FIITJEE – (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

QP Code: 100627 Common Test – 6

Time Allotted: 3 Hours Maximum Marks: 198

BATCHES – Two Yr CRP(2325) Batches

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Parts.

(i) Part-A (01-06) – Contains Six (06) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.

(ii) Part-A (07-12) – Contains Six (06) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks:  1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B)
will result in  1 marks, as a wrong option is also darkened.

(ii) Part-B (01-06) contains Six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals to Two decimal places (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and
each question carries +4 marks for correct answer and there will be no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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IT2025 (Common Test-6)-(PCM) 2

S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

1. An ideal gas is taken from the state A (pressure P, volume V) to the state B
(pressure P/2, volume 2V) along a straight line path in the P - V diagram. Select the
correct statement(s) from the following:
(A) The work done by the gas in the process A to B exceeds the work that would be done
by it if the system were taken from A to B along an isotherm
(B) In the T - V diagram, the path AB becomes a part of a parabola
(C) In the P - T diagram, the path AB becomes a part of a hyperbola
(D) In going from A to B, the temperature T of the gas first increases to a maximum value
and then decreases.

2. Inner surface of a cylindrical shell of length l and of material of T1 T2

thermal conductivity k is kept at constant temperature T1 and outer
surface of the cylinder is kept at constant temperature T2 such that
 T1 > T2  as shown in figure. Heat flows from inner surface to outer
surface radially outward. Inner and outer radii of the shell are R and
2R respectively. Due to lack of space this cylinder has to be R l
2
l R R
replaced by a smaller cylinder of length , inner and outer radii
2 4
and R respectively and thermal conductivity of material nk. If rate of
radial outward heat flow remains same for same temperatures of
inner and outer surface i.e. T1 and T2, then find the value of n.
(A) 1 (B) 2
(C) 3 (D) 4

3. The specific heat capacity of mono-atomic ideal gas for thermodynamic process
11R
P = v2, is equal to . Where  and K are positive constant and R is gas constant.
K
Find the value of K.
(A) 2 (B) 4
(C) 6 (D) 8
T
4. Two moles of an ideal monoatomic gas undergoes a cyclic
3
process as shown in the figure. The temperatures in
different states are given as 6T1 = 3T2 = 2T4 = T3 = 1800 K.
Determine the work done by the gas during the cycle. 4
2
(A) –10 kJ (B) –20 kJ
(C) –15 kJ (D) –30 kJ 1
P

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IT2025 (Common Test-6)-(PCM) 3

5. Twelve identical conducting rods from the sides of a F G

uniform cube of side . In the stead state, B and H ends H
of the cube are maintained at 100C and 0C. The E 0C
temperature of the junction A is 10 times k , then value
of k is 100C C
(A) 5 (B) 7 B
(C) 8 (D) 9 D
A

6. When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy
supplied which increases the internal energy of the gas is:
(A) 2/5 (B) 3/5
(C) 3/7 (D) 5/7

(Multi Correct Choice Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

7. Two bodies A and B have thermal emissivities of 0.01 and 0.81 respectively. The outer
surface areas of the two bodies are equal. The two bodies emit total radiant power at the
same rate. The wavelength  B corresponding to maximum spectral radiancy in the
radiation from B to shifted from the wavelength corresponding to maximum spectral
radiancy in the radiation from A by 1 m. If the temperature of A is 5802 K,
(A) The temperature of B is 1934 K (B) B  1.5 m
(C) The temperature of B is 1160 K (D) The temperature of B is 2901 K

T1 T T2
8. Two plates thickness l1 and l2 with thermal
conductivities K1 and K2 respectively are kept Heat out
in thermal contact as shown in the figure. If A Heat in
T1
T2
is area of each face, then mark the correct
options. l1 l2
l l
(A) Thermal resistance of combination is R  1  2
AK1 AK 2
A(T1  T2 )
(B) Heat flow rate through the combination is H 
 l1 l 
  2 
 K1 K 2 
l2 l
 T2 1 T1
K2 K1
(C) Temperature of joint of slabs is T 
 l1 l 
  2 
 K1 K 2 
l1  l2
(D) Equivalent thermal conductivity; of combination will be K eq 
 l1 l 
  2 
 K1 K 2 

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IT2025 (Common Test-6)-(PCM) 4

9. Two adiabatic processes bc and ad for the same gas are

P
given to intersect two isotherms at T1 and T2 (as shown). a
Then b
T1
V T V T
(A) a  2 (B) a  1
Vb T1 Vb T2 T2
1
d c
Vb  T2   1
(C)   (D) VaVc = VbVd Va Vd Vb Vc V
Vc  T1 

10. A mixture of two diatomic gases X and Y is enclosed in a container at constant

temperature.
The molecular weight of X is 16 times that of Y and mass of the gas X is 2 times that of Y.
Then
(A) The average molecular kinetic energy of X equals that of Y
(B) The r.m.s. molecular speed of translation of X is 1/4th that of Y.
(C) The pressure exerted by X is 1/8th that by Y.
(D) The pressure exerted by X is 8 times that by Y.

11. A monoatomic gas undergoes a process given by 2dU + 3dW = 0 (where dU = charge in
internal energy, dW = work done by the gas) then
(A) VT = constant (B) PV = constant
(C) PV2 = constant (D) PV5/3 = constant

12. Imagine a point source ‘s’ which is a black body at a

constant temperature T at the centre of a thick spherical
shell of inner radius ‘a’ and external radius ‘b’. The a
coefficient of thermal conductivity of the material of the s
b
shell is K. The inner surfaces of the shell is coated with
lamp black. A is the surface area of source.
(A) The amount of thermal radiation received by the inner surface from s is AT4 ( 
Stefan’s constant)
AT 4  1 1 
(B) The temperature difference across the inner and outer surface is 
4K  a b 
(C) If the external surface of the shell is in vacuum at 0 K (say) the temperature of inner
AT 4  1 1
surface I is a  b 
4K  
(D) If the external surface of the shell is in vacuum at 0 K (say) the temperature of inner
AT 4 a 2  1 1
surface I is a  b
K  

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IT2025 (Common Test-6)-(PCM) 5

PART – B
(Numerical based)

1. A solid copper sphere of diameter 10 mm is cooled to a temperature of 150 K and is then

placed in an enclosure at 290 K. Assuming that all interchange of heat is by radiation,
calculate the value of x if initial rate of rise of temperature of the sphere is 0.022x.. The
sphere may be treated as a black body.

2. A double-pane window consists of two glass sheets of area 1 m 2 and thickness 0.01 m
separated by a 0.05 m thick stagnant air space. In the steady state, the room glass
interface and the glass outdoor interface are at constant temperature of 27C and 0C,
respectively.
Find out rate of heat flow through the window pane. (in watt).

3. The molecules of a given mass of gas have rms velocity 200 ms–1 at 27°C and 105 Nm–2
pressure. When the temperature is doubled and the pressure is halved, the rms speed (in
ms–1) of the molecules of the same gas is

4. A liquid cools from 700C to 600C in 5 minute. Calculate the time taken by the liquid to cool
from 600C to 500C, if the temperature of the surrounding is constant at 300C.

5. An adiabatic cylinder has 8 gm of helium. A light smooth

adiabatic piston is connected to a light spring of force
constant 30 N/m. The other end of the spring is connected
with a block of mass 1 kg kept on a rough horizontal surface M
of coefficient of friction  = 0.3. Area of cross section of
cylinder is a = 25 cm2. Initially the spring is in a relax position
and the temperature of the gas is 400 K. The gas is heated
slowly from some time by means of an electric heater so as
the block M just starts moving. Find the value of b if work
done by the gas is b.

6. 2 kg of ice at –20°C is mixed with 5 kg of water at 20°C in an insulating vessel having

negligible heat capacity. Calculate the final mass of water (in kg) remaining in the
container. It is given that the specific heats of water and ice are 1 kcal/kg/°C and 0.5
kcal/kg/°C respectively, while the latent heat of fusion of ice is 80 kcal/kg.

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IT2025 (Common Test-6)-(PCM) 6

S
SEEC
CTTIIO
ONN--2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. The catalytic hydrogenation of which of the following alkenes is most exothermic?
(A) (B)

(C) (D)

2. n-Octane when heated to 773 K under a pressure of 10-20 atm and in presence of a
mixture of Cr2O3, V2O5 and Mo2O3 supported over Al2O3 as catalyst, gives:
(A) o-Xylene (B) m-Xylene
(C) p-Xylene (D) All of these

3. A compound X (C5H8) reacts with ammonical AgNO3 to give a white precipitate, and on
oxidation with hot alkaline KMnO4 gives the acid, (CH3)2CHCOOH. Therefore, X is
(A) CH2 = CHCH = CHCH3 (B) CH3(CH2)2C ≡CH
(C) (CH3)2CH – C ≡CH (D) (CH3)2C = C = CH

4. A compound on acidified permanganate oxidation forms two moles of same carboxylic acid
which on decarboxylation (removal of CO2) forms the simplest saturated hydrocarbon.
Therefore the compound is:
(A) 1-butene (B) 2-butene
(C) 2-pentene (D) 1-pentene

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IT2025 (Common Test-6)-(PCM) 7

5. Observe the following reactions and predict the nature of A and B.

B  HBr
Organic peroxide
 
HBr
A

Br

(A)
A and B both are

(B) A and B both are

Br

Br

(C)
A is and B is
Br

(D) A is and B is
Br Br
Br

6. In presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-
Markovnikov’s addition to alkenes because:
(A) both are highly ionic
(B) one is oxidising and the other is reducing
(C) one of the steps is endothermic in both the cases
(D) all the steps are exothermic in both reactions

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IT2025 (Common Test-6)-(PCM) 8

(Multi Correct Choice Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
7. The simplest alkene[X] on reductive ozonolysis yields sole product hexandial. Which of the
following statement(s) is/are correct for [X]
(A) The mol. wt of alkene is 82 (B) The alkene contains at least 12 carbons
(C) The alkene is cyclic (D) The alkene is acyclic

8. Consider the following reaction:

 Br  Br  Br
Step 1 
Step  2


+ Br Br
Br
Which of the following statements is/are incorrect?
(A) The Br2 addition occurs with anti-stereospecificity
(B) The final product will be a mixture of enantiomers
(C) In step-2, the Br– anion acts as a Lewis base
(D) In step-1, the Br2 molecule acts as a Lewis base

9. Which of the following product(s) is/are formed in the reaction shown below

 Br2  ?
O
Br Br

(A) (B)
O Br O Br
Br

(C) (D)
O O Br

10. In the given reaction, the possible structure of compound(X) is

Me
 X  
Conc.H2 SO4


CH3
OH
(A) (B) OH

OH OH
CH3 CH3
(C) (D)

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IT2025 (Common Test-6)-(PCM) 9

11. Which of the following hydrocarbon can discharge the reddish-brown colouration of Br2
dissolve in CCl4
(A) cyclohexane (B) cyclopropane
(C) ethylene (D) isobutylene

12. H2 ,Pd BaSO4

CH3  C  C  CH3 
Quinoline  A  
OsO 4
NaHSO3 /H2 O
 B 
The final product/s of above reaction can be
HO H
H OH
OH CH3
H
(A) (B)
CH3 CH3
CH3 HO H
CH3
CH3
CH3 H
H OH
(C) (D)
H OH
OH H
CH3
OH

PART – B
(Numerical based)

1. When relative reactivity of primary, secondary and tertiary hydrogen for bromination is 1:80
: 1600, then find the percentage of tertiary bromide in the given reaction.

Br2 , h
 
127o C
Br

2. When R - 2 – Chlorobutane undergo monochlorination, X number of dichlorinated products

are formed and when products undergo fractional distillation then Y number of fractions
2X  Y
are obtained. Therefore is
2

3 If X is the number of moles of H2 is used for the complete hydrogenation of the given
X
compound in the presence of a metal catalyst. Then is
2
CN

CN

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IT2025 (Common Test-6)-(PCM) 10

4. Alkene  Z  C7H14  

H2 ,Ni

 Optical active alkane
Alkane  Y  C7H16  
Cl2
h
 6 Monochloro structural isomers
How many isomers of alkene-Z(including stereo) give the alkane-Y on catalytic
hydrogenation.

5 ‘W’ gram of a hydrocarbon CH3CH2CH2C  C-H when heated with methyl magnesium
bromide, give 112 mL of CH4 at STP. Calculate the value of ‘W’

6. Consider the following reactions:

Total number of monochlorinated product = X(Excluding

Cl2 /h stereoisomers)
 

Total number of monochlorinated product = Y(Excluding

Cl2 /h
 
stereoisomers)
XY
Identify the value of ?
5

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IT2025 (Common Test-6)-(PCM) 11

S
SEEC
CTTIIO
ONN--3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. The roots of the equation zn = (z +1)n
(a) are vertices of a regular polygon (b) lie on a circle
(c) are collinear (d) lie on a ellipse


2. If 0  arg(z)  , then least value of 2 2z  4i is
4
(A) 6 (B) 1
(C) 4 (D) 2

3. Total number of complex number ‘z’ satisfying z  3,Re  z   3 / 2 and z  1  i  2,

is equal to
(A) 2 (B) 1
(C) 4 (D) none of these

4. The coefficient of x6 in (1 + x)6 + (1 + x)7 + . . . + (1 + x)15 is

(A) 16C9 (B) 16C5 – 6C5
16
(C) C6 - 1 (D) none of these

5. An isosceles triangle of wood is placed in a vertical plane, vertex upwards and faces the
sun. If 2a be the base of the triangle, h its height and 30o the altitude of the sun, then the
tangent of the angle at the apex of the shadow is
2ah 3 2ah 3
(A) (B)
3h  a
2 2
3h2  a 2
ah 3
(C) 2 (D) None of these
h  a2

6. In ABC,  a  b  a  b   c  b  c  , then measure of angle A, is:

(A) 30o (B) 60o
(C) 90o (D) 120o

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IT2025 (Common Test-6)-(PCM) 12

(Multi Correct Choice Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

z 1
7. If is a purely imaginary number (where i  1 ), then z lies on a
zi
(A) straight line (B) circle
1
(C) circle with radius  (D) circle passing through the origin
2

8. If z  x  iy, where i  1 , then the equation

 2z  i  m represents a circle, then m
 z  i
can be
1
(A) (B) 1
2
(C) 2 
(D)  3, 2 3 
9. If  is a complex constant, such that z2  z    0 has a real root, then
(A)     1 (B)     0
(C)     1 (D) the absolute value of real root is 1

10. In a triangle ABC, if a4  b4  c 4  2c 2 a2  b2 , then C =  

o
(A) 60 (B) 45o
(C) 120o (D) 135o

11. 3 2n  2  8n  9, n  N is divisible by
(A) 8 (B) 16
(C) 32 (D) 64

12. If n  N , then
C1  2C2 x  3C3 x 2  4C4 x 3  ..... upto n terms
(A) n 1  x  (B) 1  x 
n 1 n 1
if n is odd if n is even
(C) n 1  x  (D) n 1  x 
n 1 n 1
if n is even if n is odd

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PART – B
(Numerical based)

1. Let z  4  Re  z  . If greatest arg(z) = then k equal to ____________
k

2. If z is a non-real root of 7
 1 , then z86 + z175 +Z289 +5 is ____________.

The remainder left out when 82n   62 

2n 1
3. is divided by 9 is

4. If the positive value of ‘a’ such that co – efficient of x 5 is equal to that of x15 in the
10
 a 
Binomial expansion of  x 2  3  is  then value of 4 3 is
 x 
8
k 
5. If k R and the middle term of   2  is 1120, then the value of k is
2 

100
 1 1
6. The number of irrational terms in the expansion of  5 8  2 6  is a two digit number AB
 
 
A B
then is
5
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IT2025 (Common Test-6)-(PCM) 14

FIITJEE – COMMON TEST - 6

QP Code:
ANSWERS
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
1. A 2. D 3. C 4. A
5. B 6. D 7. AB 8. ABCD
9. CD 10. ABC 11. AC 12. ABC

PART – B
1. 3 2. 0.65 3. 200 4. 7
5. 25.15 6. 6

S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. D 2. D 3. C 4. B
5. C 6. C 7. AC 8. D
9. AB 10. ABC 11. BCD 12. BCD

PART – B
1. 90.44 (Range 90.3 to 90.5) 2. 7 3. 3.5
4. 8 5. 0.34 6. 1.6

S
SEEC
CTTIIO
ONN –– 3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. C 2. C 3. D 4. A
5. A 6. D 7. BCD 8. ABD
9. ACD 10. BD 11. ABCD 12. AC
PART – B
1. 4.00 2. 4.00 3. 2.00 4. 2.00
5. 2.00 6. 1.20

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