NUMERICALS

& Calculate the molarity of 9.8% (W(W) solution of Mason if the

density of solution is 1.02g/mL (2014)

solution-roagm
A mass of solute
9.88
=

Mass solution 200g

of
=

density of

Molacity
Bxme*oxoxoe:
-

1.02 molilite
0. A solution of glucose (molar mass =
1soglmol) in water is (2014)
labelled as 10% (bymass). What would be the molality
and molarity of the solution. (Density of solution =
1.2gmL*
Am
Mass of solute (ws) 10g
- =

of solvent (WA)
Mass =
gog
molar mass of solute (Mn) =
180g/mol
Density of solution =
1.2g/mL
Morality (m)
coxono Egx500
· =
=
0.6am
=

-S Density
volume
-] volume:
anuity =

ximes: 5
molarion =

xx1.9 =20.66M
& An unknown gas"x" is dissolved in water at 2.5 bar
pressure and has more fraction 0.04 in
solution. The
more praction of gas when the pressure of gas is
doubled at the same temperature is
<2021-2)
Am. Acc. to Henry's law
D when pressure is doubled, then X
p = kUS

3
2 .5bau 56a0
knX0.01 62.5XX
=
=

kn 62.5 bar
=

x 0.08
=
9 . calculate the solubilityof CO2 in water at 290K under 760
cky for 202 in water at 290K is
1.25x106mmng)
mm

2090 ng
Am.
* solubility of CO2=1
KU

600x100
106
=
=
& The partial pressure of ethane
over a saturated solution conta-
-ining contains
6.56x10veg of ethane is 1 bar. If the solution
50 x
200g of ethane, then what will be
the partial pressure of gas?
(NCERT, 2012, 2013)
An Abblying the relationship m= knb

In first case, 6.56x10=knX1bar

kn 6.56x10-28 bart
=

second
I
cases

52x10-8E5GXlord
her = 0.762 bar
 bubbled
If Ne
gas is
how
& many millimoles
through awater at 293K, Assume
of Ne gas would dissolve in like of water? that Ne exerts
a partial pressure of 0.987 bar. Given that Henry's law constant
for NC at 1931 is 76.48K bar.

An According to Henry's law; DNc =

kuX XNc
XNc
N 0.987 =1.29x10-5
=

.76780
If a moles of N2 are present in 11 (i.e 55.55 moles

XNz 1
-5555 of water
=

x + 55.55

:1 = 1.29x10-5 on n 1.29x10-5/55.55
=

55.55
F1.659x10-5 moles
=>

0.716 millimoles
=>
 is dissolved in
& 30g of urea (M =
60gmol) 846g
of water Calculate the vapour pressure of water
for this solution if lop of pure water at 298K
1308 (2017)
mmng
Am (wd= Jog
mass
of urea

mass
of water (WA) =
876g
vabour pressure of water pA=23.8mmng
xB
5 0.5, UA
606 47
=

= = =

More fraction of water (((A) =

UAtUS

Fo5 0.99
=
=

PA PAXYA=
=

23.8 40.99=23.5mm Ug
028gof glucose, CoMzOG(Molar mass-180g/molina tape
will this solution boil?
Iky for water=0.5eKkgmott, Boiling point
&pure water: 37315K

AMWA= 11g =
1000g T = 373.15K
WB
18g 10 0.52 KKg molt
=

MB =
1s0 g/mol To =
?
using formula
AT =
kxM

kxxyxgl
=

= 0.52X18x1000
0.052K
=

180 x 1000

&Tb Tx T= -

& To + T = T

373.15 + 0.052:3730202K
a calculate the boiling point elevation for a solution
prepared by adding log o Call, to 200g g water.
Cky for water 0.52KKg moly, molar
=
mass calle
III
(2014, 2017)
=>
g(n)
Am. Many
Callg(wD) L0g
=

Molar mass
of calls (MD) = 211
glmol
Mass water (WA) 200g
of
=

Molal Elevation constant (kb) = 0.512K Kgmolt

m =
WBX1000
tx100 0.45 m
=

MBXwA(g)
=

Calle-Cact+2Ui = 3
& Tb iX kxXM
=

= 3X0.512X0.450.
o calculate the fist of the solution when
319 gethylene
glycol ((<Mo02) is dissolved in
500g of water.
ck+ for water 1.86KKg md -1)
(2015)
=

Am Mans of ethylene glycol ((,H602) =

319
Man water
of (WA)-500g
Mass
Molar
of CalsOz
= 62
glmol
17:1086Kkgmot1, T=

using Formula, DTH =

KfXM

K+X*x(0(g)
=

1.86x310
AT =
TY-T ON TH =
T-DTf= 273-186=271014K
⑨ Some ethylene glycol, noctechon, is added to your cars
cooling system along with 5kg o water. If the greening
point of water glycol solution o-1500), what the
boiling pt of solution? (kn 0.52Kkg mot (2014) =

Kf= 1.86
KKg molt
An Tf = -15°C

kf= 1.86
KKgmolt
&T1 7=
-

T( = 0 -
( -

15) 15°
= =
28817
DT =
1)XM
288:1.86XWB *wi18g =

62.45

A Tb kbXm
=

0.52X5845
=
*
To = 80.51K

ATD =
Tb -

T'p
80.51 76-37380.51
= + 273 453.51K
=
a solute dissolved in of benzene
1g of a non-electrolyte 50g0.4ok.
lowered the
freezing point of benzene by
The
freezing point depression constant of benzene is
5.1
Kkg most. Find molar mass of solute (2008, 2013)
Am ws 1g Kf= 5016Kkg Moly
=

WA=
50g &Tt = 0.40K

& If =
kfXM
+X
wx1
wA(g)
MB =
K+XWBX1000 5.12X2x1000
= =
2569 mot
WAX DTH 50x0.40
 solution prepared by
a calculate the
boiling point of a

adding 15.00g g Nace to 250g water (Kb for water

0.51KKgmolt) (Molar man Nac= 58.44g) (CO1

=

of
#i =
0, kp 0.512KKgMoH, wp 15g
= =

Mp
58.44q mot , WA:250g
=

&Tb = PX KxXM

ixKbXBXo0 -2 X0.512x15x
-
L0
=105K
58.44X250

Tb =
T + DTb 37315K = + 1.05K 374.20K
=
8. A
in
solution prepared by
water has
dissolving 8.95
mg of a gene fragment
35mng an osmotic pressure of 0.335 for at
2500.
Assuming the gene fragment is a non-electrolyte,
determine its molar mass

An WD =

8.95mg =
8.95/10-3g
R = 0.0821 Latm K Mol -1 x = 35x10-3L

T 25+ 273k 298K π 0535 ah

= =
=

760

CYA
MB =

=
8.95x105X0.0821X298 =14193.29 glmol
083
Tr x 35X10-3
③ A molal aqueous solution of trichlowacetic acid (CC,Coot) is
1
heated to its boiling point of 100.180). Determine the vanit
not factor for trichloroacetic acid (2012)
An Molality of the solution = 1m

Boot of solution y 100.183:373.18K

=

Bot of solvent To =1000: 373K

* To =
Tx T 100.18%-100)
- =
=
0.18K

DT ix KbxM
=

0.18=1X0.512X1 i 0.35
=
 boot elevation of acid in
& The
0.3ogacetic 2008 benzene
③0.0633K. Calculate the molar man of acetic acid from this
data. What conclusion can you draw about the molecular
state of the solute in the solution? Given ky for
benzene-e,5Kgnol
I
An. MB =
kxXw5X1000 2.53x0.30 x 2000
1Cogmol
=
=

ATXWA 0.0633x100

: Molar mass
of Chloon: 60
glmol
i MB (Normal Molarman)
=
=
650 =
1 0.5
=

Mr (observed Molar Man)

therefore the solute acetic acid associated.
ec1,
& A 5% solution (bymass) of cane sugar in water has freezing point
of 271K Calculate the fipt of 5% solution (by mass) of glucose in water
·

is thefreezing point of pure water is 273015K. 2013

=Molecular masses: Glucose-150amn; cane sugar-342amn)
Am Molality of sugar solution,

wAlooo-Slog = 0.15W

AT5 T5 -T
=

= 273015-971=2.15K

DT= KXXM OU K9:

5,: 5
0.154

molality of Glucose solution,

=Xorg) =
x100 = 0.292M

*If Calucose) kfXM 25x 0.292=0.08

= =

:freezing point of glucose solution

=
273015 -
1008 =269.07K
o Calculate the boot of one molar aqueous solution (demily 1.06
g mL-1) of
Any [Kb 0.52 KBU.
-
concentration of sol-1 molar
=

Kimolt) , Mol.
Massg]
Demityof the solution: 1.06 g/mL
Mr(Molar mass) 119 glmol =

ky for water not

=
0.52KKg
molality (m) = 1000 x Molarity = 1000x 1

loooxdenity (Molacity X Mogsolute)

-

2000 x 2.06 -1x11

1.06 M
Br-i 2
=>

KBU -
k+ =

DTo = iXKOXM
= iX052X1.06 0.553K =

DTb = to T -
* Tb: TB + DTb =373 + 0.553
373553K
=
⑥ An
&
aqueous solution containing 12.48g o barium chloride
m
1kg of water boils at 37300832K Calculate the

degree of dissociation of barium chloride

↑ Given Ko for Ho = 0.52 Km
Molar Back
Mass
of =
208.34g/mol
Here, nes Because Back-> Baht +Cc-
WB 12.48g
=

Tb 373.0832K
=

WA =

1000g ko for water = 0.52kmy

and Mr (Backs) =
20834 glmol
* To =
Tb T8 +3730832
-
-
373 =0.083CK

EMDX1Ooo-0.52x12.48x10
My =

T
0.0832x1000

=MrNoualledCoE3O-86.83.5x
0 A 0.561m solutionof an unknown electrolyte depresses the
freezing
this
point of water
by 2.950. What is van't host factor
for electrolyte.? (If for water is 1.86 %
Kg Mott) (2011)

Am.
F
M = 0.561m

AT = 90930
molt
xf =
1.860kg
&T: PX1IXM
in
xm= 2.93=2.807.
1.86 x 0.561