1.
2 TEST MARK SCHEME
1. (a) H+(aq) + OH-(aq) à H2O(l) 1
(b) Ba2+(aq) + SO42-(aq) à BaSO4(s) 2
[3]
2.
(a) simplete ratio of atoms of each element in a compound (1) 1
average mass of ' entity
12
(b) mass of one atom of C (1) × 12 (1)
(or definition in terms of moles) 2
174
(c) CHO = 29 29 = 6 (1)
C6 H6 O6 (1) 2
3
(d) CH4O+ 2 O2 CO2+2H2O (1) 1
[6]
3.
mass 100
(a) (i) Mr 61 (1) = 1.64(1)
allow 1.63 to 1.64
PV = nRT (1)
nRT 3 1.64 8.31 400
V= P 100 000 (1) if no × 3 CE
allow use of p = 100 if answer in dm3
3
= 0 .1 6 4 m
(1)
allow 0.162 to 0.166
allow conseq on moles CH2NO2 5
T2 1000
0.164
(ii) V = V1 × T1 400 (1)
allow conseq on vol of gas products in (i)
= 0.410 (m3) (1)
allow 0.4 to 0.42
nRT 3 1.64 8.31 1000
V
or P 100 000 (1) or (for 1st mark)
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10
Thus if ans = ans to (i) × 4 allow 2 marks ignore units
allow conseq on moles CH3NO2 and on omission of 3 2
nRT
P
(b) (i) V (or pV = nRT) (1)
mass 153 103
n 9000
Mr 17 (1)
9000 8.31 800
P
3 (1)
= 1.99 × 107 Pa (1) (allow 1.99 to 2.00) 4
1000
(ii) 1.99 × 107 × 800 = 2.49 × 107 Pa (1)
(allow conseq) 1
9000
(iii) 1000 = 9.0 mol dm–3 (or M)
(1) (1) 2
[14]
4.
(a) % 0 = 100 – 25.9 = 74.1 (1)
wrong % AE –1
25.9 74.1
:
N : O = 14 16 (1)
= 1 : 2.5
N2O5 (1)
NO3 gains first two marks probably 3
1
(b) N2O5 2NO2 + 2 O2 (1)
allow × 2
if (d) is NO3
1
allow NO3 NO2 + 2 O2
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or × 2 1
[4]
Mill Hill High School 3
5.
(a) ratio NaCl : Na2CO3 = 2 : 1 (1)
mass ratio NaCl : Na2CO3 = 117 : 106 = 1 : 106/117 (1)
546 kg NaCl produces 546 × 106/117 (1)
= 495 kg Na2CO3 (unit required) (1)
or
moles NaCl = 546000/58.5 = 9333 (if 9.33, allow 3 max) (1)
moles NaHCO3 = moles NaCl = 9333 (1)
moles Na2CO3 = ½ moles NaHCO3 = ½ × 9333 = 4667 (1)
mass Na2CO3 = 4667 × 106 = 495 kg (unit required) (1)
or
mass ratio NaCl: NaHCO3 = 58.5 : 84 (1)
mass NaHCO3 = 546 × 84/58.5 = 784 kg (1)
mass ratio NaHCO3 : Na2CO3 = 168 : 106
mass Na2CO3 = 784 × 106/168 (1)
= 495 kg (unit required) (1) 4
(b) 0.537 g in 100 cm3 scaled to 5.37 g dm–3(1)
5.37/106 = 0.0507 mol dm–3
allow 2-4 sig. figs, condone truncation (1) 2
2
0.0454
(c) moles CO2 = moles Na2CO3 = 44 (1)
allow 0.045 to 0.046
moles in 1000 cm3 = 0.0454 × 5 = 0.227 (mol dm–3) (1)
allow 0.22 to 0.23
2nd mark allow conseq moles (from first melting point) × 5
units not essential, penalise wrong units (1 mark) 2
[8]
Mill Hill High School 4
5. (a) moles NaOH used = vol / 1000 × (1) = 21.7 (if uses 25 here only scores
first of first 4 marks)/ 1000 × 0.112
= 0.00243 (1) (consider 0.0024 as an arithmetic error loses 1
mark)
(range 0.00242 to 0.00244)
moles HCl in 25 cm3 = 0.00243 (1) (or 1 mol HCl reacts with 1 mol NaOH)
moles of HCl in 250 cm 3 = 0.0243 (1)
moles ZCl4 = 0.0243 / 4 = 0.006075 (1) (or 0.006076 or 0.006 mark is for /
4)
Mr = mass / no. Moles (1) (method mark also 1.304 / 0.006075)
= 214.7 (1) (or 0.006 gives 217) (allow 214 to 215)
Ar = 214.7 - 142 = 72.7 (1) (217 gives 75, 142 is 35.5 × 4)
Therefore element is Germanium (1) (allow conseq correct from Ar)
(75 gives As)
If not / 4 C.E. from there on but can score 2 independent marks for (mass /
moles / method and identity of element)
(for candidates who use m1v1 = m2v2 and calculate [HCl] = 0.0972 allow 1st 3
marks
if 25 and 21.7 wrong way round only award 1/3)
[9]
(b) Moles Cu = 1.25 / 63.5 = 0.0197 to 0.020 (1)
Moles NO = 2/3 × 0.0197 = 0.0131 (1)
PV = nRT
V = nRT/P = 0.0131 × 8.31 × 330 / 98000 (1)
Allow “n” consequentially to moles NO but not moles Cu
V = 3.67 × 10–4 (1)
units m3 (1)
or equivalent
[15]
Mill Hill High School 5
