Safety Data Sheet according to Regulation (EC) No 1907/2006

Page 1 of 10
SDS No. : 563770
V001.0
Revision: 30.08.2016
POLYCOAT RBE-15 printing date: 28.11.2017
Replaces version from:
-

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
POLYCOAT RBE-15
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Bituminous product

1.3. Details of the supplier of the safety data sheet

Henkel Polybit Industries Ltd.
PO BOX 293
Umm Al Quwain

Utd.Arab.Emir.

Phone: +971 (6) 7670777

Fax-no.: +971 (6) 7670197

[email protected]

1.4. Emergency telephone number

0800 202 202

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):
Acute hazards to the aquatic environment Category 1
H400 Very toxic to aquatic life.
Chronic hazards to the aquatic environment Category 3
H412 Harmful to aquatic life with long lasting effects.

2.2. Label elements

Label elements (CLP):

Hazard pictogram:

Signal word: Warning

Hazard statement: H410 Very toxic to aquatic life with long lasting effects.
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Supplemental information Contains 1,2-Benzisothiazol-3(2H)-one. May produce an allergic reaction.

Precautionary statement: P102 Keep out of reach of children.

Precautionary statement: P262 Do not get in eyes, on skin, or on clothing.

Prevention P273 Avoid release to the environment.

Precautionary statement: P501 Dispose of contents/container in accordance with national regulation.

Disposal

2.3. Other hazards

None if used properly.
Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

General chemical description:

Bituminous product
Base substances of preparation:
Bitumen

Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components EC Number content Classification

CAS-No. REACH-Reg No.
Non-ionic surfactants~ 0,25- < 1 % Aquatic Acute 1
H400
Aquatic Chronic 1
H410
Acute Tox. 4
H302
Eye Dam. 1
H318
1,2-Benzisothiazol-3(2H)-one 220-120-9 50- < 500 PPM Aquatic Acute 1
2634-33-5 H400
Aquatic Chronic 2
H411
Acute Tox. 4; Oral
H302
Skin Irrit. 2
H315
Skin Sens. 1
H317
Eye Dam. 1
H318

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information:
In case of adverse health effects seek medical advice.

Inhalation:
Move to fresh air, consult doctor if complaint persists.

Skin contact:
Rinse with running water and soap. Skin care. Remove contaminated clothes immediately.
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Eye contact:
Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remain (intensive smarting,
sensitivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital.

Ingestion:
Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed
No data available.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:
carbon dioxide, foam, powder, water spray jet, fine water spray

Extinguishing media which must not be used for safety reasons:

High pressure waterjet

5.2. Special hazards arising from the substance or mixture

In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.
Wear protective equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective equipment.
Avoid contact with skin and eyes.
Danger of slipping on spilled product.

6.2. Environmental precautions

Do not empty into drains / surface water / ground water.

6.3. Methods and material for containment and cleaning up

Remove with liquid-absorbing material (sand, peat, sawdust).
Dispose of contaminated material as waste according to Section 13.

6.4. Reference to other sections

See advice in section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid skin and eye contact.

Hygiene measures:
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.

7.2. Conditions for safe storage, including any incompatibilities

Do not store together with food or other consumables (coffee, tea, tobacco, etc.).

7.3. Specific end use(s)

Bituminous product
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SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
South Africa

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Asphalt 5 Time Weighted Average ZA REL
8052-42-4 (TWA):
[ASPHALT, PETROLEUM FUMES]
Asphalt 10 Short Term Exposure ZA REL
8052-42-4 Limit (STEL):
[ASPHALT, PETROLEUM FUMES]

Biological Exposure Indices:

None

8.2. Exposure controls:

Respiratory protection:
Suitable breathing mask when there is inadequate ventilation.
Combination filter: ABEKP (EN 14387)
This recommendation should be matched to local conditions.

Hand protection:
In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374.
material thickness > 0.1 mm
Perforation time > 480 minutes
In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than
those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the
specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be
replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the
relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is
drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating
conditions.

Eye protection:
Goggles which can be tightly sealed.
Protective eye equipment should conform to EN166.

Skin protection:
Suitable protective clothing
Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.

Advices to personal protection equipment:

The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be
conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions.
Personal protective equipment should conform to the relevant EN standard.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance liquid
dark brown
Odor Characteristic
Odour threshold No data available / Not applicable

pH 9 - 11
(150 °C (302 °F))
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Initial boiling point No data available / Not applicable

Flash point Not applicable
Decomposition temperature No data available / Not applicable
Vapour pressure No data available / Not applicable
Density 0,95 - 1,05 g/cm3
(25 °C (77 °F))
Bulk density No data available / Not applicable
Viscosity No data available / Not applicable
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) No data available / Not applicable
Solidification temperature No data available / Not applicable
Melting point No data available / Not applicable
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
Partition coefficient: n-octanol/water No data available / Not applicable
Evaporation rate No data available / Not applicable
Vapor density No data available / Not applicable
Solid content 60 - 65 %
(110 °C )
Oxidising properties No data available / Not applicable

9.2. Other information

No data available / Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
None if used for intended purpose.

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

See section reactivity

10.4. Conditions to avoid

None if used for intended purpose.

10.5. Incompatible materials

None if used properly.

10.6. Hazardous decomposition products

None known

SECTION 11: Toxicological information

11.1. Information on toxicological effects

General toxicological information:

The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.

Sensitizing:
An allergic reaction cannot be excluded after repeated skin contact.
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Acute oral toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
1,2-Benzisothiazol-3(2H)- Acute 670 mg/kg oral Expert judgement
one toxicity
2634-33-5 estimate
(ATE)
1,2-Benzisothiazol-3(2H)- LD50 670 - 784 rat EPA Guideline
one mg/kg
2634-33-5

Acute dermal toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
1,2-Benzisothiazol-3(2H)- LD50 > 5.000 mg/kg dermal rat EPA OPP 81-2 (Acute Dermal
one Toxicity)
2634-33-5

Skin corrosion/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
1,2-Benzisothiazol-3(2H)- moderately irritating 4h rabbit EPA OPP 81-5 (Acute Dermal
one Irritation)
2634-33-5

Serious eye damage/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
1,2-Benzisothiazol-3(2H)- highly irritating 48 h rabbit EPA OPP 81-4 (Acute Eye
one Irritation)
2634-33-5

Respiratory or skin sensitization:

Hazardous components Result Test type Species Method

CAS-No.
1,2-Benzisothiazol-3(2H)- sensitising Guinea pig guinea pig Magnusson and Kligman
one maximisat Method
2634-33-5 ion test

Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method

CAS-No. Route of activation /
administration Exposure time
1,2-Benzisothiazol-3(2H)- negative bacterial reverse with and without OECD Guideline 471
one mutation assay (e.g (Bacterial Reverse Mutation
2634-33-5 Ames test) Assay)
negative mammalian cell with and without OECD Guideline 476 (In vitro
gene mutation assay Mammalian Cell Gene
Mutation Test)
1,2-Benzisothiazol-3(2H)- negative oral: gavage mouse OECD Guideline 474
one (Mammalian Erythrocyte
2634-33-5 Micronucleus Test)
negative oral: unspecified rat OECD Guideline 486
(Unscheduled DNA Synthesis
(UDS) Test with Mammalian
Liver Cells in vivo)

Repeated dose toxicity

Hazardous components Result Route of Exposure time / Species Method

CAS-No. application Frequency of
treatment
1,2-Benzisothiazol-3(2H)- NOAEL=10 mg/kg oral: gavage 90 daysdaily rat OECD Guideline 408
one (Repeated Dose 90-Day Oral
2634-33-5 Toxicity in Rodents)
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SECTION 12: Ecological information

General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.
Do not empty into drains, soil or bodies of water.

12.1. Toxicity

Ecotoxicity:
Harmful to aquatic life with long lasting effects.

Hazardous components Value Value Acute Exposure Species Method

CAS-No. type Toxicity time
Study
1,2-Benzisothiazol-3(2H)-one LC50 1,4 mg/l Fish 96 h Salmo gairdneri (new name: OECD Guideline
2634-33-5 Oncorhynchus mykiss) 203 (Fish, Acute
Toxicity Test)
NOEC 0,21 mg/l Fish 30 d Oncorhynchus mykiss OECD Guideline
215 (Fish, Juvenile
Growth Test)
1,2-Benzisothiazol-3(2H)-one EC50 1,05 mg/l Daphnia 48 h Daphnia magna OECD Guideline
2634-33-5 202 (Daphnia sp.
Acute
Immobilisation
Test)
1,2-Benzisothiazol-3(2H)-one EC50 0,11 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline
2634-33-5 201 (Alga, Growth
Inhibition Test)
EC10 0,04 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline
201 (Alga, Growth
Inhibition Test)
1,2-Benzisothiazol-3(2H)-one EC 50 23 mg/l Bacteria 3h activated sludge of a OECD Guideline
2634-33-5 predominantly domestic sewage 209 (Activated
Sludge, Respiration
Inhibition Test)
1,2-Benzisothiazol-3(2H)-one NOEC 1,2 mg/l chronic 21 d Daphnia magna OECD 211
2634-33-5 Daphnia (Daphnia magna,
Reproduction Test)

12.2. Persistence and degradability

Hazardous components Result Route of Degradability Method

CAS-No. application
1,2-Benzisothiazol-3(2H)-one Rapidly degradable Not specified > 70 % OECD Guideline 309 (Aerobic
2634-33-5 Mineralisation in Surface
WaterSimulation Biodegradation
Test)

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Hazardous components LogKow Bioconcentration Exposure Species Temperature Method

CAS-No. factor (BCF) time
1,2-Benzisothiazol-3(2H)-one 6,62 Not specified OECD Guideline 305
2634-33-5 (Bioconcentration: Flow-
through Fish Test)
1,2-Benzisothiazol-3(2H)-one <3 EU Method A.8 (Partition
2634-33-5 Coefficient)

12.5. Results of PBT and vPvB assessment

Hazardous components PBT/vPvB

CAS-No.
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1,2-Benzisothiazol-3(2H)-one Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
2634-33-5 Bioaccumulative (vPvB) criteria.

12.6. Other adverse effects

No data available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product disposal:
Dispose of waste and residues in accordance with local authority requirements.

Disposal of uncleaned packages:

Use packages for recycling only when totally empty.

Waste code
08 04 09 Waste adhesives and sealants containing organic solvents or other dangerous substances
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SECTION 14: Transport information

14.1. UN number

ADR 3082
RID 3082
ADN 3082
IMDG 3082
IATA 3082

14.2. UN proper shipping name

ADR ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Non-ionic

surfactants)
RID ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Non-ionic
surfactants)
ADN ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Non-ionic
surfactants)
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Non-ionic
surfactants)
IATA Environmentally hazardous substance, liquid, n.o.s. (Non-ionic surfactants)

14.3. Transport hazard class(es)

ADR 9
RID 9
ADN 9
IMDG 9
IATA 9

14.4. Packing group

ADR III
RID III
ADN III
IMDG III
IATA III

14.5. Environmental hazards

ADR not applicable

RID not applicable
ADN not applicable
IMDG Marine pollutant
IATA not applicable

14.6. Special precautions for user

ADR not applicable

Tunnelcode: (E)
RID not applicable
ADN not applicable
IMDG not applicable
IATA not applicable

The transport classifications in this section apply generally to packed and bulk goods alike. For
containers with a net volume of no more than 5 L for liquid substances or a net mass of no more than 5
kg for solid substances per individual or inner package, the exemptions SP 375 (ADR), 197 (IATA),
969 (IMDG) may be applied, which can result in a deviation from the transport classification for packed
goods.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable
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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content 0%
(VOCV 814.018 VOC regulation
CH)

15.2. Chemical safety assessment

A chemical safety assessment has not been carried out.

SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.