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Kineiits 9 _vomplr 2actions.-
The atu chematal indi dbusome righty
compuicatid due to the occurence of Lempuix
suactions whith sruoives moxe than ens sep,
Impostront among Auth wracking ane the
following =
1) && Opporing or Ruvesble Reactions
a> Conecubve +e Gtons
BD thorn seodiom
@ Kusehea Of Spposi
oy Revesyib Reoutioms:- The
ener
Of bud peachonr ae usr AGHA
wn the Mmitiat stoge of poet shen the produc
ate doo Low oa cencthtraHon +o set up the
opposing neation at a netiadble nate,
However, when the ite weotion abo tok ab
O cemporsble yale, the becomes complicated
and the rak eonstant ebtomed wy not quite
welwable.
Qdorsider the cre seattion tn urhech the poread
OL well Os te suveaL suaskon aus hoth
who k, and ky orm nat eomrant of the
poruearc ond sroverse reactions, sunpectieliy dat @ be the inthot Lencentrahion of the reacrort A,
ts omumed thar areola the concentation of
B=-0)
Then , ajer ume, t, the coneentration 65 *& ui be.
(a-%) Sand that 6h the puoduc @ ull be 2.
The yale of dorusand wadion wk equat to k, (as
while that ©} the wea weveut meation ig k-i2.
pa met sot of the 4ocmasion of B a queen
o dx = kla-0- kyx —O
ot
I} Xe OB dhe concentrahion ef B ot equilib
iohenvthe mit s0te 1 “ZeLO, then,
k, La-xXe) — Ri%e = O
Mca em
or ky = kh, G-%)/%e — ©
Auoatitusing jor k-) *y equation (0)
wh have
de = b,(a-%) - k, (O=%e)
at Ne
awa k, (Xe) a —
ak He @
Seperakng 4Re vacables, we have
duet = GD pat 6
He-% Ke
Tite grating, we get
i Oe ett) a8 ure I & the contronr ef wtlegration
or Xe in(%-O =kt+~ — @D
oOo
At 42-0, x=0.40 thar
ae a faye, ee
(at +20, x20, ro that)
a for lL +n eq. @
—%e, Din (te) ] = hit ~ ke pn xe,
a oO
Oy. iRiter=ne Aen 75) ie -
In eq-@) gee ki sn terms of eal menuurable
quantsies
fom eq. 42% 3) | we hove
Cit R= kaos + 4/ Bo =o)
he =
Thus , pom Oo knouuedge et ky), and xe,
the sate conuraut k, 4 the move 2actHor)
can be cateutated.
Now Auppose that init oli & small amount of
B, 604 b motes, & putent ien, the not rote of
fecmotion of B, ay b motes, tr patent then gure
oY
ax = k, (A-x) — ky lb =
a ¢ (bad —O
Sina at equilibuiuro ae =0 , henw _
