SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.
Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
Sri Chaitanya IIT Academy.,India.
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT‐BTs JEE-MAIN Date: 22-12-2023
Time: : 03.00Pm to 06.00Pm GTM-02 Max. Marks: 300
KEY SHEET
PHYSICS
1) 2 2) 2 3) 3 4) 2 5) 3
6) 1 7) 1 8) 4 9) 1 10) 4
11) 1 12) 4 13) 1 14) 3 15) 4
16) 2 17) 4 18) 1 19) 2 20) 2
21) 6 22) 15 23) 4 24) 6 25) 2
26) 20 27) 363 28) 3 29) 5 30) 6
CHEMISTRY
31) 2 32) 1 33) 2 34) 3 35) 1
36) 4 37) 3 38) 4 39) 4 40) 3
41) 3 42) 4 43) 3 44) 1 45) 2
46) 2 47) 1 48) 4 49) 1 50) 2
51) 4 52) 3 53) 12 54) 8 55) 4
56) 42 57) 13 58) 2 59) 40 60) 3
MATHEMATICS
61) 4 62) 2 63) 2 64) 2 65) 1
66) 2 67) 1 68) 2 69) 3 70) 4
71) 1 72) 1 73) 2 74) 4 75) 4
76) 3 77) 2 78) 4 79) 3 80) 2
81) 1 82) 9 83) 5 84) 0 85) 4
86) 825 87) 1 88) 14 89) 3 90) 0
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 1
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
SOLUTIONS
PHYSICS
128 1000 g N 2 50 g
1.
100 100 100cm 3
50 50 50cm3
2n 2 19.6
2. Time taken by mango = 2 second
g 9.8
Distance = vt
5
6 2 3.33 m
18
3. Conceptual
4. Slope = a = - 5 = - μg
Acceleration of the body is the slope of the v-t graph
10
From the graph, slope of line 5
2
So deceleration is 5 m / s 2 5 / 10 0.50
k2 2
5. For a solid sphere ,
R2 5
9.8sin 30
a a 3.5 m / sec 2
2
1
5
Time of ascent is given by
v u at
0 1 3.5t
1
t s
3.5
Time of decent
1
t sec.
3.5
Due to symmetry of motion.
2
Total time, T 0.57 s
3.5
pr 3 M 1/2 L3/2 L3/2
6. T k 3/2 Dimensions of RHS 3/4
M 1/8 L0T 3/2
s MT
2
Dimensions of L.H.S Dimensions of R.H.S
option A
GM
7. The correct option is B
R
Gravitational potential at any inside point is given as
V
GM
2R 3
3R 2 r 2 . ….(i)
R 11GM
for r ,V
2 8R
M R
Subtracting potential due to cavity of mass M c and Rc
8 2
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 2
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
Gravitational potential at center is obtained by substituting r 0 in equation (i)
3GM c
2 Rc
M
3G
11GM 3GM c 11GM 8 V GM
V
8R 2 Rc 8R 2
R R
2
8. Conceptual
9. Conceptual
10. y A sin t
A A
Here, y , A sin t
2 2
5
So, t or
6 6
A
So, the phase difference of the two particles when they are crossing each other at y
2
5 2
in opposite directions are 1 2
6 6 3
mv 4 3
11. Pf 0 ˆj Pi mv0iˆ mv0 ˆj
2 5 5
Impulse acting on ball
4 1
J Pf Pi J mv0 i j
5 10
p p2 3 9
12. w 1 v2 v1 10 0.3 10
6 5
2 4 4
10 0.4
6
0.5 10 0.1
6
T2 T1
nR nR
5R 35
105 3.5
U n 105
2 nR 4
22 R
11 105
nc
nR
105 3.5 c
7
13. u1 u 2 v1.v2 0
u i gt j .u i gt j 0
1 2
14.
Taking torque about point C
T
60 20 50 80 100
2
3 T 100 800
300 N
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 3
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
15. xCM xdm
dm
x
1
x x 2 dx
xCM 0
x x dx
1
2
9
x CM m
20
v2 u 2
16. Area under a versus x gives
2
2
v2 10
45 v 10 m / s
2
17. 6 2 3 1 3 6 v
x is the maximum extension in the spring
1 1 1 1
9 1 200 x 2 312 6 2
2 2
2 2 2 2
1 e m1 m2 em1 m1 M
18. V2 u1 u2 Given & M >>m
m1 m2 m1 m2 m2 m
m2
e
m m 1 e u m1 u
m M or 2 0 V2
m 1 m2 2
M m1 1 2 1
m1
m1
1 1 8V V
V2 1 e u1 eu2 1 2V V 3V
3 3 3
19. In the general expression h 2T cos
rdg
r 2T 1
radius of curvature of meniscus formed so h = or R .
cos Rdg h
u2
20. Maximum range up the inclined plane Maximum range down the inclined
g (1 sin )
u2
plane The maximum possible distance between the two bullets after they hit
g (1 sin )
u2 u2 2u 2
the inclined plane d max , d max
g (1 sin ) g (1 sin ) g cos 2
21. Conceptual
22. r 2i 3 j F pk
r F 2 j 3 j pk
a 3 3
x3 5 x 5 3 15
b 2 2
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 4
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
23. 200 f m 1.5
300 f m 2.5
In solving m = 100kg
1 1 1
24. cos 2 cos 2 cos 2 1 cos 2 1
4 2 4
60 0 with z - axis 30 0 with x - y plane
at 3t
25. from figure, a cos 300 at and a sin 300 at tan 300
at at
v2 dv v t 3 2
at 3t or
1
3t v 2 3t , But at
dt
3t or 0
dv 3 tdt or v =
0 2
t
3
t 4 3t or t 3 4 Given t 22/3 s n 2
4
Fl 100 l 120l l l 100 10
26. e l1 l l2 l 1
Ay Ay Ay l2 l 120 12
11 11
Given l2 12 l1 l l1 l 10
l1
10 10
l
12l1 12 l 11l1 10 l l1 2 l l 1 x 2 10 x 20
2
1 1
27. Applying Bernoulli's theorem: P1 gh v 2 P2 0 (2v) 2
2 2
3 363
Putting the values, 4100 800{ v 2 10} v m / s x 363
2 6
28. Let x mole of the gas be dissociated, x moles of atomic becomes 2x moles of a
monatomic gas after dissociation.
3 5
Internal energy of n moles of an ideal gas = nRT for monatomic gas = nRT for
2 2
diatomic
gas so, (internal energy of 2x moles of monoatomic gas + internal energy of (4 –x) moles
3
of a diatomic gas) – internal energy of 4 moles of a diatomic gas = nRT given
2
2 x
3RT 5 RT 5 RT 3
4 x 4 RT on solving x = 3 moles
2 2 2 2
29. Taking disc element, the required volume is
5 R 3
R R
r 2 dy R y 2 dy
2
R/2 R/2
24
30. Applying conservation of energy between initial and final states
2 2
1 v 1 mg mg 6mg 2
2m k 2mg , Solving we get v 6m / sec
2 2 2 k k k
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 5
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
CHEMISTRY
31. Charcoal
1
32. Screening effect
Ionization Potential
33. Last electron enters into p - Orbital
34. Both A and R are true but R is not the explanation for A.
35. Only two optically inactive isomers
Br CONH2
1 COOH
4 2
5 3
6
36. CHO COCl
2
37. CO has a single structure i.e., resonance hybrid of the above three structures.
3
38. 2 nodes are possible for 3s orbit.
39. More the number of keto group more is the stability order.
Incase of II structure as the positive charge is present on adjacent carbons it is unstable.
Z2
40. E 2
n
r1 for H n 2
rn =
rn n 2
Z
nh 2h
mvr
2 2
h
V
ma0
1
K .E mv 2
2
h2
32 2 ma02
41. 8 mole atoms – 1 mole
0.25 mole atoms ?
0.25 1
3.125 102
8
42. Equivalent weight is not fixed
43. Conceptual
44. Conceptual
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 6
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
45.
46. Hoffmann elimination followed by reductive ozonylysis.
1
47. Heat of combustion Stability
48. In order of generate electrophile HNO3 acts as base.
49.
50. Pd / BaSO4 is for syn addition
Br
2
1
3
5
4
51. Cl 7
52. E2 Elimination
53. Cr24 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 5 4s1
For s - orbital electrons l m 0
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 7
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
2 2 2 2 2 1 1 = 12
56.14 0.347
54. 1
161.4 0.347
43.86 2.4366
7
18 0.347
x 1, y 7
x y 1 7 8
55. C4 H10 48 10 58
1000 13
32 3.586 kg 4 kg
58 2
12.6
Optical purity = 100 42%
56. 30
PV PV
57. 1 1
2 2
T1 T2
760 V1 749 13 22.4
273 290
760 V1 736 22.4
273 290
736 273
V1 22.4
760 290
V1 0.96842 0.9413 22.4
0.911 22.4
28 20.42
%N
22, 400 wt.of organic sample
28 20.42
224 0.2
28 20.42 14 20.42
224 0.2 224
12.76
=13
58. Conceptual
59. H 2 H P H R (Enthalpy of product-enthalpy of reaction)
= 10 50
=40
60. A
O3 / H 2O
Aldehyde
on. vap
A 448 mL at STP
Cholorocompound 1.53g
As A undergoes ozonolysis so A is unsaturated Let A is Cn H 2n1Cl
A vapour
1.53 g 448 mL at STP
1.53
22400 22400 mL = 76.5g n = 3
448
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 8
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
MATHEMATICS
61. tan 1 sin cot 1 cos sin cos
2
2 sin cos 2, 2
n
1 1 1
n 1 n 2 n 22 n 2k 1
62. lim ....
n n n
n n
1
1 1 1 1 1 k 1
e
1 2 ..... k 1 2 21 k
e 2 2 2
e 2
1
1
2
1
1 x 2 2
63. f 1 x e x e . x3
2 x
2 1 2 1
x 1 1 2
3
1 2
x e 3 e 2 3 x
x x2 4
f 11
e x e
x2
2 x 2 2
x
1
1 1 x2 4 6
f 11 x e x e x6 x4
4x 4x x
x 1
e 1 x 2 2 2 1
f 11 x 1 e 4 3 2 , 2
4x x x x 4
64.
x y
Equation of L is 1
2 4
2x y 4 0 1
1
Equation of L1 is y – 1 = x 2
2
2y 2 x 2
x 2y 4 0 2
Solving 1 & 2 ,
4 12
5 5
65. Projection of OA on (4, 3, 0) ; (0, 4, 0)
12 12
The SD is equal to
4 3 2 2 5
66. Any point 2 1,3 2,6 3
Given 4 2 9 2 36 2 9
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 9
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
3
49 2 9
7
g x x 1
67. fog x x 3 x
f g x
2
x 1 3 x 1 5
f x x 2 3x 5
f 0 5
1 1 1 0 0 1
1 1
68. A 4 6 8 2 2 8 2 A
2
100 100 99 0 1 99
Adj 2 A 2 A 2 A 23 A
2
1 1
23 A 23 A
2
26. 23 16 4 12
4 2
69. Use 0 & 3 0
1 2 3
4 3 4 0 3 16 2 4 32 3 16 24 0
8 4
3 16 8 64 24 0
72
5 72 0
5
1 2 3
4 3 4 0 27 3 16 2 36 4 32 3 16 24 0
8 4 9
21
5 21 0
5
70. 1 t .2 0
1 2
Taking dot with
. .1 .2
2
4 6 20 .t 0 10 t
1
10 t 16 9 25 t
5
1 1
2 2
5 5
i 2 j 4k 15 4i 3 j 5k 9i 135j 15k
5 . i j k 9i 13 j 15k . i j k 9 13 15 7
2
71. {x+b} = {x} where b is an integer
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 10
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
1000
x
x b 1000 x
x
b 1 1000 1000
x x x
72.
Statement 2 is a property of an A.P so it is true.
a1 a 4 a7 a16 147
a1 a16 a4 a13 a7 a10 147
3 a1 a16 147 a1 a16 49
a1 a6 a11 a16 a1 a16 a6 a11 2 a1 a16 98
73.
x 1 x 0
1 x 0 x 1
74. f x
x 1 x 2
1 x 2 x 3
Clearly f is discatinuous at x 0,1,2 no.of points = 3
75. Conceptual
76. A (1, 0, 7) B (1, 6, 3)
Midpoint of AB= (1, 3, 5) lies in the line
DR’s of AB (0, 6, -4) the line passing through A and B is perpendicular to the given line
hence B in the mirror image.
Statement II is also true but not a correct explanation of I as there are infinitely many
lines passing through the midpoint of the line segment and one of the lines is
perpendicular bisector
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
77.
x f x
78. f Put x y 1
y f y
f x h f x
f 1 x lt
h0 h
f x h xh
1 f 1
f x x
f x . lt f x . lt
h0 h h 0 h
h
f 1 f 1
f x f x 1 2 f x
. lt
x
. f 0 f 1 1 2
x h0 h x x
x
79. lt f 2 h f 2
h 0
lt a 14 2 h 48 3 22
h 0
a 14 45
a 2011
80. AT A and B T B
A B A B A B A B
A2 AB BA B 2 A2 AB BA B 2
AB BA
AB 1 AB
T K
BT AT 1 AB
K
BA 1 AB
K
AB 1 AB
K
K is odd
4 cos 3 3cos cos 3
81. 4 cos 2 3
cos cos
0 0 0 0
cos 27 cos 81 cos 243 cos 729 cos 7290
ꞏ ꞏ ꞏ 1
cos 90 cos 27 0 cos 810 cos 2430 cos 9 0
82. We have x > 1
1
log8 x 2 x 2.log 1 x 1 0
3 2
1 1
log 2 x x 2 log 2 x 1 0
2
3 3
log 2 2 log 2 x 2 x 6.log 2 x 1 0
2 x 1 2 x 1
6 5
log 2 1 1
x x 1 x
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 12
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
Put x – 1 = y as y > 0
2 y5 2 y5 y 1 2 y5 2 y y 1
1 0 0 0
y 1 y 1 y 1
2 y y 4 1 y 1
0
y 1
2 y y 2 1 y 2 1 y 1 2 y y 1 y 2 1 1
0 y 1 0
y 1 y 1
y 1 2 y y 2 1 y 1 1 y 1
0 0 y 1 0
y 1 y 1
y 1 x 2
83. f x 3x 2 3 0 f x is increasing
a
f 3 27 f 0 3; a 1 r 3
1 r
2
a 2 81 a9 r
3
84. Let p x a0 x4 a1 x3 a2 x2 a3 x a4
p1 1 0 p1 2 0
p x 1
Also lim 2
1 a4 0, a3 0 and a 2 1, a1 1, a0
x0 x 4
1 4
p x x x3 x 2 p 2 0
4
85.
3 1 5 2 7 3 9 4 11 5 13 6 15 7
86.
17 8 19 9 2110
10
2r 1 r 825
r 1
87. f 1 1
f 2 f f 1 f 2 f 1 f 1 f 1 2
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 13
SRI CHAITANYA IIT ACADEMY, INDIA 22‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐02_KEY &SOL’S
f 3 f f 2 f 3 f 2 f 2 f 1
2+1 = 3
1 20 1
Thus f n n f r 1 2 3 ...... 20
30 r 1 30
1 20 21
. 7 1
30 2 7
x 2 y 1 z 6
88. Lines are
3 2 2
x 6 y 1 z 8 c a b d
S.D
3 2 0 bd
b 3iˆ 2 ˆj 2kˆ, d 3iˆ 2 ˆj a 2iˆ ˆj 6kˆ, c 6iˆ ˆj 8kˆ
4 2 14
3 2 2
3 2 0 16 12 168 196
14
ˆi ˆj kˆ 4iˆ 6 ˆj 12kˆ 14
3 2 2
3 2 0
Tr 1 1 1 1 1
T1 a; T2 a T3 2 a..........T7 6 a
89. Tr 3 3 3 3
a 1
6
a3
3 243
a a a2 32 1
Tr Tr 1 r 1 r 2 r 1 2 r 1 2 r 3
3 3 3 3 3
1 1 1
r 1
Tr .Tr 1 3 3 5 ........
3 3 3
3 27
3.375
1 8
1 2
3
3
2x 1
Lt f x Lt x
sin x log 2 log 1 x log 4
x 0 x 0 2
90. log 2 .log 4
x log 2 x 2 log 4
log 2
3
1
log 2
log 2 2 log 2 2
1
log 2 0
2
Sec: Sr.Super60_ Elite, Target & LIIT‐BTs Page 14
