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C1100 Test

This document appears to be a mock exam for a general chemistry course consisting of 10 multiple choice questions covering various topics in thermodynamics including: [1] reversible processes; [2] internal energy; [3] calculation of enthalpy change (ΔH) and energy (ΔE) for chemical reactions using standard enthalpies of formation; [4] estimation of enthalpy change using bond energies; [5] calculation of heat required to melt ice using specific heats and heat of fusion; [6] calculation of change in entropy for a phase change; [7] calculation of work done by an ideal gas during an isobaric process; [8] calculation of change in entropy of surroundings; and

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44 views2 pages

C1100 Test

This document appears to be a mock exam for a general chemistry course consisting of 10 multiple choice questions covering various topics in thermodynamics including: [1] reversible processes; [2] internal energy; [3] calculation of enthalpy change (ΔH) and energy (ΔE) for chemical reactions using standard enthalpies of formation; [4] estimation of enthalpy change using bond energies; [5] calculation of heat required to melt ice using specific heats and heat of fusion; [6] calculation of change in entropy for a phase change; [7] calculation of work done by an ideal gas during an isobaric process; [8] calculation of change in entropy of surroundings; and

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Lebanese University

Faculty of Sciences
Department of Chemistry and Biochemistry
Hadath / Lebanon

General Chemistry / C1100


Fall 2015-2016
Mock Exam (30 min)

Name: _________________

Choose the correct answer:

1- Which of the following is a reversible process?


a) Melting of ice at 10oC and 1 atm
b) Evaporation of water at 100oC and 1 atm
c) Freezing of water at -10oC and 1 atm
d) Freezing of water at -25oC and 1 atm

2- The internal energy of a system


a) is the sum of the kinetic energy of all of its components
b) is the sum of the rotational, vibrational, and translational energies
c) refers only to the energies of the nuclei of the atoms of the component molecules
d) is the sum of the potential and kinetic energies of the components

3- In which of the following reactions will the value for ∆E be greater than that of ∆H?

a) CaCN2 (s) + 3H2O (l)  CaCO3 (s) + 2NH3 (g)


b) 3H2 (g) + N2 (g)  2NH3 (g)
c) UO2 (s) + 4HF (l)  UF4 (s) + 2H2O (l)
d) H2 (g) + I2 (g)  2HI (g)

4- Find the enthalpy of the following equation: C2H2(g) + 5/2 O2(g)  2CO2(g) + H2O(l)

Given the following information:


(1) 2C (graphite) + H2 (g)  C2H2 (g) ∆Hof = +226.7 kJ
(2) C (graphite) + O2 (g) CO2 (g) ∆Hof = -393.5 kJ
(3) H2 (g) + 1/2O2 (g)  H2O (l) ∆Hof = -285.8 kJ

a) -1230 KJ b) 1230 KJ c) -1299.5 KJ d) -869 KJ

5- Estimate the enthalpy of the equation: C2H2(g) + 5/2O2 (g)  2CO2(g) + H2O(l)
Bond energies are given below in kJ/mol.

C-C H-C H-O C=O C=C C=C O=O


347 414 464 803 611 837 498

a) -1230 KJ b) 1230 KJ c) -2475 KJ d) -869 KJ

1
6- Calculate the amount of heat (in kJ) required to melt 35.0 g of ice at 0oC.

Use the information in this table to answer the above question.


Specific heat of ice 2.09 J/g oC
Specific heat of water 4.18 J/g oC
Specific heat of steam 1.84 J/g oC
Heat of fusion of water ( Hfus) 6.01 kJ/mol

a) 3.09 kJ b)11.7 kJ c) 20.9 kJ d) 79.1 kJ

7- If the heat of vaporization of water is 539 Kcal/Kg, calculate the change in entropy of
1 Kg of water as it turns entirely to steam at 100 oC.

a)1.4 cal/K b) 14 cal/K c)140 cal/K d)1400 cal/K

8- In an isobaric process, calculate the net work done by an ideal gas of pressure, p,
which expands to three times its original volume, V.

a) 3P/V b) 2PV c) P/3V d)PV/3

9- Calculate the change in entropy of the surroundings (∆S surr) if a system absorbs 5.79
kJ of heat and the surroundings are at 95.7◦C.

a) 60.5 J/K b) – 60.5 J/K c) -15.7 J/K d) 15.7 J/K

10- Consider the reaction: FeO(s) + Fe(s) + O2(g) Fe2O3(s)

Given the following table of thermodynamic data at 298K:

Substa
ΔHof (kJ/mol) So(J/K mol)
nce
FeO(s) -271.9 60.75
Fe(s) 0 27.15
O2(g) 0 205
Fe2O3(s) -822.16 89.96

The value of K for the reaction at 25oC is:

-14 85 19
a) 3.8 x 10 b) 370 c) 7.1 x 10 d) 8.1 x 10

Good luck

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