0% found this document useful (0 votes)
46 views28 pages

DC90-006-2RF MSDS

The document provides safety information for DOWSIL 90-006-2 RF Base. It identifies the product and company, lists hazard identification and classifications, outlines first aid measures, firefighting measures, accidental release measures, handling and storage guidelines, exposure controls and personal protective equipment recommendations.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
46 views28 pages

DC90-006-2RF MSDS

The document provides safety information for DOWSIL 90-006-2 RF Base. It identifies the product and company, lists hazard identification and classifications, outlines first aid measures, firefighting measures, accidental release measures, handling and storage guidelines, exposure controls and personal protective equipment recommendations.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 28

SAFETY DATA SHEET

DOW SILICONES CORPORATION

Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020


Print Date: 02/26/2020
DOW SILICONES CORPORATION encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. IDENTIFICATION
Product name: DOWSIL™ 90-006-2 RF Base

Recommended use of the chemical and restrictions on use


Identified uses: Polymer

COMPANY IDENTIFICATION
DOW SILICONES CORPORATION
2200 WEST SALZBURG ROAD
MIDLAND MI 48686-0994
UNITED STATES

Customer Information Number: 800-258-2436


[email protected]

EMERGENCY TELEPHONE NUMBER


24-Hour Emergency Contact: 1 800 424 9300
Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Reproductive toxicity - Category 2

Label elements
Hazard pictograms

Signal word: WARNING!

Hazards
Suspected of damaging fertility or the unborn child.

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 16


company of Dow
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response
IF exposed or concerned: Get medical advice/ attention.

Storage
Store locked up.

Disposal
Dispose of contents/ container to an approved waste disposal plant.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature: Silicone


This product is a mixture.
Component CASRN Concentration

Cristobalite 14464-46-1 >= 6.0 - <= 10.0 %

Quartz 14808-60-7 >= 0.34 - <= 0.46 %

Octamethyl Cyclotetrasiloxane 556-67-2 >= 0.11 - <= 0.15 %

4. FIRST AID MEASURES


Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.

Inhalation: Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact: Wash off with plenty of water.

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.

Ingestion: No emergency medical treatment necessary.

Page 2 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Most important symptoms and effects, both acute and delayed:


Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed


Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis.

5. FIREFIGHTING MEASURES
Extinguishing media

Suitable extinguishing media: Water spray. Alcohol-resistant foam. Carbon dioxide (CO2).
Dry chemical.

Unsuitable extinguishing media: None known..

Special hazards arising from the substance or mixture

Hazardous combustion products: Carbon oxides. Silicon oxides. Nitrogen oxides (NOx).
Oxides of phosphorus.

Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health..

Advice for firefighters

Fire Fighting Procedures: Use water spray to cool unopened containers.. Evacuate area..
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.. Contain fire water run-off if possible. Fire water run-off, if
not contained, may cause environmental damage..
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Remove undamaged containers from fire area if it is safe to do so.

Special protective equipment for firefighters: In the event of fire, wear self-contained
breathing apparatus.. Use personal protective equipment..

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures: Use personal protective
equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions: Do not release the product to the aquatic environment above defined
regulatory levels Prevent further leakage or spillage if safe to do so. Retain and dispose of
contaminated wash water. Local authorities should be advised if significant spillages cannot be
contained.

Page 3 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Methods and materials for containment and cleaning up: Wipe up or scrape up and contain for
salvage or disposal. Local or national regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will need to determine
which regulations are applicable. For large spills, provide dyking or other appropriate containment to
keep material from spreading. If dyked material can be pumped, store recovered material in
appropriate container. Sections 13 and 15 of this SDS provide information regarding certain local or
national requirements.
See sections: 7, 8, 11, 12 and 13.

7. HANDLING AND STORAGE


Precautions for safe handling: Do not swallow. Avoid contact with eyes. Avoid prolonged or
repeated contact with skin. Take care to prevent spills, waste and minimize release to the
environment. Handle in accordance with good industrial hygiene and safety practice. CONTAINERS
MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product residue follow all
(M)SDS and label warnings even after container is emptied.
Use only with adequate ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.

Conditions for safe storage: Keep in properly labelled containers. Store locked up. Store in
accordance with the particular national regulations.

Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Octamethyl US WEEL TWA 10 ppm
Cyclotetrasiloxane

Although some of the components of this product may have exposure guidelines, no exposure would
be expected under normal handling conditions due to the physical state of the material.

Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures


Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material when prolonged or
frequently repeated contact could occur. Examples of preferred glove barrier
materials include: Butyl rubber. Neoprene. Nitrile/butadiene rubber ("nitrile" or
"NBR"). Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Polyvinyl

Page 4 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove barrier materials


include: Natural rubber ("latex"). NOTICE: The selection of a specific glove for a
particular application and duration of use in a workplace should also take into account
all relevant workplace factors such as, but not limited to: Other chemicals which may
be handled, physical requirements (cut/puncture protection, dexterity, thermal
protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Wear clean, body-covering clothing.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, wear respiratory protection when adverse effects, such as
respiratory irritation or discomfort have been experienced, or where indicated by your risk
assessment process. For most conditions, no respiratory protection should be needed;
however, if handling at elevated temperatures without sufficient ventilation, use an approved
air-purifying respirator.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance
Physical state paste
Color red
Odor slight
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point Not applicable
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.45
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic Viscosity Not applicable
Kinematic Viscosity Not applicable
Explosive properties Not explosive

Page 5 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Oxidizing properties The substance or mixture is not classified as oxidizing.


Molecular weight No data available
Particle size No data available

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY


Reactivity: Not classified as a reactivity hazard.

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions: Can react with strong oxidizing agents. When heated to
temperatures above 180 °C (356 °F) in the presence of air, trace quantities of formaldehyde may be
released. Adequate ventilation is required.

Conditions to avoid: None known.

Incompatible materials: Oxidizing agents

Hazardous decomposition products:


Decomposition products can include and are not limited to: Formaldehyde.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Information on likely routes of exposure


Eye contact, Skin contact, Ingestion.

Acute toxicity (represents short term exposures with immediate effects - no chronic/delayed
effects known unless otherwise noted)

Acute oral toxicity


Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.

Based on information for component(s):


LD50, Rat, > 5,000 mg/kg Estimated.

Information for components:

Cristobalite
Single dose oral LD50 has not been determined.

Quartz
Single dose oral LD50 has not been determined.

Octamethyl Cyclotetrasiloxane
LD50, Rat, male, > 4,800 mg/kg No deaths occurred at this concentration.

Page 6 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Acute dermal toxicity


Prolonged skin contact is unlikely to result in absorption of harmful amounts.

Based on information for component(s):


LD50, Rabbit, > 2,000 mg/kg Estimated.

Information for components:

Cristobalite
The dermal LD50 has not been determined.

Quartz
The dermal LD50 has not been determined.

Octamethyl Cyclotetrasiloxane
LD50, Rat, male and female, > 2,400 mg/kg No deaths occurred at this concentration.

Acute inhalation toxicity


Brief exposure (minutes) is not likely to cause adverse effects. Vapor from heated material
may cause respiratory irritation.

As product: The LC50 has not been determined.

Information for components:

Cristobalite
Vapors are unlikely due to physical properties. Dust may cause irritation of the upper
respiratory tract (nose and throat) and lungs. Excessive exposure may cause lung
injury.

The LC50 has not been determined.

Quartz
The LC50 has not been determined.

Octamethyl Cyclotetrasiloxane
LC50, Rat, male and female, 4 Hour, dust/mist, 36 mg/l OECD Test Guideline 403

Skin corrosion/irritation
Based on information for component(s):
Brief contact is essentially nonirritating to skin.
May cause drying and flaking of the skin.

Information for components:

Cristobalite
May cause skin irritation due to mechanical abrasion.
May cause drying and flaking of the skin.

Quartz
May cause skin irritation due to mechanical abrasion.
May cause drying and flaking of the skin.

Octamethyl Cyclotetrasiloxane

Page 7 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Brief contact is essentially nonirritating to skin.

Serious eye damage/eye irritation


Based on information for component(s):
May cause slight temporary eye irritation.

Information for components:

Cristobalite
Solid or dust may cause irritation or corneal injury due to mechanical action.

Quartz
Solid or dust may cause irritation or corneal injury due to mechanical action.

Octamethyl Cyclotetrasiloxane
Essentially nonirritating to eyes.

Sensitization
For skin sensitization:
Contains component(s) which did not cause allergic skin sensitization in guinea pigs.
Contains component(s) which have not demonstrated the potential for contact allergy in mice.

For respiratory sensitization:


No relevant data found.

Information for components:

Cristobalite
For skin sensitization:
No relevant data found.

For respiratory sensitization:


No relevant data found.

Quartz
For skin sensitization:
No relevant data found.

For respiratory sensitization:


No relevant data found.

Octamethyl Cyclotetrasiloxane
Did not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:


No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)


Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Information for components:

Cristobalite
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Page 8 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Quartz
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Octamethyl Cyclotetrasiloxane
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

Information for components:

Cristobalite
Based on physical properties, not likely to be an aspiration hazard.

Quartz
Based on physical properties, not likely to be an aspiration hazard.

Octamethyl Cyclotetrasiloxane
May be harmful if swallowed and enters airways.

Chronic toxicity (represents longer term exposures with repeated dose resulting in
chronic/delayed effects - no immediate effects known unless otherwise noted)

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Contains a component(s) that is/are not expected to be bioavailable due to the physical state of the
material under normal handling and processing conditions.

Information for components:

Cristobalite
Repeated excessive exposure to crystalline silica may cause silicosis, a progressive and
disabling disease of the lungs.
For similar material(s):
In humans, effects have been reported on the following organs:
Kidney.
Due to the physical state of the material, this component is not expected to be bioavailable
under normal handling and processing conditions.

Quartz
In humans, effects have been reported on the following organs:
Kidney.
Repeated excessive exposure to crystalline silica may cause silicosis, a progressive and
disabling disease of the lungs.
Due to the physical state of the material, this component is not expected to be bioavailable
under normal handling and processing conditions.

Octamethyl Cyclotetrasiloxane
In animals, effects have been reported on the following organs:
Kidney.
Liver.
Respiratory tract.
Female reproductive organs.

Page 9 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Carcinogenicity
For similar material(s): Did not cause cancer in long-term animal studies which used routes of
exposure considered relevant to industrial handling. Positive results have been reported in other
studies using routes of exposure not relevant to industrial handling. Contains an additional
component(s) that is not expected to be bioavailable due to the physical state of the material under
normal handling and processing conditions.

Information for components:

Cristobalite
Has caused cancer in humans. Has caused cancer in laboratory animals. Due to the physical
state of the material, this component is not expected to be bioavailable under normal handling
and processing conditions.

Quartz
Has caused cancer in humans. Has caused cancer in laboratory animals. Due to the physical
state of the material, this component is not expected to be bioavailable under normal handling
and processing conditions.

Octamethyl Cyclotetrasiloxane
Results from a 2 year repeated vapour inhalation exposure study to rats of
octamethylcyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of
female animals. This finding occurred at the highest exposure dose (700 ppm) only. Studies to
date have not demonstrated if these effects occur through pathways that are relevant to
humans. Repeated exposure in rats to D4 resulted in protoporphyrin accumulation in the liver.
Without knowledge of the specific mechanism leading to the protoporphyrin accumulation the
relevance of this finding to humans is unknown.

Teratogenicity
Contains component(s) which did not cause birth defects or any other fetal effects in lab animals.

Information for components:

Cristobalite
For similar material(s): Did not cause birth defects or any other fetal effects in laboratory
animals.

Quartz
For similar material(s): Did not cause birth defects or any other fetal effects in laboratory
animals.

Octamethyl Cyclotetrasiloxane
Did not cause birth defects or any other fetal effects in laboratory animals.

Reproductive toxicity
Contains component(s) which have been shown to interfere with reproduction in animal studies.
Contains component(s) which have interfered with fertility in animal studies.

Information for components:

Cristobalite
No relevant data found.

Quartz

Page 10 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

No relevant data found.

Octamethyl Cyclotetrasiloxane
In laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals. In animal studies, has been shown to
interfere with fertility.

Mutagenicity
Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in
others.

Information for components:

Cristobalite
For similar material(s): In vitro genetic toxicity studies were negative in some cases and
positive in other cases.

Quartz
In vitro genetic toxicity studies were negative in some cases and positive in other cases.

Octamethyl Cyclotetrasiloxane
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity

Cristobalite
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.

Acute toxicity to aquatic invertebrates


Based on data from similar materials
EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l

Quartz
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.

Octamethyl Cyclotetrasiloxane
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.
No toxicity at the limit of solubility
LC50, Oncorhynchus mykiss (rainbow trout), flow-through, 96 Hour, > 0.022 mg/l
No toxicity at the limit of solubility
LC50, Cyprinodon variegatus (sheepshead minnow), flow-through, 14 d, > 0.0063 mg/l

Acute toxicity to aquatic invertebrates


No toxicity at the limit of solubility
EC50, Mysidopsis bahia (opossum shrimp), flow-through test, 96 Hour, > 0.0091 mg/l

Page 11 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

No toxicity at the limit of solubility


EC50, Daphnia magna (Water flea), flow-through test, 48 Hour, > 0.015 mg/l

Acute toxicity to algae/aquatic plants


No toxicity at the limit of solubility
ErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate, > 0.022 mg/l

Chronic toxicity to fish


No toxicity at the limit of solubility
NOEC, Oncorhynchus mykiss (rainbow trout), 93 d, >= 0.0044 mg/l

Chronic toxicity to aquatic invertebrates


No toxicity at the limit of solubility
NOEC, Daphnia magna (Water flea), 21 d, >= 0.0079 mg/l

Persistence and degradability

Cristobalite
Biodegradability: Biodegradation is not applicable.

Quartz
Biodegradability: Biodegradation is not applicable.

Octamethyl Cyclotetrasiloxane
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Not applicable
Biodegradation: 3.7 %
Exposure time: 28 d
Method: OECD Test Guideline 310

Stability in Water (1/2-life)


Hydrolysis, DT50, 69.3 - 144 Hour, pH 7, Half-life Temperature 24.6 °C, OECD Test Guideline
111

Photodegradation
Atmospheric half-life: 16 d
Method: Estimated.

Bioaccumulative potential

Cristobalite
Bioaccumulation: Partitioning from water to n-octanol is not applicable.

Quartz
Bioaccumulation: Partitioning from water to n-octanol is not applicable.

Octamethyl Cyclotetrasiloxane
Bioaccumulation: Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and
7).
Partition coefficient: n-octanol/water(log Pow): 6.49 Measured
Bioconcentration factor (BCF): 12,400 Pimephales promelas (fathead minnow) Measured

Mobility in soil

Page 12 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Cristobalite
No relevant data found.

Quartz
No relevant data found.

Octamethyl Cyclotetrasiloxane
Expected to be relatively immobile in soil (Koc > 5000).

13. DISPOSAL CONSIDERATIONS


Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device. For additional information, refer to:
Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section10
Regulatory Information, MSDS Section 15

Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.

14. TRANSPORT INFORMATION


DOT
Not regulated for transport

Classification for SEA transport (IMO-IMDG):


Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):


Not regulated for transport

This information is not intended to convey all specific regulatory or operational


requirements/information relating to this product. Transportation classifications may vary by container

Page 13 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

volume and may be influenced by regional or country variations in regulations. Additional


transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION


Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Reproductive toxicity

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Pennsylvania Right To Know


The following chemicals are listed because of the additional requirements of Pennsylvania law:

Components CASRN
Polydimethylsiloxane hydroxy-terminated 70131-67-8
Iron oxide 1332-37-2
Cristobalite 14464-46-1
Diatomaceous earth, Flux-calcined 68855-54-9
Ethyl polysilicate 11099-06-2

California Prop. 65
This product contains a chemical that is at or below California Propositions 65’s "safe harbor level" as
determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65
chemical on the SDS or label.

United States TSCA Inventory (TSCA)


All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

16. OTHER INFORMATION

Hazard Rating System


NFPA
Health Flammability Instability
0 1 0
HMIS
Physical
Health Flammability
Hazard
0* 1 0
* = Chronic Effects (See Hazards Identification)

Page 14 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

Revision
Identification Number: 4102428 / A713 / Issue Date: 02/17/2020 / Version: 9.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
TWA 8-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)

Full text of other abbreviations


AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative

Information Source and References


This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

DOW SILICONES CORPORATION urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here

Page 15 of 16
Product name: DOWSIL™ 90-006-2 RF Base Issue Date: 02/17/2020

pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US

Page 16 of 16
SAFETY DATA SHEET
DOW SILICONES CORPORATION

Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019


Print Date: 02/26/2020
DOW SILICONES CORPORATION encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. IDENTIFICATION
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst

Recommended use of the chemical and restrictions on use


Identified uses: Vulcanising agents

COMPANY IDENTIFICATION
DOW SILICONES CORPORATION
2200 WEST SALZBURG ROAD
MIDLAND MI 48686-0994
UNITED STATES

Customer Information Number: 800-258-2436


[email protected]

EMERGENCY TELEPHONE NUMBER


24-Hour Emergency Contact: 1 800 424 9300
Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Reproductive toxicity - Category 2
Specific target organ toxicity - repeated exposure - Category 1 - Oral

Label elements
Hazard pictograms

Signal word: DANGER!

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 12


company of Dow
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

Hazards
Suspected of damaging fertility or the unborn child.
Causes damage to organs (Central nervous system) through prolonged or repeated exposure if
swallowed.

Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response
IF exposed or concerned: Get medical advice/ attention.

Storage
Store locked up.

Disposal
Dispose of contents/ container to an approved waste disposal plant.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature: Silicone


This product is a mixture.
Component CASRN Concentration

Chromium oxide (Cr2O3) 1308-38-9 >= 4.0 - <= 5.0 %

Bis[(2-ethyl-2,5- 68928-76-7 >= 1.8 - <= 2.4 %


dimethylhexanoyl)oxy](dimethyl)stannane

4. FIRST AID MEASURES


Description of first aid measures
General advice:
If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Inhalation: Move person to fresh air; if effects occur, consult a physician.

Skin contact: Wash off with plenty of water.

Page 2 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.

Ingestion: No emergency medical treatment necessary.

Most important symptoms and effects, both acute and delayed:


Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed


Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES
Extinguishing media

Suitable extinguishing media: Water spray. Alcohol-resistant foam. Carbon dioxide (CO2).
Dry chemical.

Unsuitable extinguishing media: None known..

Special hazards arising from the substance or mixture

Hazardous combustion products: Carbon oxides. Silicon oxides. Metal oxides. Nitrogen
oxides (NOx).

Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health..

Advice for firefighters

Fire Fighting Procedures: Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations..
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Use water spray to cool unopened containers. Collect contaminated fire
extinguishing water separately. This must not be discharged into drains. Remove undamaged
containers from fire area if it is safe to do so. Evacuate area.

Special protective equipment for firefighters: In the event of fire, wear self-contained
breathing apparatus.. Use personal protective equipment..

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures: Use personal protective
equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions: Discharge into the environment must be avoided. Prevent further
leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil

Page 3 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if
significant spillages cannot be contained.

Methods and materials for containment and cleaning up: Soak up with inert absorbent material.
Clean up remaining materials from spill with suitable absorbant. Local or national regulations may
apply to releases and disposal of this material, as well as those materials and items employed in the
cleanup of releases. You will need to determine which regulations are applicable. For large spills,
provide dyking or other appropriate containment to keep material from spreading. If dyked material can
be pumped, Sections 13 and 15 of this SDS provide information regarding certain local or national
requirements.
See sections: 7, 8, 11, 12 and 13.

7. HANDLING AND STORAGE


Precautions for safe handling: Avoid inhalation of vapour or mist. Do not swallow. Avoid contact
with eyes. Avoid prolonged or repeated contact with skin. Take care to prevent spills, waste and
minimize release to the environment. Handle in accordance with good industrial hygiene and safety
practice.
Use with local exhaust ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.

Conditions for safe storage: Keep in properly labelled containers. Store locked up. Store in
accordance with the particular national regulations.

Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Chromium oxide (Cr2O3) OSHA Z-1 TWA 0.5 mg/m3 , chromium
ACGIH TWA Inhalable 0.003 mg/m3 ,
fraction chromium
Further information: URT irr: Upper Respiratory Tract irritation; skin irr: Skin irritation;
A4: Not classifiable as a human carcinogen; varies: varies
Bis[(2-ethyl-2,5- OSHA Z-1 TWA 0.1 mg/m3 , Tin
dimethylhexanoyl)oxy](dimet
hyl)stannane
ACGIH TWA 0.1 mg/m3 , Tin
Further information: Central nervous system; immune eff: Immune effects; URT irr:
Upper Respiratory Tract irritation; headache: Headache; eye irr: Eye irritation;
nausea: Nausea; A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption; varies: varies
ACGIH STEL 0.2 mg/m3 , Tin
Further information: Central nervous system; immune eff: Immune effects; URT irr:
Upper Respiratory Tract irritation; headache: Headache; eye irr: Eye irritation;
nausea: Nausea; A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption; varies: varies
OSHA P0 TWA 0.1 mg/m3 , Tin
Further information: X: Skin notation

Page 4 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

NIOSH REL TWA 0.1 mg/m3 , Tin


Further information: Also see specific listing for Cyhexatin.; skin: Potential for dermal
absorption

Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures


Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material when prolonged or frequently
repeated contact could occur. Examples of preferred glove barrier materials include: Butyl rubber.
Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Ethyl vinyl alcohol laminate ("EVAL").
Polyvinyl alcohol ("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove
barrier materials include: Natural rubber ("latex"). NOTICE: The selection of a specific glove for a
particular application and duration of use in a workplace should also take into account all relevant
workplace factors such as, but not limited to: Other chemicals which may be handled, physical
requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove
materials, as well as the instructions/specifications provided by the glove supplier.
Other protection: Wear clean, body-covering clothing.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or
guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or
discomfort have been experienced, or where indicated by your risk assessment process. For most
conditions, no respiratory protection should be needed; however, if material is heated or sprayed, use
an approved air-purifying respirator.
The following should be effective types of air-purifying respirators: Organic vapor cartridge with a
particulate pre-filter.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance
Physical state viscous liquid
Color green
Odor slight
Odor Threshold No data available
pH No data available
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) 100 °C ( 212 °F)
Flash point Pensky-Martens closed cup >101.1 °C ( 214.0 °F)
Evaporation Rate (Butyl Acetate No data available
= 1)
Flammability (solid, gas) Not applicable
Lower explosion limit No data available
Upper explosion limit No data available

Page 5 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

Vapor Pressure No data available


Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.1
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Kinematic Viscosity 7000 mm2/s at 25 °C (77 °F)
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
Particle size Not applicable

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY


Reactivity: Not classified as a reactivity hazard.

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions: Can react with strong oxidizing agents. When heated to
temperatures above 180 °C (356 °F) in the presence of air, trace quantities of formaldehyde may be
released. Adequate ventilation is required.

Conditions to avoid: None known.

Incompatible materials: Oxidizing agents

Hazardous decomposition products:


Decomposition products can include and are not limited to: Formaldehyde.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Acute toxicity
Acute oral toxicity
Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.

As product: Single dose oral LD50 has not been determined.

Based on information for component(s):


LD50, Rat, > 5,000 mg/kg Estimated.

Acute dermal toxicity

Page 6 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

Prolonged skin contact is unlikely to result in absorption of harmful amounts.

As product: The dermal LD50 has not been determined.

Based on information for component(s):


LD50, > 2,000 mg/kg Estimated.

Acute inhalation toxicity


At room temperature, exposure to vapor is minimal due to low volatility. Vapor from heated
material or mist may cause respiratory irritation.
As product: The LC50 has not been determined.

Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.

Serious eye damage/eye irritation


May cause slight temporary eye irritation.
May cause mild eye discomfort.
Corneal injury is unlikely.

Sensitization
For skin sensitization:
Contains component(s) which did not cause allergic skin sensitization in guinea pigs.

For respiratory sensitization:


No relevant information found.

Specific Target Organ Systemic Toxicity (Single Exposure)


Available data are inadequate to determine single exposure specific target organ toxicity.

Specific Target Organ Systemic Toxicity (Repeated Exposure)


Contains component(s) which have been reported to cause effects on the following organs in animals:
Thymus.
Central nervous system.

Carcinogenicity
For the major component(s): Did not cause cancer in long-term animal studies which used routes of
exposure considered relevant to industrial handling. Positive results have been reported in other
studies using routes of exposure not relevant to industrial handling.

Teratogenicity
Contains component(s) which caused birth defects in laboratory animals only at doses toxic to the
mother.

Reproductive toxicity
Contains component(s) which have been shown to interfere with reproduction in animal studies.

Mutagenicity
Contains component(s) which were negative in some in vitro genetic toxicity studies and positive in
others. Contains component(s) which were negative in animal genetic toxicity studies.

Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.

Page 7 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

COMPONENTS INFLUENCING TOXICOLOGY:

Chromium oxide (Cr2O3)


Acute inhalation toxicity
No adverse effects are anticipated from single exposure to dust. Excessive exposure may
cause irritation to upper respiratory tract (nose and throat) and lungs.

LC50, Rat, male and female, 4 Hour, dust/mist, > 5.41 mg/l OECD Test Guideline 403

Bis[(2-ethyl-2,5-dimethylhexanoyl)oxy](dimethyl)stannane
Acute inhalation toxicity
The LC50 has not been determined.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity

Chromium oxide (Cr2O3)


Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 10,000 mg/l, ISO 7346/1

Acute toxicity to algae/aquatic plants


EC50, Desmodesmus subspicatus (green algae), 72 Hour, > 848.6 mg/l, OECD Test
Guideline 201

Toxicity to bacteria
EC50, 3 Hour, > 10,000 mg/l

Chronic toxicity to fish


NOEC, Danio rerio (zebra fish), 30 d, 1,000 mg/l

Chronic toxicity to aquatic invertebrates


No toxicity at the limit of solubility
NOEC, Daphnia magna (Water flea), 21 d, > 0.02 mg/l

Bis[(2-ethyl-2,5-dimethylhexanoyl)oxy](dimethyl)stannane
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
For similar material(s):
LC50, Zebra fish (Danio/Brachydanio rerio), semi-static test, 96 Hour, > 100 mg/l, OECD Test
Guideline 203 or Equivalent

Acute toxicity to aquatic invertebrates


For similar material(s):
EC50, Daphnia magna, static test, 48 Hour, 17 mg/l, OECD Test Guideline 202 or Equivalent

Acute toxicity to algae/aquatic plants

Page 8 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

For similar material(s):


ErC50, Algae (Scenedesmus subspicatus), Growth rate, 72 Hour, Growth rate, 37 mg/l, OECD
Test Guideline 201 or Equivalent
For similar material(s):
NOEC, Algae (Scenedesmus subspicatus), Growth rate, 72 Hour, Growth rate, 1.1 mg/l,
OECD Test Guideline 201 or Equivalent

Toxicity to bacteria
For similar material(s):
EC50, Bacteria, 3 Hour, Respiration rates., 14 mg/l

Persistence and degradability

Chromium oxide (Cr2O3)


Biodegradability: Biodegradation is not applicable.

Bis[(2-ethyl-2,5-dimethylhexanoyl)oxy](dimethyl)stannane
Biodegradability: For similar material(s): Material is expected to biodegrade very slowly (in
the environment). Fails to pass OECD/EEC tests for ready biodegradability.
For similar material(s): 10-day Window: Fail
Biodegradation: 3 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent

Bioaccumulative potential

Chromium oxide (Cr2O3)


Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 2.97 Estimated.
Bioconcentration factor (BCF): 39 Fish Estimated.

Bis[(2-ethyl-2,5-dimethylhexanoyl)oxy](dimethyl)stannane
Bioaccumulation: No relevant data found.

Mobility in soil

Chromium oxide (Cr2O3)


Potential for mobility in soil is high (Koc between 50 and 150).
Partition coefficient (Koc): 80 Estimated.

Bis[(2-ethyl-2,5-dimethylhexanoyl)oxy](dimethyl)stannane
No relevant data found.

13. DISPOSAL CONSIDERATIONS


Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS

Page 9 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR


UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device. For additional information, refer to:
Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section10
Regulatory Information, MSDS Section 15

Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.

14. TRANSPORT INFORMATION


DOT
Not regulated for transport

Classification for SEA transport (IMO-IMDG):


Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):


Not regulated for transport

This information is not intended to convey all specific regulatory or operational


requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION


Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Reproductive toxicity
Specific target organ toxicity (single or repeated exposure)

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
The following components are subject to reporting levels established by SARA Title III, Section 313:
Components CASRN
Chromium oxide (Cr2O3) 1308-38-9

Page 10 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)


Section 103
This material does not contain any components with a CERCLA RQ.
This material does not contain any components with a CERCLA RQ.

Pennsylvania Right To Know


The following chemicals are listed because of the additional requirements of Pennsylvania law:

Components CASRN
Siloxanes and silicones, dimethyl 63148-62-9
Chromium oxide (Cr2O3) 1308-38-9

California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.

United States TSCA Inventory (TSCA)


All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

16. OTHER INFORMATION

Hazard Rating System


NFPA
Health Flammability Instability
0 1 0
HMIS
Physical
Health Flammability
Hazard
3* 1 0
* = Chronic Effects (See Hazards Identification)

Revision
Identification Number: 4101537 / A713 / Issue Date: 09/03/2019 / Version: 6.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL USA. NIOSH Recommended Exposure Limits
OSHA P0 USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
STEL Short-term exposure limit
TWA 8-hour, time-weighted average

Full text of other abbreviations


AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic

Page 11 of 12
Product name: DOWSIL™ 90-006-2 RF SEMKit Catalyst Issue Date: 09/03/2019

Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative

Information Source and References


This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

DOW SILICONES CORPORATION urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US

Page 12 of 12

You might also like