see the source document.
Exposure guidelines
US ACGIH Threshold Limit Values: Skin designation
Solvent naphtha (petroleum), medium aliph. Can be absorbed through the skin.
(CAS 64742-88-7)
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
controls Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. Provide easy access to water supply or an emergency shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Nitrile or neoprene gloves are recommended. Other suitable gloves
can be recommended by the glove supplier.
Skin protection
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Check with respiratory protective
equipment suppliers.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Observe any medical surveillance requirements. When using do not smoke. Always observe good
considerations personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.
9. Physical and chemical properties
Appearance
Physical state Liquid.
Form Liquid.
Color Gray.
Odor Hydrocarbon.
Odor threshold Not available.
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 4 / 10
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point 111.2 °F (44.0 °C) Setaflash
Evaporation rate < 1 (n-Butyl acetate=1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower 0.9 %
(%)
Flammability limit - upper 7%
(%)
Vapor pressure 0.8 kPa (25°C / 77°F)
Vapor density > 1 (Air=1) (25°C / 77°F)
Relative density 2.88 (H2O=1)
Solubility(ies)
Solubility (water) Slightly soluble in water.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 1800 mPa·s (25°C / 77°F)
Other information
Bulk density 24 lb/gal
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
VOC 385 g/l
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Protect against direct sunlight. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Decomposition is not expected under normal conditions of use and storage. Fire or high
products temperatures create: Carbon oxides. Fumes of metal oxides.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion May cause discomfort if swallowed.
Symptoms related to the Narcosis. Behavioral changes. Decrease in motor functions. Direct contact with eyes may cause
physical, chemical and temporary irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause
toxicological characteristics chronic effects.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 5 / 10
Components Species Test Results
Ethylbenzene (CAS 100-41-4)
Acute
Dermal
LD50 Rabbit 15400 mg/kg
Inhalation
LC50 Rat 17.4 mg/l, 4 hours
Oral
LD50 Rat 3500 - 4700 mg/kg
Solvent naphtha (petroleum), medium aliph. (CAS 64742-88-7)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Oral
LD50 Rat > 5000 mg/kg
Zinc (CAS 7440-66-6)
Acute
Oral
LD50 Mouse > 5 g/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization Not classified. However: The product contains a small amount of sensitizing substance which may
provoke an allergic reaction among sensitive individuals.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Suspected of causing cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.
Solvent naphtha (petroleum), medium aliph. 3 Not classifiable as to carcinogenicity to humans.
(CAS 64742-88-7)
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Causes damage to organs (central nervous system) through prolonged or repeated exposure.
repeated exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful. Causes damage to organs through prolonged or repeated
exposure. Prolonged exposure may cause chronic effects.
Further information Symptoms may be delayed.
12. Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.
ZRC Cold Galvanizing Compound SDS US
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Components Species Test Results
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Aquatic
Fish LC50 Rainbow trout,donaldson trout 2.9 mg/l, 96 hours
(Oncorhynchus mykiss)
Ethylbenzene (CAS 100-41-4)
Aquatic
Acute
Crustacea EC50 Water flea (Daphnia magna) 1.81 - 2.38 mg/l, 48 hours
Fish LC50 Rainbow trout,donaldson trout 4.2 mg/l, 96 hours
(Oncorhynchus mykiss)
Chronic
Crustacea EC50 Ceriodaphnia dubia 3.6 mg/l, 7 days
Zinc (CAS 7440-66-6)
Aquatic
Acute
Crustacea EC50 Daphnia magna 0.07 mg/l
Fish LC50 Oncorhynchus mykiss 0.14 mg/l
Zinc oxide (CAS 1314-13-2)
Aquatic
Crustacea LC50 Water flea (Daphnia magna) 0.098 mg/l, 48 Hours
Persistence and degradability The product contains inorganic compounds which are not biodegradable.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Ethylbenzene (CAS 100-41-4) 3.15
Mobility in soil The product is slightly soluble in water. Expected to be slightly to moderately mobile in soil.
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential. This product contains one or more substances identified as hazardous air pollutants
(HAPs) per the US Federal Clean Air Act (see section 15).
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. Do not allow this material to drain into sewers/water supplies. Do not contaminate
ponds, waterways or ditches with chemical or used container. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
UN number UN1263
UN proper shipping name Paint
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group III
Environmental hazards
Marine pollutant Yes
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 7 / 10
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IATA
UN number UN1263
UN proper shipping name Paint
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group III
Environmental hazards Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1263
UN proper shipping name Paint
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
EmS F-E, S-E
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Nonane (CAS 111-84-2) 1.0 % One-Time Export Notification only.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ethylbenzene (CAS 100-41-4) Listed.
Nonane (CAS 111-84-2) Listed.
Zinc (CAS 7440-66-6) Listed.
Zinc oxide (CAS 1314-13-2) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated
“active”.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Flammable (gases, aerosols, liquids, or solids)
categories Skin corrosion or irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Ethylbenzene 100-41-4 0.1 - 1
Zinc 7440-66-6 75 - 85
Zinc oxide 1314-13-2 2-3
ZRC Cold Galvanizing Compound SDS US
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Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Ethylbenzene (CAS 100-41-4)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Ethylbenzene (CAS 100-41-4)
Nonane (CAS 111-84-2)
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
US. New Jersey Worker and Community Right-to-Know Act
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Ethylbenzene (CAS 100-41-4)
Nonane (CAS 111-84-2)
Solvent naphtha (petroleum), medium aliph. (CAS 64742-88-7)
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
US. Pennsylvania Worker and Community Right-to-Know Law
Ethylbenzene (CAS 100-41-4)
Nonane (CAS 111-84-2)
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
US. Rhode Island RTK
Ethylbenzene (CAS 100-41-4)
Nonane (CAS 111-84-2)
Zinc (CAS 7440-66-6)
Zinc oxide (CAS 1314-13-2)
California Proposition 65
WARNING: This product can expose you to Ethylbenzene, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.
California Proposition 65 - CRT: Listed date/Carcinogenic substance
Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Ethylbenzene (CAS 100-41-4)
Zinc (CAS 7440-66-6)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 9 / 10
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 14-December-2013
Revision date 28-February-2020
Version # 07
NFPA ratings
2
2 0
Disclaimer This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
workers and the environment.
ZRC Cold Galvanizing Compound SDS US
917537 Version #: 07 Revision date: 28-February-2020 Issue date: 14-December-2013 10 / 10