JR CHEMISTRY 1:5 IMP QUESTIONS 2023-24
QUESTIONS:
QUESTION NO-1 (STATES OF MATTER)
1) What is Boltzmann’s constant? Give its value.
2) Which of the gases diffuses faster among N2 , O2 and CH 4 Why?
3) Calculate Kinetic energy of 5 moles of nitrogen at 270 C?
4) Why is pressure cooker used for cooking food on hills?
5) What is surface tension?
6) What is an Ideal gas?
QUESTION NO-2 (ACIDS AND BASES)
1) What are Lewis acid & base? Give suitable example.
2) What is homogeneous equilibrium? Write two homogeneous reactions.
3) Calculate the pH of 0.05M H 2 SO4 solution
4) What is the effect of pressure on a gaseous chemical equilibrium
5) What is Bronsted base? Give an example.
6) Why does BF3 behave as Lewis Acid?
7) Find the PH of 0.05M Ba(OH)2 Aqueous solution?
QUESTION NO-3 (ENVIRONMENTAL CHEMISTRY)
1) Which oxides cause acid rain? and what is its value?
2) What is chemical oxygen demand (COD)&(BOD)?
3) Define the terms sink, TLV & Receptor?
4) a) What is Greenhouse effect? It is caused by ........and .... gases
b) Mention the harmful effects caused by Global warming
5) What is PAN? What Effect is caused by it?
6) Name the common compounds of Photochemical smog?
7) Mention the Harmful effects caused due to Depletion of Ozone layer?
QUESTION NO-4 (STOICHIOMETRY)
1) The empirical formula of compound is CH2O . Its molecular weight is 90. Calculate the molecular
formula of the compound.
2) Calculate the oxidation number of ‘Cr’ in K2Cr2O7 or Cr2O7-2
3) What volume of CO2 is obtained at STP by heating 4g of CaCO3 ?
4) How many numbers of moles of glucose are present in 540 gms of glucose?
5) Calculate the weight of 0.1 Mole of sodium carbonate?
6) Calculate the Molarity of NaOH in the solution prepared by disloving 4grms in enough Water to form
250ML of the solution?
QUESTION NO-5 (CHEMICAL BOND)
1) Why H2O has higher BP than HF
2) What type of bonds are present in NH4Cl? Write its structure.
3) Which of the two ions ca 2 or Zn 2 is more stable and why?
4) How many sigma and pi bonds are present in
a) C2 H 2 b) C2 H 4
5) What is octet rule?
QUESTION NO-6 (14 TH GROUP ELEMENTS)
1) How does graphite function as a lubricant
2) Diamond has high melting point – explain
3) Graphite is a good conductor-explain
4) How is water gas or blue gas prepared?
5) Write the use of ZSM-5
6) What is allotropy? Give the crystalline allotropes of carbon.
7) Write the hybridisation of carbon in the following
(a) CO2 (b) Diamond (c) Graphite (d) Fullerene
QUESTION NO-7 (S -BLOCK ELEMENTS)
1) What happens when magnesium metal is burnt in air?
2) Why are alkali metals not found in the free state in nature
3) Why is gypsum added to cement?
4) Which is called milk of magnesia? Give its uses?
5) What happens, When Mg(NO3)2 is heated? Give the balanced equation?
6) Lithium salts are mostly hydrated why?
7) Describe the important uses of sodium carbonate?
QUESTION NO-8 (13th GROUP ELEMENTS)
1) Give the formula of borazine. What is its common name?
2) What is inertpair effect?
3) Give two uses of Aluminium?
4) Explain why atomic radius of Ga is less than that of Al.
5) Explain why atomic radius of Ga is less than that of Al ?
QUESTION NO-9 (THERMODYNAMICS)
1) State the first law of thermodynamics. Explain its mathematical notation
2) What are intensive and extensive properties
3) State the third law of thermodynamics.
4) What is entropy? Explain with examples.
5) Define a system. Give an example.
QUESTION NO-10 (ORGANIC CHEMISTRY)
1) Write the reagents required for conversion of benzene to methyl benzene.
2) Write a short note on a) Wurtz reaction b) Friedel craft alkylation
3) Write the structural formula of the given compounds -
(a) 3,4,4,5 - Tetramethyl heptane (b) 2-Methyl -1-butene
4) Write the IUPAC names of
0
(1) CH3 CH2 CH 2 CH CH 2 (2)
CH 3 C CH 3
5) Write the functional isomers of organic compound C3 H6O.
6) What is fridel craft acylation?
7) What is polymerization of ethylene?
8) What is position isomerism?
9) What is decarboxylation ?
10) Kolbe”s electrolytic method?
11) How is nitrobenzene prepared.
II SHORT ANSWER QUESTIONS:
QUESTION NO-11 (STATS OF MATTER)
1) Deduce (a) Boyle’s law and (b) Charle’s law (c) Graham’s law
(d) Dalton’s law from Kinetic gas equation.
2) Write the postulates of Kinetic Molecular Theory of Gases.
3) State and explain Graham’s law of Diffusion?
4) State and explain Dalton’s law of partial pressures.? Problems
5) Derive Ideal gas equation.
QUESTION NO-12 (CHEMICAL BOND)
1) Explain the hybridization involved in PCl5 molecule.
2) What is Hydrogen bond Explain the different types of Hydrogen bonds with examples.
3) Explain the hybridization involved in SF6 molecule
4) Predict the shape of the following molecules by using VSEPR theory
a) XeF4 b) BrF5 c) ClF3 d) lCl4
QUESTION NO-13 (CHEMICAL BOND
1) Explain the formation of Coordinate covalent bond with one example
2) Explain Fajan’s rules and give suitable examples.
3) Define Dipole moment. Write its applications.
4) a) NH3 has a higher dipole moment compared to NF3 . Why?
b) dipole moment observed for NF3 and not BF3 . why?
OR
(THERMODYNAMICS)
1) State and explain the Hess’s law of constant Heat summation.
2) State the second law of thermodynamics and explain it.
3) What is entropy explain with examples?
4) Explain spontaneity of a process in terms of Gibbs energy.
5) What are Cp and Cv? Show that Cp - Cv =R
QUESTION NO-14 (STOICHIOMETRY)
1) Balance the following redox equation by ion- electron method taking place in acidic medium.
a)
Cr2O7 2 NO2 Cr 3 NO3 b)
MnO41 SO32 Mn 2 SO42
2) Determination of Empirical formula and molecular formula
A carbon compound contains 12.8%carbon, 2.1%hydrogen, 85.1% bromine. The molecular weight of
the compound is 187.9. Calculate the molecular formula.
3) Determination of Empirical formula and molecula formula A compound having 4.07% hydrogen,
24.27% carbon and 71.65 % chlorine its molecular weight is 98.96 what are its emperical formula.
and molecular formula
4) Balance the following redox equation by ion-electron method taking place in basic medium.
MnO2 I 2
P4
OH
PH 3 H 2 PO2 b)
MnO4 I
QUESTION NO-15 (CHEMICAL EQUILIBRIUM)
1) What is Lechatlier’s principle? Discuss the application of lechatelier”S principle for the industrial
synthesis of ammonia by haber”s process?
2) Derive the relation between Kc and Kp for equilibrium reaction
a) N 2 g 3H 2 g 2 NH 3 g b) 2 SO2 g O2 g 2SO3 g
3) a) What is a conjugate acid-base pair? Illustrate with examples.
b) Write conjugated acid and bases for following species
i) H 2O ii) NH3 iii) HCO3 iv) HSO4 v) OH vi) H 2O2
4) Explain the Arrhenius concept of acids and bases?
5) What are electron deficient compound. Explain why BF3 act a Lewis acid.
QUESTION NO-16 (HYDROGEN AND ITS COMPOUNDS)
1) Explain the terms hard water and soft water. Write a note on the
(i) ion - exchange method and
(ii) Calgon method for the removal of hardness of water.
2) Explain the following with suitable examples
(a) electron-deficient hydrides b) Electron Precise hydrides c) Electron rich hydrides d) Ionic hydrides
3) Discuss with relevant chemical equations, various methods of preparing peroxide, wich of these methods
is useful to prepare D2O2?
4) Write a few liens on the utility of hydrogen as a fuel ?
5) Write chemical reactions two justify that hydrogen peroxide can function as a oxidising as well as reducing
agent
QUESTION NO-17 (13TH GROUP ELEMENTS)
1) Explain the structure of diborane.
2) Explain borax bead test with a suitable example.
3) Lithium reacts with water less vigorously than sodium. Give your reasons.
4) What are electron deficient compound? an electron deficient species.Explain
QUESTION NO-18 (S -BLOCK ELEMENTS)
.1) What is Plaster of Paris? Write a short note on it.
2) What do you know about Castner-Kellner process? Write the principle involved in it
3) Given an account of the biological importance of Na and k ions..
4) Give an account of the biological importance of Mg 2 and Ca 2
OR
(14 TH GROUP ELEMENTS)
1) Explain the difference in properties of diamond and graphite on the basis of their structure.
2) Why is diamond hard?
3) What do you understand by a) Allotropy b) inert pair effect c) catenation
4) Write a note on (a) silicates (b) zeolites (c) Fullerenes
LONG ANSWER QUESTION
QUESTION NO-19 (ATOMIC STRUCTUR)
1) What are the postulates of Bohr’s model of hydrogen atom? Discuss the importance of this model to
explain various series of line spectra in hydrogen atom?
2) How are the quantum numbers n, l and m, s arrived at? Explain the significance of these quantum.
numbers.?
3) (a) Explain (i) Aufbau Principle (ii) Hund’s Rule (iii) Pauli’s Principle?
(b) Advantages and Limitations of Bohr’s theory
QUESTION NO-20 (PERIODIC TABLE)
1) What is a periodic property? How the following properties vary in a group and in a period? Explain
(a) Atomic radius (b) IE (c) EN
(d) Electron gain enthalpy or electron affinity (e) Nature of oxides
2) Write an essay on s,p,d and f- block elements.
3) Define IE1 and IE2. Why is IE2 > IE1 for a given atom? Discuss the factors that affect IE
of an element.
QUESTION NO-21 (ORGANIC CHEMISTRY)
1) Describe any two methods of preparation of benzene? Explain the halogenation, alkylation, acylation,
nitration and sulphonation of benzene.
2) Describe two methods of preparation of ethylene. Give equation for the reaction of ethylene with the
following
(a) Ozone (b) Hypohalous acid
(c) Cold and dil.alk KMnO4 (d) Heated with O2 at high pressure
3) How does acetylene react with the following reagents? Give the corresponding equation send and name
the product formed in the reactions.
(a) Acetic acid (b) Water (c) Hydrogen (d) Halogens
(e) Hydrogen halide (f) Ammonical AgNO3 andCu2Cl2
4) a) Complete the following reaction and name the product A, B and C.
AlCl3 CH3Cl
CaC2
H2o
A
hot metal tube
B C
b) Name the products A, B and C formed in the following reactions. Give the equations for the
reactions. Ethylene
Br2 / CCl4
A
Alc . KOH
B
Br2
C
(OR)
(CHEMICAL BOND)
1) What do you understand by Hybridisation? Explain different types of hybridization involving s and
p orbitals.
2) Give an account of VSEPR Theory, and its applications
3) Explain the factors favourable for the formation of Ionic compounds
4) Give the Molecular Orbital Energy Diagram of (a) N 2 and (b) Calculate the respective bond order.
Write the magnetic nature of and molecules
