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Assignment- Ch-2 - Solutions
Q1-Define with example-(a) Raoult’s law i) for volatile
solute ii) for non volatile solute (b) Henry law with application (c) Osmotic pressure (d) Azeotrope (e) Vant Hoff factor (f) Isotonic solution (g) Colligative properties (h) Antifreeze (i) Reverse osmosis (j) Abnormal molar mass (k) Ideal solution (l) Molal elevation constant (m) Molal depression constant Q2- Explain +ve and –ve deviation from Raoult’s law with example. Q3-Give reasons- (a) Osmotic pressure of 1M NaCl is twice of osmotic pressure of 1M glucose sol? (b) Osmotic pressure method is preferred over elevation in Boiling point method to determine the molar mass of biomolecules. (c) Aquatic animals are more comfortable in cold water than in warm water. (d) Liquid NH3 bottle is cooled in ice before opening it
f) In cold countries ethylene glycol is added to water to be
used as coolant for automobiles. g)- Temperature of solution increases when chloroform is added to acetone. h)Intravenous injection should be isotonic with 0.91% NaCl solution. i)-The Boiling point of a liquid increases while freezing pt decreases when non-volatile solute is added to it. j)- Which will show more elevation in boiling pt and why 1m NaCl or 1m BaCl2 sol. Q4- Write the condition resulting in reverse osmosis. Give application of reverse osmosis. Q5- On mixing 10ml of A and 10ml of B the volume of resulting sol was 20.1ml.what type of deviation do you expect and why? Q6- Which of the following solution has highest depression freezing pt and why. 1m NaCl or 1m glucose Q7- Give similarity and difference between Raoult’s law and Henry’s law Q8- Blood cells are isotonic with 0.91% NaCl solution. What happens when blood cells are placed in solution containing a) 1.2% NaCl solution b) 0.4% NaCl solution Q9- How does sprinkling of salt help in clearing the snow covered roads in hilly areas explain Q10- Can we separate the components of azeotropic mixture by distillation explain Q11- At the same temperature, H2 is more soluble in water than helium. Which of them will have a higher value of KH and why? Q12- Osmotic pressure method has advantage over other methods to determine the molar mass of macro molecules and why? Q13- Explain why on addition of one mol of NaCl to 1L of water, the boiling point of water increases . Q14-Helium is used in diving apparatus why? Q15-Why is the molar mass determined by measuring a colligative property in case of some solutes abnormal ? Explain Q16- When 3.26g of selenium dissolved in 226g of benzene the observed frezzing point is 0.1120C lower than for pure benzene. Find out the molecular formula of selenium ( At mass Se = 78.8g / mol, Kf = 4.9 K kg / mol) Q17- 1.0 molal aqueous solution of trichloroacetic acid (C Cl3COOH) is heated to its boiling point. The solution has the boiling point of 100.180C. Determine the vant hoff factor for this acid. (Kb = 0.52 K kg / mol) Q18- Calculate the boiling point of solution when 2g of Na2SO4 (M= 142g / mol was dissolved in 50g of water, assuming Na2SO4 is completely dissociated. (Kb = 0.52 K kg /mol) Q19- A 0.01 molal aqueous solution of AlCl3 freezes at - 0.0680C. Calculate the percentage of dissociation. (Kf 1.86 K kg /mol) Q20- A solution containing 15g of urea (M=60g / mol) per litre of solution in water has same osmotic pressure as a solution of glucose (M=180g /mol) in water. Calculate the mass of glucose present in 1L of its solution.