A Premier Institute for Engineering & Medical A TEST ID 24140
24140 Chemical Euilibirum with Solution
1. (c) Any change in coefficient is change in power of K
1 1 1
2. (d) K2 5 x 1016
K1 4 x 10 –34 2 x 10–17
3. (c) Reaction must shift in backward direction.
4. (c) k p k c (RT)n
n 1 – 3 –1
2 2
x2
5. (a) As, n 0, k p k c
(1 – x)2
6. (d) Increase in pressure shifts equlibrium towards lesser no.of moles
N2 3H2 2NH3
7. (d)
1 3 O
As, 1 – x = 0.6 x = 0.4
n = 4– 2 x = 3.2
n 1
8. (d) Active mass =
v 4
2 2
9. (a) k Ca2 F– 4 Ca2 F–
new
2 1 2 1
F– F –
new 4 old 2
10. (a)
H2 I2 2HI
4.5 4.5 O
4.5–x 4.5–x 2x
ATQ, 2 x = 3 so, x = 1.5
32
k 1
3 x3
11. (b)
NH4 HS(s) NH3(g) H2 S(g)
p p
2 p = 30
p = 15
kp = (15) = 225
Chandigarh: SCO -25, 2nd floor,Sector-20
G o d h a s nDe ve
8699438881
r g ive n d re a m s Page No. 8
SCF-07, 1st floor, Sector-15, Panchkula nd
Panchkula: SCF-10, 2 floor,Sector-15, w it 9217610408
h o u t a b il ity t o a c h ie ve it . Page No. 8
9217610408,8699438881,8699438882
A Premier Institute for Engineering & Medical A TEST ID 24140
12 (d) Conceptual
13. (b) As, ratio of NO & Br2 is 2 : 1
p 2P p P
No Br2
9 9
2P P 2P
p P—
NOBr 9 9 3
2
kp
2 P P 4P2 x P x 9
9 9
P
2 2 2 81
2 P 3 9 x9 x 4P
kp 1
P 81
A B C D
14. (d) [D] 2 [A]
t=O a a o o x= 2 a– 2x
2a
t= q a–x a–x x x x
3
2a x 2a
K 3 3 4
a x a
3 3
CO2
15. (d) 5
CO
CO2 = 5 x 2.5 x 10 –2
= 0.125 m
16. (a) Ratio of volume will be ratio of moles for gases
N2 3H2 Vf 0.64 4
2NH3
Vi 0.8 5
0.2 0.6 0
0.2 – x 0.6– 3x 2x
n 0.8 — 2x 0.64
(0.331)2
17. (a) K 2.5
(0.662)2 (0.101
K is
2
SO3
2.5
SO2 2 O2
1
O2 0.4 atm
2.5
Chandigarh: SCO -25, 2nd floor,Sector-20
G o d h a s nDe ve
8699438881
r g ive n d re a m s Page No. 9
SCF-07, 1st floor, Sector-15, Panchkula nd
Panchkula: SCF-10, 2 floor,Sector-15, w it 9217610408
h o u t a b il ity t o a c h ie ve it . Page No. 9
9217610408,8699438881,8699438882
A Premier Institute for Engineering & Medical A TEST ID 24140
18. (a) K = [A] [B]
[A] = 2 [A]
[A] [B] = [2A] [B’]
1
B' B
2
19. (b) Pressure & volume have no effect if n = O
kf 2 x 10–4
20. (c) Kq 40
kb 5 x 10–6
21. (c)
1 1
K2
k1 10
22. (c) When n = O, there is no effect of temperture & pressure
23. (c)
NH4 Br(s) NH3(g) HBr(g)
p p
2 2
p p 1 2
kp p .p x p
NH3 HBr 2 2 4
24. (c) Kq only depend upon temperature
[ ]
25. (d) 0.64
[A] [B]2
1 10
[B] 1.25
0.64 8
kp 14
kp 1 10 108 atm –1
26. (a) kp
2 106
27. (a)
CH 3 COOH C2H5 OH CH3 COOC2H5 H2 O
t=O 1.2 1.2 O O
t=q 1.2 – x 1.2 – x x x
[Ester] = [H2O] = x = 0.4
0.4 x 0.4 1
K
0.8 x 0.8 4
28. (d) kp = kc (RT)n
If Dn > O
kp > kc
29. (d) Conceptual
Chandigarh: SCO -25, 2nd floor,Sector-20
G o d h a s nDe ve
8699438881
r g ive n d re a m s Page No. 10
SCF-07, 1st floor, Sector-15, Panchkula nd
Panchkula: SCF-10, 2 floor,Sector-15, w it 9217610408
h o u t a b il ity t o a c h ie ve it . Page No. 10
9217610408,8699438881,8699438882
A Premier Institute for Engineering & Medical A TEST ID 24140
30. (a)
AB A B
1–x x x
x = 0.5
0.5 x 0.5 P
kp x
0.5 1.5
P = 3 x kp
31. (c)
A 2B 2C
1–x 1–2x
[A] > [B]
D–d
32. (a)
(2 – 1)d
‘d’ decreases with increase in ' ' .
33. (c) Conceptual
34. (c)
PCl5 PCl3 Cl2
[PCl3] = [Cl2]
PCl PPCl 0.25 x 2 0.5
2 3
35. (d) Conceptual
36. (a) Conceptual
37. (a)
2 NO N2 O2
x x
4–x 2 2
ATQ, x = 0.4
0.2 x 0.2 1
K
(3.6)2 (18)2
(0.7)2
38. (c) k 49
(0.1 (0.1)
39. (d) No effect
D
40. (c) —1
d
If x is zero, D = d
41. (d) 42. (d) 43. (d) 44. (c) 45. (a)
Chandigarh: SCO -25, 2nd floor,Sector-20
G o d h a s nDe ve
8699438881
r g ive n d re a m s Page No. 11
SCF-07, 1st floor, Sector-15, Panchkula nd
Panchkula: SCF-10, 2 floor,Sector-15, w it 9217610408
h o u t a b il ity t o a c h ie ve it . Page No. 11
9217610408,8699438881,8699438882
