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Name and Surname: Shan Botan Tahsin Tahsin Student ID No: 210320125 Analytical Chemistry 1 - Laboratory Report

(1) The student performed a titration experiment to determine the concentrations of Ca2+ and Mg2+ ions in tap water using EDTA solution. (2) The average ppm of Ca2+ was found to be 360.7 ppm and the average ppm of Mg2+ was found to be 451.98 ppm. (3) In a second experiment, the molarity of Mg2+ in hard water was calculated to be 0.0021979M, equivalent to a concentration of 52.75 ppm Mg2+.

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28 views4 pages

Name and Surname: Shan Botan Tahsin Tahsin Student ID No: 210320125 Analytical Chemistry 1 - Laboratory Report

(1) The student performed a titration experiment to determine the concentrations of Ca2+ and Mg2+ ions in tap water using EDTA solution. (2) The average ppm of Ca2+ was found to be 360.7 ppm and the average ppm of Mg2+ was found to be 451.98 ppm. (3) In a second experiment, the molarity of Mg2+ in hard water was calculated to be 0.0021979M, equivalent to a concentration of 52.75 ppm Mg2+.

Uploaded by

shan.botan2003
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© © All Rights Reserved
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Name and Surname: Shan botan tahsin Tahsin

Student ID No: 210320125


ANALYTICAL CHEMISTRY 1 – LABORATORY REPORT

Experiment Name: TITRIMETRIC DETERMINATION of Ca2+ and Mg2 + IONS in TAP


WATER

Aim:

Is to determine the presence of Mg2+ and Ca2+ ions in tap water, by using EDTA solution
as the titrant

Results:

Question 1:

The amount of EDTA spent The amount of EDTA spent


(ml) Ca2+ (ml) Ca2+ and Mg2+

1. Titration 2.6 6.3

2. Titration 1.9 7.5

Average 2.25 6.9

The amount of Ca+2 in ppm:

25 mL water

0.1M EDTA

Mwt= Ca (40.08 g/mol)

nCa = MEDTA . VEDTA


nCa first titration= (0.1)(2.6 × 10−3)= 2.6 × 10−4mol
nCa second titration = (0.1)(1.9× 10−3)= 1.9 × 10−4mol
mCa = nCa . MwCa
mCa first titration= (2.6 × 10−4) (40.08) = 0.01042𝑔 → 10.42𝑚𝑔
mCa second titration = (1.9 × 10−4) (40.08) = 7.6152 × 10−3𝑔 → 7.6152𝑚𝑔
Name and Surname: Shan botan tahsin Tahsin
Student ID No: 210320125
ANALYTICAL CHEMISTRY 1 – LABORATORY REPORT

10.42𝑚𝑔 𝑚𝑔
1 Titration→ 𝑝𝑝𝑚 𝐶𝑎2+ = = 416.8 25×10−3𝐿 𝐿

7.6152𝑚𝑔 𝑚𝑔
2 Titration→ 𝑝𝑝𝑚 𝐶𝑎2+ = = 304.608 25×10−3𝐿 𝐿

The amount of Mg+2 in ppm:

25 mL water
0.1M EDTA
Mwt= Mg (24.3 g/mol)

VMg =VEDTA total - VEDTA Ca


VMg of first titration: 6.3 - 2.6 = 3.7 mL VMg of second titration: 7.5 - 1.9 = 5.6 mL

nMg = MEDTA .VEDTA

nMg first titration= (0.1)( 3.7× 10−3)= 3.7 × 10−4mol


nMg second titration= (0.1)(5.6× 10−3)= 5.6 × 10−4mol
mMg = nMg . MwMg

mMg first titration= (3.7 × 10−4)(24.3) = 8.991 × 10−3𝑔 → 8.991𝑚𝑔

mMg second titration= (5.6 × 10−4)(24.3) = 0.013608𝑔 → 13.608𝑚𝑔

1 titration ppm Ca2+ = 8.991 mg = 359.64 mg/L

25 X 10-3L

2 titration ppm Ca2+ = 13.608 mg = 544.32 mg/L

25 X 10-3 L
Name and Surname: Shan botan tahsin Tahsin
Student ID No: 210320125
ANALYTICAL CHEMISTRY 1 – LABORATORY REPORT
ppm Mg2+ ppm Ca2+

1. Titration 359.64 416.8

2. Titration 544.32 304.6

Average 451.98 360.7

Question 2:

The volume of EDTA required for Ca2+ and Mg2+ = 23.65 mL The volume of EDTA
required only for Ca2+ = 14.53 mL
The volume of EDTA required for Mg2+ = 23.65 - 14.53= 9.12mL

Formula: M1V1 = M2V2

n1 n2

M1 X 50mL = 0.01205M X 9.12mL

1 mol 1 mol

M1 = 0.0021979 M

∴ 𝑀𝑜𝑙𝑎𝑟𝑖𝑡𝑦 𝑜𝑓 Mg+2 𝑖𝑛 h𝑎𝑟𝑑 𝑤𝑎𝑡𝑒𝑟 = 0.0021979𝑀


⇒ 0.0021979 𝑚𝑜𝑙𝑒𝑠 Mg+2 𝑖𝑠 𝑖𝑛 1000 𝑚𝐿 h𝑎𝑟𝑑 𝑤𝑎𝑡𝑒𝑟
⇒ 0.0021979 × 24 = 0.05275𝑔 Mg+2 𝑖𝑠 𝑖𝑛 1 𝑚𝐿 h𝑎𝑟𝑑 𝑤𝑎𝑡𝑒𝑟 ⇒ 52.75 𝑚𝑔 Mg+2
⇒ 52.75 𝑚𝑔/𝐿 Mg+2 → 52.75 𝑝𝑝𝑚 Mg+2
Name and Surname: Shan botan tahsin Tahsin
Student ID No: 210320125
ANALYTICAL CHEMISTRY 1 – LABORATORY REPORT

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