SAFETY DATA SHEET

UCRETE PART 2 COMMON SMALL

Version Revision Date: SDS Number: Date of last issue: -

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SECTION 1. IDENTIFICATION

Product name : UCRETE PART 2 COMMON SMALL

Product code : 000000000050345101 000000000050345101

Manufacturer or supplier's details

Company name of supplier : Master Builders-Construction Systems
US, LLC

Address : 23700 CHAGRIN BLVD

Beachwood OH 44122

Emergency telephone : ChemTel: +1-813-248-0585

Recommended use of the chemical and restrictions on use

Recommended use : Floor coating

Restrictions on use : Reserved for industrial and professional use.

National Emergency : USA: +1-800-255-3924 ChemTel contract no. MIS9240420

Telephone Number

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Acute toxicity (Inhalation - : Category 4
vapour)

Skin irritation : Category 2

Eye irritation : Category 2B

Respiratory sensitization : Category 1

Skin sensitization : Category 1

Carcinogenicity : Category 2

Specific target organ toxicity : Category 3 (Respiratory system)

- single exposure

Specific target organ toxicity : Category 2 (Olfactory organs, Respiratory system)

- repeated exposure (Inhala-
tion)

GHS label elements

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Hazard pictograms :

Signal Word : Danger

Hazard Statements : H332 Harmful if inhaled.

H315 + H320 Causes skin and eye irritation.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing diffi-
culties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Olfactory organs, Respira-
tory system) through prolonged or repeated exposure if inhaled.

Precautionary Statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
P285 In case of inadequate ventilation wear respiratory protec-
tion.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/
doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

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Other hazards
CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY
CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND
REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM
EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE,
INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR
CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME
INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS
INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY
SENSITIZATION.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : isocyanate

Components
Chemical name CAS-No. Concentration (% w/w)
Isocyanic acid, polymethylenepoly- 9016-87-9 >= 30 - < 50
phenylene ester (P-MDI)
Diphenylmethane-4,4'-diisocyanate 101-68-8 >= 30 - < 50
(MDI)
diphenylmethane-2,4'-diisocyanate 5873-54-1 >= 5 - < 10
1,3-Diazetidine-2,4-dione, 1,3-bis[4- 17589-24-1 >= 0.1 - < 1
[(4-isocyanatophenyl)methyl]phenyl]-
Isocyanic acid, polymethylenepoly- 57636-09-6 >= 0.1 - < 1
phenylene ester, polymer with alpha-
hydro-omega-hydroxypoly(oxy-1,2-
ethanediyl)
2,2'-Methylenediphenyl diisocyanate 2536-05-2 >= 0.1 - < 1
Actual concentration is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice : First aid personnel should pay attention to their own safety.
Immediately remove contaminated clothing.

If inhaled : Keep patient calm, remove to fresh air.

If symptoms persist, seek medical advice.

In case of skin contact : After contact with skin, wash immediately with plenty of water
and soap.
Under no circumstances should organic solvent be used.
If irritation develops, seek medical attention.

In case of eye contact : Contact lenses should be removed. Hold eyelids open and
flush with copious amounts of clean, fresh water or a special
eyewash solution and seek medical advice.

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If swallowed : Immediately rinse mouth and then drink 200-300 ml of water,

seek medical attention.
Do not induce vomiting unless told to by a poison control cen-
ter or doctor.

Most important symptoms : Causes skin and eye irritation.

and effects, both acute and May cause an allergic skin reaction.
delayed Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficul-
ties if inhaled.
May cause respiratory irritation.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated
exposure if inhaled.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam

Water spray
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : water jet

media

Hazardous combustion prod- : fumes/smoke

ucts harmful vapours
Carbon oxides
nitrogen oxides
carbon black

Further information : The degree of risk is governed by the burning substance and
the fire conditions.
If exposed to fire, keep containers cool by spraying with water.
Collect contaminated extinguishing water separately, do not
allow to reach sewage or effluent systems.
Contaminated extinguishing water must be disposed of in
accordance with official regulations.

Special protective equipment : Wear a self-contained breathing apparatus.

for fire-fighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
tive equipment and emer- Wear eye/face protection.
gency procedures Use personal protective clothing.
Handle in accordance with good building materials hygiene
and safety practice.

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Environmental precautions : Contain contaminated water/firefighting water.

Do not discharge into drains/surface waters/groundwater.

Methods and materials for : Pick up with suitable appliance and dispose of.
containment and cleaning up Dispose of absorbed material in accordance with regulations.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Avoid inhalation of dusts/mists/vapours.

Avoid skin contact.
Ensure adequate ventilation.
No special measures necessary provided product is used
correctly.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Further information on stor- : Keep only in the original container in a cool, dry, well-
age conditions ventilated place away from ignition sources, heat or flame.
Protect from direct sunlight.

Recommended storage tem- : 41 - 86 °F / 5 - 30 °C

perature

Further information on stor- : PROTECT FROM FREEZING.

age stability

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Isocyanic acid, polymeth- 9016-87-9 C 0.02 ppm OSHA Z-1
ylenepolyphenylene ester (P- 0.2 mg/m3
MDI)
C 0.02 ppm OSHA P0
0.2 mg/m3
TWA 0.005 ppm NIOSH REL
0.05 mg/m3
C 0.02 ppm NIOSH REL
0.2 mg/m3
Diphenylmethane-4,4'- 101-68-8 TWA value 0.005 ppm ACGIHTLV
diisocyanate (MDI)
REL value 0.005 ppm NIOSH
0.05 mg/m3

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Ceil_Time 0.020 ppm NIOSH

0.2 mg/m3
CLV 0.02 ppm 29 CFR
0.2 mg/m3 1910.1000
(Table Z-1)
CLV 0.02 ppm 29 CFR
0.2 mg/m3 1910.1000
(Table Z-1-A)
TWA 0.005 ppm ACGIH
C 0.02 ppm OSHA Z-1
0.2 mg/m3
C 0.02 ppm OSHA P0
0.2 mg/m3
TWA 0.005 ppm NIOSH REL
0.05 mg/m3
C 0.02 ppm NIOSH REL
0.2 mg/m3
diphenylmethane-2,4'- 5873-54-1 C 0.02 ppm OSHA Z-1
diisocyanate 0.2 mg/m3
C 0.02 ppm OSHA P0
0.2 mg/m3
TWA 0.005 ppm NIOSH REL
0.05 mg/m3
C 0.02 ppm NIOSH REL
0.2 mg/m3
2,2'-Methylenediphenyl diiso- 2536-05-2 C 0.02 ppm OSHA Z-1
cyanate 0.2 mg/m3
C 0.02 ppm OSHA P0
0.2 mg/m3
TWA 0.005 ppm NIOSH REL
0.05 mg/m3
C 0.02 ppm NIOSH REL
0.2 mg/m3
Engineering measures : Ensure adequate ventilation.

Personal protective equipment

Respiratory protection : Wear appropriate certified respirator when exposure limits
may be exceeded.
Wear a NIOSH-certified (or equivalent) respirator as neces-
sary.

Hand protection

Remarks : Chemical resistant protective gloves Manufacturer's direc-

tions for use should be observed because of great diversity of
types.

Eye protection : Wear safety glasses with side shields or goggles.

Skin and body protection : Impervious clothing

Choose body protection according to the amount and con-
centration of the dangerous substance at the work place.

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Protective measures : Do not inhale dust/fumes/aerosols.

Avoid contact with the skin, eyes and clothing.
Avoid exposure - obtain special instructions before use.
Handle in accordance with good building materials hygiene
and safety practice.
Wearing of closed work clothing is recommended.

Hygiene measures : When using, do not eat, drink or smoke.

Hands and/or face should be washed before breaks and at
the end of the shift.
At the end of the shift the skin should be cleaned and skin-
care agents applied.
Gloves must be inspected regularly and prior to each use.
Replace if necessary (e.g. pinhole leaks).
When using do not eat or drink.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : dark brown

Odor : faintly aromatic

Odor Threshold : not determined

pH : 8-9
slightly alkaline

Melting temperature : Not applicable

Boiling point/boiling range : > 565 °F / > 296 °C

(1.013 hPa)

Flash point : > 392 °F / > 200 °C

Method: Flashpoint test using closed cup, determination of

flashpoint.

Evaporation rate : not determined

Flammability (liquids) : Not classified as a flammability hazard

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapor pressure : No data available

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Relative vapor density : not determined

Relative density : No data available

Density : approx. 1.24 g/cm3 (68 °F / 20 °C)

Solubility(ies)
Water solubility : insoluble (68 °F / 20 °C)

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Autoignition temperature : > 752 °F / > 400 °C

Decomposition temperature : No decomposition if stored and handled as pre-

scribed/indicated.

Viscosity
Viscosity, dynamic : approx. 90 - 300 mPa.s (73 °F / 23 °C)

Viscosity, kinematic : No data available

Explosive properties : Not explosive

Oxidizing properties : not fire-propagating

Sublimation point : No data available

Molecular weight : No data available

Metal corrosion rate : No corrosive effect on metal.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No hazardous reactions if stored and handled as pre-

scribed/indicated.

Chemical stability : The product is stable if stored and handled as pre-

scribed/indicated.

Possibility of hazardous reac- : The product is stable if stored and handled as pre-
tions scribed/indicated.

Conditions to avoid : See SDS section 7 - Handling and storage.

Incompatible materials : Strong acids

Strong bases
Strong oxidizing agents
Strong reducing agents

Hazardous decomposition : No hazardous decomposition products if stored and handled

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products as prescribed/indicated.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if inhaled.
Product:
Acute inhalation toxicity : ATE: approx. 2.0 mg/l
Exposure time: 4 h
Remarks: Determined for mist

Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye irritation
Causes eye irritation.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Suspected of causing cancer.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
May cause respiratory irritation.
STOT-repeated exposure
May cause damage to organs (Olfactory organs, Respiratory system) through prolonged or re-
peated exposure if inhaled.
Aspiration toxicity
Not classified based on available information.
Further information

Product:
Remarks : Health injuries are not known or expected under normal use.
The product has not been tested. The statements on toxicolo-
gy have been derived from the properties of the individual
components.

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SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Acute aquatic toxicity : This product has no known ecotoxicological effects.

Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Persistence and degradability

Product:
Biodegradability : Remarks: Taking into consideration the properties of several
ingredients, the product is estimated not to be readily biode-
gradable according to OECD classification.

Bioaccumulative potential

Components:

Isocyanic acid, polymethylenepolyphenylene ester (P-MDI):

Bioaccumulation : Remarks: Accumulation in organisms is not to be expected.

Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Do not release untreated into natural waters.
mation Do not allow to enter soil, waterways or waste water channels.
The product has not been tested. The statements on ecotoxi-
cology have been derived from the properties of the individual
components.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with national, state and local regula-
tions.
Do not discharge into drains/surface waters/groundwater.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.

Contaminated packaging : Contaminated packaging should be emptied as far as possible

and disposed of in the same manner as the sub-
stance/product.

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SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

SARA 313 : The following components are subject to reporting levels es-
tablished by SARA Title III, Section 313:

Isocyanic acid, 9016-87-9 >= 30 - < 50 %

polymethylene-
polyphenylene
ester (P-MDI)

Diphenylme- 101-68-8 >= 30 - < 50 %

thane-4,4'-
diisocyanate
(MDI)

US State Regulations

Pennsylvania Right To Know

Isocyanic acid, polymethylenepolyphenylene ester (P-MDI) 9016-87-9
Diphenylmethane-4,4'-diisocyanate (MDI) 101-68-8
diphenylmethane-2,4'-diisocyanate 5873-54-1
New Jersey Right To Know
Isocyanic acid, polymethylenepolyphenylene ester (P-MDI) 9016-87-9
Diphenylmethane-4,4'-diisocyanate (MDI) 101-68-8
diphenylmethane-2,4'-diisocyanate 5873-54-1
The ingredients of this product are reported in the following inventories:
TSCA : All substances listed as active on the TSCA inventory

DSL : All components of this product are on the Canadian DSL

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SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

Flammability
HEALTH

1 FLAMMABILITY

Health Instability
2 0 PHYSICAL HAZARD

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
cant hazards or risks. The "*" represents
Special hazard a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

29 CFR 1910.1000 (Table Z- : OSHA - Table Z-1-A (29 CFR 1910.1000)
1-A)
29 CFR 1910.1000 (Table Z- : OSHA - Table Z-1 (Limits for Air Contaminants) 29 CFR
1) 1910.1000
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIHTLV : American Conference of Governmental Industrial Hygienists -
threshold limit values (US)
NIOSH : NIOSH Pocket Guide to Chemical Hazards (US)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants -
1910.1000
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
29 CFR 1910.1000 (Table Z- : Ceiling Limit Value:
1-A) / CLV
29 CFR 1910.1000 (Table Z- : Ceiling Limit Value:
1) / CLV
ACGIH / TWA : 8-hour, time-weighted average
ACGIHTLV / TWA value : Time Weighted Average (TWA):
NIOSH / Ceil_Time : Ceiling Limit Value and Time Period (if specified):
NIOSH / REL value : Recommended exposure limit (REL):
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / C : Ceiling value not be exceeded at any time.
OSHA P0 / C : Ceiling limit
OSHA Z-1 / C : Ceiling

AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa-

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tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of
the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso-
ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har-
monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification
System; IARC - International Agency for Research on Cancer; IATA - International Air Transport
Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan-
gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In-
ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus-
trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population;
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin-
istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC
- No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and
Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative

Revision Date : 05/26/2021

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

US / EN

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