Sec: JR.IIT_*CO SC(MODEL-A) WAT-40 Date: 19.02.

22
Time: 3 Hrs 2020_P1 Max. Marks: 198
KEY SHEET
PHYSICS
1 D 2 A 3 C 4 D 5 D
6 D 7 ABC 8 BD 9 AC 10 ABCD
11 ACD 12 BC 13 3 14 4 15 4
16 5 17 9 18 2

CHEMISTRY
19 C 20 A 21 A 22 B 23 A
24 A 25 AD 26 ACD 27 ABC 28 AC
29 BD 30 ACD 31 3 32 4 33 4
34 7 35 2 36 7

MATHEMATICS
37 C 38 B 39 C 40 B 41 C

42 B 43 ABC 44 ABC 45 ABC 46 ABCD

47 AD 48 ACD 49 2 50 6 51 8

52 1.33 53 8 54 3
Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
SOLUTIONS
PHYSICS
k k k k k k
1. v  0  0  0  0  0  0 ...........
x 0 2x 0 3x 0 4x 0 5x 0 6x 0
k  1 1 1 1 1 1 
VNet  0 1       ............ 
x0  2 3 4 5 6 7 
use ln series expansion of ln 1  x 
x2 x3 x4 x5 x6
ln 1+x   x      ........
2 3 4 5 6
x 1
 1 1 1 1 1 
ln 1  1  1      ....... 
 2 3 4 5 6 
k
VNet  0 ln  2 
x0
19a
2. PO1  and PA = 6a
4
VA 6a
W  q 0 V  q 0  VD  VA   q 0  VO1  VA    dV   E dr
V01 19a / 4

  24 
or VO1  VA  log e  
2 0  19 
Kq Kq in Kq
3. Vc     Vin
r R r'
Kq Kq
 Vin  
r r'
4. V   4 r 
dq    2 r  dr
dWNet  du   dq  V

dq
r
dq charge will distributed
dr on a layer of radius r of
thickness dr

du    2r  dr   4 r 
du  8 2 rdr
R

U Net   du   8 r 2 rdr
0

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
R

U Net  8 2  r 2 dr
0

 2 R 
3

  8
3 
U Net

5. Conceptual
6. First, find the charge appearing on the outer sphere by equating its potential to zero. (Because the
outer sphere is earthed).
Then, find the potential at a distance r from the center.
1 kq 2 1
7. (1) o  mv 02   mv 2
2 R 2
R
(2) mv 0  mvR .
2
Kq 2
Kq 2 1 2 1 1
8. Interaction energy of the dipole = 2 2  q   
d2  r2 r 2o  d 2  r 2 r 
Using binomial approximation (1 + x)n  1 + nx,
2q 2  1  d   q2d 2
2
U 1     1 
4o r  2  r   4o r
3

9. Let Q be the charge on the sphere at t = t and Ro be the initial separation between centre of the sphere
and charge q. So at t = t, potential of sphere
Q q
V  0
4o R 4o  R o  vt 
qR
 Q
 R o  vt 
dQ Rqv
 i
 R o  vt 
2
dt
 (A), (C)
10. Conceptual
11. We assume that the charges on surfaces 2, 3 and 5 are q1 , q2 and q3 in equilibrium. Following
conservation of charge, we see that surfaces 1, 4 and 6 have charges Q  q1 , 3Q  q2 and Q  q3
respectively. The electric field inside a metallic plate is zero; therefore fields at points P, Q and R are
zero.
y

x
Q  q
1 1
P
q
1 2
q2 3
Q
3Q  q
2 4
q
3 5
R
Qq 6
3

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
Resultant field at P: Thus we have three equations, as follows. Considering upward field as
positive, we get
Q  q   1 q1

q2

3Q  q2

q3

Q  q3
 0.....1
2 0 2 02 0 2 0 2 0 2 0
Q  q1 q 3Q Q
Or  1   0
2 0 2 0 2 0 2 0
q1 5Q 5
Or  or q1   Q
0 2 0 2
Q  q1 q q 3Q  q2 q
Resultant field at P:  1  2   3 0
2 0 2 0 2 0 2 0 2 0
Q 3Q 2q2 Q
Or    0
2 0 2 0 2 0 2 0
q2 5Q
Or 
 0 2 0
5
Or q2   Q
2

Resultant field at R:
Q  q1 q
 1  2 
q  3Q  q2   q3  Q  q3  0
2 0 2 0 2 0 2 0 2 0 2 0
Q 3Q Q 2q
Or    3 0
2 0 2 0 2 0 2 0
q3 Q
Or 
0 2 0
Q
Or q3  
2
Thus the final charge distribution on all the faces is:
3 / 2Q

5 / 2Q

5 / 2Q

Q / 2

Q / 2

3Q / 2

q q
12. through centre through shade face.
8 0 24 0
13. Conceptual
14.   2 1  cos 
 b 
 2 1  
 R 2  b2 
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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
Q 
 
4 0
 kQ 2 kQ 2 kQ 2 kQ w kQ 2
15. v    
b a 2b 2Q a
kQ 2 kQ 2
V 
2a 2b
x y  4
16. Total energy comprising of electrostatic potential energy and surface energy due to surface tension of
all the drops eventually acquires a minimum value.
17.

Charge centre be enclosed in a pyramid with a square here of a 2 side

'q '
Flux centre divided in 4 equal parts a 5
4 0

'q ' 1th q

Through square base will base & through base will bass flux through triangular part
6 0 4 24 0
q q
will be 
4 0 24 0
sq
Q
24 0
n5 m4
nm9
18.    E. ds

CHEMISTRY
19. The cell design is
Ag | AgNO3 || AgNO3 | Ag
I II
Anode: Ag  Ag   e
Cathode: Ag   e  Ag

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
Now, E cell  E OP  E RP
Ag/Ag  Ag  /Ag

Using Nernst’s equation.

0.059 0.059
= Eº OP   log[Ag  ]I  Eº RP   log[Ag  ]II
Ag/Ag 1 Ag /Ag 1
[Ag  ]II
 E cell  0.059 log
[Ag  ]I
Now,
[Ag  ]I  C·  0.2  0.75
 0.15M (Given   0.75 )

[Ag ]II  C·  0.05  0.95  0.0475M
(   0.95 )
0.059 [0.0475]
 E cell  log  0.029V
1 [0.15]
20. Use Ag  Ag   e; E OP º
 –0.799V
Ag(NH 3 ) 2  e  Ag  2NH 3
Ag(NH 3 ) 2  Ag   2NH 3
0.059 [Ag(NH 3 ) 2 ]
And, E cell  E cell
º
 log10
1 [Ag  ][NH 3 ]2
Also, E cell  0

And
º
E cell  E OP
º
 E ºRP
Ag/Ag  Ag ( NH3 )
2 /Ag

0.059
º
E cell  log10 K c
1
0.059
= log10 6  1014  0.780, V
1
E Ag( NH ) / Ag  0.780  0.799  0.019V
º
3 2

0.059
21. E1  Eº  log[H  ]1
1
0.059
E 2  Eº  log[H  ]2
1
On adding (also E ºH  0 )
0.059
E1  E 2   [log[H  ]1  log[H  ]2 ]
1
Now for CH 3COOH  CH 3COO   H 
K [CH 3COOH]
[H  ]  a
[CH 3COO  ]
y
[H  ]1  K a
x
x
[H  ]2  K a
y
0.059  K y K x
 E1  E 2    log a  log a 
1  x y 
 0.059[2 log K a ]

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
E1  E 2
log K a 
2  (0.059)
E  E2
log K a   1
0.118
E  E2
Or pK a  1
0.118
22. Conceptual
23. At L.H.S.
From CH 3COOH  CH 3COO   H 
K 
[H  ]  C·  C  a   K a ·C
 C0 
 (1.8  10 –5  0.1)  1.342  10 3 mol litre –1
At R.H.S. From NH 4 OH  NH 4  OH 
K 
[OH  ]C.  C  b   K b .C
 C 
= (1.8  10 5  0.01)
= 0.424 103 mol litre 1
 1014
[H ] 
0.424 103
= 2.359 1011 mol litre 1
1
Now for cell H 2  H   e  At anode, i.e., L.H.S.
2
1
H   e  H 2 At cathode, i.e., R.H.S.
2
E cell  E OP   E RP 
H/H H /H

0.059 [H  ]L.H.S. 0.059 [H  ]R.H.S

 E OP
º
 log10  E º
RP   log10
H/H  1 [PH2 ]1/2 H /H 1 [R H2 ]1/2
0.059 [H  ]R.H.S
 log10 
1 [H ]L.H.S
= ( PH 2  1 atm on both sides)
0.059 2.359 1011
= log10
1 1.342 103
= 0.4575 volt
24. H 2S dissociates in two steps as follows:
H 2S  HS  H 
[HS ][H  ]
K1   108 …(1)
[H 2S]
HS  S2  H 
[S2 ][H  ]
K2  
 1.11013 ….(2)
[HS ]
[S2 ][H  ]2
 K1  K 2  108  1.1 1013 
[H 2S]

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
21
1.110  0.1
[S2 ] 
(103 )2
( [H  ]  10 3 and [H 2S]  0.1M)
[S2 ]  0.111015  1.110 16
Thus for Ag 2S :
K sp  [Ag  ]2 [S2 ]
2 1049  [Ag  ]2 [1.110 –16 ]
2 1049
[Ag  ]2  16
 18.18  1034
1.110
[Ag  ]  4.26 1017 M
0.059
For cell: E Ag  / Ag  E ºAg  /Ag  log[Ag  ]
1
0.059
= 0.8  log[4.26  10 17 ]
1
= 0.8  0.059  (16.3706)
= 0.1658V
25. Conceptual
26. Conceptual
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
0.059 1
31. E  Eº  log 
n [H ]
0.059
0.177  0  log[H  ]
1

log[H ]  3
 pH   log[H  ]  3
32. Ni  Ni 2   2e º
E OP  0.236V
E ºRP  0
2H   2e  H 2
 E cell
º
 0.236V
0.059 [H  ]2
E cell  E cell
º
 log10
2 [Ni 2 ]
0.059
0  0.236  log10 [H  ]2
2

 log10 H  4  pH  4

33. Anode: H 2  2H   2e
(negative polarity) [H  ]  106 M
Cathode: 2H   2e  H 2
(positive polarity) [H  ]  aM
 E cell  E OP  E RP 
H/H  H /H

0.059 0.059
º
= E OP  log10 [H  ]Anode
2
 E RP
º
 log10 [H  ]Cathode
2
H/H  2 
H /H 2
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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
 2
0.059 [H ] Cathode
= log10  2
2 [H ] Anode

0.059 [H  ]Cathode
2
0.059 [H  ]Cathode
0.118  log10  log
(106 ) 2 106
10
2 1
 [H  ]Cathode  10 4 M
34. Conceptual
35. Conceptual
0.0591
36. º
E cell  log K eq.
2
MATHS
Q R is a focal chord  Q   at , 2at1  and R   at2 , 2at2   t1t2  1
2 2
39. 1

0 0 1
2A
A  t2 at12
2at1 1  a 2t1t2  t1  t2    a 2  t1  t2   2a  t1  t2  
a
at22  2at2 1
Parabola y  4  x  y 
2
40.
Circle is   x  r   4  x  1  r 2 has equal roots
2

41. Write the general equation of tangent to parabola (y k)2  4a(x  h) then compare with given line to
get the values of h,k
43. Key : ABC
4
Clearly equation of directrix is y  x
3

(6,8)

48 1 1 1
And distance from focus S (6,8) to if is 2a  and  
5 SP SQ a
45. Key : ABC

Let R be the radical centre of the three circles where RD = RE = RF = 1

 Circum radius = 1

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
46. ABCD

Let Q  x1 y1  be the mid point of SP  P   2 x1  a ,2 y1  lies on y 2  4 ax

 4 y12  a  2 x1  a 
 y12  2ax1  a 2
 a
Locus is y  2a  x 
2

 2
a 
Vertex   ,0 
2 
Directrix is x  a / 2   a / 2  x  0
Focus   a,0 
47. (AD)
A   at12 , 2at1  B   at32 , 2at3  , P   at 2 , 2at 
4
APB  900   1  1
 t1  t  t  t3 
Let t2 , t4 be the roots of (1)
t2  t4    t1  t3 
t2  t4
1 and t2t4  t1t3  4
t1  t3
 t2t4  t1t3  4
3x  4 y  2
 x  2  y2 
2
50.
5
4
 a
5

16
Now consider parabola y 2  x
5
t1t2  1
2
4 1
 t2    5
5 t2 

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Narayana IIT Academy 19-02-22_JR.IIT_*COSC(MODEL-A) _WAT-40_Key&Sol’s
1 5 1
t1    t1  , t2  2
t2 2 2

A  .4a  t1  t2  a  t22  t12   12

1
2
A
6
2

52. Key:4
 t2 1  2 2  t 1
2

 a  at 
2 2
 2   9 and  a  at   2   16
 t   t 
9 4  144
 t 2   4a    4a   4
16 125
54. Focus is intersection point of circles x  x  1  y  y  1  0 and
 x x  4   y  y  8  0
 6 2 
 , 
 2 5

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