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Advanced Chemistry Practice Sheet

The document provides examples of organic chemistry reactions and questions testing understanding of reaction mechanisms. It includes questions about identifying products of reactions involving nitro compounds, halogen substitution, acid-base reactions of carboxylic acids and amines, and properties of functional groups. The last question involves identifying correct statements about reactivity patterns and physical properties.

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384 views3 pages

Advanced Chemistry Practice Sheet

The document provides examples of organic chemistry reactions and questions testing understanding of reaction mechanisms. It includes questions about identifying products of reactions involving nitro compounds, halogen substitution, acid-base reactions of carboxylic acids and amines, and properties of functional groups. The last question involves identifying correct statements about reactivity patterns and physical properties.

Uploaded by

amarsharma2401
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

P Prayaas 2.

0
W

APS by PS-17
(Anjaam Practice Sheet by Pankaj Sir)
O
14 15 D+
N N C
1. NO2

The possible products of the above reaction are:


NO2
O
14 15
+ O
(a) D N N (b) 14 15
C
N N D +

NO2
O
14 15
+ O
(c) D N N (d) 14 15
D N N +
C

1 Equivalent
2. Br – Cl

The major product is:

Cl Br

(a) (b)
Cl
Br

Br
(c) (d)
Br
Cl Cl

3. COOH
D2SO4
D

The possible major product of the above reaction is:


O O O O
(a) (b)
D D
D O O
O
(c) (d)
D
Prayaas 2.0 P
W

NH2
4. NaNO2 Base
HCl/0-5°C D

The possible final product of this reaction is:

(a) (b) (c) (d)

5.
HBr

The major product of the reaction is:


Br Br
Br
(a) (b) (c) (d)

Br
O

6. Br Br
NaNH2 O
(excess) Z D W

The compound ‘W’ is:


O

O O
O
(a) (b) O (c) (d)
O O
O
O O
O O
O O
O
7. An unknown saturated amine A yields an alkali soluble derivative when reacted with benzenesulfonyl chloride. Compound A on reaction
with nitrous acid gives an alcohol B, which responds to the haloform reaction. Hydrochloride of A contains 37.2% of chlorine. Find
numbers of carbon atoms in A.
Br
HBr
8. *Reactant

Br
The reactant ‘X’ can be:

(a) (b) (c) (d)


P Prayaas 2.0
W

9. *Which of the following indicates correct feasible products?


O
H
N
(a)
(i) CH3C N,conc. H2SO4
(ii) H3O+

OH

MgBr CHO

(b) HC(OC2H5)3 +

(c) (i) CH3Li (i) O3 (i) OH–


(ii) H3O+ (ii) Me2S (ii) D

CCl3

(d) Peroxide
+ CHCl3

10. *Which of the following are correct statements.


(a) A nitroso (– N O) group activates ortho-and para-positions towards both electrophilic and nucleophilic aromatic substitutions.
(b) Mg can be used in place of Zn in the Reformatsky reaction
(c) Furan has a lower boiling than pyrrole
NH2 C N
(d) has a lesser dipole moment than

N N

Answer Key
1. (d) 2. (c) 3. (a) 4. (c) 5. (b) 6. (a) 7. (3) 8. (b, c, d)
9. (a, b, c, d) 10. (a, c)

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