Solution Objective Test

ENGLIS
TheHmolality of pure water is
1 (a) 55.5 (b) 50.5 (c) 18 (d) 60.5
2 The number of moles of NaCl in 3 litres of 3M solution is
(a) 1 (b) 3 (c) 9 (d) 27
3 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the resultant
solution is _____________.
(a) 0.004 (b) 0.008 (c) 0.012 (d) 0.016
4 Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ____________.
(a) low temperature (b) low atmospheric pressure
(c) high atmospheric pressure (d) both low temperature and high atmospheric pressure
5 Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will
show a positive deviation from Raoult’s law?
(a) Methanol and acetone. (b) Chloroform and acetone. (c) Nitric acid and water. (d) Phenol and aniline.
6 Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0 M NaOH (b) 1.0 M Na2SO4 (c) 1.0 M NH4NO3 (d) 1.0 M KNO3
7 In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl 2 solution
(a) the same (b) about twice (c) about three times (d) about six times
8 An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _____________.
(a) it gains water due to osmosis. (b) it loses water due to reverse osmosis.
(c) it gains water due to reverse osmosis. (d) it loses water due to osmosis.
9 Which of the following statements is false?
(a) Two different solutions of sucrose of same molality prepared in different solvents will have the same
depression in freezing point.
(b) The osmotic pressure of a solution is given by the equation ∏ = CRT (where C is the molarity of the solution).
(c) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium chloride,
acetic acid and sucrose is BaCl2 > KCl > CH3COOH > sucrose.
(d) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is directly
proportional to its mole fraction in the solution.
10 The value of Henry’s constant KH is _____________.
(a) greater for gases with higher solubility. (b) greater for gases with lower solubility.
(c) constant for all gases. (d) not related to the solubility of gases.
11

Consider the figure and mark the correct option.

(a) water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on piston (B).
(b) water will move from side (B) to side (A) if a pressure greater than osmotic pressure is applied on piston (B).
(c) water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on piston (B).
(d) water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on piston (A).
12 We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M, 0.01M and
0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the order _____________.
(a) iA < iB < iC (b) iA > iB > iC (c) iA = iB = iC (d) iA < iB > iC
13 A solution containing 10 g per dm3 of urea (molar mass 60 g mol–1) is isotonic with 5% solution of non-volatile
solute, MB of solute is
(a) 300 g mol–1 (b) 350 g mol–1 (c) 200 g mol–1 (d) 250 g mol–1
–3
14 Conc. H2SO4 is 98 % H2SO4 by mass has d = 1.84 g cm . Volume of acid required to make one litre of 0.1 M
H2SO4 is
(a) 5.55 mL (b) 10 mL (c) 20 mL (d) 30 mL
15 What is mole fraction of solute in 1.00 m aqueous solution?
 (a) 0.0354 (b) 0.0177 (c) 0.177 (d) 1.770
16 When 1 mole of benzene is mixed with 1 mole of toluene (vapour pressure of benzene = 12.8 kPa, Toluene = 3.85
kPa)
(a) The vapour will contain equal amount of benzene and toluene.(b) Not enough information is given for
prediction.
(c) The vapour will contain a higher percentage of benzene. (d) The vapour will contain higher percentage of
toluene.
17 At 100°C, the vapour pressure of a solution of 6.5 g of solute in 100 g of water is 732 mm. If Kb is 0.52 K/m, the
boiling point of solution will be
(a) 102°C (b) 103°C (c) 101°C (d) 100°C
18 Which of the following is incorrect for an ideal solution?
(a) ∆Hmix = 0 (b) ∆Vmix = 0 (c) ∆P = Pobs – Pcalculated = 0 (d) ∆Gmix = 0
19 If molality of dilute solution is doubled, the value of molal depression constant (K f ) will be
(a) halved (b) tripled (c) unchanged (d) doubled
20 The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atm
is (R = 0.082 L atom K–1 mol–1)
(a) 360°C (b) 180 K (c) 300 K (d) 360 K
21 Which has the highest freezing point?
(a) 1 M glucose (b) 1 M NaCl (c) 1 M CaCl2 (d) 1 M AlF3

22. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not
depend upon ____________.
(a) Temperature (b) Nature of solute (c) Pressure (d) Nature of solvent
23. On the basis of information given below mark the correct option. Information:
(i) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as
A–B type interactions.
(ii) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type
interactions.
(iii) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type
interactions.
(a) Solution (B) and (C) will follow Raoult’s law. (b) Solution (A) will follow Raoult’s law.
(c) Solution (B) will show negative deviation from Raoult’s law.
(d) Solution (C) will show positive deviation from Raoult’s law.
24. KH value for Ar(g), CO2(g), HCHO(g) and CH4(g) are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively. Arrange
these gases in the order of their increasing solubility.
(a) HCHO < CH4 < CO2 < Ar (b) HCHO < CO2 < CH4 < Ar
(c) Ar < CO2 < CH4 < HCHO (d) Ar < CH4 < CO2 < HCHO
° °
25. If P A = 100 mm, P B = 200 mm and mole fraction xA = 0.4, what will be yA (mole fraction) in vapour phase?
(a) 0.25 (b) 0.30 (c) 0.75 (d) 0.50
26. Which of the following is maximum boiling azeotropic?
(a) CH3COOH + C5H5N (pyridine) (b) H2O + ethanol (c) cyclohexane + ethanol (d) H2O + methanol

27.
Kb (molal elevation constant) is inversely proportional to
(a) boiling point of solvent (b) ∆vapH of solvent (c) Molar mas of solvent (d) All of these

28. Out of 1m solution of following dissolved in water. Which one will have lowest freezing point
(a) Urea (b) NaCl (c) Na2SO4 (d) Al2(SO4)3
29. Which of the following will have lowest vapour pressure? (Boiling points are given in brackets)
(a) H2O (373 K) (b) CHCl3 (334 K) (c) Anilines (457 K) (d) Benzene (353 K)
30. The pgas dissolved a liquid is directly proportional to its
(a) Mole fraction (b) Molar mass (c) B. P of liquid (d) Molar mass of solvent
31. Which of the following factor do not affect solubility of solid solute in liquid ?
a. Temperature (b) Pressure (c) Nature of solute (d) All of these
32. 18 g of glucose (C6H12O6) is added to 178.2 g of water. The vapour pressure of water for this
aqueous solution is
(a) 76.00 torr (b) 752.40 torr (c) 759.00 torr (d) 7.60 torr
33. Negative deviation from Raoult’s law is observed in which one of the following binary liquid
mixtures?
a. Ethanol and acetone b. Benzene and toluene c. Acetone and chloroform
d. Chloroethane and bromoethane

34. A solution of sucrose (molar mass = 342 g mol–1) has been prepared by dissolving 68.5 g of
sucrose in 1000 g of water. The freezing point of the solution obtained will be (Kf for water =
1.86 K kg mol–1).
(a) – 0.372°C (b) – 0.520°C (c) + 0.372°C (d) – 0.570°C
–3 –1 –1
35. Henry’s law constant of oxygen is 1.4 × 10 mol L atm at 298 K. How much oxygen will be
dissolved in 100 ml at 298 K when its partial pressure is 0.5 atm?
(a) 1.4 g (b) 3.2 g (c) 22.4 mg (d) 2.24 mg
36. Match the laws given in Column I with expresions given in Column II.
Column I Column II
(a) Raoult’s law (i) ∆Tf = Kf m
(b) Henry’s law (ii) ∏ = CRT
(c) Elevation of boiling point (iii)
(d) Depression in freezing point (iv) ∆Tb = Kbm
(e) Osmotic pressure (v) p = KH.x
37. Assertion: When methyl alcohol is added to water, boiling point of water increases.
Reason: When a volatile solute is added to a volatile solvent elevation in boiling point is observed
38. Assertion: When a solution is separated from the pure solvent by a semipermeable membrane, the
solvent molecules pass through it from pure solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration solution to a region of low
concentration solution.
39. Assertion : Molarity of a solution in liquid state changes with temperature.
Reason : The volume of a solution changes with change in temperature.
40. Assertion : If a liquid solute more volatile than the solvent is added to the solvent, the vapour
pressure of the solution may increase i.e., ps > po.
Reason : In the presence of a more volatile liquid solute, only the solute will form the vapours and
solvent will not.
41. Assertion : If one component of a solution obeys Raoult’s law over a certain range of composition,
the other component will not obey Henry’s law in that range.
Reason : Raoult’s law is a special case of Henry’s law
42. Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling
points either greater than both the components or less than both the components.
Reason : The composition of the vapour phase is same as that of the liquid phase of an azeotropic
mixture.
43. Assertion : When methyl alcohol is added to water, boiling point of water increases.
Reason : When a volatile solute is added to a volatile solvent elevation in boiling point is observed.
44. Assertion : When NaCl is added to water a depression in freezing point is observed.
Reason : The lowering of vapour pressure of a solution causes depression in the freezing point.
45. Assertion : When a solution is separated from the pure solvent by a semi- permeable membrane,
the solvent molecules pass through it from pure solvent side to the solution side
Reason : Diffusion of solvent occurs from a region of high concentration solution to a region of low
concentration solution.
.