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Objective Test
(Solution + Electrochemistry + Chemical Kinetics)
1. Assertion: If temperature increases, solubility of gas decreases, reaction is endothermic.
Reason: if temperature increases, solubility of gas decreases, Le – Chatelier’s principle can be
applied.
2. The solubility of N, in water at 300 K and 500 torr partial pressure is 0.01 g L –1. The solubility
(in g L–1) at 750 torr partial pressure is:
(a) 0.0075 (b) 0.005 (c) 0.02 (d) 0.015
3. Which one of the following binary mixtures forms an azeotrope with minimum boiling point
type?
(a) acetone-ethanol (b) H2O-HNO3 (c) benzene-toluene (d) n-hexane-n-heptane
4. Two open beakers one containing a solvent and the other containing a mixture of that solvent
with a non-volatile solute are together sealed in a container. Over time:
(a) the volume of the solution increases and the volume of the solvent decreases
(b) the volume of the solution decreases and the volume of the solvent increases
(c) the volume of the solution and the solvent does not change
(d) the volume of the solution does not change and the volume of the solvent decreases
5. Henry's law constant K of CO2 in water at 25°C is 3.0 × 10–2 mol L–1atm–1. The mass of CO2
present in 100 L of soft drink bottled with a partial pressure of CO2 of 4 atm at the same
temperature is
(a) 5.28 g (b) 12.0 g (c) 428 g (d) 528 g
6. How many grams of methyl alcohol should be added to 10 L tank of water to prevent its
freezing at 268 K? (Kf for water is 1.86 K kg mol-1)
(a) 880.07 g (b) 899.04 g (c) 886.02 g (d) 868.06 g
7. Vapour pressure of solution containing 2 mol of liquid A (P0A = 80 torr) and 3 mol of liquid B
(P0B = 100 torr) is 87 torr. We can conclude that
(a) there is negative deviation from Raoult's law
(b) boiling point is higher than that expected for ideal solution
(c) molecular attractions between unlike molecules are stronger than those between like
molecules
(d) All of these statements are correct
8. Two solutions A and B are prepared by dissolving 1g of non-volatile solutes X and Y,
respectively in 1 kg of water. The ratio of depression in freezing points for A and B is found to
be 1: 4. The ratio of molar masses of X and Y is:
(a) 1:4 (b) 1:0.25 (c) 1:0.20 (d) 1:5
9. The temperature at which 10% aqueous solution (w/v) of glucose will exhibit the osmotic
pressure of 14 bar is –
(a) 307.3°C (b) 307.3 K (c) 34K (d) -34°C
10. The van't Hoff factor i for a compound which undergoes dissociation in one solvent and
association in other solvent is respectively:
(a) less than one and greater than one. (b) less than one and less than one.
(c) greater than one and less than one. (d) greater than one and greater than one.
11. Which of the following statement is correct?

Shastri Nagar | Ganga Nagar Academics : 9th – 12th

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(a) Cathode is -ve terminal in both, galvanic and electrolytic cells.

(b) Anode is + ve terminal in both, galvanic and electrolytic cells.
(c) Cathode and anode are -ve terminal in electrolytic and galvanic cell.
(d) Cathode and anode are +ve terminal in electrolytic and galvanic cell.
12. Based on the cell notation for a spontaneous reaction, at the anode:
Ag(s) | AgCI(s) | CI–(aq) || Br–(aq) | Br2(l) | C(s)
(a) AgCI gets reduced (b) Ag gets oxidized
(c) Br- gets oxidized (d) Br2 gets reduced
13. Standard electrode potential for Sn | Sn couple is + 0.15 V and that for the Cr3+ | Cr couple
4+ 2+

is -0.74V. These two couples in their standard state are connected to make a cell. The cell
potential will be:
(a) +1.19V (b) +0.89 V (c) +0.18 V (d) +1.83 V
14. In which of the following half cells, electrochemical reaction is pH dependent?
(a) Pt | Fe3+, Fe2+ (b) MnO4– | Mn2+ (c) Ag|AgCI|CI– (d) F2|F–
0 +
15. The standard electrode potentials (E M |M) of four metals A, B, C and D are - 1.2 V, 0.6 V,
0.85 V and - 0.76 V, respectively. The sequence of deposition of metals on applying potential
is:
(a) A, C, B, D (b) B, D, C, A (c) C, B, D, A (d) D, A, B, C
16. When electric current is passed through acidified water, 112 mL of hydrogen gas at STP
collected at the cathode in 965 seconds. The current passed in amperes is
(a) 1.0 (b) 0.5 (c) 0.1 (d) 2.0
17. For an electrolvte solution of 0.05 mol L–1, the conductivity is found to be 0.011 S cm–1. The
molar conductivity is
(a) 0.055 S cm2 mol–1 (b) 550 S cm2 mol–1 (c) 0.22 S cm2 mol–1 (d) 220 S cm2 mol–1
18. A current of 2.0 A passed for 5 hours through a molten metal salt deposits 22.2 g of metal (At
wt. = 177). The oxidation state of the metal in the metal salt is
(a) +1 (b) +2 (c) +3 (d) +4
19. The specific conductivity of N/10 KCI solution at 20°C is 0.212 ohm cm–1 and the resistance
–1

of the cell containing this solution at 20°C is 55 ohm. The cell constant is
(a) 4.616 cm–1 (b) 11.66 cm–1 (c) 2.173 cm–1 (d) 3.324 cm–1
20. Identify the correct statement:
(a) Corrosion of iron can be minimized by forming a contact with another metal with a higher
reduction potential
(b) Iron corrodes in oxygen free water
(c) Corrosion of iron can be minimized by forming an impermeable barrier at its surface
(d) Iron corrodes more rapidly in salt water because its electrochemical potential is higher
21. The rate law for a reaction between the substances A and B is given by rate = K[A]n[B]m. On
doubling the concentration of A and halving the concentration of B, the ratio of the new rate
to the earlier rate of the reaction will be as
(a) (m+ n) (b) (n - m) (c) 2(n+m) (d) 1/2(m+n)
22. For a first order reaction, a plot of log (a - x) against time is a straight line with a negative
slope equal to
(a) -k/2.303 (b) -2.303k (c) 2.303/k (d)-Ea/2.303R
23. For the reaction 2A + 3B + 3/2C → 3D, which statement is correct?
𝑑𝑛 3𝑑𝑛𝐵 3𝑑𝑛𝐶 𝑑𝑛 𝑑𝑛 𝑑𝑛 𝑑𝑛 4𝑑𝑛𝐵 4𝑑𝑛𝐶 𝑑𝑛 2𝑑𝑛𝐵 3𝑑𝑛𝐶
(a) 𝐴 = = (b) 𝐴 = 𝐵 = 𝐶 (c) 𝐴 = = (d) 𝐴 = =
𝑑𝑡 2𝑑𝑡 4𝑑𝑡 𝑑𝑡 𝑑𝑡 𝑑𝑡 𝑑𝑡 3𝑑𝑡 3𝑑𝑡 𝑑𝑡 3𝑑𝑡 4𝑑𝑡
24. For the reaction H2(g) + Br2(g) → 2HBr(g), the experimental data suggest, rate = K[H2][Br2]1/2.
The molecularity and order of the reaction are respectively

Shastri Nagar | Ganga Nagar Academics : 9th – 12th

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(a) 2,3/2 (b) 3/2,3/3 (c) 1,1 (d) 1,1/2

25. For a chemical reaction t1/2, is 2.5 hours at room temperature. How much of the reactant will
be left after 7.5 hours if initial weight of reactant was 160 g?
(a) 10 g (b) 40 g (c) 80 g (d) 20 g
26. The activation energy of the reaction, A + B → C + D + 38 kcal is 20 kcal. What would be the
activation energy of the following reaction?
C+D→A+B
(a) 20 kcal (b) -20 kcal (c) 18 kcal (d) 58 kcal
27. In a reaction, 2A → products, the concentration of A decreases from 0.50 M to 0.38 M in 10
min. What is the rate of reaction (in M s–1) during this interval?
(a) 0.012 (b) 0.024 (c) 0.002 (d) 0.0002
28. A chemical reaction is catalyzed by a catalyst X. Hence X
(a) reduces enthalpy of the reaction.
(b) decreases rate constant of the reaction.
(c) increases activation energy of the reaction.
(d) does not affect equilibrium constant of the reaction.
29. Consider the consecutive reactions:
𝒌 = 𝟐 ×𝟏𝟎−𝟓 𝒔−𝟏 𝒌 =𝟖 ×𝟏𝟎−𝟔 𝒔−𝟏 𝒌 = 𝟑 ×𝟏𝟎−𝟑 𝒔−𝟏
𝑨 → 𝑩→ 𝑪→ 𝑫
The rate determining step of the reaction is:
(a) A → B (b) C → D (c) B → C (d) A → D
30. Which of the following will react at the highest rate?
(a) 1 mole of A and 1 mole of B in a 1-L vessel
(b) 2 mole of A and 2 mole of B in a 2-L vessel
(c) 3 mole of A and 3 mole of B in a 3-L vessel
(d) All would react at the same rate

Shastri Nagar | Ganga Nagar Academics : 9th – 12th

9897670452 | 8077550690 Competition :
[email protected] JEE | NEET | CUET