artyex Chemis

h manomotacale is opplisd a chemut

pues trhieh vhas a ,vey high mgeunlar mas of he
oxdu of 10 cint
Jhi giat metiusks ike DxA wkieh Cotuin oll
peuesj Tha protes
he emehe infokmohoifos dhe emayiesho Coamse
v e ,
ofBux usdk dmd sKiny
the veadions thaf occux iouN bo amdtha mam
efc
mode Compoumds Pstyetheme, bakeuE, PVe
uke othi
renis ov Patymar. D
CalkA marom
atcnles haye a
ë,Pemeys o, mavo m
216 elastiu
mo of Ckaadeihs ropeyhes, Suck as
uppovt eight, hilil lo14orw ibes
abillo iilm Sinilanmcktulss
mckulss
l o l f e x s r d i a l e 4hem frm
etc
haningmallex mskula ize c4= cHO
Prympy Camerem Ewb iveek RodsT
In0od P
mkaws unut/ .

mamy' amd me ONOT

Pdy mea

he Gaanli molenles fhat are toxmeol

ra o uctual avts janad lõaethor y
Gcavalen bond mdze o
iple linkge AOmd
Cofloidal ronqeo16
Ahie falls ito Sooo milion Dodtons
mofecwla wt, in
the xange
Jhuse qiamt anu Called mauromoLmdes.
mitues

malecnlar mao amd

Potymens hawe very his
Mae ase alco Callad Navo-
beComa of thuix lage
JhaVs Poy mexs and macioma osts
mdecmes.
uad uuthmt am dihmehon
O qemws aly
peakirg, ir is nut ta
HopeveY, srichy
HoweveY
 A Prymay alsys Consists 0t a lax9g mo: of
repeatiing, mmomeY wnits.Cm the otheyamd, a
Whie may
mAtNO mafecnle is a 1apm molue Fov
monome umus examp
m Coctains
ay K hareaarded
a mauro moktnles b
Ciooplyu s otai peotna
s Patmus asiE does Mat
bokellemd P6ytheng
monomes mit. Houweve, nell a Pita
o
m
maUro atecnles Delld Pym
aNe anded o 0 F e p e o i n g mnbwe
becanethey. Comdauin:longe
all
0et matxo mate cunles but
JhwsoalPoymess
M.Ouoakcales0oe ot PstyANS
TEC
eautive motkrom ekthe
i e ple
E
hmtura Uhitt of2aPoymex
epeaing Forexample:
r

dutive one CaMed M0womkxs.

nCkh=C 7n-1
EAund Hooyi) kepertg Poyetheleneswal,
(MonomiY)un cnOM s
Peynik)
HomgpotymeysA, Pmor ob{aintd aom idntia
monomex units îs caMd howoscymees. outhn
PVC ank thaxammples homopotymmerset
N
CAcHDDn2-ttH
Ethylena (moiomar)AD J2Prinetyome (Payie
NC

90
Vi cherida s

mopm 29e PV
IToret2 1
Copsmexs A PebmY obtained om tup diferel
monomexS îs Coltod a Coprty me

Ex oUDJS Sid3yer CouC2yec d

923 pymesizahop
'at
Hexamehylene diaminetAdipic i d e

(mmomwmAr)

12
t9
NH-CH-N6-4)o
Nylm-6,6 + n Hp
Poma

i R tion Petymersrdrd ro&uriadsi

Clasi fcatim Bsed noua gNa
NaUN awmexs hese athe gomplia compands
m o l r mos6Btaimuds fvm iotutal
o hig x ukbex a n
Pmsacchasides, qums,
oUY ces. oteins,
some impotam exaples of
notutal Poymurs.

i ihehe Prym
made CommeY-
hexe ndsm mdless YANUuy of mam
aiépeufiediPropesties
&oPetymex +Frodusts Duie
e thethepo wbbex, ce beadi oave sue
eait ber cacheived ui natralrube
Prope Kte
So me 9an; mplesuaxePV l o ,bákeü Get
tSem-Shehic PsumexApon tan akeve to0 ypes of
Poymas dheve is amother pe,cak4 6emindhei
Jhe ane made b moditgig dhe propevi of natmal Polymok
Ex Ni trocelMoe, Cellulose acetali et.
Clasi ffcatn bamed m Smdue 0 Poiymo
Linea ckain Pdamesp)
monomeic wmits ane inkd
i these PoymeS,
i
Jhe vausuo Py-
togethey fosminea Chains
over a n anan
Ovex a amoh
me vic choins are them
tocked
-

htuxe Du
weu
Lo
Packed
o give
Give a weu
unea"Petymers
have i e R
PaKed uctue,
"metin Pimt
Pint
and ih
tuns H
b temsila
PVeNylos, ett
1M(15)-14 M
nea P me

i) Branched ehain PmoY

monomer umits Cobim lo to
h e s e Paymeys,
chains o bram ches of diffeyemi lengths alg
se do n
choin (Hain Cho. Jhe
h the linan
linear FoymeY
have utures ike
weu Packed
A S a e s u , they
hawe lower deily , loner m.p,
chairr
temsile 4trengk Compare fo unear
amd les
Paymey Ex:Tlalirdenoly Po
then, zcogem, amylopechc

aksos inked or 3D ekrnm Pstymrs

h s e t Pobymers the inikay formd lineanchm
aeECsossSinkedd 5geffor to fovm 3D utaoK On u
CKOSS - ikad pe polymev chain are reauiA La jon
togethey i t h , long Ohatmsonsnndestpf a
1aml mokemus De t8 Psesehu tCrous-linkod bery
Bakelëli,
d Hexent Prmir chodmit,As namad o Ex:
meiamir nese ae hayd,,*19id
26
. tr2)
 Casiffcohon Based om Spthesis o
A h sousS bykich Polymes ae yoxmad is (alool
Pomeintto,t ,cam be deidd i t wv clases
tDb 21 J .
Cmdemsoaion Pmehtvho o1
o 5 , Ptmurizotn by wrich Pyumcicno
monomaY. Combimes t Tom ágiamt moe hy
eiminationof kimplk mdkli kioh js H20alcns
Cmdensoven Pty mes 7iie md the Ppmers
s Colen
wweh au formed by Hhis pro as Clltd Cdensaion
ubber, Teyleme
PoMmO Ex: Nylm Bakelili, Silicme
cogH esahiv
N-CHsNH+ooc-(
2
hemamuthyut ritAdipicidsl3merstr

hunamA Jascipiro oomx) vo l t

diamumctat
(momom tco-(C cottE
ly
r
ltN
9neotos 19
nyln 6,6 o Jaqpreaxs
oTtst:ci dogi - 3pqit c 2hrod -14
-14
ymei2ovtin
Addition 2ht rersot t
SnPsoues by sAieh monome wmit.jotned ogehr
uishiu
simple uinhoaotom giamt maucuHo,ol
y ciko
eliminnon ofmoll mticudes sue s
.Such Pymer
additio Pymi2ation.
NHgSColled
ISCouled additien Pamr 2i
24 meu, " _
a
E4hyleme

(memomt) qANPVGPoymx)

Ch=
Styyem Ph
 Degree o5 Potymusi9ain
Dse F Poymusizvtiom speufes
choin umgt
the

pomex. E is detind
a the mumber d times
of a
self in e
ne choin
Choin
morom wnit epeads mOnomu
1 r s the no. of
o Psyrmey" ookcule motkcinle
givem py my
mtts psnt n a PoymeN)
tott .
PDP M:W. of manomar mLtciueil
restto2re hrea
22 Os
Clans tindOE Patymosm the bisisob Molecaar pras
ELmtomevs m his pe of Poymevs, the întexmcesr
foxus opesouing Oe the WeokeE. Dnl o the presen a
of vexy weakimtexmateular foxuS, the plymu chouuns
ove n times m the applicotion
cam be retched
be
s e t u n l5 theis original positín
of tres Omd they An impovtaml
emovoM 0t pplied fora.
on the
e l a t o m e x s is notuRl Tubbes.
exampll of
in
i Fibres, Jheae have Mxangest idex moieunlar fores
form of H-bnds
tha
he os dipote dipote infexatigs
D sto POLSma toOg forus These axe high-
towsilkhenh"owerelontilg amd hanp Meling (
ptTshese potmeYsare«thin amd thead like
NovemDhKNe Jore fheae aseuats d
omd Coy, be
make fubres. ExNlm yle .to r
iermdedy
u) Jhxmoplarics Sn this ype of Patrnexs,
foxus ot athadion ae in hawe betwem those df elosBomers
amd fibres. . hvrmopiticS iRaN pomer chain
a a fes chemico bmds athng a% Coss-inke
h e s e ave
had ai o o
p Such Psms hem
heoied become soft o Sud uke amd em Cambt
mowided in amy de sired Shape. Ex: Polythema Pebyshynen
PVC et.
 Plasici zersCertoin Plantics do no 80ftem ve m u c
hechng onees, hesa Cam be lsiky 8oftemed amd
made o Kable by the odditom of sonme osgamie Compas
coullld Plastiu Fov exampla, PVc is entreamy Stisf
~exs.
omd hand b
Omd ir cam be mode 8oft amd oubber
ke ay Odditiom of n-bulg Ptholali (a plastu2er)

Jhumo seitim Plastics Jheac Potymevs au qenta mod

hawing low mecnlar w.
6nbetamces
forom semi flid omd tom
a mauld, hey become infusible
Om heovingm betp riymt
m a due lo Csoss- inkig
isduble hasd
am
bonds.Ex: Bakel la,
BD utoYK of
choisfoming

ieme of Monomer
baaed on the Stexeochemisty
Claiscation

Same Odder)
1sotatie ( Gnek miami ng
au 09nRmded
0tuended
he Side ckaims/groups
thes poymr Chain having
bidl of dha main Prmer
the same
O
O osdov.
amd dfenil+
Fukay CH Cdy-(Hm

R
mamu Atexnoting Order")
ymdiotaihic ( 12ek
ae onienlia
his Potymurs
ihe 6idk chein/ 6iroups
9n main chain
the both Side db
attexnatively on R
CHCH,-CH m
tth-H-H2
mm
Pay mey
his Paty moy
(xeek maaniY
no der) : n Choin.
u) Atacti _uierdodiin Of Side
Iheke ane i3xegulax, Jamdom
Hheke
Uh-CH-h