PT.
SANINDO PERKASA ABADI
Kawasan Industri Ritz Gate. Jalan Muncul Blok E2-F2. Gedangan, Sidoarjo 61254 Jawa Timur
Telp: (031) 853 8830-31 . Fax: (031)854 0190. Email:
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HARTINDO AF11E
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DATA TECHNIC
Material Safety Data Sheets
(MSDS)
HARTINDO-AF11E
HARTINDO AF11E
MATERIAL SAFETY DATA SHEET
Identity (as used on label) Hartindo AF11E
IDENTIFICATION OF SUBSTANCE / PREPARATION
Manufacturer’s Name Newstar Chemicals (M) Sdn Bhd
Address No. 5, Block B, Jalan SS13/5
Subang Jaya Industrial Estate
47500 Petaling Jaya
Selangor Darul Ehsan MALAYSIA
Information/Emergency Telephone Number (603) 5621 2168
Facsimile Number (603) 5621 1168
Date Prepared December 28th, 1994
Prepared by Randall Hart - Agus Paryono
Revision Date September 04th, 1995
Revised by Agus Paryono
Approved by Randall Hart
HAZARDAOUS INFORMATION
Hazardous Components Ethane, 2,2-dichloro-1,1,1-trifluoro
CAS No. Mixture
OSHA (ppm) None Established.
TWA (mg/m3) None Established.
ACGIH (ppm) None Established.
Percent 99.5
INGREDIENT INFORMATION
Hydrochlorofluorocarbon (HCFC) CAS No. : 306-83-2
Concentrate Proprietary
PHYSICAL/CHEMICAL CHARACTERISTICS
Liquid Density (at 25 oC) 1.46 g/cm3.
Vapour Pressure (at 25 oC) 672 mmHg.
Boiling Point 27.6 oC at 760 mmHg.
Relative Vapour Density (Air = 1) 5.3
Solubility in water (at 25 oC) 39 Percent by Weight.
Relative Evaporation Rate (CCl4 = 1) Less than 1.
Appearance and Odor Clear, Colorless, Slight Lemon, Liquid.
ODP (CFC11 = 1) 0.016
GWP (CFC11 = 1) 0.018
The information contained herein is believed to be reliable, butFull-scale testing and end product performance are theTHE IMPLIED WARRANTIES OF MERCHANTABILITY AND
no representations, guarantees or warranties of any kind areresponsibility of the user. HARTINDO shall not be liable for andFITNESS FOR A PARTICULAR PURPOSE. Nothing
made as to its accuracy, suitability for particular applications orthe customer assumes all risk and liability of any user orcontained herein is to be considered as permission,
the results to be obtained therefrom. The information is basedhandling of any material beyond HARTINDO’s direct control.recommendation, nor as an inducement to practice any
on laboratory work with small-scale equipment and does notThe SELLER MAKES NO WARRANTIES, EXPRESS ORpatented invention without permission of the patent owner.
necessarily indicate end product performance. IMPLIED, INCLUDING, BUT NOT LIMITED TO,
Newstar Chemicals (M) Sdn Bhd
Copyright 1995 ©
Newstar Chemicals (M) Sdn Bhd No.5, Block B, Jalan SS13/5, Subang Jaya Industrial Estate 47500 Petaling Jaya September 1995
Selangor Darul Ehsan MALAYSIA
Material Safety Data Sheet No. H-008E-R AF11E (2 of 4)
FIRE AND EXPLOSION HAZARD DATA
Flash Point
Flammable Limit Non Flammable.
LEL Not Applicable.
UEL Not Applicable.
Extinguishing Media
As appropriate for combustibles in area.
SPECIAL FIRE FIGHTING PROCEDURES
Use water to cool containers Self-Contained Breathing Apparatus (SCBA) is required if drums
rupture and contents are spilled under fire conditions.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may rupture under fire conditions. Decomposition may occur.
STABILITY AND REACTIVITY DATA
Stability Stable.
Conditions to Avoids Avoid open flames and high temperature.
Hazardous Polymerization Will not occur
INCOMPATIBILITY
Incompatible with Alkali or Alkaline Earth Metals-Powdered Al, Zn, Be, etc. Long term contact with water can
deplete stabilizers followed by slow hydrolysis which produces composite acids.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
Decomposition Products can be Hazardous. The only decomposition by product is Hydrogen Fluoride. The HF
levels are the lowest of all amongst other halocarbons (LPC 19th June 2000).
HEALTH AND HAZARD DATA
Health Hazardous (Acute and Chronic)
ANIMAL DATA
LC50 > 750,000 ppm in rats.
Oral ALD 9,000 mg/kg in rats.
Skin Absorption LD50 >2,000 mg/kg in rabbits.
Ames Assay Negative.
Micronucleus Negative.
The compound is not skin sensitizer in animals. Toxic effects noted in animals from exposure by inhalation at
concentrations of 10,000 ppm or greater include central nervous system effects, anesthetic effects, liver effects,
and non-specific preterminal effects. Preliminary results of a long term inhalation study at 300, 1000 or 5000 ppm
caused an increased in benign testicular and benign pancreatic tumors in male rats. None of these benign tumors
are considered life-threatening. No animals test reports are available to define reproductive hazards. Animal
testing indicates that this compound does not have embryo toxic effects. Tests in bacterial or mammalian cell
cultures demonstrate no mutagenic activity.
Material Safety Data Sheet No. H-008E-R AF11E (3 of 4)
HUMAN HEALTH EFFECT
Human health effects of over exposure by eye contact may include eye irritation with discomfort, tearing or
blurring of vision. Overexposure by inhalation to the vapors may cause temporary nervous system depression
with anaesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness; or
with gross overexposure (>20), possibly temporary alteration of heart’s electrical activity with irregular pulse.
CARCINOGENICITY
NTP None Established.
IARC Monographs None Established.
OSHA Regulated None Established.
SIGNS AND SYMPTOMS OF EXPOSURE
INHALATION
At normal room temperature AF11E cannot sustain a vapour, thus negating any inhalation problems under
normal conditions.
SKIN
The compound is not a skin irritant.
EYE
The compound causes mild eye irritation.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Intentional misuse or deliberate inhalation may cause possible disturbances of the cardiac rhythm,
catecholamine drugs, such as epinephrine should be considered only as a last resort in life-threatening
emergencies.
EMERGENCY AND FIRST AID PROCEDURES
INHALATION
If high concentration are inhaled, immediately remove to fresh air. Keep persons calm. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Call a physician.
In case of skin contact, flush with water for 15 minutes. Get medical attention if irritation is present.
SKIN CONTACT
EYE CONTACT
In case of eye contact, immediately flush eyes with plenty of water for 15 minutes. Call a physician.
INGESTION
No specific intervention is indicated as the compound is not likely to be hazardous by ingestion. Consult a
physician if necessary. Do not induce vomiting because the hazard of aspirating the material into the lungs is
considered greater than swallowing it.
Material Safety Data Sheet No. H-008E-R AF11E (4 of 4)
PRECAUTION FOR SAFE HANDLING AND USE
Steps to be Taken in Cases Material is Released or Spilled
NOTE
Review Fire and Explosion Hazard Data and Precautions to be taken in Handling and Storing before proceeding
with clean up. Use appropriate personal protective equipment during clean up.
DIKE SPILL
Prevent liquid from entering sewers, waterways or low areas. Ventilate area. Collect on absorbent material and
transfer to steel drums for recovery/disposal. Comply with Federal, States, and Local Regulations on reporting
releases.
WASTE DISPOSAL METHOD
Recover by distillation or remove to permitted waste disposal facility. Comply with Federal, State, and Local
Regulations.
PRECAUTION TO BE TAKEN IN HANDLING AND STORING
Use with sufficient ventilation to keep employee exposure below recommended limits. Provide adequate
ventilation for storage, handling, and use, especially for enclosed or low spaces. Avoid contact of liquid with eyes
and prolonged skin exposure. Do not allow product to contact open flame or electrical heating elements because
dangerous decomposition products may form.
STORAGE CONDITIONS
Clean, dry, well-ventilated area. Do not heat above 30oC.
CONTROL MEASURES
RESPIRATORY PROTECTION (SPECIFY TYPE)
Under normal manufacturing conditions, no respiratory protection is required when using this product. Self-
Contained breathing apparatus (SCBA is required if a large spill occurs).
VENTILATION
Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should be used
when large amounts are released. Mechanical ventilation should be used in low places.
EYE / SKIN PROTECTION
Impervious gloves should be used to avoid prolonged or repeated exposure. Chemical splash goggles should be
available for use as needed to prevent eye contact.
ADDITIONAL INFORMATION
OTHER COMMENTS
Though no ACGIH TLV or OSHA PEL are assigned, the result of long term toxicity testing is now being
discussed by PAFT I (Program for Alternative Fluorocarbon Toxicity Testing I).
