Revision date: 09/12/2019 Revision: 4A Supersedes date: 03/07/2019

SAFETY DATA SHEET

CONPLAST NC

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CONPLAST NC

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Accelerating Admixture

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number

Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Ox. Liq. 2 - H272

Health hazards Acute Tox. 4 - H302 Eye Irrit. 2 - H319

Environmental hazards Aquatic Acute 1 - H400

Classification (67/548/EEC or -
1999/45/EC)

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.

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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P220 Keep away from combustible materials.
P264 Wash contaminated skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P501 Dispose of contents/ container in accordance with national regulations.

Contains SODIUM NITRITE

Supplementary precautionary P270 Do not eat, drink or smoke when using this product.
statements P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P330 Rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P391 Collect spillage.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SODIUM NITRITE 10-30%

CAS number: 7632-00-0 EC number: 231-555-9
M factor (Acute) = 10000000

Classification
Ox. Sol. 3 - H272
Acute Tox. 3 - H301
Eye Irrit. 2 - H319
Aquatic Acute 1 - H400

TRIETHANOLAMINE (TEA) <1%

CAS number: 102-71-6 EC number: 203-049-8 REACH registration number: 01-
2119486482-31-XXXX

Classification
Eye Irrit. 2 - H319

DIETHANOLAMINE <1%
CAS number: 111-42-2 EC number: 203-868-0 REACH registration number: 01-
2119488930-28-XXXX

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
STOT RE 2 - H373
Aquatic Chronic 3 - H412

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The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing.

Ingestion Rinse mouth thoroughly with water.

Skin contact Remove contaminated clothing and rinse skin thoroughly with water.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause discomfort.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Severe irritation, burning and tearing.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Dry chemicals, sand, dolomite etc.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards May intensify fire; oxidiser. Sulphurous gases (SOx).

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Cool containers exposed to flames with water until well
firefighting after the fire is out. Control run-off water by containing and keeping it out of sewers and
watercourses.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate.

6.2. Environmental precautions

Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses.

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6.3. Methods and material for containment and cleaning up

Methods for cleaning up Collect and place in suitable waste disposal containers and seal securely. Label the
containers containing waste and contaminated materials and remove from the area as soon
as possible.

6.4. Reference to other sections

Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid inhalation
of vapours. Use approved respirator if air contamination is above an acceptable level.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
SODIUM NITRITE
Short-term exposure limit (15-minute): WEL 0.5 mg/m3 total dust
TRIETHANOLAMINE (TEA)
Long-term exposure limit (8-hour TWA): ACGIH/TLV:0.1 mg/m3 res
TLV - Threshold Limit Value 5 mg/m³
DIETHANOLAMINE
Long-term exposure limit (8-hour TWA): TWA 0,46 ppm 2 mg/m3
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

DIETHANOLAMINE (CAS: 111-42-2)

DNEL Workers - Inhalation; Long term local effects: 1 mg/m³

Workers - Dermal; Long term systemic effects: 0.13 mg/kg/day

PNEC - Fresh water; 0.0022 mg/l

- marine water; 0.00022 mg/l
- STP; 100 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

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Hand protection Wear protective gloves. Nitrile gloves are recommended, but be aware that the liquid may
penetrate the gloves. Frequent change is advisable.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Promptly remove any clothing that becomes contaminated. Wash
promptly with soap and water if skin becomes contaminated. Use appropriate skin cream to
prevent drying of skin. When using do not eat, drink or smoke.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Straw.

Odour Odourless.

Initial boiling point and range >100 ̊ C

Relative density 1.18 - 1.28 g/cm3

Solubility(ies) Completely soluble in water.

Auto-ignition temperature >200°C

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties The product contains a substance classified as oxidising.

9.2. Other information

Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity After contact with peroxide, there will be a violent reaction.

10.2. Chemical stability

Stability No decomposition if used and stored according to specifications.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials

Materials to avoid Strong acids. Amines. Reducing agents. Strong oxidising agents. Flammable/combustible
materials.

10.6. Hazardous decomposition products

Hazardous decomposition Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
products

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CONPLAST NC

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 353.36

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause discomfort. May be harmful if swallowed and enters airways.

Skin contact Prolonged skin contact may cause redness and irritation.

Eye contact Prolonged contact may cause redness and/or tearing.

Target organs Skin Eyes Respiratory system, lungs

Toxicological information on ingredients.

DIETHANOLAMINE

Acute toxicity - oral

Notes (oral LD₅₀) LC50 ~1600 mg/kg, Oral, Rat

SECTION 12: Ecological information

Ecotoxicity The product contains substances which are toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity The product contains a substance which is toxic to aquatic organisms.

Ecological information on ingredients.

SODIUM NITRITE

Acute aquatic toxicity

LE(C)₅₀ 0.00000001 < L(E)C50 ≤ 0.0000001

M factor (Acute) 10000000

DIETHANOLAMINE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 1460 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic EC₅₀, 48 hours: 30.1 mg/l, Daphnia magna

invertebrates

12.2. Persistence and degradability

Persistence and degradability Expected to be not readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility Soluble in water.

12.5. Results of PBT and vPvB assessment

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Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3139

UN No. (IMDG) 3139

UN No. (ICAO) 3139

UN No. (ADN) 3139

14.2. UN proper shipping name

Proper shipping name OXIDIZING LIQUID, N.O.S. (CONTAINS SODIUM NITRITE)
(ADR/RID)

Proper shipping name (IMDG) OXIDIZING LIQUID, N.O.S. (CONTAINS SODIUM NITRITE)

Proper shipping name (ICAO) OXIDIZING LIQUID, N.O.S. (CONTAINS SODIUM NITRITE)

Proper shipping name (ADN) OXIDIZING LIQUID, N.O.S. (CONTAINS SODIUM NITRITE)

14.3. Transport hazard class(es)

ADR/RID class 5.1

ADR/RID classification code O1

ADR/RID label 5.1

IMDG class 5.1

ICAO class/division 5.1

ADN class 5.1

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

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14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-Q

ADR transport category 2

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information Only trained personnel should use this material. For professional users only.

Revision date 09/12/2019

Revision 4A

Supersedes date 03/07/2019

SDS number 23696

Hazard statements in full H272 May intensify fire; oxidiser.

H301 Toxic if swallowed.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H373 May cause damage to organs (Blood, Kidneys, Liver) through prolonged or repeated
exposure if swallowed.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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