Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 1
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
1. Identification of the substance/preparation and company
Trade name
DODIGEN 226
Material number: 108068
Use of the substance/preparation.
Industry sector : Raw Materials (Base Chemicals)
Type of use : Raw material for disinfectants.
Identification of the company
PT Clariant Indonesia
Gatot Subroto Km. 4, Jl. Kalisabi No.1, Kec. Cibodas
15138 Tangerang, Indonesia
Telephone no. : +62 21 5538589
Information about the substance/preparation
Corp Product Stewardship
Emergency telephone number : 00800-5121 5121
2. Composition/information on ingredients
Chemical characterization
Aqueous solution of C12-C16-alkyl dimethylbenzyl ammonium chloride
Hazardous ingredients
C12-C16 Alkyldimethylbenzyl ammonium chloride
Concentration : 50 %
CAS number : 68424-85-1
EINECS number : 270-325-2
Hazard symbols C N
R phrases 22 34 50
3. Hazards identification
Harmful if swallowed.
Causes burns.
Very toxic to aquatic organisms.
4. First aid measures
General information
Remove soiled or soaked clothing immediately
After contact with skin
In case of contact with skin wash off immediately with soap and water
Summon a doctor immediately.
Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 2
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
After contact with eyes
Summon a doctor immediately.
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of
water.
After ingestion
When swallowed, allow water to be drunk.
Do not induce vomiting.
Summon a doctor immediately.
Advice to doctor
Symptoms
No symptoms known currently.
Hazards
No hazards known at this time.
Treatment
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
carbon dioxide
water spray jet
foam
dry powder
Extinguishing media that must not be used for safety reasons
strong water jet
Special hazards from the substance itself, its combustion products or from its vapours
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrous gases (NOx)
Hydrogen chloride (HCl)
Special protective equipment for firefighting
Use self-contained breathing apparatus
6. Accidental release measures
Personal precautions
Wear suitable personal protective equipment.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Take up with absorbent material (eg sand, kieselguhr, universal binder)
Additional information
Information regarding Safe handling, see chapter 7.
Information regarding personal protective measures see, chapter 8.
Information regarding Waste Disposal, see chapter 13.
Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 3
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
7. Handling and storage
Advice on safe handling
Ensure adequate ventilation.
Open and handle container with care.
Advice on protection against fire and explosion
No special measures necessary
Requirements for storage rooms and vessels
Do not use steel containers.
Further information on storage conditions
Keep container tightly closed in a cool, well-ventilated place
- sensitive to frost - In case of the product becoming opaque, thickening or being frozen due
to the effects of cold, allow to thaw slowly at room temperature. Stir briefly before use.
Keep only in the original container at temperature not exceeding 50 °C
8. Exposure controls/personal protection
General protective measures
Avoid contact with skin
Avoid contact with eyes
Hygiene measures
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary, face
shield.)
Body protection : Depending on the degree of hazard, when handling corrosive
substances, aprons, boots or full protective clothing made of
suitable materials (e.g. rubberized or PVC-coated) must also
be worn.
9. Physical and chemical properties
Form : Liquid
Colour : colourless
Odour : slight, original odour
Melting point : approx. -5 °C
Boiling temperature : approx. 100 °C
Flash point : 160 - 170 °C
Ignition temperature : not tested.
Oxidizing properties : Not applicable
Self-ignition temperature : not self-igniting
Lower explosion limit : not tested.
Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 4
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
Upper explosion limit : not tested.
Evaporation rate : not tested.
Vapour pressure : not tested.
Density : 0,98 g/cm3 (20 °C)
Method : DIN 51757
Bulk density : Not applicable
Vapour density in relation to not tested.
air :
Solubility in water : (20 °C)
soluble
Soluble in ... : fat
not tested.
pH value : 6 - 7 (20 °C, 50 g/l)
Octanol/water partition Not applicable
coefficient (log Pow) :
Viscosity (dynamic) : 100 - 300 mPa.s (20 °C)
Source : CEFIC/APAG
Viscosity (kinematic) : not tested.
Combustion number : Not applicable
10. Stability and reactivity
Thermal decomposition : > 350 °C
Method : DTA
Hazardous reactions
No hazardous reactions when stored and handled according to prescribed instructions.
Hazardous decomposition products
When handled and stored appropriately, no dangerous decomposition products are known
Conditions to avoid
None known.
Materials to avoid
not known
11. Toxicological information
Acute oral toxicity : LD50 500 - 2.000 mg/kg (rat)
Method : OECD 401
Acute inhalation toxicity : not tested.
Acute dermal toxicity : not tested.
Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 5
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
Irritant effect on skin : corrosive (rabbit)
Method : OECD 404
Irritant effect on eyes : risk of serious damage to eyes
Method : OECD 405
Information derived from the corrosive effect on skin
Sensitization : not tested.
Repeated dose toxicity: not tested.
Mutagenicity : Not mutagenic in Ames Test.
Teratogenicity : not tested.
Carcinogenicity : not tested.
Toxicity to reproduction: not tested.
12. Ecological information
Biodegradability : > 80 %
Method : OECD 301 A
The product is readily biodegradable according to OECD
criteria.
Fish toxicity : LC50 1 - 10 mg/l (96 h, zebra fish)
Method : OECD 203
Daphnia toxicity : EC50 0,028 mg/l (24 h)
Method : DIN 38412 T.11
Algae toxicity : EC50 0,049 mg/l (72 h, Selenastrum capricornutum)
Method : OECD 201
Source : Analogy
Bacteria toxicity : EC50 10 mg/l (activated sludge)
Method : OECD 209
Chemical oxygen demand 1.210 mg/g
(COD) :
Bioaccumulation: not tested.
Remarks
No data available.
13. Disposal considerations
Product
In accordance with local authority regulations, take to special waste incineration plant
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste
Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 6
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
14. Transport information
IATA
Proper shipping name: Corrosive liquid, n.o.s.
Class: 8
Packing group: II
UN/ID number: UN 1760
Primary risk: 8
Remarks Shipment permitted
Hazard inducer(s): Alkyldimethylbenzylammoniumchloride
IMDG
Proper shipping name: Corrosive liquid, n.o.s.
Class: 8
Packing group: II
UN no. UN 1760
Primary risk: 8
Remarks Shipment permitted
Hazard inducer(s): Alkyldimethylbenzylammoniumchloride
Marine pollutant: Marine Pollutant
EmS : F-A S-B
15. Regulatory information
Labelling in accordance with EC-Directives
hazard warning labelling compulsory
Hazard symbols
C Corrosive
N Dangerous for the environment
Hazardous component(s) to be indicated on label
C12-C16 Alkyldimethylbenzyl ammonium chloride
R phrases
22 Harmful if swallowed.
34 Causes burns.
50 Very toxic to aquatic organisms.
Safety data sheet in accordance with
2001/58/EC
DODIGEN 226 Page 7
Substance key: SXR024642 Revision Date: 13.11.2013
Version : 3 - 4 / RI Date of printing : 21.11.2013
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
28.2 After contact with skin, wash immediately with water and soap.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
61 Avoid release to the environment. Refer to special instructions/Safety data
sheets.
National regulations
Other regulations
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.
16. Other information
Observe national and local legal requirements
Text of the R-phrases which are allocated to the ingredients/components mentioned
in section 2 of this Safety Data Sheet.
22 Harmful if swallowed.
34 Causes burns.
50 Very toxic to aquatic organisms.
The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply
any guarantee of a particular or general specification. It is the responsibility of the user of
the product to ensure to his satisfaction that the product is suitable for the intended purpose
and method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.
