16th Swiss and Liechtenstein

Chemistry Olympiad
First round
Multiple Choice : 32 Questions

Duration : 40 minutes

Questions : - Multiple Choice Questions (MC)

- Multiple True False Questions (MTF)

Grading : Each fully correct reply is worth one point.

Aids and tools : All aids are allowed (Text books, calculators,
periodic table, etc.). However, the test has to be
solved on one’s own without the help from others.

Participation conditions : - born on or after 1st of Juli 2002

(according to IChO) - not yet immatriculated at an university
- attending a Swiss school (now or previously)

Due date : 9th of October 2021

Due address : Wissenschafts-Olympiade

Universität Bern
Hochschulstrasse 6
3012 Bern

Online participation is recommended. For the print version of the exams and
details regarding participation on paper, see chemistry.olympiad.ch/en/teachers

Good luck!
Question 1 (MC): Question 5 (MC):
What is the pH of an aqueous solution of Determine the right stoichiometric coeffi-
L HCl (pKa (HCl) � -6)?
0.67 mol cients for the following reaction:
n Al(OH)3 + m H2 SO4 → x Al2 (SO4 )3 +
A 0.67 y H2 O
B 13.1
A n: 2, m: 3, x: 1, y: 6
C 0.17
B n: 2, m: 6, x: 2, y: 6
D -6.3
C n: 1, m: 3, x: 1, y: 3
E 0.63
D n: 1, m: 6, x: 1, y: 3
Question 2 (MC): E n: 2, m: 6, x: 1, y: 3
Calculate the pH of an aqueous solution of
Question 6 (MC):
L acetic acid (pKa (AcOH) = 4.76).
2 mol
Determine the right stoichiometric coeffi-
A 2.38 cients for the following reaction:
B 4.76 a Na2 [B4 O7 ] + b SiO2 + c Na + d H2 →
C 2.46 x NaBH4 + y Na2 SiO3
D 2.23 A a: 2 , b: 7 , c: 16 , d: 16
E -3.0 B a: 1 , b: 7 , c: 16 , d: 8
Question 3 (MC): C a: 1 , b: 7 , c: 16 , d: 16
Determine the oxidation number of all atoms D x: 8 , y: 1
in the following molecule: HCO3 − E x: 1 , y: 1

A H: +1 / C: -4 / O: +2, 0 Question 7 (MC):

B H: +1 / C: +2 / O: -1 How much PbSO4 (KL = 2.53 · 10−8 mol2
)
L2
C H: +1 / C: +4 / O: -2 can be dissolved in 2L of water?
D H: -1 / C: -4 / O: +2, 0
A 0.096 g
E H: -1 / C: +2 / O: -2
B 0.068 g
Question 4 (MC): C 0.048 g
Which is the right order representing the D 5.06 · 10−6 mol
strength of the following acids: E 5.06 · 10−8 mol
HBr, HI, HCl, HF?
Question 8 (MC):
A HI > HBr > HCl > HF
The yield of the following reaction is 20 % at
B HI > HCl > HF > HBr 2 bars and 290 K, what happens if we increase
C HCl > HF > HBr > HI the pressure?
D HF > HCl > HI > HBr CO2 + KOH − ← −
−→
− KHCO3
E HF > HCl > HBr > HI A The yield increases
B The reaction goes to completion
C Nothing
D No Product at all is formed
E The yield decreases

Chemistry Olympiad 2021/22 1 of 6 1st round

Question 9 (MC): Question 13 (MC):
Calculate the volume of 0.4 moles of PH3 at Which percentage of a 212 Bi sample has de-
31°C and 1.5 bars. cayed after 5 min (t1/2 = 3633 s)?

A 6.44 m3 A 0.1 %
B 148 m3 B 50 %
C 6.74 L C 5.6 %
D 0.69 L D 94 %
E 6.87 · 10−4 m3 E 9.1 %
Question 10 (MC): Question 14 (MC):
Calculate the energy of one photon at 460 nm. Which is the correct equation for an alpha
decay of 235 U?
A 4.32 · 10−8 kJ
A 235 U → 231 Th2− + 4 He2+
B 4.32 · 10−8 J
B 235 U → 231 Th +4 He2+ + energy
C 9.13 · 10−32 kJ
C 235 U → 231 Th +4 He
D 4.32 · 10−19 J
D 235 U → 231 Th +4 He + energy
E 3.04 · 10−31 J
E 235 U → 231 Th2− + 4 He2+ + energy
Question 11 (MC):
Question 15 (MC):
Which is the correct expression for the equi-
librium constant of the following reaction? In which mode of radioactive decay does 99 Tc
4 NH3 + 5 O2 −
←−−→
− 4 NO + 6 H2 O decay into 99 Ru+ ?
[NO]−4 [H2 O]−6
A K= [NH3 ]4 [O2 ]5
A Alpha decay
[NO]4 [H O]6 B Beta minus decay
B K= 2
[NH3 ]4 [O2 ]5
[NH3 ][O2 ]
C Electron capture
C K= [NO][H2 O] D Gamma decay
[NH3 ]4 [O2 ]5
D K= [NO]4 [H2 O]6 E Beta plus decay
[NO][H2 O]
E K= [NH3 ][O2 ] Question 16 (MC):
Question 12 (MC): The transmission of a 0.3 molar solution of
Sudan II (a red dye) is 0.2 at a wavelength of
Calculate the combustion enthalpy of propane 500 nm and a width of 1 cm. Calculate the
(the reaction of C3 H8 with oxygen): molar extinction coefficient at 500 nm.
Δf H(CO2 ) = -393.5 kJ/mol
L
Δf H(H2 O) = -241.8 kJ/mol A 2.33 mol · cm
Δf H(C3 H8 ) = -104.0 kJ/mol B 5.36 mol L· cm
A Δc H = -2043.7 kJ/mol C 0.67 mol L· cm
B Δc H = -2251.7 kJ/mol D 10.01 mol L· cm
C Δc H = -3288.7 J/mol E 0.0067 mol L· cm
D Δc H = -3288.7 kJ/mol
E Δc H = 2043.7 kJ/mol

Chemistry Olympiad 2021/22 2 of 6 1st round

Question 17 (MC): Question 20 (MTF):
The combustion of one mole of an organic Which assignments are true?
substance with 4.5 equivalents of oxygen pro-
duces solely 72 g H2 O and 132 g CO2 . What
is the sum formula of the organic substance?

A C 4 H6 O
B C 3 H8 O 2
C C 3 H8 O
D C 4 H8 O 2
E C 3 H8
Question 18 (MC):
Which of the following molecules contains a
mass percentage of phosphorous of 66 % and A II carboxylic acid
a mass percentage of oxygen of 34 %? B I ketone
C V amide
A PO2
D IV nitrile
B P4 O10
E III ether
C P 4 O6
D P 2 O2 Question 21 (MC):
E P 3 O4 Which ones are the right stereoindicators of
this compound?
Question 19 (MC):
According to IUPAC, what ist the name of
the following compound?

A 1R / 2R
B 1S / 2S
C 1R / 2S
D This compound has no chiral centers.
A 5-ethyl-2,4,7-trimethylnonane E 1S / 2R
B 2,4-diethyl-5,7-dimethyloctane
C 5-ethyl-3,6,8-trimethylnonane
D 5,7-diethyl-2,4-dimethylnonane
E 5,7-diethyl-2,4-dimethyloctane

Chemistry Olympiad 2021/22 3 of 6 1st round

Question 22 (MC): Question 24 (MC):
How many isomers are composed of C4 H7 ON Which is the correct order regarding the boil-
and contain the following motif? (Hint: As ing points of these substances?
you can see in the figure, no double bonds to
the nitrogen are allowed) A n-butane < propane < 1-butanol
< tert-butyl alcohol < butyric acid
B propane < n-butane < tert-butyl alcohol
< 1-butanol < butyric acid
C propane < n-butane < butyric acid
< tert-butyl alcohol < 1-butanol
D n-butane < propane < tert-butyl alcohol
< 1-butanol < butyric acid
E propane < n-butane < 1-butanol
< tert-butyl alcohol < butyric acid
A 17
B 12
C >19
D 7
E 3
Question 23 (MC):
What are the reaction types of the following
reactions?

A 1 – Elimination / 2 – Elimination /
3 – Substitution
B 1 – Substitution / 2 – Elimination /
3 – Addition
C 1 – Addition / 2 – Elimination /
3 – Substitution
D None of these options.
E 1 – Addition / 2 – Substitution /
3 – Elimination

Chemistry Olympiad 2021/22 4 of 6 1st round

Question 25 (MC): Question 26 (MTF):
How many of the following statements are Mark the correct statements (everything
true (see Figure below)? refers to the periodic table of elements).

• For the energy E given to the system A The electronegativity increases from the bot-
with boundaries EA,A < E < EA,B , the tom left to the upper right.
major product is A. B The size of atoms decreases from bottom to
top.
• When the energy given to the system
E > > EA,B the major product is A. C The size of the atoms increases from the left
to the right.
• When the energy given to the system D The ionisationation energy increases from
E = EA,A the major product is B. upper right to bottom left.
• When the energy given to the system E The number of valence electrons increases
E > > EA,B the major product is B. from the left to right.

• A catalyst that favours the reaction to Question 27 (MC):

product B, lowers the free energy of What reactant(s) is/are needed for this
product B. reaction?
• A catalyst does not change the free en-
ergy of product A.

• In general, a catalyst increases the acti-

vation energy.
A CHBr3
B Br2 / FeBr3
C HBr / H2 O
D This reaction is impossible.
E LiBr / NaBr (1:1)
Question 28 (MC):
Which of the following salts has the highest
absolute lattice energy? (Hint: Consider the
strenght of the ionic interaction)

A LiF
B NaBr
C CaO
D MgO
A 5 E NaCl
B 4
C 6
D 3
E 2

Chemistry Olympiad 2021/22 5 of 6 1st round

Question 29 (MTF): Question 32 (MC):
Which molecule(s) contain(s) a permanent Which of these statements is true?
dipole?
A If the activation energy increases, the reac-
A (CH3 )2 CO (acetone) tion deccalerates and less product is formed
B CH4 in equilibrium.
C CO2 B If the activation energy increases, the reac-
tion accalerates and more product is formed
D H2 O
in equilibrium.
E CO3 2−
C The activation energy only has an effect on
Question 30 (MC): the product formation and not on the forma-
tion of the educt in an equilibrium.
What is the name of [Pt(NH3 )4 ]Cl2 ?
D The activation energy does not have an effect
A Platinum(II) tetramino dichloride on the reaction rate and the product forma-
B Dichloride tetraaminoplatinum(II) tion in equilibrium
C Dichlorotetraamonium platinum E The activation energy only has an effect on
D Dichloro tetraaminoplatinum the reaction rate.
E Tetraaminoplatinum(II) chloride
Question 31 (MC):
What is the right geometry of IF4 + ?

A II
B IV
C This molecule doesn’t exist.
D I
E III

Chemistry Olympiad 2021/22 6 of 6 1st round