Sri Chaitanya IIT Academy, India 10-09-2023_Jr.

Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 10-09-2023
Time: 09:00AM to 12:00PM CTM-01 Max. Marks: 300

KEY SHEET

PHYSICS
1) 4 2) 4 3) 2 4) 1 5) 2
6) 4 7) 2 8) 1 9) 2 10) 1
11) 4 12) 4 13) 1 14) 4 15) 3
16) 2 17) 4 18) 3 19) 2 20) 3
21) 6 22) 5 23) 3 24) 3 25) 1
26) 2 27) 6 28) 4 29) 5 30) 3

CHEMISTRY
31) 3 32) 2 33) 2 34) 1 35) 1
36) 1 37) 1 38) 2 39) 2 40) 1
41) 1 42) 4 43) 2 44) 3 45) 2
46) 1 47) 4 48) 3 49) 4 50) 2
51) 8 52) 3 53) 1 54) 6 55) 1
56) 7 57) 7200 58) 239 59) 317 60) 257

MATHEMATICS
61) 1 62) 4 63) 2 64) 3 65) 3
66) 2 67) 4 68) 4 69) 2 70) 1
71) 1 72) 1 73) 4 74) 2 75) 2
76) 4 77) 2 78) 2 79) 3 80) 3
81) 0 82) 20 83) 2 84) 4 85) 2
86) 1 87) 4 88) 2 89) 37 90) 1

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
SOLUTIONS
PHYSICS
1.

h  y  10 cm … (i)
PA  PB
or 1.3g x 10  13.6 x g x y + 0.8 x g x h
or 13  13.6 y + 0.8 h … (ii)
After solving above equations, we get
h  9.6 cm
2.

 R 2 h1  R 2 h2
 h1  h2

F1  gh1 x  R 2 h
  1 1
F2  gh2 x R 2
h2
3. Conceptual
4. Conceptual
5.

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s

 mconcrete  msawdust  g  V  w g
4 4 4
2.4 x   R 3  r 3   0.3 x  r 3   R 3x 1
3 3 3
3
R3  r 3
2
4
mconcrete
 concrete   R 3  r 3 
  3
msawdust 4
sawdust  r 3
3
3 3 3
r r 
2.4  2  4
3
0.3 r
6. Conceptual
7.

Fb  Vd  g  a 

Fb  T  mg   ma

or T  Vd  g  a   Vρ  g  a 

 V  d    g  a 

8. P  2mK , and P '  2m  K  3K   2 P

P ' P 2P  P
x 100  x 100  100%
P P
At x  0, vi  5  0 
32
9. 0

and x  2 m, v f  5  2 
32
 5 8 m/s

W  K
1 1
 m  v 2f  vi2   x 0.5  5 8    0 2   50 J
2

2 2  

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
10. P  (  gh)mercury  (  gh) water
 m hm 13.6  76cm
hw    1033cm  10.3m
w 1
1 2 gh(m2  m1 )
11. m2 gh  m1 gh   m1  m2  v2 v 
2 m1  m2

12. v 2  u 2  2 gh

 
2
 5 gl  2 gh
v  5 gl  2 gh
Lowest point h  0, v  5 gl
Highest point h  2l , v  gl
Horizontal h  l , v  3gl
l
At 60, h  , v  4 gl
2
13. Conceptual
14. T cos  mg …(i)
T sin   mr 2  m  l sin    2 …(ii)
Solving these two equations we get,
g g
cos  2 
l l  2 n 
2

10
 2
(l  1 m)
 2
 2 x  
  cos 1  5 8 

a 10 3
15. tan     3
g 10
  60,  30
A is false
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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
16. Conceptual
17.  mg  mR 2

 2 
g

1 3 g  4g
R 5a 4 15a
18. a A  g sin 

v 2 2 gh 2 gh 1  cos 
aB   
R R R
Given, a A  aB
 sin   2  2cos
Squaring these two equations we have,
sin 2   4  4cos 2   8cos 
or 1  cos 2   4  4cos 2   8cos
On solving this equation, we get
3
cos  or  cos 1  3 5 
5
v2 4
19. 
r r2
2
v 
r
2m
P  mv 
r
20. Conceptual
2
21. h
2g
r 1
2
 r22 

40  40 2 2
h
20
10  5   104

h  80  75 104  6000 104

 0.60 m
 60 cm  10 n
n  6
a 1
22. tan   
g 2
 a  5m / s 2
P1  P2   al  1000  5  10  102  500 Pa 100n  500 n5
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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
23. Apparent mass when submerged in water
m1  m  ρV
46  50  1 V
∴Volume of ornament V  50  46  4cm3
Let x grams of copper is added.
 mass of gold  50  x
Now
Volume of ornament  Volume of gold  Volume of copper
50  x x
4 
20 10
x  30 gram
10n  30
n  3
24. For increase in gravitational potential energy of a rod we see the centre of the rod

W  change in potential energy

1
 mg 1  cos 
2
Substituting the value, we have
2
W   0.6 10    1  cos 60 
2
3 J
25. Decrease in potential energy of sphere = Increase in kinetic energy of both
1 1
 mgR  mv 2  m  v cot  
2

2 2
1
 mv 2cosec 2
2
 v  2 gR sin   speed of sphere and speed of wedge  v cot 
1
 2 gR cos   2 x 10 x 0.20 x  1 m/s
2
26. Increase in potential energy per unit time = decrease in kinetic energy of both
d 1 1   dv   dv 
   m1v12  m2v22   v1   m1 1   v2   m2 2   v1  m1a1   v2  m2a2 
dt  2 2   dt   dt 
dU
or  v1   F1   v1   F2  … (i)
dt
Here,  F1   F2  kx  200 x 0.1  20N
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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
Substituting in Eq. (i) we have,
dU
  4  20    6  20 
dt
 200 J/s
100  n  200
n  2
mu 2
27. Lowest point T1  mg 
l
mv 2
Highest point T2  mg 
l
1 1
Energy conservation mu 2  0  mv 2  mg  2l 
2 2
From (i) (ii) (iii)
T1  T2  6mg For all values of u  5 gl
28.

N  mR 2
 N  mg
From these two equations we get,
g 10
   2.5 rad/s
R 0.4 x 4
10
 2.5
n
n  4
2h 2 x 20
29. t   2sec
g 10
Horizontal distance x  vt
x 10
 v    5 m/s
t 2
2
V 25
a   10 m/s 2
R 2.5
2n  10
n  5
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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s

 
2
v2  v02  2 gh  0.5 gr  2 gr 1  cos 
30.
  2.25 gr  2 gr cos 
At the time of leaving contact, N  0
mv 2
 mg cos   2.25mg  2mg cos
r
2.25 3 n
cos   
3 4 n 1
n  3

CHEMISTRY
31. Heat released by reaction  C T
 500x2  1000J
1000
E  x16  160 kJ/mol
0.1
32. Conceptual
33. Enthalpy of formation of A is given by the equation B  A; H  100 kcal
34. In adiabatic expansion, work is done at the cost of internal energy, hence the temperature
of the system is lowered
Hcombustion
35. Calorific value =
Mw of the substance
36.  Hcombustion of Benzene   f H products   f H reactants

37. H   25.4   2x  13.7   2 kcal/mol

38. Hess’s Law
 nRT2 nRT1 
39. For adiabatic irreversible compression ΔU=W, nC v,m  T2 -T1    P2  
 2P P1 
40. Hess’s Law
41. Bacl2 ( s )  aq  Bacl2 (aq )
 H  20.6 kJ
Bacl2 .2 H 2O ( s )  aq  Bacl2 ( aq )
 H  8.8 kJ
42.  ( S .F )   ( S .F ) Products  ( S .F ) Reactants
43. H reaction   B.E of reactants   B.E of products

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
44. PH 3 ( g )  P ( g )  3H ( g ) H  954 kJ
3xB.EP- H  954
P2 H 4 ( g )  2 P ( g )  4 H ( g ) H  1488 kJ
B.EP-P  4 B.EP-H  1488
B.EP- P  216 kJ/mol
45. Second law of thermodynamics states that total heat can never be converted in to
equivalent amount of work
46. Cyclic process
47. Extensive properties are independent of mass
48. U  q  w
49. Conceptual
50. n  2, t  300 K ,V2  40 L,V1  4 L

V 
W  2.303nRT log  2 
 V1 
51. U  q  w
52. G  H  T S , and H  E  nRT
53. Conceptual
54. G  H  T S
PV PV
55. 1 1
 2 2
T1 T2

56. PV   K
57. Total heat absorbed  H fusion temp rise  H  H Vap  Ans  7200 cal
nRT
58. V2  and w  PV  Ans  239 L bar 
P
59. S reaction   S products   S reactants  Ans  317 
60. G reaction   G ( f ) products   G( f ) reactants  Ans  257 

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
MATHEMATICS
1
61. y  2  AM  GM 
y
 1
  y    2 or sin x  cos x  2 and sin x  cos x  2
 y
1
Hence, y   2 and sin x  cos x  2
y

Which is possible for y  1, x 
4
2 x
62. 4cos     4sin x  sin x  cos x 
2 2 2

 4 2

  
2 1  cos   x    4sin 2 x
 2 
2  2sin x  2sin x
63.   180   ,   360   ,   540  
  1 
Then 4sin  3sin  2sin  sin
2 2 2 2
   
 4sin  3cos  2sin  cos  2 1  sin   2 1  K
2 2 2 2
64. f 2  x   f3  x 

1 1
  tan 9 x  tan x    tan 27 x  tan x 
2 2

    1 1
f 2    f3     1  1   1  1  1
4 4 2 2
65. f ( x )  7  cos  x  {6 x}
66. We have,
f ( x)  x 2  x  1
f '( x)  2 x  1
1
Which is one-one, when x   .
2
In [0,3], f ( x) is one-one and its range is which is [ f (0), f (3)]  [1,13] codomain.
1  4 x  3
Hence, its invertible and its inverse is ∴Statement I is correct and Statement
2
II is also correct but not correct explanation of Statement I.
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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
e 1
2x
67. If x  0, y 
2e2 x
1
e2 x  1
1 2y
1 y
1 0  0
1 2y 2y 1

0  y  12

 x    x  
68. f ( x)  4cos 4    2cos  2 
 4  2 
2

 x  
 1  cos 2  2 
 2 

Period of f ( x )   2 3
1
2 2

 2 tan x  1  cos 2 x   sec x  2 tan x 

2

69. f 
 1  tan x 
2
2
2 tan x
1
1  tan 2 x
f ( x)  1  x

 3   1  13  4 3
f 1

70. f   x    f ( x)

 f   x  is odd function

71. Range of sin x  cos x is 1, 2 

  sin x  cos x   1

72. f (0)  1  0, f ( 1)  b  c  0 so,   (1,0)

f (0)  1  0, f ( 1)  b  c  0 so,   (1,0)

2 tan 1 (cos ec )  tan 1 (2sin  sec 2  )

 1
 2 tan 1 
 sin 
 1  2sin  
  tan 

2
 1  1
  2  tan 
 1  sin     sin 


1 


  tan  sin     2 
  
2

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
73. {x}  0
f ( x)   3  x 7 
1
7

f  f  x   x
f  f  x    x  f 1 ( x)  f ( x)
f 1 (50)  f (50) and f  f 100    100
f 1 (50)  f (50)  f  f 100    100

2   22 r 1  1 
n n
74. lim  Cot 1 r 1
 1  lim  Cot  1

n
r 1
2r n 
r 1  2
r

n
2r  n
1  2
r 1
 2r 
 lim  tan  1
r 1 
 lim  tan  r 1 
 1  2  2  n r 1 1 2  2 
n  r r
r 1

n

 lim   tan 1 2r 1  tan 1 2 r   lim  tan 1 2n 1  tan 1 2    tan 12  cot 1 2
n
r 1
n  2
75. Let x  cos . Then,
1 1 
 x  1   cos  1  0   
2 2 3
 x 3  3x 2 
∴ cos 1 x  sin 1   
 2 2 
 1 3 
   sin 1  cos  sin  
 2 2 
   
   sin 1 sin cos  sin  
 6 6 
   
   sin 1 sin     
  6 
      
          0         
 6 6 3 6 6 2
So, statement 1 is true.
Let x  sin  . Then,
1 1 1 1  
 x   sin      
2 2 2 2 4 4

 
∴ sin 1 2 x 1  x 2  sin 1  sin 2   2  2sin 1 x

So, Statement 2 is true.

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
x
76. f ( x)  2  2  0 for all x  R
x

Range of f  R(codomain)
 f is an into function

For x1 , x2 , x1  x2  2 x1  2 x2
x1 x2
 2x  2  2x  2
1 2

 f ( x1 )  f ( x2 )
 f ( x ) is one-one function. Hence f ( x ) is one-one and into
1  tan  1 2
77. cos 2  1  
3 1  tan 2  3

3  3tan 2   1  tan 2 
4 tan 2   2

tan 2   1  tan 8   1
2 16

2cos 2   3cos   32 1
16
2  
2cos 2   3cos   2  0
 cos   2  2cos   1  0
cos   2 or cos   1
2
  2n  2 3 , n  z

78. Let u  cos {sin   sin 2   sin 2  }

 u  sin  cos   cos 2   sin 2   sin 2  

2

u 2 tan 2   24 tan   4 2  sin 2   0

Since tan  is real, D  0

u 2  1  sin 2    0

| u | 1  sin 2 
79. sin x tan 4 x  cos x
sin x sin 4 x  cos x cos 4 x

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
cos  4 x  x   0

cos5 x  0

5 x   2n  1  , n  z
2
x   2n  1  ,n z
10
x  , 3 , 5 , 7 , 9
10 10 10 10 10
2
80. 2sin 2 A  2 cos B
3
1
ec  1 3
ec
The equation will satisfy when sin 2 A  1,cos 2 B  0 and e c  1
3  3
   2, ,B  , and c  0
2 2 2
Number of ordered triplets is 4

81. tan x  1  x  n  
4
2 x  2n  
2
When 2 x  2n   , tan 2 x is not defined
2
Given solution has no solution

4
82. sin 3 A  1 3sin A  sin 3 A 
27
27sin 3 9°   3sin 9°  sin 27°
4
9sin 27°  9  3sin 27°  sin81°
3
4
3sin 3 81°  3  3sin81°  sin 243°
4
sin 3 243°  1  3sin 243°  sin 729°
4
Adding all these
27sin 3 9°  9sin 3 27°  3sin 3 81°  sin 3 243°
 1  81sin 9  sin 9   80 sin 9  20sin 
4 4 20
  20,   20
   6   20
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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
83. Conceptual
84. f  f  x  x

  x   4 x
f f 4

f  f  x   f  f  4   4
x

85. af ( x )   f 1 x   bx  x __________ 1

Replace x by 1
x

 x    f ( x)  b x   x
af 1 ___________ 2

1+2

 x  b    2  2
f ( x)  f 1
 a      x   b    
f ( x)  f 1 x 1
x

x 1 a  1
x
 
86. sin
 2 x  (1  cos 2 x)  cos
x  0 for x   0, 
0
   0  2
0

Hence no solution
m0
  7  1  7  
n  sin  tan 1  tan   cos  cos 
  6   3  


 sin 
6
  1
3 
m  n  0 11
 1   1 
a 2  3a  3   2
b 2  2b  b   b3
2  a    2  b 
2
87. 1
sgn  cot 1 a  sgn(1  b )

 1   1 
Here   0
 2  a   2  b 
2 2

sgn  cot 1 a   sgn 1  (b)   1

 a 2  3a  3  b 2  3b  3  1
(a, b)  (1,1),(2, 2),(1,2),(2,1)
No. of ordered pairs = 4

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 Sri Chaitanya IIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Key & Sol’s
2
x
88. Let t
x2  1
t
x2   t   0,1
1 t
  f ( x)  
4 2
b

 2 2
a 
4
2  cos x  sin x   1  1  2  cos x  sin x 
2
89.
 
pur cos x  sin x  t
2t 2  1  2t  2t 2  2t  1  0

t
2  10

2 1 5  
4 4

cos x  sin x 

2 1 5 
4

1  cos x  sin x   
 5 1 
2 4

sin x  
4   sin   10 or sin11 10
x    or 11
4 10 10
17
x  11  
10 4 20
a  17, b  20
a  b  37
 cos 61  cos 62   cos119 
90. 1  1        1  
 cos1  cos 2   cos59 

 cos1  cos61  cos 2  cos 62   cos59  cos119 

   
 cos1  cos 2   cos59 
 2sin 31 sin 30  2sin 32 sin 30   2sin 39 sin 30 
     
 cos1  cos 2   cos59 
 cos59  cos58   cos1 
   
 cos1  cos 2   cos59 
1

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