Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY
UNDERTAKING
1.1 Product identifier
Product Name Simple Solution Stain and Odour Remover for Dogs 4L
Product Code(s) 90424
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use For amateur use only as a stain and odour remover
1.3 Details of the supplier of the safety data sheet
Company Manna Pro
Barnack House
Suite 2
Orton Southgate
Peterborough
PE2 6GP
Technical Phone No. 44-(0)-1733 404390 (Office Hours)
Fax 44-(0)-1733 685437
E-mail Address
[email protected] 1.4 Emergency telephone number
Emergency Phone +44-(0)-1733 404390 (Office Hours)
National Emergency telephone number +44 (0) 844 892 0111 (Uk only)
SECTION 2: HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFICATION according to Regulation EC 1272/2008 Classification, Labelling and Packaging
Not classified.
2.2 Label elements
There are no statutory label elements
2.3 Other hazards
Mixture not classed as PBT or vPvB
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixtures
Chemical Name CAS-No./ Annex Index/ Classification according to Concentration
EC-No. REACh number Regulation EC 1272/2008: [%]
Ethanol 64-17-5/ 603-002-00-5/ Flam. Liq. 2;H225 1.0 – 3.0
200-578-6 01-2119457610-43 Eye Irrit. 2; H319
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures
GENERAL ADVICE
Consult a physician in all cases of doubt. Show this safety data sheet to the doctor in attendance.
Page 1 of 8
Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
AFTER INHALATION
If breathed in, move person into fresh air.
AFTER SKIN CONTACT
Wash off with soap and water.
AFTER EYE CONTACT
Rinse thoroughly with plenty of water for at least 15 minutes, if any soreness or irritation persists
seek medical advice.
AFTER INGESTION
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Obtain medical advice if any irritation persists.
4.2 Most important symptoms and effects, both acute and delayed
None reported.
4.3 Indication of any immediate medical attention and special treatment needed
None reported.
SECTION 5: FIRE FIGHTING MEASURES
5.1 Extinguishing media
EXTINGUISHING MEDIA
Suitable extinguishing media: Not expected to be flammable. Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Not expected to be flammable. When exposed to high temperatures, the preparation may release dangerous
decomposition products such as carbon monoxide and dioxide, smoke and/or nitrogen oxide.
Material can create slippery conditions.
5.3 Advice for firefighters
Firefighters should wear a self-contained breathing apparatus and full protective gear.
SPECIFIC METHOD(S) OF FIRE FIGHTING Use water spray to cool fire-exposed containers.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin, eyes, and clothing. Use personal protective equipment. Refer to protective
measures listed in sections 7 and 8. Prevent further leakage or spillage if safe to do so. Material can create
slippery conditions
6.2 Environmental precautions
Avoid release of neat product into surface water and sanitary sewage system.
6.3 Methods and material for containment and cleaning up
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Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
Methods for Containment
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
Methods for Cleaning up
Clean preferably with a detergent, do not use solvents.
6.4. Reference to other sections
Refer to sections 7, 8 and 13
SECTION 7: HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Do not eat, drink or smoke when
using this product. Ensure adequate ventilation.
7.2 Conditions for safe storage, including any incompatibilities
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of
the reach of children.
7.3 Specific end use(s)
For amateur use only as a stain and odour remover.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Components with Workplace Exposure Limits:
ETHANOL
UK:
Workplace exposure Limits as defined by UK HSE in document EH40/2005:
Substance CAS number Workplace Exposure Limit Comments
The Carc, Sen and Sk
Long-term exposure Short-term exposure notations are not
limit limit exhaustive.
(8-hr TWA reference (15 minute reference Notations have been
period) period) applied to the
substances identified
ppm mg.m-3 ppm mg.m-3 in IOELV Directives*
Ethanol 64-17-5 1000 1920 - - -
*IOELV – Indicative Occupational Exposure Limit Values (IOLEV).
Sk = Can be absorbed through the skin.
Germany:
TRGS 900 Occupational exposure limit value: 960 mg/m³
TRGS 900 Occupational exposure limit value: 500 ppm
Excess factor: 2(II)
Remark (TRGS 900): DFG, Y
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Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
DNELs and PNECs for components where available:
ETHANOL:
Type Effect Value Population
DNEL Inhalation 950 mg/m3 Industry
DNEL Dermal 343 mg/m3 Industry
DNEL Inhalation 114 mg/m3 Consumer
DNEL Dermal 206 mg/m3 Consumer
DNEL Oral 87 mg/m3 Consumer
PNEC Freshwater 0.96 mg/l -
PNEC Marinewater 0.79 mg/l -
Source: Univar SDS date: 08/05/2013
8.2 Exposure controls
Engineering Measures
General ventilation is normally adequate
Personal Protective Equipment
Use personal protection equipment as per Directive 89/686/EEC
Hand Protection
Long term use eg: continuous wear or immersion;. Wear suitable protective gloves conforming to EN 374. Type
of gloves suggested :. Nitrile rubber. PVC. Neoprene gloves. For break through times, refer to glove
manufacturers recommendations.
Eye Protection
Safety glasses if the method of use presents the likelihood of eye contact. Approved to EN 166.
General Hygiene Considerations
Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and
safety practice. Wash hands before breaks and at the end of workday.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance: Light yellow
Physical State: liquid
Odour: Vanilla
pH 6.0
Boiling point: 100 oC
Melting point: -5 oC
Flash Point > 62oC
Specific Gravity 1.0 g/cm3
Viscosity No information available
Solubility Soluble in water
Autoignition Temperature No information available
Flammability Limits in Air % Not applicable
Evaporation Rate No information available
Vapor Pressure No information available
Vapor Density No information available
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Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
Explosive properties No information available
Oxidizing Properties No information available
VOC Content (%) 2.57 %
9.2 Other information
None available.
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
No reactions reported.
10.2 Chemical stability
Stability: Stable under recommended storage conditions.
Materials to Avoid: No chemical incompatibility is known.
10.3 Possibility of hazardous reactions
None reported.
10.4 Conditions to avoid
Keep out of direct sunlight. Keep container tightly closed.
10.5 Incompatible materials
None reported.
10.6 Hazardous decomposition products
Hazardous Polymerization: Will not occur
No chemical incompatibility is known.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity: Not expected to be toxic.
Skin corrosion/irritation: Product is not classified as a skin corrosive/irritant.
Serious eye damage/irritation: Product is not classified as causing eye damage or irritation.
Respiratory or skin sensitisation: Product is not classified for respiratory or skin sensitisation.
Germ cell mutagenicity: No information specified.
Carcinogenicity: No information specified.
Reproductive toxicity: No information specified.
STOT-single exposure: Product is not classified as having Specific Target Organ Toxicity
for single exposure
STOT-repeated exposure: No information specified.
Aspiration hazard: No information specified.
Toxicity information on ingredients where available:
Ethanol:
Acute toxicity - oral
Page 5 of 8
Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
Acute toxicity oral (LD₅₀ mg/kg) 10,740
Species rat
OECD 401: Acute Oral Toxicity; Experimental value)
Acute toxicity - dermal
Acute toxicity dermal (LD₅₀mg/kg) >16,000
Species: Rabbit
Literature study
Source: Barrettine SDS, 04/08/2016
SECTION 12: ECOLOGICAL INFORMATI ON
12.1 Toxicity
The mixture is not classified as harmful to the environment.
Ecotoxicity information on ingredients where available:
Ethanol:
LC50 fish: 13000 mg/l (LC50; 96 h; Salmo gairdneri; Static system; Fresh water)
Persistence and degradability: Readily biodegradable in water. Biodegradable in soil. No
(test)data available on mobility of the substance.
Biochemical oxygen demand (BOD): 0,8 - 0,967 g O₂/g substance
Chemical oxygen demand (COD): 1,70 g O₂/g substance
Theoretical Oxygen Demand ThOD: 2,10 g O₂/g substance
Source: Barrettine SDS, 04/08/2016
12.2 Persistence and degradability
The surfactant(s) contained in this preparation complies (comply) with the biodegradability criteria as laid
down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of
the competent authorities of the Member States and will be made available to them, at their direct request or
at the request of a detergent manufacturer.
12.3 Bioaccumulative potential
Information not available.
12.4 Mobility in soil
Soluble in water.
12.5 Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB, as defined under
the regulation EC 1907/2006.
12.6 Other adverse effects
None specified.
SECTION 13: DISPOSAL CONSIDERATIONS
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Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
13.1 Waste treatment methods
Waste from Residues / Unused Products
The used product can be drained to sewage if it does not contain hazardous materials and the pH is neutral
(typically 5.5 to 9).
Contaminated Packaging
Empty remaining contents. Empty containers should be taken for local recycling, recovery or waste disposal.
Recycle according to official regulations.
EWC waste disposal No
The following EWC/ AVV waste codes may be applicable: 07 06 01* aqueous washing liquids and mother
liquors
Other Information
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
SECTION 14: TRANSPORT INFORMATI ON
14.1 UN number
Not classified
14.2 UN proper shipping name
Not classified
14.3 Transport hazard class(es)
Not classified
14.4 Packing group
Not classified
14.5 Environmental hazards
Not classified
14.6 Special precautions for user
Remarks:
Not classified as hazardous according to ADR European Agreement Concerning the International Carriage of
Dangerous Goods by Road.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Applicable for Maritime bulk transport only. Check with carrier.
SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This product is classified and labelled in accordance with Regulation (EC) No 1272/2008 of the European
Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, and Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACh).
This is a detergent product and complies with the Detergent Regulation (EC) No.648/2004.
Labelling for contents (REGULATION (EC) No 648/2004):
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Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
Safety Data Sheet
According to Regulation (EC) 1907/2006
SDS completed: 08.01.2020
Version No: 4
Revision No: 1
Supersedes: SDS Dated 12.06.2019
Perfume, hexyl cinnamal, bronopol, 1,2- Benzisothiazolin-3-one
WGK Classification
Low hazard to waters (WGK 1), Classification according VwVwS
15.2 Chemical safety assessment
Chemical safety assessment not undertaken for this product.
SECTION 16: OTHER INFORMATION
Abbreviations:
Eye Irrit. 2 Eye Irritation category 2
Flam. Liq. 2 Flammable Liquid category 2
DNEL Derived No-Effect Level
LD50/LC50 Lethal Dose/Lethal Concentration 50%
OECD Organisation for Economic Co-Operation and Development
PNEC Predicted No-Effect Concentration
PBT Persistent, bioaccumulative and toxic.
vPvB very Persistent and very Bioaccumulative.
Full text of H-statements referred to under section 3:
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
WARRANTY
The information given in this safety data sheet is based on knowledge available at the time of completion and
is intended to describe the product only in terms of health and safety requirements. It does not signify any
warranty with regard to specific properties or specifications.
Page 8 of 8
Manna Pro UK Limited | Suite 2, Barnack House, Southgate Way, Orton Southgate, PE2 6GP | 01733 404390
