SAFETY DATA SHEET
Page 1 of 3
Product Name: FoamSMARTTM Standard PU Chemical Part B (MDI)
SDS No: 140 Revision No: 3 Issued by: Sha
Issue Date: 12 Nov 2018
Section 1 – Company Details
Company Name: FoamSMARTTM Products Tel: +65 6748 4292
Address: Blk 3017A, #01-12, Fax: +65 6749 0844
Ubi Road 1 Email:
[email protected] Singapore 408709
Section 2 – Composition
INGREDIENTS CAS No % CHIP Classification
2, 4’ - Diphenylmethane diisocyanate 5873-54-1 10 R20; R36/37/38; R42/43
4, 4’ - Diphenylmethane diisocyanate 101-68-8 60 R20; R36/37/38; R42/43
Diphenylmethane diisocyanate, isomers 9016-87-9 30 R20; R36/37/38; R42/43
& homologues
Section 3 – Hazardous Identification
Hazards identification:Irritant
Risk Phrases: R20 Harmful by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42/43 May cause sensitization by inhalation and skin contact.
Safety Phrases: S18 Handle and open container with care
S23 Do not breathe fumes
S28 After contact with skin, wash immediately with plenty of water and soap
S30 Never add water to this product
S32 In case of contact with eyes, rinse immediately with water and seek
medical advice
S38 In case of insufficient ventilation, wear suitable respiratory equipment
S45 In case of accident or if you feel unwell, seek medical advice immediately
Section 4 – First Aid Measures
Inhalation: Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation. If breathing
difficult, give oxygen. Call a physician. Effects may be delayed.
Skin: Wash immediately with water followed by soap and water. If symptoms persist, obtain
medical attention. Contaminated clothing should be laundered before reuse.
Eye: Irrigate immediately with plenty of clear water or an eyewash solution for at least 15
minutes. Apply sterile castor oil or simple eye ointment. Obtain medical attention.
Ingestion: If swallowed immediately call physician who will decide on need and method of emptying
the stomach.
Section 5 – Fire Fighting Measures
Extinguishing Media: Water fog, CO2, dry chemical, and foam.
Protective Equipment: Fire fighters must wear a full-face, positive pressure, self-contained
breathing apparatus and protective clothing.
Other Information: Products of combustion are CO, CO2, nitrogen oxide and ammonia. Do not
breathe smoke when burning
SAFETY DATA SHEET
Page 2 of 3
Product Name: FoamSMARTTM Standard PU Chemical Part B (MDI)
SDS No: 140 Revision No: 3 Issued by: Sha
Issue Date: 12 Nov 2018
Section 6 – Accidental Release Measures
Personal Precautions: Remove all possible sources of ignition in the surrounding area.
Environmental Precautions: Do not discharge into drains or river. Contain the spillage using bunding.
Clean-up Methods: Neutralize small spillage with a decontaminant (mixture of water with 2% of
a detergent and 5-10% of either concentrated ammonia or sodium
carbonate). Absorb large spillage onto an inert, non-flammable absorbent
carrier. Shovel the resulting mixture in waste drums and remove for
contamination and disposal. Wash the spillage area clean with liquid
contaminant. People dealing with major spillage should wear full protective
clothing including respiratory protection.
Other Information: Observe all relevant local regulations.
Section 7 – Handling and Storage
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use
adequate ventilation. Wash hands and face thoroughly after handling.
Storage: Do not store drums uncovered out of doors. Do not reseal containers unless it is
certain that no moisture contamination has occurred.
Section 8 – Exposure Control / Personal Protection
INGREDIENTS CAS No % CHIP Classification
2, 4’ - Diphenylmethane diisocyanate 5873-54-1 10 R20; R36/37/38; R42/43
4, 4’ - Diphenylmethane diisocyanate 101-68-8 60 R20; R36/37/38; R42/43
Diphenylmethane diisocyanate, isomers 9016-87-9 30 R20; R36/37/38; R42/43
& homologues
Respiratory Type Respiratory protection not required.
Eye Protection Non-fogging chemical safety goggles or safety glasses with side shields.
Glove Type Wear suitable impervious protective gloves such as PVC or Nitrile gloves.
Skin Protection Wear suitable impervious protective clothing.
Section 9 – Physical And Chemical Characteristics
Physical: Dark brown liquid
Odour: Characteristic
Density (25C): 1.24 g/cm3
Colour: Dark Brown
Water Solubility: Not soluble in water and reactive
Viscosity (25C): 200 – 300 cps
Section 10 – Stability and Reactivity
Stability: Stable
Products to Avoid: Water, alcohols and strong bases
Hazardous Reactions: Reaction with water/moisture produces CO2 gas. Exothermic reaction
with materials containing active hydrogen groups.
Hazardous Decomposition: Above 270C, it produces CO, HCN and Nitrogen oxide
SAFETY DATA SHEET
Page 3 of 3
Product Name: FoamSMARTTM Standard PU Chemical Part B (MDI)
SDS No: 140 Revision No: 3 Issued by: Sha
Issue Date: 12 Nov 2018
Section 11 – Toxicological Information
Inhalation: Inhalation of MDI mists or vapors may cause respiratory irritation, breathlessness, chest
discomfort and reduced pulmonary function.
Skin: Skin contact with MDI may result in irritation and a mild tanning action, depending on the
amount and length of contact.
Eyes: Direct eye contact with MDI products may produce severe watering, irritation and
inflammation of mucous membranes. Corneal opacity and discharge may result, if MDI is
not removed.
Ingestion: The effects of ingestion include irritation and burning of the mouth, esophagus, and stomach.
Section 12 – Ecological Information
Ecotoxicity: Not established
Mobility: Readily absorbed into soil. Soluble in water.
Persistence/ Degradability: Not readily biodegradable
Bioaccumulation: Does not bio accumulate significantly
Section 13 – Disposal Considerations
Disposal Operation: Disposal should be accordance with local, state or national legislation. The
generation of waste should be avoided or minimised wherever possible. If this is not
possible, destruction is to be in approved facility under controlled conditions.
Section 14 – Transport Information
Declaration for land shipment: ---
Declaration for sea shipment: ---
Declaration for shipment by air: ---
Other information: Not dangerous cargo. Irritating to skin and eyes. Keep dry. Avoid heat
above 50C and below 0C. Keep away from foodstuffs, acids and alkalis.
Section 15 – Regulatory Information
None known
Other Information:
Section 16 – Other This safety data sheet is prepared in accordance with Commission Regulation (EU)
Information
No 453/2010.
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. This company shall not be held liable damage resulting from handling or from contact with
the above product. We therefore provide no warranty, either explicit or otherwise regarding the suitability of
our products for any applications. It is the responsibility of the user to ensure that any proprietary rights and
existing laws and legislation are observed
