0% found this document useful (0 votes)
443 views13 pages

Reserpine Stereochemistry

Reserpine synthesis stereochemisty

Uploaded by

Dipak Kalokhe
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
0% found this document useful (0 votes)
443 views13 pages

Reserpine Stereochemistry

Reserpine synthesis stereochemisty

Uploaded by

Dipak Kalokhe
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
You are on page 1/ 13
JANATA SHIKSHAN SANSTHA'S KISAN VEER JUNIOR MAHAVIDYALAYA, WAI. —— _ _Examination 201 Class. ——Subject— Hpac 20, —RolNo- in figure — in Words -- —- Answer Book— —— Suppliments = tied together. - | Sigrrature*of the Supervisor |_| QueNo.] 1 | 2] 3] 4 = ‘Signature of Total_| ths Examinor a ~ ° ° 3 Marks = The Seieokis} mutter et. cl isolated “eterbioe. Bom tee plage _ Saurwakig seepeukina, Rauwollia. copesceus, Cauwe]biq Vomjtersa. ne such as bypetrpsive & sedative drugs in beatmert «| headeche, i nfank ‘hyper act disarders. Structure Sk. Reseobipe tm = tis used in medi dermate hina [ermulae => e,MgaMOy ‘Scanned by CamScanner {SoG oH peas 8 X= "Yabimbine Desesbicdén é 7 Ciecteme tery Resey}ine) D stereochemishy at Cis aod Cop es O12 ing juncken tx Bye two seses ol tronsd. mabey gS =2Bminabion ae cod be conxerled| into Sais deb Iie Sac¥ aa alcaho ‘Scanned by CamScanner poe = __Ia-decory €or? = MBs foe Sealab er ee a Yehinbive « Formabes ef Xa ohinb ) echo) s— ast a a nae Joni LAY : yw Bes fF oR neo = eas This transbenahon te Deserpidipe to 2-yohimbioe Abpect ying junction ie: Cis—uncion. a 4 Yekinby aioe The Deserpidine ap _aiicaline hydeslysis gives meds deveserpidate ohich is simisior 44 ye thy! Yee Danshermabans lent athe d steveochemishy ek tigi ¢ independep! evident tom Ltheye is at Os § Con Seas . Scanned by CamScanner Hep | veserpabe Behaviour as Sale S nyse P- Tohtgctine stb Rash © The presence OL P= Telucne salphanala inn can be conwmnd — by EA chsosphon at 9.65 SIs, 5-94. Aise this quaternary compoune) s) Pht. wily NaT in acebonilosle sol Nol + #cctenitile + Sual comp —— ppt. eee H demabon of quaterncry amnentiinn sk is pessilic only when DIE sing junchon is cigs D_ Stereochemishy af Ct e re le" Sc Tsoreseapine The conkquvabion at Oy isnot easily delectrd becouse emvabve eeadily undeego epinresssabon ab cephre dispoored & having 4- oriephatyen im ise. compound: indicaag that ins ; is equilorially disposed S having p-orient : reserpine hpdvagen ot 6 is equiburiolly dispesrd & having p-orientabon Ste $ ip? The ead ‘mokion. ta laden by nese pie_ocid prevercts Qcis= ci pitino He Subsiiyedt ab Ces Cg 0 Scanned by CamScanner the posthility of opined subon at cpg cleving tadone ovmaliap s¢ exchuicled __since Lay weduchin_oflactsnes gives reseaplae eio)2—— ally Change ib sedlabion tubith atronspanies. (eusakon of cquitess a) poziben 7 Teo estes afsips 2 ———s Gheve the plane and Squitor el) disposed. DIE Sra is a bh c —stH, ak Ci —— > x-o%entabep G axially ditspesecp } ble. since Quatertisahen is pos. + * Slerveochemisy s| Yohimbine i- ot “ehinmbine § its several isomers cap be vepresented as > the conbquraban ty Hse of te isapa ert jonbine 2 carpPhpths duc 4 bjeab: on Wd ty] aes a ke—aF $ Tonal by-using aaseciples el conf vedalinnal analysis : we Hyeeo. 5, —| [ee COO Yehimbioe Caryanthi. = pq asion is Trans 3- ae — ‘shirbine ap hy dvolysis give? Vohimbic acid an Sic dilahon Scanned by CamScanner 2 usher -# Conkouvaton “ohimbne | ‘ikaline Nrehimbic acid - sh meter carbon: leqees ok Cig. the moe i must dite Zenkumaben is oven jor Yehim bine Copbguraben SIV te caryantine- of Yohimbioe takesplace easily hile eat 2) doespt takes place equilowal { ae = VPohinbine Ne ° Cokiguoaken S Cia bperercy greius Cacia . 1 a Meelis ) AY vey.) | Wea ae | | Yohinobing Smid? Re iz Scanned by CamScanner —The_preduch_epiyshimber..oblaioed by vedudie shimbire | 8 Pragressively. enlich ere 5-quankitysoit must); mere _sdoble epimey je. cis-Fouipersa|. hic ingpliss thok be group Oe fit is anal tp cases Yabiesbens 5 pence in-tar cre |-_Yerhinobine- }——Tolunbine ta epiyahimbines en Seskp—ak—Cisaie-satal-l is ee ae + eonkguvabon el Rina ES Sabstikvesls > t _ Is ot £92}. eo ot i 13 eel ie cangrobine ots Shae ly-mealoan in ghth sient mi nate eee exyinthine. pe a oe LA dal kale it enyf 2504. | Fi CSG SEE ee eet 95 __similloy treatment sith Yohimbjne i} doect give els abo. spt 4 up-as if lercks te aode- epl oot Ascppointed. : spa etatshaa sl c ‘Scanned by CamScanner JANATA SHIKSHAN SANSTHA'S _KISAN VEER JUNIOR MAHAVIDYALAYA, WAI Examination 201 Glass vision. Subject Date: / 4204 $y” —Rolt No-in-figure———— ———— in Words ~~ Taaanae * = tied together Signature of the Examinor Cher alkaloids tt aas St “ eakatcids colt an tH chm ak & exhibib & “bevo 300 fo 2966 cs) oy low toave lace side ok hoe ee at @boaf 2geoas!) tohile those cei) Se Thys A’ evence_in FR: specham reflect Ree al] eos et to His, adetibongl prakin TR. ave vxl Bow by those _alkaldids talu'cb possess on aviah = Tig stable conbirmalseo. feet iver by sso ppay c sequatoaial Gch ton gives A=0 in 2 6] sehwrated CH axbsoephe : _3- equeton al 7al-Aparege Seer obser ae @ conf r BE akal Pelabrs bel a The meytuatic ocelot e oaidabitn 6 Scanned by CamScanner 29. Quinshidine inwelve sont coplanar c)im N= meycurated ors plex: — Che Ses Sa Compeunds sh Dorma) serfes as Yohimbioes G ot Seno. €9. Ao shi mbineg acccpled to adopt Sealyjmeshon nD whith -- L otk Pydregen adam oxie} tang te the IKE 6} Ny: cohich will zi veadily gre S- dehydrodesyahves. | The peado Yohimbioes for whith such Con kiran |}——18 ret possible, was nob exciaise) under cerdibor a bisved™ x Steveochemistey el cholestage o Tt _is present in on most Shable coolirmatiens SA & 5p Chelestone aS dollocss. I~ Be rah 4 SrA> cholestave ‘Scanned by CamScanner Revay analysis of Abe chedeybery~) Gedide hoe edabdinher| tak idephe all hale §s bal} chair confirmaban ia Cegsbal lallice | ———Becouce of impessibihly ef ducing ale mended aing Ve anediier Le ough dvans= cliaxiad linkage ncihit, Upc Can Mederrqe i cenrnralion Change fei evnalive: al) heir aydens Veke uns Syclalenanc. And els = checane. “The_confienrabon of. po pubelitu cok al cath pecibiet, in. ~seaies is indivaled q» Jellovs « eee ey qt A ZL : Seu enay ly oe [SSE eeeeeeeeceeseesereeee RCo i ok the siktabom in.s.px seas es differ cok any wilt, weqaees L'a! _subsliinent: the. Con|yenrahion “oe whith tre op peste [eben p_h:ans A] psleveld- i i ey Cook. Lguxahion ab-Cis 6 Cn are ssslaned —_ See ea oo. * Shape of 79 ‘Do’ "adepls hal chair coofinmab en :— [The shape of the D=sing_o/ slecaictisnouch ce | tok The Knot thot ink-oduch'od—o halogen atstn int | __ A= pesibo: phe cycloberanane praduces.. chavactesshic Chas. (renee abies depending on whetner haleges in —equinina’ a|_ox_oeial_ souprmabens. ease __ ae emia Sleraid srigD pci csitth, these a ip_c=halede: ‘ eo ee cue ai fajoed ir ale § H-balo_cerivabves v Scanned by CamScanner — Here OR \ies_above the plose—debined by Sy 1S. Studied at same clishance bella ine diane SASF B Subsihient -posses—sanse_cqtitetal Chavachen §— | canoe ete - | ed Pscude=equalesia| j= Th_lé-helo=1p= Gre sleveidl_ol lyst: secies spectnal “Gain G_s83.Uhts_ol dipole moments siggest thak_afng “p+ | —ts_ap_emvetepcedfnagheo. eeareeseecte 2 b = bisechonal beads Cx coplaner. eee et ee = : : $Ish_& Is8 ebshbhyembe Spsducle costa): ae # Sterpidas side chain — Me ray crystalegraphic Studies ok f and of ~resutt 8-ep-sg-aj iedoarelede Cq ttipencid certs . q which had gmav side Chain adopts a tuity stag cophrmabenal analysis. LiAln, veduch'so of _stevoids possesing a 12 main bab Olhecwise unsulsstshled ipaing 260 H y ae i. ep = — - [at is acctimed that bychite attach takenplace as 2 ~ Scanned by CamScanner inles rect! ate having & Confyymahva similiax ts taqh of re ViQid + 2am Ore vide taeda Taen_if’s_kallecos | Ban's sale Ina} Inis_may be echsesenled. Ff aidisigtdislattisusttinuausinl L. —_ Scanned by CamScanner

You might also like