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UMEED BATCH
MOLE CONCEPT
1. The number of atoms in 4.25 g of NH3 is approximately:
(A) 1 × 1023 (B) 1.5 × 1023
23
(C) 2 × 10 (D) 6 × 1023

2. Which of the following contains maximum number of atoms?

(A) 4 g of H2 (B) 16 g of O2
(C) 28 g of N2 (D) 18 g of H2O

3. Number of neutrons present in 1.7 g of ammonia is –

(A) NA (B) NA/10 × 4
(C) (NA/10) × 7 (D) NA × 10 × 7

4. Elements A and B form two compounds B2A3 and B2A. 0.05 moles of B2A3 weigh 9.0 g and 0.10
mole of B2A weigh 10 g. Calculate the atomic weight of A and B.
(A) 20 and 30 (B) 30 and 40
(C) 40 and 30 (D) 30 and 20

5. If 3.01 × 1020 molecules are removed from 98 mg of H2SO4, then the number of moles of H2SO4 left
are:
(A) 0.1 × 10–3 (B) 0.5 × 10–3
–3
(C) 1.66 × 10 (D) 9.95 × 10–2

6. A gas is found to have the formula (CO)x. It's VD is 70. The value of x must be:
(A) 7 (B) 4
(C) 5 (D) 6

7. A hydrocarbon contains 80% of carbon, then the hydrocarbon is-

(A) CH4 (B) C2H4
(C) C2H6 (D) C2H2.

8. The simplest formula of a compound containing 50% of element X (atomic wt. = 10) and 50% of
element Y (atomic wt. = 20) is:
(A) XY (B) X2Y
(C) XY2 (D) X3Y

9. 2.2 g of a compound of phosphorous and sulphur has 1.24 g of 'P' in it. Its empirical formula is:
(A) P2S3 (B) P3S2
(C) P3S4 (D) P4S3

10. Insulin contains 3.4% sulphur; the minimum molecular weight of insulin is:
(A) 941.176 (B) 944
(C) 945.27 (D) None
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11. Caffeine has a molecular weight of 194. It contains 28.9% by mass of nitrogen. Number of atoms of
nitrogen in one molecule of it is:
(A) 2 (B) 3
(C) 4 (D) 5

12. The number of litres of air required to burn 8 litres of C2H2 is approximately:
(A) 40 (B) 60
(C) 80 (D) 100

13. If 0.5 mol of BaCl2 is mixed with 0.2 mol of Na3PO4, the maximum number of moles of Ba3(PO4)2
that can be formed is:
3BaCl2 + 2Na3PO4 → Ba3(PO4)2 + 6NaCl
(A) 0.7 (B) 0.5
(C) 0.3 (D) 0.1

14. For the reaction A + 2B → C, 5 mol of A and 8 mol of B will produce

(A) 5 mole of C (B) 4 mole of C
(C) 8 mole of C (D) 13 mole of C

15. Molecular weight of tribasic acid is W. Its equivalent weight will be:
(A) W/2 (B) W/3
(C) W (D) 3W

16. 0.45 g of acid (molecular wt. = 90) was exactly neutralised by 20 mL of 0.5 N NaOH. Basicity of the
acid is:
(A) 1 (B) 2
(C) 3 (D) 4

17. 0.126 g of an acid requires 20 mL of 0.1 N NaOH for complete neutralisation. Equivalent weight of
the acid is:
(A) 45 (B) 53
(C) 40 (D) 63

18. If 1.2 g of a metal displaces 1.12 L of hydrogen at NTP, equivalent mass of the metal would be:
(A) 1.2 × 11.2 (B) 12
(C) 24 (D) 1.2 + 11.2

19. The atomic weight of a metal (M) is 27 and its equivalent weight is 9, the formula of its chloride will
be:
(A) MCl (B) MCl2
(C) M3Cl (D) MCl3

20. 5 L of gas at STP weighs 6.25 g. What is its gram molecular weight?
(A) 1.25 (B) 14
(C) 28 (D) 56

21. 0.44 g of a colourless oxide of nitrogen occupies 224 mL at STP. The compound is
(A) N2O (B) NO
(C) N2O4 (D) NO2

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22. Which one of the following pairs of compound illustrate the law of multiple proportions?
(A) H2O, Na2O (B) MgO, Na2O
(C) Na2O, BaO (D) SnCl2, SnCl4

23. The law of conservation of mass holds good for all of the following except
(A) All chemical reactions (B) Nuclear reactions
(C) Endothermic reactions (D) Exothermic reactions

24. If law of conservation of mass was to hold true, then 20.8 g of BaCl2 on reaction with 9.8 g of H2SO4
will produce 7.3 g of HCl. Determine the weight of BaSO4 produced.
(A) 11.65 g (B) 23.3 g
(C) 25.5 g (D) 30.6 g

25. Specific heat of a solid element is 0.1 Cal g–1 °C and its equivalent weight is 31.8. Its exact atomic
weight is –
(A) 31.8 (B) 63.6
(C) 318 (D) 95.4

26. A sample of ammonium phosphate (NH4)3PO4 contains 3.18 moles of hydrogen atoms. The number
of moles of oxygen atoms in the sample is
(A) 0.265 (B) 0.795
(C) 1.06 (D) 4.00

27. The total number of electrons in 1.6 g of CH4 to that in 1.8 g of H2O is
(A) Double (B) Same
(C) Triple (D) One fourth

28. An element, X has the following isotopic composition 200X : 90% 199X : 8% 202
X : 2.0%. The
weighted average atomic mass of the naturally occurring element X is closest to
(A) 201 amu (B) 202 amu
(C) 199 amu (D) 200 amu

29. Two metallic oxides contain 27.6% and 30% oxygen respectively. If the formula of the first oxide is
X3O4, that of the second will be
(A) XO (B) XO2
(C) X2O5 (D) X2O3

30. Haemoglobin contains 0.334% of iron by weight. The molecular weight of haemoglobin is
approximately 67200. The number of iron atoms (Atomic weight of Fe is 56) present in one molecule
of haemoglobin is
(A) 4 (B) 6
(C) 3 (D) 2

31. Calculate the molality of solution containing 3 g glucose dissolved in 30 g of water. (molar mass of
glucose = 180)
(A) 0.50 m (B) 0.56 m
(C) 0.091 m (D) 0.05 m

32. How many grams of NaOH should be added to water to prepare 250 ml solution of 2 M NaOH?
(A) 9.6 × 103 (B) 2.4 × 103
(C) 20 (D) 24

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33. The total number of electrons in 4.2 g of N3– ion is (NA is the Avogadro’s number)
(A) 2.1 NA (B) 4.2 NA
(C) 3 NA (D) 3.2 NA

34. The number of electrons in 1.6 g of CH4 is approximately

(A) 25 × 1024 (B) 1.5 × 1024
(C) 6 × 1023 (D) 3.0 × 1024

35. Number of Fe atoms in 100 g Haemoglobin if it contains 0.33% Fe. (Atomic mass of Fe = 56)
(A) 0.035 × 1023 (B) 35
(C) 3.5 × 1023 (D) 7 × 108

36. The amount of zinc required to produce 1.12 ml of H2 at STP on treatment with dilute HCl will be
(A) 65 g (B) 0.065 g
(C) 32.5 × 10–4 g (D) 6.5 g

37. Volume of CO2 obtained at STP by the complete decomposition of 9.85 g Na2CO3 is
(A) 2.24 litre (B) Zero
(C) 0.85 litre (D) 0.56 litre

38. An organic compound containing C and H gave the following analysis C = 40%, H = 6.7%. Its
empirical formula would be
(A) CH4 (B) CH2O
(C) C2H4O2 (D) C2H4

M M
39. When 100 ml of H2SO4 is mixed with 500 ml of NaOH then nature of resulting solution and
10 10
normality of excess of reactant left is
N N
(A) Acidic, (B) Basic,
5 5
N N
(C) Basic, (D) Acidic,
20 10

40. Mole fraction of solvent in aqueous solution of NaOH having molality of 3 is

(A) 0.3 (B) 0.05
(C) 0.7 (D) 0.95

41. 6.025 × 1020 molecules of acetic acid are present in 500 ml of its solution. The concentration of
solution is
(A) 0.002 M (B) 10.2 M
(C) 0.012 M (D) 0.001 M

42. Equivalent weight of crystalline oxalic acid is

(A) 90 (B) 63
(C) 53 (D) 45

43. Equivalent mass of H3PO4 (Molar mass = M) for the given reaction, H3PO4 + Ca(OH)2 → CaHPO4 +
2H2O is

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M M
(A) (B)
1 2
M
(C) 2 M (D)
4

44. The density of 2 M aqueous solution of NaOH is 1.28 g/cm3. The molality of the solution is [Given
that molecular mass of NaOH = 40 g mol–1]
(A) 1.32 m (B) 1.20 m
(C) 1.56 m (D) 1.67 m

45. The number of moles of hydrogen molecules required to produce 20 moles of ammonia through
Haber's process is :
(A) 10 (B) 20
(C) 30 (D) 40

46. A mixture of gases contains H2 and O2 gases in the ratio of 1 : 4 (w/w). What is the molar ratio of the
two gases in the mixture?
(A) 2 : 1 (B) 1 : 4
(C) 4 : 1 (D) 16 : 1

47. Mole fraction of the solute in a 1.00 molal aqueous solution is

(A) 1.7700 (B) 0.1770
(C) 0.0177 (D) 0.0344

48. How many grams of CH3OH should be added to water to prepare 150 ml solution of 2 M CH3OH?
(A) 9.6 × 103 (B) 2.4 × 103
(C) 9.6 (D) 2.4

49. Change in volume when 100 mL PH3 decomposed to solid phosphorus and H2 gas.
(A) Increase in 50 mL (B) Decrease in 50 mL
(C) Increase in 150 mL (D) Decrease in 200 mL

50. In the reaction, 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l), when 1 mole of ammonia and 1 mole of O2
are made to react to completion
(A) All the oxygen will be consumed (B) 1.0 mole of NO will be produced
(C) 1.0 mole of H2O is produced (D) All the ammonia will be consumed

51. The volume of 0.1 N dibasic acid is sufficient to neutralize 1 g of a base that furnishes 0.04 mol of
OH– in aqueous medium is:
(A) 400 mL (B) 600 mL
(C) 200 mL (D) 800 mL

52. A sample of a hydrate of barium chloride weighing 61g was heated until all the water of hydration is
removed. The dried sample weighed 52g. The formulae of the hydrated salt is: (atomic mass, Ba=137
amu, Cl = 35.5 amu)
(A) BaCl.H2O (B) BaCl2.2H2O
(C) BaCl2.3H2O (D) BaCl2.4H2O

53. Iron pyrite, FeS2 (molar mass of Fe: 56 g mol–1) is converted into ferric oxide and sulphur dioxide.
The mass of residue left behind from 1.08 g iron pyrite ignited to a constant mass in air would be

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(A) 0.72 g (B) 0.85 g

(C) 0.54 g (D) 0.46 g

54. The volume of concentrated sulphuric acid (98 mass % H2SO4, density 1.84 g cm–3) required to
prepare 5 dm3 of 0.5 mol dm–3 solution of sulphuric acid is
(A) 68 cm3 (B) 136 cm3
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(C) 204 cm (D) 272 cm3

55. The volume of concentrated hydrochloric acid (density : 1.20 g mL–1) containing 36.5 mass percent
of HCl required for preparing 2L of 0.1 M hydrochloric acid solution is about
(A) 15.4 mL (B) 16.7 mL
(C) 17.5 mL (D) 22.5 mL

56. A 25.0 mm × 40.0 mm piece of gold foil is 0.25 mm thick. The density of gold is 19.32 g/cm3. How
many gold atoms are in the sheet? (Atomic weight: Au = 197.0)
(A) 7.7 × 1023 (B) 1.5 × 1023
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(C) 4.3 × 10 (D) 1.47 × 1022

57. 1 g mixture of equal number of mole of Li2CO3 and other metal carbonate (M2CO3) required 21.6 mL
of 0.5 N HCl for complete neutralization reaction. What is the approximate atomic mass of the other
metal?
(A) 25 (B) 23
(C) 51 (D) 118
58. Specific volume of cylindrical virus particle is 6.02 × 10–2cc/g. whose radius and length are 7Å &
10Å respectively.
If NA = 6.02 × 1023mol–1, find molecular weight of virus
(A) 3.08 × 103 kg/mol (B) 3.08 × 104 kg/mol
4
(C) 1.54 × 10 kg/mol (D) 15.4 kg/mol

59. 10 moles SO2 and 15 moles O2 were allowed to react over a suitable catalyst. 8 moles of SO3 were
formed. The remaining moles of SO2 and O2 respectively are
(A) 2 moles, 11 moles (B) 2 moles, 8 moles
(C) 4 moles, 5 moles (D) 8 moles, 2 moles

60. What is the molarity of SO 24 − ion in aqueous solution that contain 34.2 ppm of Al2(SO4)3? (Assume
complete dissociation and density of solution 1g/mL)
(A) 3 × 10–4 M (B) 2 × 10–4 M
(C) 10–4M (D) None of these

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ANSWERS KEY

1. (D) 31. (B)

2. (A) 32. (C)
3. (C) 33. (C)
4. (C) 34. (C)
5. (B) 35. (A)
6. (C) 36. (C)
7. (C) 37. (B)
8. (B) 38. (B)
9. (D) 39. (C)
10. (A) 40. (D)
11. (C) 41. (A)
12. (D) 42. (B)
13. (D) 43. (B)
14. (B) 44. (D)
15. (B) 45. (C)
16. (B) 46. (C)
17. (D) 47. (C)
18. (B) 48. (C)
19. (D) 49. (A)
20. (C) 50. (A)
21. (A) 51. (A)
22. (D) 52. (B)
23. (B) 53. (A)
24. (B) 54. (B)
25. (B) 55. (B)
26. (C) 56. (D)
27. (B) 57. (D)
28. (D) 58. (D)
29. (D) 59. (A)
30. (A) 60. (A)

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