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SECTION 1: IDENTIFICATION OF THE PRODUCT AND SUPPLIER

PRODUCT INFORMATION
PRODUCT: TONSAN®TS919 Silicon Sealant for PV
PRODUCT DESCRIPTION: Modules Silicone sealant
INTENDED USE: Adhesive
PRODUCT IDENTIFIER: 839212PM

SUPPLIER INFORMATION
Tonsan Suzhou Adhesive Co., Ltd.
40 Youxiang Rd., Wuzhong Economic Development Zone, 215000, Suzhou, China
Telephone: +86-512-87775588
Fax: +86-512-65020968

Tonsan Adhesive, Inc.

5 Shuangyuan Rd. Badachu High-Tech Zone, 100041, Beijing, China
Telephone: +86-10-88795588
Fax: +86-10-68865252

Beijing Hystic New Materials Co., Ltd.

5 Shuangyuan Rd. Badachu High-Tech Zone, 100041, Beijing, China
Telephone: +86-10-68865588
Fax: +86-10-68865252

24 HOUR EMERGENCY PHONE NUMBER: 0532-83889090

FIRE: 119

SECTION 2: HAZARDS IDENTIFICATION

GHS Hazard Symbols:

GHS Signal Word: Warning

GHS Classification: Skin Sensitisation Category 1
Serious Eye Damage/Eye Irritation Category 2
Carcinogenicity Category 2
Skin Corrosion/Irritation Category 3
GHS Hazard Phrases: Causes mild skin irritation May cause an allergic skin reaction. Causes serious eye
irritation. Suspected of causing cancer.
GHS Precautions:
Safety Precautions: Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash
thoroughly after handling. Contaminated work clothing should not be allowed out of
the workplace. Wear protective gloves/protective clothing/eye protection/face
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protection.
First Aid Measures: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. IF exposed or concerned: Get medical advice/attention. If skin irritation or
rash occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Wash contaminated clothing before reuse.
Storage: Store locked up.
Disposal: Dispose of contents/container in accordance with local/regional/national/international
regulation for hazardous wastes.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture.

Chemical Name CAS # PERCENT Classification Note

Calcium carbonate 471-34-1 30 - 50 * (see below)

Silane 2224-33-1 1-5 Eye Dam. 1; H318

Skin Irrit. 2; H315
Skin Sens. 1; H317
Silanes Proprietary 1-5 Eye Irrit. 2; H319
Skin Irrit. 2; H315
Skin Sens. 1; H317
Titanium dioxide 13463-67-7 1-5 * (see below)

*This material is only hazardous when present as an airborne dust. As supplied, and during normal use, the material
is encapsulated within the product and will not present an exposure risk.

Unlisted components are not classified as hazardous.

SECTION 4: FIRST AID MEASURES

EYE CONTACT: Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to
prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention.
SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists.
INHALATION: Remove to fresh air. Call a physician if symptoms persist.
INGESTION: Do not induce vomiting. Seek medical attention if symptoms develop. Provide medical care provider
with this MSDS.
NOTES TO DOCTOR: No additional first aid information available

SECTION 5: FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water spray, foam, dry chemical or carbon dioxide.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Material will burn in a fire.
There is a possibility of pressure buildup in closed containers
when heated. Water spray may be used to cool the containers.
SPECIAL FIRE FIGHTING INSTRUCTIONS: Persons exposed to products of combustion should wear self-
contained breathing apparatus and full protective equipment.
HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, Carbon monoxide Silicon dioxide
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SECTION 6: ACCIDENTAL RELEASE MEASURES

SPECIAL PROTECTION: No adverse health effects expected from the clean-up of spilled material.
Follow personal protective equipment recommendations found in
Section 8 of this SDS.
METHODS FOR CLEAN-UP: Dike if necessary, contain spill with inert absorbent and transfer to
containers for disposal. Keep spilled product out of sewers, watersheds,
or water systems.

SECTION 7: HANDLING AND STORAGE

HANDLING No special handling instructions due to toxicity.

PRECAUTIONS: This product contains an ingredient that may release formaldehyde at heated cure
temperatures.
This product contains an ingredient that may react with water or humidity to
release methyl ethyl ketoxime (MEKO), CAS#96-29-7. The AIHA WEEL TWA
for MEKO is 10 ppm.
This product contains an ingredient that may react with water or humidity to
release ethanol (64-17-5). The TWA for ethanol is 1000 ppm.
This product contains an ingredient that may react with water or humidity to
release methanol (67-56-1). The TWA for methanol is 200 ppm.
STORAGE ADVICE: Store in a cool, dry place.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

EXPOSURE LIMITS:
Chemical Name Note CHINESE OCCUPATIONAL ACGIH EXPOSURE LIMITS
EXPOSURE LIMITS (2007)
Titanium dioxide * (see 8 mg/m3 TWA (total dust) 10 mg/m3 TWA
below) 16 mg/m3 STEL (total dust)

*This material is only hazardous when present as an airborne dust. As supplied, and during normal use, the material is encapsulated within the
product and will not present an exposure risk.

EXPOSURE CONTROL METHODS:

ENGINEERING CONTROLS: Use local exhaust ventilation or other engineering controls to

minimize exposures.
RESPIRATORY PROTECTION: Respiratory protection may be required to avoid overexposure when
handling this product. Use a respirator if general room ventilation is
not available or sufficient to eliminate symptoms.

EYE PROTECTION: Wear safety glasses with side shields when handling this product.
Wear additional eye protection such as chemical splash goggles
and/or face shield when the possibility exists for eye contact with
splashing or spraying liquid, or airborne material. Have an eye wash
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station available.
SKIN PROTECTION: Not normally required. Wear chemically resistant gloves to prevent
prolonged or repeated contact.
GLOVES: Not normally required. Use nitrile gloves if conditions warrant.
OTHER PROTECTION: No smoking, eating and drinking at work place. Avoid alcoholic
beverages before work. Take a shower and change clothes after work.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Semi-solid

COLOR: White
ODOR: Neutral
pH: Not established
FREEZING/MELTING POINT (°C): Not established
BOILING POINT (°C): Not established
FLASH POINT: Not applicable
EVAPORATION RATE: Not established
FLAMMABILITY: Not a flammable solid or gas
UPPER EXPLOSION LIMIT: Not established
LOWER EXPLOSION LIMIT: Not established
VAPOR PRESSURE (mm Hg): Not established
VAPOR DENSITY: Not established
RELATIVE DENSITY (WATER=1): 1.380
RELATIVE VAPOR DENSITY (AIR=1): Not established
WATER SOLUBILITY: Not determined
OCTANOL/WATER COEFFICIENT: Not established
IGNITION TEMPERATURE: Not established
DECOMPOSITION TEMPERATURE: Not established
VISCOSITY: No data available.
SOLIDS (% by weight): 100.0
VOC, weight percent Not determined
MAJOR FUNCTION: Adhesive

SECTION 10: STABILITY AND REACTIVITY

STABILITY: Stable under normal conditions.

CHEMICAL INCOMPATIBILITY: Not established
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide Silicon dioxide

SECTION 11: TOXICOLOGICAL INFORMATION

Component Toxicity / Toxicology Data:

COMPONENT NAME LD50/LC50
Calcium carbonate ORAL LD50 RAT 6,450 MG/KG

Titanium dioxide ORAL LD50 RAT > 10,000 MG/KG

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POTENTIAL HEALTH EFFECTS BY ROUTE OF ENTRY:
Skin corrosion / irritation: Can cause minor skin irritation, defatting, and dermatitis.
Serious eye damage / irritation: Can cause moderate irritation, tearing and reddening.
Respiratory / skin sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: No data available.
Carcinogenicity: Contains a material that is suspected of causing cancer.
Reproductive toxicity: No data available.
Single Exposure Target Organ Effects: No data available.
Respiratory irritation / Narcotic effects: No data available.
Repeated Exposure Target Organ Effects: No data available.
Target Organs Potentially Affected by Lungs
Exposure:
Aspiration hazard: Not an aspiration hazard.

Medical Conditions Aggravated by Exposure: Lung disease

SECTION 12: ECOLOGICAL INFORMATION

OVERVIEW: No ecological information available for this product.

MOBILITY: No data available.
PERSISTENCE: No data available.
BIOACCUMULATION: No data available.

This product has not been tested for ecological effects. Relevant information for components is listed below:

Component： Ecotoxicity values:

No data available. Acute Toxicity (Fish):
Acute Toxicity (Daphnia):
Acute Toxicity (Algae):

SECTION 13: DISPOSAL CONSIDERATIONS

DISPOSAL METHODS: Disposal should be in accordance with local or national legislation.

SECTION 14: TRANSPORT INFORMATION

Consult Bill of Lading for transportation information.

US DOT: NOT REGULATED

IATA: NOT REGULATED
AUSTRALIA ADG: NOT REGULATED
TRANSPORTATION Not applicable
INSTRUCTION

SECTION 15: REGULATORY INFORMATION

INVENTORY STATUS
CHINA IECSC INVENTORY: This product is in compliance with the Inventory of Existing Chemical
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Substances in China (IECSC) requirements.
U.S. EPA TSCA: This product is in compliance with the Toxic Substances Control Act's
Inventory requirements.
CANADIAN CEPA DSL: The components of this product are included on the DSL or are exempt
from DSL requirements.
EUROPEAN REACH: As supplied, this product does not meet the registration requirements
under REACH. Articles using this product may be imported into the
European Union. See below for information on SVHC content.
AUSTRALIA AICS: This product contains a component that is not on the Australian
Inventory (AICS).

Substances of Very High Concern (SVHC) Content:

Unless listed below, this product does not contain SVHC’s.

SECTION 16: OTHER INFORMATION

SDS VERSION DATE: 10-26-2015

This Safety Data Sheet meets Chinese standards and regulations, but may not meet the requirements of other
countries.

This Safety Data Sheet has been prepared in accordance with GBT16483-2008.

Prepared by: The Global Regulatory Department

Phone: 651-236-5842

The information and recommendations set forth herein are believed to be accurate. Because some of the information
is derived from information provided to the H.B. Fuller Company from its suppliers, and because the H.B. Fuller
Company has no control over the conditions of handling and use, the H.B. Fuller Company makes no warranty,
expressed or implied, regarding the accuracy of the data or the results to be obtained from the use thereof. The
information is supplied solely for your information and consideration, and the H.B. Fuller Company assumes no
responsibility for use or reliance thereon. It is the responsibility of the user of H.B. Fuller Company products to
comply with all applicable federal, state and local laws and regulations.