Scribd
Upload
53 views4 pages

Assignment Solutions

Uploaded by

sunilk24423
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
53 views4 pages

Assignment Solutions

Uploaded by

sunilk24423
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 4

Assignment- Ch-2 - Solutions

Q1-Define with example-(a) Raoult’s law i) for volatile


solute ii) for non volatile solute (b) Henry law with
application (c) Osmotic pressure (d) Azeotrope (e) Vant
Hoff factor (f) Isotonic solution (g) Colligative properties (h)
Antifreeze (i) Reverse osmosis (j) Abnormal molar mass
(k) Ideal solution (l) Molal elevation constant (m) Molal
depression constant
Q2- Explain +ve and –ve deviation from Raoult’s law with
example.
Q3-Give reasons-
(a) Osmotic pressure of 1M NaCl is twice of
osmotic pressure of 1M glucose sol?
(b) Osmotic pressure method is preferred over
elevation in Boiling point method to determine the
molar mass of biomolecules.
(c) Aquatic animals are more comfortable in cold water
than in warm water.
(d) Liquid NH3 bottle is cooled in ice before opening it

f) In cold countries ethylene glycol is added to water to be


used as coolant for automobiles.
g)- Temperature of solution increases when chloroform is
added to acetone.
h)Intravenous injection should be isotonic with 0.91%
NaCl solution.
i)-The Boiling point of a liquid increases while freezing pt
decreases when non-volatile solute is added to it.
j)- Which will show more elevation in boiling pt and why
1m NaCl or 1m BaCl2 sol.
Q4- Write the condition resulting in reverse osmosis. Give
application of reverse osmosis.
Q5- On mixing 10ml of A and 10ml of B the volume of
resulting sol was 20.1ml.what type of deviation do you
expect and why?
Q6- Which of the following solution has highest
depression freezing pt and why. 1m NaCl or 1m glucose
Q7- Give similarity and difference between Raoult’s law
and Henry’s law
Q8- Blood cells are isotonic with 0.91% NaCl solution.
What happens when blood cells are placed in solution
containing
a) 1.2% NaCl solution
b) 0.4% NaCl solution
Q9- How does sprinkling of salt help in clearing the snow
covered roads in hilly areas explain
Q10- Can we separate the components of azeotropic
mixture by distillation explain
Q11- At the same temperature, H2 is more soluble in
water than helium. Which of them will have a higher value
of KH and why?
Q12- Osmotic pressure method has advantage over other
methods to determine the molar mass of macro
molecules and why?
Q13- Explain why on addition of one mol of NaCl to 1L of
water, the boiling point of water increases .
Q14-Helium is used in diving apparatus why?
Q15-Why is the molar mass determined by measuring a
colligative property in case of some solutes abnormal ?
Explain
Q16- When 3.26g of selenium dissolved in 226g of
benzene the observed frezzing point is 0.1120C lower than
for pure benzene. Find out the molecular formula of
selenium ( At mass Se = 78.8g / mol, Kf = 4.9 K kg / mol)
Q17- 1.0 molal aqueous solution of trichloroacetic acid
(C Cl3COOH) is heated to its boiling point. The solution
has the boiling point of 100.180C. Determine the vant hoff
factor for this acid. (Kb = 0.52 K kg / mol)
Q18- Calculate the boiling point of solution when 2g of
Na2SO4 (M= 142g / mol was dissolved in 50g of water,
assuming Na2SO4 is completely dissociated. (Kb = 0.52 K
kg /mol)
Q19- A 0.01 molal aqueous solution of AlCl3 freezes at -
0.0680C. Calculate the percentage of dissociation. (Kf 1.86
K kg /mol)
Q20- A solution containing 15g of urea (M=60g / mol) per
litre of solution in water has same osmotic pressure as a
solution of glucose (M=180g /mol) in water. Calculate the
mass of glucose present in 1L of its solution.

You might also like