C

SEC: JR_*CO-SC Date: 22-01-22

Time: 3 Hrs Max. Marks: 186
22-01-22_JR.IIT_STAR CO-SC (MODEL-B)_JEE ADV_WAT-36_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Sound waves (longitudinal waves) as
pressure waves, displacement waves, velocity of sound waves and
echoes, Power, Intensity in sound waves, Organ pipes, Experiment:
Speed of sound in air at room temperature using a resonance tube
PREVIOUS WEEK (20%): Superposition (Interference) of waves,
Reflection and transmission of waves at a boundary, Standing waves
& modes of vibration of stretched strings, energy and power in
standing waves. (Exclude: Sound Wave)
CHEMISTRY: PRESENT WEEK (80%): Alkenes: Preparation, Mechanism of
Elimination reactions (E1, E2, E1CB) (Including Hoffman elimination
and pyrolysis of ester)
PREVIOUS WEEK (20%): Alkanes: Preparation of alkanes from
(Hydrogenation, Kolbe electrolysis), Preparation of alkanes from
different compounds(Wurtz reaction, Reductions, sodalime
decarboxylation, Hydroboration acidolysis), Preparation of
alkanes from different compounds, Alkane preparation,
Physical properties of alkanes , reactions of alkanes,
Mechanism of Free radical Substitution
MATHEMATICS: PRESENT WEEK (80%): Equation of Plane, Distance of point from
plane, angle between two planes, Family of Planes, Unsymmetrical
form of line, Image of point and line with respect to plane, System of
three planes
PREVIOUS WEEK (20%): 3D-GEOMETRY : Introduction of 3-D,
Direction Ratios and Direction Cosines, Equation of straight line in
Space, Angle between two lines and intersection of two lines, Skew
lines and shortest distance between them
Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. For a sound wave travelling towards + direction sinusoidal longitudinal
displacement at a certain time is given as a function of . If bulk modulus of air is
= 5 × 10 N/m , the variation of pressure excess will be

A) B)

C) D)
2. A gas is a mixture of two parts by volume of hydrogen and one part by volume of
nitrogen. If the velocity of sound in hydrogen at 0°C is 1300 m/s then the velocity of
sound (approx.) in the gaseous mixture at 27C is

A) 591 m/s B) 325 3 m/s C) 325 m/s D) 1200m/s

3. The length of an organ pipe is 33 cm. What is the change in its length required to
maintain its frequency unchanged if the temperature falls from 90C to 27C?

A) increase by 3 cm B) decrease by 3 cm

C) increase by 6cm D) decrease by 6 cm

4. Calculate the velocity of sound in a mixture of oxygen, nitrogen and argon at 0C. The
mixture consists of the gases oxygen, nitrogen and argon in the mass ratio 2:7:1.
(Given R = 8.323 J mol–1 K–1. Ratio of specific heats of the gases are, argon 1.67,
oxygen 1.4, nitrogen 1.4. The molecular weights of the respective gases are 40, 32 and
28.
A) 330 m/s B) 300m/s C) 325 m/s D) 600m/s
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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
5. A string of length 0.4 m and mass 10 kg is clamped at one end. The tension in the
string is 1.6 N. The identical wave pulses are generated at the free end after regular
interval of time, Δ . The minimum value of Δ , so that a constructive interference
takes place between successive pulses is
A) 0.1 s B) 0.05 s C) 0.2 s

D) Constructive interference cannot take place

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
6. A student performed the experiment to measure the speed of sound in air using
resonance air-column method. Two resonances in the air-column were obtained by
lowering the water level. The resonance with the shorter air-column is the first
resonance and that with the longer air column is the second resonance. Then,
A) The intensity of the sound heard at the first resonance was more than that at the
second resonance.
B) The prongs of the tuning fork were kept in a horizontal plane above the resonance
tube
C) The amplitude of vibration of the ends of the prongs is typically around 1 cm
D) The length of the air-column at the first resonance was somewhat shorter than
1/4 th of the wavelength of the sound in air
7. A sonic source, located in a uniform medium, emits waves of frequency . If intensity,
energy density (energy per unit volume of the medium) and maximum speed of
oscillations of medium particle are, respectively, , and at a point, then which of
the following graphs are correct?

A) B) C) D)

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
8. Energy density (energy per unit volume) of the medium at a distance from a sound
source varies according to the curve shown in figure, which of the following are
possible

A) The source may be a point isotropic source

B) If the source is a plane source then the medium particles have damped oscillations
C) If the source is a plane source then power of the source is decreasing with time
D) Density of the medium decreases with distance from the source
9. Plane harmonic waves of frequency 500 Hz are produced in air with displacement

amplitude of 10 m. Given that density of air is 1.29 kg/m and speed of sound in air

is 340 m/s. Then

A) The pressure amplitude is 13.8 N/m

B) The energy density is 6.4 × 10 J/m

C) The intensity of the wave is 0.22 J / m 2 s

D) Only ( ) and ( ) are correct

10. In an experiment to measure the speed of sound by a resonating air column, a tuning
fork of frequency 500 Hz is used. The length of the air column is varied by changing
the level of water in the resonance tube. Two successive resonances are heard at air
columns of length 50.7 cm and 83.9 cm. Which of the following statements is (are)
true?

A) The speed of sound determined from this experiment is 332 m/s

B) The end correction in this experiment is 0.9 cm

C) The wavelength of the sound wave is 66.4 cm

D) The resonance at 50.7 cm corresponds to the fundamental harmonic

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
11. It is desired to increase the fundamental resonance frequency in a tube which is closed

at one end. This can be achieved by

A) Replacing the air in the tube by hydrogen gas

B) Increasing the length of the tube

C) Decreasing of length of the tube

D) Opening the closed end of the tube

12. An air column in a pipe, which is closed at one end, will be in resonance with a

vibrating tuning fork of frequency 264 Hz if the length of the column in cm is (speed

of sound =330 m/s)

A) 31.25 B) 62.50 C) 93.75 D) 125

13. Two speakers are placed as shown in figure

Mark out the correct statement(s)

A) If a person is moving along , he will hear the sound as loud, faint, loud and so

on

B) If a person moves along , he will hear loud, faint, loud and so on

C) If a person moves along , he will hear uniform intense sound

D) If a person moves along , he will hear uniform intense sound

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. Find the number of possible natural oscillations of air column in a closed organ pipe
whose frequencies lie below = 1250 Hz. The length of the pipe is = 85cm. The
velocity of sound is = 340 m/s.

15. A steel rod 2.5 m long is rigidly clamped at its centre C and longitudinal waves are set
up on both sides of C by rubbing along the rod. Young’s modulus for steel = 2 ×
10 N/m , density of steel = 8000 kg/m

If two antinodes are observed on either side of , the frequency of the mode in which
the rod is vibrating will be n 103 Hz . Find the value of n.

16. The average power transmitted across a cross-section by two sound waves moving in
the same direction are equal. The wavelengths of two sound waves are in the ratio of
1:2, then find the ratio of their pressure amplitudes

17. A string of length 20 cm and linear mass density 0.40 g/cm is fixed at both ends and is
kept under a tension of 16 N. A wave pulse is produced at = 0 near an end as shown
in figure which travels towards the other end

When will the string have the shape shown in the figure again? (in × 10 s)
18. Loudness of sound from an isotropic point source at a distance of 70 cm is 20 dB.
What is the distance (in m) at which it is not heard (ie where sound level becomes
zero)

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19.
CH3 CH3
X
X2 / h

Above product will obtained in better yield if X is

A) Cl2 B) I 2 C) Br2 D) can’t be predicted

20.
Cl

Na
dry ether A
14

Which of the following is not formed as product ‘A’ is:

14
14
14 14
A) B) 14 C) D)
14 14
14

21. The ene-yne that produces a chiral compound upon treatment with Lindlar’s catalyst is

A) B)

C) D)

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
22.
OH
H3C
Conc.H2SO4
H3C CH3 Major product

H3C

A) B) C) D) None of these

23.
COOH
KOH
H3C CH CH CH3 Product;
Electrolysis
COOH
Θ

 
COO K COO K

A) B) C) D)
Θ


COO K

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases

OH

H + Ph
Ph
24. Ph

Which statement(s) is (are) true for above reaction?

A) It is dehydration reaction

B) The mechanism followed by reaction isE1

C) The reaction is stereo selective

D) The major product is Z-alkene

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
25. Which of the following are correct for the given reaction?

Ag2O,H2O

N 

A) Major product of reaction is

N

B) Major product of reaction is

N

C) Hoffmann’s alkene is major product of reaction

D) Reaction is unimolecular

26. Which of the following cases, the major product has been correctly shown?
Br

H2O
A)

Θ


Me3CO K
B)
Br
Θ

Br
EtO
C)
EtOH

C2H5OH
Br
D) 

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P

27. When is reacted with conc. H 2 SO4 and heated then the intermediates and
products formed are

28. Which of the following compounds will give E1 reaction?

Br
Br
A) C CH 2CH 3 B) Ph CH CH3

Cl
D) Cl
C ) H2C CH CH CH3

29. Which of the following alkanes can be produced by Kolbe electrolysis of sodium or
potassium salts of carboxylic acids?

A) Methane B) Ethane C) Butane D) Hexane

30. Which of the following can give E1 cb reaction in basic medium?

H

OH
B) Cl C CF 3

A) H3C CH C N Cl

O OH

C)
D) HCF 2 CCl 3

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
31. Which of the following compounds cannot give E2 reaction with strong base?
OTs F

A) B)

Br
D) CH
C)
Br

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32.

 X  products
alc.KOH
a 
Br

Br

Y 
alc.KOH
 b
c alc.KOH
Z 
Br
CH3 H

d H3C alc.KOH

 P
Br
CH3

Sum of X  Y  Z  P 
33.
H+ H+
a   x b  y
OH  OH 
OH
H+
c  z  d H+

 p
 HO

Total number of products obtained n above reactions including minor products in

(including stereoisomers)

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
34.
CH2 OH HO OH
H+
1
+
H
 A  2 
 B


OH
OH
H+
 3 C  H+
  4  D
OH 
OH

Sum of molecular masses of A, B, C, D (i.e., A+B+C+D) is equal to _________

35.

x
N

is total number of Hem (Hoffman Exhaustive Methylation and emliminations) to

remove nitrogen from given compound.

alc.KOH
y
Br is total number of possible E2 product (including stereoisomer)

Sum of x  y  ?

36. Consider the following reactions

X Y
The value of is
4

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
37. The edges of a parallelepiped are of unit length and are parallel to non-coplanar unit
^ ^ ^ ^ ^ ^ ^ ^ ^ 1
vectors a, b, c such that a . b  b . c  c . a 
2

Then the volume of the parallelepiped is

1 1 3 1
A) B) C) D)
2 2 2 2 3

38. Consider the planes

P1 : x  y  z  1
P2 : x  y  z  1
P3 : x  3 y  3z  2.

Let L1 , L2 , L3 be the lines of intersection of the planes P2 and P3 , P3 and P1 , P1 and P2 ,

respectively.
Statement-1: At least two of the lines L1 , L2 and L3 are non-parallel.
Statement-2: The three planes do not have a common point
A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
B) Statement-1 is True, Statement-2 is True; Statement-2 is a not correct explanation
for Statement-1
C) Statement-1 is True, Statement-2 is False
D) Statement-1 is False, Statement-2 is True
39. Let P(3,2,6) be a point in space and Q be a point on the line
 ^ ^ ^
  ^ ^ ^

r   i  j  2 k     3 i  j  5 k  .
   

Then the value of  for which the vector PQ is parallel to the plane x  4 y  3z  1 is

1 1 1 1
A) B)  C) D) 
4 4 8 8

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
x y z
40. Equation of the plane containing the straight line   and perpendicular to the
2 3 4
x y z x y z
plane containing the straight lines   and   is
3 4 2 4 2 3

A) x  2 y  2 z  0 B) 3x  2 y  2 z  0 C) x  2 y  z  0 D) 5x  2 y  4 z  0

41. If the distance of the point P(1, -2, 1) from the plane x  2 y  2 z   , where   0 , is 5,
then the foot of the perpendicular from P to the plane is

A)  , ,   B)  ,  ,  C)  , ,  D)  ,  , 
8 4 7 4 4 1 1 2 10 2 1 5
3 3 3 3 3 3 3 3 3  3 3 2

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
^ ^ ^ ^ ^ ^
42. The vector(s) which is/are coplanar with vectors i  j  2 k and i  2 j  k , and
^ ^ ^
perpendicular to the vector i  j  k is/are
^ ^ ^ ^ ^ ^ ^ ^
A) j  k B)  i  j C) i  j D)  j  k
x 1 y  1 z x 1 y 1 z
43. If the straight lines   and   are coplanar, then the plane(s)
2 k 2 5 2 k
containing these two lines is(are)
A) y  2 z  1 B) y  z  1 C) y  z  1 D) y  2 z  1
44. A line l passing through the origin is perpendicular to the lines
^ ^ ^
l1 :  3  t  i   1  2t  j   4  2t  k ,   t  

^ ^ ^
l2 :  3  2 s  i   3  2 s  j   2  s  k ,   s  

Then, the coordinate(s) of the point(s) on l2 at a distance of 17 from the point of

intersection of l and l1 is (are)

A)  , ,  D)  , , 
7 7 5 7 7 8
B)  1,  1, 0  C) 1,1,1
 3 3 3 9 9 9

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P
y z y z
45. Two lines L1  x  5,  and L2  x   ,  are coplanar. Then  can take
3   2 1 2  
value(s)

A) 1 B) 2 C) 3 D) 4
  
46. Let x, y and z be three vectors each of magnitude 2 and the angle between each pair
     
of them is . If a is a nonzero vector perpendicular to x and y  z and b is a nonzero
3
  
vector perpendicular to y and z  x , then
         
A) b   b . z  z  x  B) a   a . y  y  z 
          
C) a . b   a . y  b . z  D) a   a . y  z  y 

47. In R3 , consider the planes P1 : y  0 and P2 : x  z  1 . Let P3 be a plane, different from P1

and P2 , which passes through the intersection of P1 and P2 . If the distance of the point
(0, 1, 0) from P3 is 1 and the distance of a point  ,  ,   from P3 is 2, then which of
the following relations is (are) true?

A) 2    2  2  0 B) 2    2  4  0

C) 2    2  10  0 D) 2    2  8  0

48. In R3 , let L be a straight line passing through the origin. Suppose that all the points on
L are at a distance from the two planes P1 : x  2 y  z  1  0 and P2 : 2 x  y  z  1  0 . Let M
be the locus of the feet of the perpendiculars drawn from the points on L to the Plane
P1 . Which of the following points lie(s) on M?

A)  0,  ,   B)   ,  ,  C)   , 0,  D)   , 0, 
5 2 1 1 1 5 1 1 2
 6 3  6 3 6  6 6  3 3

49. Consider a pyramid OPQRS located in the first octant  x  0, y  0, z  0  with O as

origin, and OP and OR along the x-axis and the y-axis, respectively. The base OPQR
of the pyramid is a square with OP=3. The point S is directly above the mid-point T of
diagonal OQ such that TS=3. Then

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Narayana IIT Academy 22-01-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-36_Q’P

A) the acute angle between OQ and OS is
3

B) the equation of the plane containing the triangle OQS is x  y  0

C) the length of the perpendicular from P to the plane containing the triangle OQS is
3
2

15
D) the perpendicular distance from O to the straight line containing RS is
2

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
50. If the distance between the plane Ax  2 y  z  d and the plane containing the lines
x 1 y  2 z  3 x 2 y 3 z 4
  and   is 6 , then d is
2 3 4 3 4 5

 ^ ^  ^ ^  ^ ^ ^ 
51. Let a   i  k , b   i  j and c  i  2 j  3 k be three given vectors. If r is vector such that
       
r  b  c  b and r. a  0 , then the value of r. b is

     
If a and b are vectors such that a  b  29 and a   2 i  3 j  4 k    2 i  3 j  4 k   b , then
^ ^ ^ ^ ^ ^
52.
   
 
a positive value of  a  b  .  7 i  2 j  3 k  is
^ ^ ^

 
  
53. Let a, b and c be three non- coplanar unit vectors such that the angle between every
       
pair of them is . If a  b  b  c  pa  qb  rc , where p, q and r are scalars, then the
3
p 2  2q 2  r 2
value of is
q2
   
54. Let a and b be two unit vectors such that a . b  0 . For some x, y   , let
       
 
c  xa  yb  a  b . If c  2 and the vector c is inclined at the same angle  to both a

and b , then the value of 8cos2  is ________.

Jr.IIT_*CO SC Page No: 17