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Module 2

This document provides a template for an internal exam containing 12 questions divided into two parts. Part A contains 3-mark questions and Part B contains 14-mark questions. The questions cover topics related to spectroscopy including infrared spectroscopy, UV-visible spectroscopy, nuclear magnetic resonance spectroscopy, and their applications. Various concepts are tested including absorption and emission spectra, factors affecting chemical shifts in NMR, types of vibrational modes and electronic transitions.

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0% found this document useful (0 votes)
32 views7 pages

Module 2

This document provides a template for an internal exam containing 12 questions divided into two parts. Part A contains 3-mark questions and Part B contains 14-mark questions. The questions cover topics related to spectroscopy including infrared spectroscopy, UV-visible spectroscopy, nuclear magnetic resonance spectroscopy, and their applications. Various concepts are tested including absorption and emission spectra, factors affecting chemical shifts in NMR, types of vibrational modes and electronic transitions.

Uploaded by

hndc1884
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Question Bank template for internal exam 2 - Part A - 3 mark questions

Questio Question Mark Bloom’s CO


n No taxonomy level
1 1. Distinguish between absorption spectrum and emission spectrum? 3 2 2
2. Compare IR & UV spectra 3 2 2

3. Explain absorption and intensity shifts. 3 2 2

2 1. Which of the following nuclei can show NMR spectra a) 1H b) 19F 3 3 2


c) 12C d)16O

2. Which of the following molecules can give IR spectrum : O2 , N2 , 3 3 2


HCN , HCl

3. Which of the following molecules show UV-visible absorption 3 3 2


spectrum? Explain.
a) Methane b) Benzene c) 1,3- butadiene d) Cyclohexene

3 1. What is the selection rule for IR? 3 1 2


2. What is electromagnetic spectrum? 3 1 2
3. Define Chemical Shift? 3 1 2
4 1. Predict the number of signals, their relative position & multiplicity 3 2 2
for Ethyl acetate?
2.How many chemical shift signals are shown by the following 3 2 2
molecules in H-NMR : Acetone , 1-Bromopropane

3.The C=C stretching absorbs at higher wave number(~1600cm-1) 3 2 2


compared to C-C stretching (~1200cm-1). Give reason

5 1. Why TMS is selected as a standard reference in NMR? 3 3 2


2. Explain the reason for broadening of UV-Visible spectrum. 3 3 2
3. Write any three applications of IR spectroscopy. 3 3 2
6 1. Arrange the following in the increasing order of tau value. Give 3 2 2
Reason? CH3F , CH3-O-CH3 , (CH3)3N , CH3-CH3
2. A solution of thickness 3cm transmits 30% incident light. Calculate 3 2 2
the concentration of the solution , given Extinction coefficient =
4000 dm3mol-1 cm-1.
3. What is the requirement for a molecule to be IR active? Write two 3 2 2
examples for IR active and inactive molecules.

Question Bank template for internal exam 2 - Part B - 14 mark questions


Questio Question Mark Bloom’s CO
n No
taxonomy level
1A. Explain spin-spin splitting? Distinguish between 1-propanol and 2- 10 2 2
7
propanol by NMR?
4 3 12
1B .Write any four applications of NMR.

2A. Explain chemical shift? What are the factors affecting chemical shift? 10 2 2

2B. Explain the term shielding and deshielding in NMR spectroscopy 4 3 2

3A Explain the theory of NMR 10 2 2

3B Write a brief note on MRI as an application of NMR spectroscopy. 4 3 2


1A. Explain stretching and bending vibrations by taking water molecule as 3 2
8 10
example?

4 2 2
1B. The fundamental vibrational frequency of CO is 2140cm-1. Calculate
the force constant of the molecule. Given atomic masses 12C = 19.9 10-27kg
and 16O = 26.6×10-27 kg.

2A What are the various modes of vibrations possible for CO2. Which of 10 3 2
them areIR active? Give reason?

2B Calculate the force constant of HF molecule if it shows IR absorption at 4 2 2


4138 cm-1. Given the atomic masses of Hydrogen and Flourine are 1u and
19u respectively.
3A What are the various types of electronic transitions possible in organic 10 3 2
molecules? Give examples of each.
3B Suggest structural formula for the following compounds such that they 4 2 2
give a single signal in proton NMR spectroscopy. a) C9H18O and b) C12H18

1A. Sketch the molecular orbital energy diagram of 1,3-butadiene and show 10 2 2
9
HOMO and LUMO transition. What happens to wavelength of absorption
maximum when more double bonds come in conjugation?
1B. State and explain the law governing absorption of electromagnetic 4 2 2
radiation by matter. Give any one limitation of this law.
2A. Explain the instrumentation of UV-Visible spectrophotometer with a 8 2 2
neat diagram.
2B. Explain the different types of electronic transitions. 6 2 2

3A. What are the different types of NMR active nuclei? How many spin 10 2 2
orientations are possible in a magnetic field when I=1/2 and I=1. Give
examples.
3B. Calculate the concentration of a solution if it shows a transmittance of 4 2 2
20% when taken in a cell of 2.5cm thickness. (Molar absorption coefficient
is 12000 dm3mol-1cm-1).
10. 1A. Sketch the modes of vibration possible for HCl, CO 2 and H2O.Predict 10 2 2
the IR activity of each mode of vibration
1B. Write any four applications of NMR spectroscopy 4 2 2
2A How many vibrational modes are possible for the molecules CO, 8 2 2
NO,CO2, and H2O? Draw the vibrational modes of CO 2 and H2O and
explain their IR active modes.
2B. Each compound gives only one signal in its 1H-NMR spectrum. Propose 6 2 2
a structural formula for each a) C8H18 and b) C8H18O
3A Define Beer Lambert law and deduce the integrated form. Discuss the 8 2 2
plot of absorbance verses concentration, what does the slope of the graph
represents?

3B The CO molecule absorbs infrared radiation of wavenumber 2154 cm-1. 6 3 2


Calculate the force constant of the chemical bond, given that atomic masses
of C =12 amu and O=16 amu (Given that 1 amu = 1.66 x 10-27Kg)
11 1A Explain the principle of vibrational spectroscopy. Deduce the formula 10 2 2
for finding the fundamental vibrational frequency of a molecule.

1B How will you distinguish inter and intra molecular hydrogen bonding? 4 1 2

2A Write a note on magnetic resonance imaging (MRI). List applications of 8 2 2


it in medical diagnosis

2BPredict high resolution 1H NMR spectra of 1-Chloroethane and 2- 6 1 2


Chloropropane.

3A Explain the principle of NMR spectroscopy. Which of the following 10 2 2


nuclei can have a presence in NMR spectrum?1) 16O8 2)13C6 and 3) 2H1.
Write the reason for your answer.
3B CHCl3 gives a singlet at 7.26 ppm while CH 3Cl shows singlet at 3.06 4 2 2
ppm in the 1H NMR spectrum. Give reason.

12 1A Draw the molecular orbital energy diagram of i) Ethene, ii) 1, 3- 10 2 2


butadiene iii)1,3,5-hexatriene and iv) benzene to explain their UV-Vis
absorption.
1B CHCl3 gives a singlet at 7.26 ppm, while CH3Cl shows singlet at 3.06 4 2 2
ppm in the1H NMR spectrum. Give reason.

2A Discuss the principle of IR spectroscopy. Arrive at the expression for 10 2 2


vibrationalenergy states of a diatomic molecule. Draw the potential energy
diagram.
2B An organic compound C3H6O contains a carbonyl group. How will its 4 2 2
NMRspectrum decide whether it is an aldehyde or a ketone?
3A How can we differentiate NMR spectrum of CH 3CH2Cl and CH3CHCl2 8 2 2
using the concept of spin-spin splitting.
3B Comment on various electronic transitions that are possible in the 6 2 2
following molecules 1)C2H6 2)CH3CH2OH and 3) 1,3-butadiene

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