Safety Data-Sheet NaturaMais ARTEVAPS [Eeemacnnns 1- PRODUCT ID Product name: ART EVAP 80 Product internal ID code: EVA/008 2- INGREDIENTS COMPOSITION AND INFORMATION ‘Substance: Copolymer acrylate acrylamide Chemical or general name: Polyacrylamide Synonym: Copolymer acrylate Chemical Abstract Service registration (CAS): Hazardous ingredients: ‘Chemical Name CAS Concentration Band Symbol —_R phrases Acrylamide 000079-06-1 25-30% T 45-46-24/25-48/23/24/25 Classifications System: the ingredient was classified according to Directive 57/548/EEC 3- HAZARD ID Primary Hazards: Makes the floor slippery when in contact with water. Product Effects: Adverse effects on human health: ‘May cause skin and eye irritation. Avoid eye, skin and clothing contact. Do not ingest. Environmental effects: Affects the soil, flora ad fauna. Physical and chemical hazards: May emanate NOx under burning conditions. Organic remains may inflame if water evaporates. Specific hazards: Not applicable. Primary symptoms:te) Safety Data-Sheet NaturaMais TRTEVAPSO [iaaemicriao| An available data review does not identify any symptom from previously unmentioned exposition. Chemical product classification: Not applicable, product not ranked on hazard group, 4- FIRST AID MEASURES Inhalation: Provide fresh air. Symptomatic treatment. Immediately consult a doctor. Skin contact: Wash with water and soap; take a bath if a large scale required. occurs. Immediate medical assistance Eye contact: Immediately consult a doctor. Immediately wash with abundant water for 15 minutes, keeping eyelids open. Ingestion: ‘Wash mouth with water. Do not provoke vomiting Immediately consult a doctor. Actions to be avoided: Keep product on direct skin contact. First aid giver protection and/or doctor notes: No specific antidote. Support treatment. Treatment to be based on doctor's judgment, answering to the patient's reaction. 5. FIRE FIGHTING MEASURES Proper fire-extinguishing measures: This product is not expected to burn unless all water evaporates. Organic remains may be burned. Use water to cool packages exposed to fire. Improper fire-extinguishing measures: ‘Not determined. Specific hazards: May emanate NOx under burning conditions. Organic remains may inflame if water evaporates. Special methods:NaturaMais Name of product yD Safety Data-Sheet | SO ee Not applicable If possible, remove the packages from hazardous place. Fire Brigade protection: Clothing must include safety goggles, helmets and shoes. 6-CONTROL MEASURES FOR LEAKAGE AND SPILLS Personal Precautions: Removal of Ignition Sources: Not determined Prevention against inhalation and skin, mucosal and eye contact: Breathing protection in case of insufficient ventilation, or prolonged exposition. Environment Precautions Do not contaminate superficial waters. Cleaning methods: Gather using absorbing material. Treatment: Recovery or burning in an approved incinerator, according to federal, state and municipal laws. Deposition: Deposition on waste pits, according to local laws. ‘Secondary hazard prevention: Packages must not be reused. Packages must be properly eliminated. 7- HANDLING AND STORAGE, Handlin; Emergency equipment (against fires, leakages, spills, etc.) must always be available. When handling, use individual protection equipment. Worker exposition protection: Handling the product with normal work clothing is enough, Wear safety goggles when handling. Explosion and fire prevention: Use water to cool packages exposed to fire.D NaturaMais ‘Name of product ARTEVAP SO Eareesome| Precautions for safe handling: Provide good ventilation in workplace. Handle the containers with care. Guidelines for safe handling: ‘Avoid skin and eye contact, adequate ventilation or exhaustion recommended. Storage Store in a well-ventilated place, away from incompatible products. Keep the containers shut when not in use. Proper technical measures: Keep the packages intact, in a well-ventilated place. Storage Conditions Proper: Store in covered, dry and ventilated places. Avoid: Do not store in uncovered, humid and unventilated place. Incompatible products and materials: Not determined. Safe packaging materials Recommended: Floating drums, drums or IBC. Inadequate: Metal drums. 8- EXPOSITION CONTROL AND INDIVIDUAL PROTECTION Engineering and control measures: ‘On most conditions, good general ventilation must be enough. ‘Specific control standards: ‘Recommended monitoring procedures:TRTEVAP SD Eorenas| ‘Adopt national and/or international procedures. Regulation norm 15 of MB, hygiene work norms of FUNDACENTRO, NIOSH procedure, or ACGIH procedures, Proper personal safety equipment: Wear PVC gloves, safety boots, apron, masks with polyvalent chemical filter and splash goggles. Breathing protection: If there are significant levels of mist or acrossols, wear facial mask with approved MTB multi-gas filter. Hand protection: ‘Wear PVC gloves. Eye protection: Wear splash goggles or face protector. Skin and body protection: Normal work clothing and gloves are enough. Special precautions: According to work conditions. Hygiene Measures: Good workplace ventilation. Exhaustion procedure. Avoid product emanations on the air. Keep the containers shut. Keep a clean workplace. Do not eat, drink or keep food in the workplace. Wash hands with water and soap after product handling. 9- PHYSICAL-CHEMICAL PROPERTIES. Physical state: liquid Shape: fluid Color: discolored/slightly murky Odor: characteristically neutral pH: 6.00 + 1.00 Boiling point: >1500C Auto-ignition temperature: not applicableSafety Data-Sheet ARTEVAP 80 ae Superior-inferior explosive limit: not applicable ‘Vapor density (air=1): 1.10 +0.15 Density: 1.15 + 0.10g/em3 Solubility with solvent indicatior completely soluble in water. 10- STABILITY ANS REACTIVITY Instability Completely stable. ‘Hazardous reactions: None verified. Conditions to be avoided: Avoid exposition to heat. Incompatible matters or substances: ‘Avoid contact with oxidant energetic agents (chlore, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which may generate heat, fire, explosions and the release of toxic fumes. Additives and inhibitors necessity: Not determined. Hazardous decomposition products: ‘Combustion may produce CO2, CO and NOx. Do not breathe the fumes, Use proper protection equipment. 11- TOXICOLOGICAL INFORMATION Information regarding different exposition ways. Acute toxicity: No studies about acute toxicity were conducted on this product, but toxicological studies with its components were revised. Local effects: ‘No data available. 12- ECOLOGICAL INFORMATION Environmental effects, product impact and behavior» NaturaMais ART EVAP 80 [sree eee Mobility: ‘All measures must be taken in conformity with local environmental organs requirements. Environmental impact: Inhibition of bacterian activity in residual waters. 13- CONSIDERATIONS REGARDING TREATMENT AND DISCHARGE, Products: Discharge on industrial waste pits, according to the local laws. Do not discharge this product on sewers, rivers, lakes or water currents. Product remains: Remains which will no longer be used must be disposed according to the local laws. Used packages: Packages must not be reused. 14- TRANSPORT INFORMATION National and international regulations: Terrestrial (Brazil) According to the Regulation of Terrestrial Transport of products approved by decree 96.044 of May 18", 1988, this product is not ranked, and is not part of the product chart from Portaria 204 of May 20", 1997, 15- REGULATIONS Safety and hazard information as written on label: ‘The proper name/hazard regarding transport may vary due to packaging, property and way of transport 16- OTHER INFORMATION Product must be handled only by trained professionals. Bibliographical reference: Diretiva 67/548/EEC Portaria 3.214 of 08/06/1978 Portaria 204 of 20/05/1997Safety Data-Sheet ARTEVAPS®D [Eso] Legend R10— inflammable R34 — causes buns R45 — may cause cAncer R46 — may cause hereditary genetic alterations R24/25 — toxic when ingested or by skin contact R48/23/24/25 — toxic: hazard of grave health effects in case of prolonged exposition by inhalation, skin contact or ingestion. $45 — in case of accident or indisposition, immediately consult a doctor (if possible, show him/her the label). $53 — avoid exposition — obtain special instructions before use. $26 — in case of eye contact, immediately wash with abundant water. Consult a specialist. $36 — use proper protective clothing. “Information contained here is merely for orientation on good faith, while not incurring responsibility, expressed or implicit. When product data is not available, the information is based on knowledge of its components. If clarifying or additional information is necessary, consult us”.