General Parameter Identification Procedure and Comparative Study of Li-Ion Battery Models
General Parameter Identification Procedure and Comparative Study of Li-Ion Battery Models
Abstract—Accurate and robust battery models are required models is a trade-off between model complexity, parameter
for the proper design and operation of battery-powered systems. estimation effort, and accuracy.
However, the parametric identification of these models requires In general, battery models can be classified into three cate-
extensive and sophisticated methods to achieve enough accuracy.
This article shows a general and straightforward procedure, based gories: electrochemical, mathematical, and electrical. Electro-
on Simulink and Simscape of Matlab, to build and parameterize chemical models consist of a set of partial differential-algebraic
Li-ion battery models. The model parameters are identified with the equations along with a wide range of limitations [5], [6]. The
Optimization Toolbox of Matlab, by means of an iterative process to estimation of the electrochemical model is very accurate [7].
minimize the sum of the squared errors. In addition, this procedure However, simulation with these models can be time-consuming,
is applied to a selection of five different models available in the
literature for electric vehicle applications, obtaining a comparative since it requires to solve a complex set of equations to identify
study between them. Also, the performance of each battery model the electrochemical properties [8]. Mathematical models are an
is evaluated through two current profiles from two driven profiles alternative based on empirical formulas approaches [9], [10].
known as the Urban Driving Cycle (ECE-15 or UDC) and the These models are empirical functions with parameters derived
Hybrid Pulse Power Characterization (HPPC). The experimental from datasheet or from static measurements and use a fewer
results obtained from a Li-ion polymer battery have been compared
with the data provided by the models, confirming the effectiveness number of equations. However, these models cannot represent
of the proposed procedure, and also, the application field of each the dynamic information correctly and provide inaccurate results
model as a function of the required accuracy. in the order of 5%–20% error. Finally, circuit-based or electri-
Index Terms—ECE15, HPPC, Li-ion battery models, Matlab, cal models are able to accurately exhibit the current-voltage
parameter estimation, Simscape, Simulink. characteristics of the batteries while maintaining simulation
efficiency. The accuracy of these electrical models lies between
I. INTRODUCTION electrochemical and mathematical models [11]. These models
N RECENT years, rechargeable batteries are playing an are based on resistors and capacitors connected to controlled
I essential role as energy storage and as power sources for
some electrical systems such as communications systems, re-
voltages sources, and they can represent the fast dynamic of the
battery with a high level of accuracy [12].
newable power systems, electric vehicles, electric buses, etc. In the literature, several papers develop a comparative study
[1], [2]. Lithium-ion batteries are being an essential technology among different models. So, [13] shows a systematic review of
in powertrain electrification of hybrid electric vehicles (HEV) ten models, using nonlinear identification technique with the
and pure electric vehicles (EV), which allow reducing fuel dual Extended Kalman Filter (dual-EKF). This paper concludes
consumption and decreasing greenhouse gas emissions [3]. This the RC model provides the best dynamic response and accuracy.
kind of battery presents some performances very suitable for In addition, [14] examines eleven electrical circuits models in
transportation applications, such as high energy/power density which parameters are estimated with a genetic algorithm (GA),
ratio, slow self-discharge, high cycle life and lack of hysteresis and it concludes that the higher and constant RC networks
effect in some of them [4]. have better robustness considering parameter variations and
In the state-of-the-art, numerous battery models have been sensor errors.
reported for system-level modeling. Choosing between those The main contribution of this paper is the proposal of a general
and straightforward offline-procedure in order to estimate the
Manuscript received February 14, 2019; revised June 30, 2019 and October 2, battery model parameters. The identification method is based on
2019; accepted October 27, 2019. Date of publication November 11, 2019; date the interface of MATLAB System Identification Toolbox, which
of current version January 15, 2020. This work was supported by the Ministry uses numerical optimization to minimize the error between the
of Economy and Competitiveness and FEDER funds through the research
project “Storage and Energy Management for Hybrid Electric Vehicles based measured and the estimated battery voltage. In order to verify the
on Fuel Cell, Battery, and Supercapacitors”—ELECTRICAR-AG-(DPI2014- identification procedure, a comparative analysis of the most used
53685-C2-1-R). The review of this article was coordinated by Prof. M. Preindl. battery models for electric vehicle applications is performed.
(Corresponding author: Henry Miniguano.)
The authors are with the Power Electronics Systems Group, Universidad The selected models can represent the most important battery
Carlos III de Madrid, Leganés 28911, Spain (e-mail: [email protected]; effects that affect the control and battery.
[email protected]; [email protected]; [email protected]; The next sections are organized as follows: Section II de-
[email protected]).
Digital Object Identifier 10.1109/TVT.2019.2952970 scribes the parameter estimation procedure for battery models
0018-9545 © 2019 IEEE. Personal use is permitted, but republication/redistribution requires IEEE permission.
See http://www.ieee.org/publications_standards/publications/rights/index.html for more information.
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MINIGUANO et al.: GENERAL PARAMETER IDENTIFICATION PROCEDURE AND COMPARATIVE STUDY OF LI-ION BATTERY MODELS 237
Fig. 2. Parameter estimation: (a) general equivalent circuit model, (b) equivalent circuit model in Simulink, (c) equivalent circuit model in Simscape, and
(d) general identification procedure.
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238 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 69, NO. 1, JANUARY 2020
Fig. 3. (a) Battery testing system. Current profiles for identification: (b) constant and (c) pulsating current discharge profile for verification: (d) HPPC and
(e) ECE15.
Some techniques are presented in [24], where the tendency of Fig. 3d shows the HPPC test, described in [25]. It is applied
estimation is a mixture of probabilistic and artificial intelligence repeatedly for almost one hour to validate how robust is the
techniques. battery model long-time response. Fig. 3e shows the ECE15
The Coulomb counting method is used in this paper for SOC test, described in [26], which is applied repeatedly for almost
calculation because it is simple and provides good accuracy. In one hour.
order to obtain the data for battery model identification, current
pulses of 10% SOC are applied, as shown in Fig. 3c.
In addition, to verify the robustness and accuracy of the battery IV. BATTERY MODELS
models, two verification test profiles are applied: HPPC profile This section analyses five battery models selected from the
and ECE15 profile. These profiles are widely used in the battery literature, on which the procedure shown in Section II has been
and supercapacitor modeling, in electric vehicles. applied.
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MINIGUANO et al.: GENERAL PARAMETER IDENTIFICATION PROCEDURE AND COMPARATIVE STUDY OF LI-ION BATTERY MODELS 239
TABLE II
SHEPHERD MODEL BATTERY PARAMETERS
A. Shepherd Model
Fig. 5. Nonlinear RC Battery: (a) model structure and (b) OCV vs. SOC.
The Li-ion battery model proposed in [30] is used due to the
fact that this model requires only a few data from manufacturer
datasheet and the battery discharge curve. This model is based
B. The Nonlinear Model
on the modified Shepherd model, and it can accurately reflect
the macro-level characteristics of current and voltage that are The proposed model in [31] is demonstrated to be more
important for system-level simulations, as shown in Fig. 4. appropriate than the well-known Randles’s battery circuit model
This battery model is implemented in Simulink, and it is com- applied for lead-acid battery technologies. Despite the good
posed of a controlled voltage source and an internal resistance. results obtained with the modified Randles’s model, however,
The controlled voltage source value depends on two expressions, for lithium-polymer battery, this model is not appropriated due
one for battery discharge and other for battery charge. Where E0 to the battery nonlinearly behavior. For this reason, a nonlinear
is the battery constant voltage (V), K is the polarization constant RC battery model is proposed in [35]. The proposed model
(V Ah−1 ), Q is the maximum battery capacity (Ah), i∗ is the consists of a nonlinear voltage source, Open Circuit Voltage,
filtered battery current (A), it is the actual battery charge (Ah), A OCV(SOC) as a function of SOC in order to represent nonlinear
is the exponential zone amplitude (V), B is the exponential zone characteristics; a capacitance Cp to model polarization effect; a
time constant inverse (Ah−1 ), Tc is the battery time constant (s), propagation resistor Rb ; a diffusion resistor Rp ; and an ohmic
and R is the battery internal resistance (Ω) [34]. resistance Rt , as shown in Fig. 5a.
Applying a discharge curve of 0.2 C and using the Parameter The obtained parameter values are shown in Fig. 5b and
Estimation tool shown in Section II along with the battery model Table III, after using the identification procedure proposed in
in Simulink, the different estimated parameters for this model Section II. The model parameters depend on the state of charge
are obtained, as shown in Table II. at each current level during discharging.
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240 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 69, NO. 1, JANUARY 2020
TABLE III
BATTERY DYNAMIC MODEL PARAMETERS
Fig. 7. The 3rd Order RC Model with One-State Hysteresis (3RCH): (a)
electric circuit and (b) OCV versus SOC.
i(k) · γ · Δt
h(k) = exp − · h(k)
Fig. 6. PNGV model: (a) electric circuit and (b) parameter values. Q
i(k) · γ · Δt
− 1 − exp − · sgn (i (k)) (2)
Q
C. Partnership for a New Generation of
Vehicles (PNGV) Model
The PNGV model is accurate and able to describe the battery The hysteresis voltage, Vh (in the order of few millivolts), is
behavior during the discharge process [32]. In [36], research Mh(k), where M is the maximum hysteresis value, γ adjusts the
about Li-ion battery enhances the PNGV model by adding changing rate of hysteresis voltage and Q is the total capacity. In
variable RC components, as shown in Fig. 6a. This model is [37], the authors provide a robust and consistent methodology
composed of the OCV0 represents the initial constant voltage to assess the OCV of different chemistry lithium-ion cells. This
source (V), and C0 (SOC) represents a variable capacitor, both method is applied to the under-test cell to get a variation of 10%
connected in series represent the nonlinear voltage characteris- of SOC using a 1C current until the cut-off voltage, as shown in
tics of the battery, which is dependent on SOC. R0 (SOC) rep- Fig. 7b. This information allows to obtain the parameter used in
resents the battery internal resistance (Ω), and also two parallel (2) needed to calculate Vh.
networks based on R1 , C1 , R2, and C2 as a function of SOC. The Table IV shows the average values of RC and the average
values of the different parameters estimated for this model, with hysteresis parameters from charge and discharge curves.
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MINIGUANO et al.: GENERAL PARAMETER IDENTIFICATION PROCEDURE AND COMPARATIVE STUDY OF LI-ION BATTERY MODELS 241
TABLE IV TABLE V
DYNAMIC MODEL BATTERY PARAMETERS OUTPUT VOLTAGE ERROR WITH HPPC TEST
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242 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 69, NO. 1, JANUARY 2020
Fig. 9. Time response of lithium-ion battery: (a)–(d) current profile HPPC and (e)–(h) current profile ECE15. (a) current profile HPPC, (b) simulated and
experimental voltage, (c) voltage relative error, (d) maximum and average voltage relative error; (e) current profile ECE15, (f) simulated and experimental voltage
and (g) voltage relative error and (h) maximum and average voltage relative error.
whether short, medium or long term, since with a sufficient The results obtained indicate that the Three RC Network
number of RC networks all phases of polarization of the battery Model, followed by the 3rd Order RC Model with One-State
can be represented. Hysteresis are the two models with the best results, although
However, the PNGV model produces long-term accumulation most of the parameters of the 3rd Order RC Model with
of voltage on the capacitor, which increases the model voltage One-State Hysteresis are constant, so this model is easier to
error. implement.
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MINIGUANO et al.: GENERAL PARAMETER IDENTIFICATION PROCEDURE AND COMPARATIVE STUDY OF LI-ION BATTERY MODELS 243
TABLE VIII
PNGV MODEL PARAMETERS
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244 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 69, NO. 1, JANUARY 2020
TABLE IX
THEVENIN MODEL PARAMETERS
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MINIGUANO et al.: GENERAL PARAMETER IDENTIFICATION PROCEDURE AND COMPARATIVE STUDY OF LI-ION BATTERY MODELS 245
[35] I.-S. Kim, “Nonlinear state of charge estimator for hybrid electric vehicle Antonio Lázaro was born in Madrid, Spain, in 1968.
battery,” IEEE Trans. Power Electron., vol. 23, no. 4, pp. 2027–2034, He received the M.Sc. degree in electrical engineering
Jul. 2008. from the Universidad Politécnica de Madrid, Madrid,
[36] S. Castano, L. Gauchia, E. Voncila, and J. Sanz, “Dynamical modeling Spain, in 1995, and the Ph.D. degree in electrical en-
procedure of a Li-ion battery pack suitable for real-time applications,” gineering from the Universidad Carlos III de Madrid,
Energy Convers. Manage., vol. 92, pp. 396–405, 2015. Leganés, Spain, in 2003. Since 1995, he has been
[37] A. Barai, W. D. Widanage, J. Marco, A. Mcgordon, and P. Jennings, “A an Assistant Professor with the Universidad Carlos
study of the open circuit voltage characterization technique and hysteresis III de Madrid. Since 1994, he has been involved
assessment of lithium-ion cells,” J. Power Sources, vol. 295, pp. 99–107, in power electronics, participating in more than 50
2015. research and development projects for industry. He
holds seven patents and software registrations and has
authored/coauthored nearly 140 papers in IEEE journals and conferences. His
research interests include switched-mode power supplies, power factor correc-
tion circuits, inverters (railway and grid-connected applications), modeling and
control of switching converters, and digital control techniques.
Henry Miniguano was born in Ambato, Ecuador, in Pablo Zumel (M’06) received the B.S. degree in
1984. He received the M.Sc. and Ph.D. (cum laude) electrical engineering from the University of Burgos,
degrees in electrical engineering from the Carlos Burgos, Spain, in 1995, the first M.S. degree in electri-
III University of Madrid, Leganés, Spain, in 2013 cal engineering from the Universidad Politécnica de
and 2019, respectively. From 2014 to 2019, was in- Madrid (UPM), Madrid, Spain, in 1999, the second
volved in power electronics research and develop- M.S. degree in electrical engineering from the Ecole
ment projects with the Power Electronics Systems Centrale Paris, Paris, France, in 2000, and the Ph.D.
Group, Carlos III University of Madrid. His research degree in electrical engineering from UPM in 2005.
interests include modeling, identification, and con- From 1999 to 2003, he was a Researcher with the
trol of power electronics converters, batteries, and UPM. Since 2003, he has been with the Department
supercapacitors. Dr. Miniguano is the recipient of the of Electronic Technology, Carlos III University of
Young Engineer Award (IEEE International Conference ESAR-ITEC 2016) and Madrid, Leganés, Spain, where he is currently an Associate Professor. He
Best Presenter Award (18th International Symposium Doctoral School of Energy has authored/coauthored more than 100 scientific papers in main international
and Geotechnology III 2019). conferences and journals, has filed four patents, and is the Co-Founder of a
spin-off company targeting CAD for power electronics. He has participated in
more than 50 research projects in the field of power electronics. His research
interests include digital control in power electronics, modeling and control
techniques, modular power converters, design optimization, and educational
topics in power electronics.
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