GT 1
GT 1
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is strictly
prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ______________________________
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A student is performing the experiment of resonance column. The diameter of the column
tube is 6 cm. The frequency of the tuning fork is 504Hz. Speed of the sound at the given
temperature is 336 m/s. The zero of the meter scale coincides with the top end of the
resonance column tube. The reading of the water level in the column when the first
resonance occurs is
1) 13 cm 2) 16.6 cm 3) 18.4 cm 4) 14.8 cm
2. If the source of light used in a Young’s double slit experiment is changed from red to violet
1) The fringes will become brighter
2) The central bright fringe will become a dark fringe
3) Consecutive fringe lines will come closer
4) The intensity of minima will increase
3. In Young’s double slit arrangement, slits are separated by a gap of 0.5 mm, and the screen is
placed at a distance of 0.5 m from them. The distance between the first and the third bright
fringe formed when the slits are illuminated by a monochromatic light of 5890 A0 is :-
1)1178 10 –9 m 2) 1178 10 –6 m
IR IR 2 I 2R I 2R
1) 2) 3) 4)
2 al al al 2 al
11. A lamp (pure resistance) is connected in series with a capacitor
A) When a dc source is connected to the combination, the lamp will not glow in steady state
B) When ac source is connected to the combination, the brightness of glow of lamp
increases with increases of frequecncy of ac.
1) A is true B is false 2) A is false B is true
3) A & B are true 4) A & B are false
12. An electron revolving in an orbit of radius 0.5 A0 in a hydrogen atom executes 10 revolutions
per second. The magnetic moment of electron due to its orbital motion will be
1 1 1 1
3
1) (2cot ) 3 2) (2 tan ) 3 3) (2cot ) 4) (2 tan ) 3
15. If in hydrogen atom, radius of nth Bohr orbit is rn , frequency of revolution of electron in nth
orbit is f n , choose the correct option
1) 2)
of 236 140 94
92U , 54 Xe, 38 Sr be 7.5 MeV, 8.5 MeV and 8.5 MeV respectively. Considering different
conservation laws, the correct option is
1) x n, y n, K Sr 129 MeV , K Xe 86 MeV
2) x p, y e , K Sr 129 MeV , K Xe 86 MeV
3) x p, y n, K Sr 129 MeV , K Xe 86 MeV
4) x n, y n, K Sr 86 MeV , K Xe 129 MeV
18. A symmetric star conducting wire loop is carrying a steady state current I as shown in figure.
The distance between the diametrically opposite vertices of the star is 4a. The magnitude of
the magnetic field at the center of the loop is
0 I 0 I
1) 6 3 1 2) 6 3 1
4 a 4 a
0 I 0 I
3) 3 3 1 4) 3 2 3
4 a 4 a
19. The logic circuit shown below has the input waveforms ‘A’ and ‘B’ as shown. Pick out the
current output waveform.
Output is
1) 2)
3) 4)
20. The figure gives the magnetic field of an electromagnetic wave at a certain point and at a
certain instant. The wave transports energy in negative y-direction. Then the direction of
electric field at this point and instant is
Z'
y
B
x
1) z – axis 2) – z – axis 3) x – axis 4) – x – axis
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A closed organ pipe of length L and an open organ pipe contain gases of densities 1 and 2
respectively. The compressibility of gases are equal in both the pipes. Both the pipes are
vibrating in their first overtone with same frequency. The length of the open pipe is
x
L 1 where x is _____. (Round off to the Nearest Integer)
3 2
22. In the arrangement of capacitors shown in the figure, if each capacitor is 9 pF, then the
effective capacitance between the points A and B is (in pF)
23. A cylindrical wire of radius 0.5 mm and conductivity 5 107 S / m is subjected to an electric
field of 10 mV/m. The expected value of current in the wire will be x3 mA .The value of x
is __________.
24. In a series LCR circuit R = 200 and the voltage and the frequency of the main supply is
220 V and 50 Hz respectively. On taking out the capacitance from the circuit the current lags
behind the voltage by 300 . On taking out the inductor from the circuit the current leads the
voltage by 300 . The power dissipated in the LCR circuit is
25. A solenoid is of length 50 cm and has a radius of 2cm. It has 500 turns. Around its central
section a coil of 50 turns is wound. Calculate the mutual inductance of the system. (in H )
(Round off to the Nearest Integer)
26. Consider the circuit shown in figure. With switch S1 closed and the other two switches open,
the circuit has a time constant 0.05sec. With switch S2 closed and the other two switches
open, the circuit has a time constant 2 sec. With switch S3 closed and the other two switches
open, the circuit oscillates with a period T. Find T (in sec). (Take 2 10 )
27. Find the current measured by the ammeter in the circuit shown in figure ( in 10 1 A )
30. One of the lines in the emission spectrum of Li2+ has the same wavelength as that of the 2nd
line of Balmer series in hydrogen spectrum. The electronic transition corresponding to this
line is n 12 n .Find the value of x.
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. Plots showing the variation of the rate constant (k) with temperature (T) are given below.
The plot that follows Arrhenius equation is
1) 2)
3) 4)
32. For a first order homogeneous gaseous reaction, A 2 B C if the total pressure after time t
was Pt and after long time ( t ) was P then k in term of Pt , P and t, is
2.303 P 2.303 2 P
1) k log 2) k log
t P Pt t P Pt
2.303 2 P
3) k log 4) None of these
t 3( P Pt )
33. Statement 1: Addition of HgI 2 to aqueous solution of KI increases the freezing point
liquid solution of X and Y at 27o C has a vapour pressure of 50 torr. The mole fraction of Y
in solution is : (Given: R = 0.082 atm/L/mol/K; Molar mass of X = 75; Molar mass of
Y = 88)
1) 0.48 2) 0.52 3) 0.62 4) 0.247
35. A hydrogen electrode X was placed in a buffer solution of sodium acetate and acetic acid in
the ratio a : b and another hydrogen electrode Y was placed in a buffer solution of sodium
acetate and acetic acid in the ratio b : a. If reduction potential values for two cells are found
to be E1 and E2 respectively w.r.t. standard hydrogen electrode, the pK a value of the acid
can be given as
E1 E2 E E2 E1 E2 E1
1) 2) 1 3) 0.118 4)
0.118 0.118 E2 0.118
36. How many electrons are delivered at the cathode during electrolysis by a current of 1amp in
60 seconds?
1) 3.74 1020 2) 6.0 1023 3) 7.48 1021 4) 6.0 1020
37. Statement 1: Oxygen is more electronegative than sulphur, yet H 2 S is more acidic than
H 2O .
Statement 2: H – S bond is weaker than O – H bond.
1) Statement 1 is True, Statement 2 is true; Statement 2 is a correct explanation for
Statement 1
2) Statement 1 is True, Statement 2 is true; Statement 2 is NOT a correct explanation for
Statement 1
3) Statement I is True, Statement 2 is False
4) Statement 1 is False, Statement is True
38.
Column I (Species) Column II (Colour in aq – solution)
b) Fe 2 q) Blue pink
c) Cu 2 r) Green
d) Mn3 s) Violet
e) Fe3 t) Blue
1) a – q, b – r, c – t, d – s, e – p 2) a – p, b – r, c – q, d – s, e – t
3) a – t, b – r, c – q, d – s, e – p 4) a – q, b – s, c – p, d – r, e – t
39. Statement 1: For the reaction 2 I S 2O82 I 2 2 SO42 , Fe(III) catalyst is used
Statement 2: 2 Fe3 2 I 2 Fe 2 I 2
2 Fe2 S2O82 2 Fe3 2 SO42
1) Statement 1 is True, Statement 2 is true; Statement 2 is a correct explanation for
Statement 1
2) Statement 1 is True, Statement 2 is true; Statement 2 is NOT a correct explanation for
Statement 1
3) Statement I is True, Statement 2 is False
4) Statement 1 is False, Statement is True
40. Select the correct graphical representation
1) 2)
3) 4)
41. Consider the following staements
3
Statement 1: Cr NH 3 6 is an inner orbital complex with crystal field stabilization
energy equal to 1.2 0
Statement 2: The octahedral complex formed by joining the CN ligands to Fe3 ion has
theoretical value of spin only magnetic moment equal to 1.73 BM
the oxidation states of iron are same and arrange in the order of true / false
1) FTF 2) TTF 3) TTT 4) FFF
42. The correct statement on the isomerism associated with the following complex ions
2 2 2
P) Ni H 2O 5 NH 3 Q) Ni H 2O 4 ( NH 3 ) 2 R) Ni H 2O 3 ( NH 3 )3 is
18 HBr
Major Product is
OH CCl4
44.
18
O O
1) 2)
OH Br
Br OH
3) 4)
H3C CH3
OH (1) Hg(OAc)2
Product formed is
(2) NaBH4
45. H3C
O CH3
CH3
CH3
O CH3
1) H3C 2) H3C
CH3
O
CH3
3) 4)
O O
18 A
R C O H R ' OH R C O R ' H 2O
46. Fischer esterification is represented as follows
here R CH 3 , R ' C2 H 5 in the above reaction A/2 is equal to
1) 8 2) 9 3) 6 4) 12
Ph
CH 3 C CH 2
H
CH3OH
C
47. O , C will be
Ph
Ph Ph OH Ph OCH3
CH 3 C CH 2
O+ CH 3 C CH 2 CH 3 C CH 2 CH 3 C CH 2
1) H 2) OH 3) OCH3 4) OCH3
48. Which of the following plots is (are) correct for the given reaction? ( P0 is the initial
concentration of P)
CH3 CH3
H3C Br + NaOH H 3C OH +NaBr
CH3 CH3
(P) (Q)
P Q
Initial rate
t1/ 2
P 0 P 0
1) 2)
P
Q
P
P0 0
3) Time 4) Time
Br / P HOH / H
49. CH 3 COOH B
2 A C . The product (C) will be
NaCN
COOH
CH2 COOH
CH2
1)
COOH 2) CH2 COOH
CH2 CO CO
O CH2 CH O
3) CH2 CO 4) CO
50. Which of the following azodyes cannot be prepared by combining benzene diazonium
chloride with corresponding compounds?
CH3
CH3
N
CH3
N N CH3
N N
1) 2)
OH
N N
N N
OH
3) 4)
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
chloride are 83, 127 and 426 mho cm 2 eq 1 at 25o C respectively. Calculate the equivalent
conductance of butyric acid at infinite dilution in same units.
53. How many of the following statement(s) is (are) correct when a mixture of NaCl and
K 2Cr2O7 is gently warmed with conc. H2SO4?
1) A deep red vapour is evolved
2) The vapours when passed into NaOH solution gives a yellow solution of Na2CrO4
3) Chlorine gas is evolved
4) Chromyl chloride is formed
54. How many of the following compounds will decolourize the colour of acidified KMnO4 ?
H 2S FeSO4 NaNO2 Na2 SO3
PbS Na2 S NaNO3 Na2 SO4
CO2 SO3 P2O5
55. Please help Santa and Banta to decode the lock of their car XYZT
Given:
XeF2 XeF4 XeF6 XeO3 XeOF4 XeO2 F2
Code 1 2 3 4 5 6
1) No. of planar compounds = T
2) Code of the compound which is linear = Z
3) Code of the compound which has distorted octahedral shape = X
4) Code of the compound which is pyramidal = Y
56. How many species do not exist?
PH 3 , PH 5 , PCl5 , PBr5 , SiF62 , SF6 , Al2 F6 , PbI 4 , NCl5 , AlCl3 , OF2 , OH 2 , OF4 ,
HFO4 , FeI3 , B2 F6
57. If 3-chloro 3 – methyl hexane is treated with C2 H 5ONa / C2 H 5OH , E2 Elimination
reaction takes place predominantly. How many isomeric alkenes would be formed?
58. Among the following how many compounds are showing both reactivity with “ LiAlH 4 ” &
Aldol condensation & I 2 / NaOH ?
CHO
O O
CH 3 C H CH 3 CH 2 C CH 2 CH 3
1) 2) CH 2 CH 2 3) 4)
O
CHO C Cl
C CH3 C H O O
O O CH 3 C CH 2 C CH 3
5) 6) 7)
59. Specific rotation for -anomer of a given mono saccharide is 100o for -anomer is 20o .
62. PN is an ordinate of the parabola y 2 4ax (P on y 2 4ax and N on x-axis). A straight line
is drawn parallel to the axis to bisect NP and meets the curve in Q. NQ meets the tangent at
the vertex A in a point T such that AT=kNP, then the value of k is (where A is the vertex)
3 2 1
1) 2) 3) 1 4)
2 3 3
63. Let n , n be the distinct roots of the equation x 2 n 1 x n 2 0. If
2021
1
a
can be expressed in the form , where a and b are positive integers
n2 n
1 n 1 b
relatively prime to each other, then value of b a , is :
1)1 2) 3 3) 6 4) 9
3) ln y x 2 y 2 ln y C 0 4) ln y x 2 y 2 C 0
a x y
65. If A x b z where a, b, c, x, y, z1,2,3,4,5,6 and also a , b, c, x, y , z are distinct. Then
y z c
rational roots.
2
Statement- 2: The quantity 2m 1 4 2n 1 , where m, n I , can never be perfect
square.
Have to select the correct choice as given below .
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for Statement
-1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true
25
1
68. Statement -1 : The term independent of x in the expansion of x 2 2 is 50C25.
x2
Statement-2 : In a binomial expansion middle term is independent of x.
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for
Statement -1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true
69. Statement-1 : If f : a1, a2 , a3 , a4 , a5 a1, a2 , a3 , a4 , a5 , f is onto and f x x for each
x a1, a2 , a3 , a4 , a5 , then number of such functions is equal to 44.
70. Statement –1 : The only circle having radius 10 and a diameter along line 2 x y 5 is
x2 y 2 6 x 2 y 0 .
Statement-2: 2 x y 5 is a normal to the circle x 2 y 2 6 x 2 y 0
1) Statement -1 is false, Statement-2 is true;
2) Statement -1 is true, Statement-2 is true; Statement-2 is a correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is true, Statement -2 is true, Statement 2 is not a correct explanation for .
statement-1.
71. The first of two groups of samples has 100 observations with mean 15 and Standard
deviation(S.D) = 3, if the two groups together have 250 observations with mean 15.6 and
S.D = 13.44 then S.D of second group is
1) 4 2) 5 3) 6 4) 3.52
72. Mean and standard deviation of 100 observations were found to be 40 and 10, respectively.
If at the time of calculation two observations were wrongly taken as 30 and 70 in place of 3
and 27 respectively, then the correct standard deviation is .
1)10.24 2)8.24 3)6.24 4) 12.24
73. A circle has the same centre as an ellipse and passes through the foci F1 and F2 of the
ellipse, such that the two curves intersect in 4 points. Let ‘P’ be any one of their point of
intersection. If the major axis of the ellipse is 17 and the area of the triangle PF1F2 is 30,
then the distance between the foci is :
1)11 2) 12 3) 13 4) 14
z i 5
74. Let z be a complex number such that 1 and z . Then the value of z 3i is :
z 2i 2
7 15
1) 10 2) 3) 4) 2 3
2 4
75. If ax 2 by 2 2 x cy 11 a , b, c R is the locus of centre of circles whose radius is 5 and
bisect the circumference of circle x 2 y 2 2 x 4 y 4 then the value of a b c is equal
to
1) -2 2)-4 3) 4 4) 6
18
17 x 27 x 1
76. If x 26
x 1 5 x 3 dx C , where C is constant of integration, then the
k
value of k is :
1)3 2) 6 3)9 4)12
77. The 1st , 2nd and 3rd terms of an arithmetic series are a,b and a2 , where a is negative then
sum of an infinite geometric series whose first three terms are a, a2 and b respectively, is:
1 3 1 1
1) 2) 3) 4)
2 2 3 4
x , 2 x 1
78. Let a function f x be defined in 2,2 as f x sgn x , 1 x 1 , where x
x , 1 x 2
denotes fractional part, then area bounded by graph of f x and x-axis is :
1) 2 2) 3 3) 4 4) 5
5 9 13 ......... 4 y 1
79. Let y 1og 2 x log 4 x log16 x ......... and 4log 4 x , then
1 3 5 ........ 2 y 1
the value of x 2 y equals :
1) 20 2) 22 3) 24 4) 28
80. Consider the cuves on the Argand plane as
C1 : arg z
4
3
C2 : arg z and C3 : arg z 5 5i , where i 1 .
4
25
Statement- 1: Area of the region bounded by the curves C1, C2 and C3 is
2
Statement-2 : The boundaries of C1, C2 and C3 constitute a right isosceless triangle.
1) Statement -1 is true, Statement-2 is true; Statement-2 is correct explanation for Statement
-1
2) Statement -1 is true, Statement-2 is true; Statement-2 is not correct explanation for
Statement -1
3) Statement -1 is true, Statement -2 is false
4) Statement -1 is false, Statement -2 is true
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. Point ‘O’ is the centre of the ellipse with major axis AB and minor axis CD. Point F is one
focus of the ellipse. If OF=6 and the diameter of the inscribed circle of triangle OCF is 2,
then the product of (AB) (CD) =
f t
x
82. If f : R R be a differentiable function satisfying f x x ln x x t.nt dt x R ,
1
1
then the value of f ' e f "
4
83. Mr. A either walks to school or take bus to school everyday. The probability that he takes a
bus to school is 1/ 4 . If he takes a bus, the probability that he will be late is 2 / 3 . If he walks
to school, the probability that he will be late is 1/ 3 . The probability that Mr. A will be on
p
time for at least one out of two consecutive days is , where p and q are co-prime, the value
q
of q p is
84. The contents of three urns are 1white, 2 red, 3 green balls; 2white, 1red and 1 green balls; 4
white, 5 red and 3 green balls. Two balls are drawn from an urn chosen at random and are
found to be one white and one green. If the probability that the balls so drawn came from the
a
third urn can be expressed as , where a and b are co-prime positive integers, then the value
b
of (a + b)=
of integration)
3
86.
Let I1 x 2 x 3 f x3 2 x 2 5 x 2020 dx and
1
3
I 2 4 x 2 3 x 2 f x3 2 x 2 5 x 2020 dx . If the value of
2 I1 a
where a and b are
3I 2 b
1
and D are externally tangent to each other and internally tangent to S. If DAC 120o . The
value of Rr 3R 3r is
a
89. Let f be a continuous and even function such that f x dx 10. If g(x) is a continuous
0
a
positive function such that g x g x 1 and g x dx 5 , then the value of
0
f x
a
1 g x
dx is ______
a
90. If area of the triangle formed by latus recturm and tangents at the end points of latus rectum
x2 y2
of 1 is A, then 80 A is
16 9
JEE-MAIN Date: 20-12-2023
Time: 09.00Am to 12.00Pm GTM-01 Max. Marks: 300
KEY SHEET
PHYSICS
1) 4 2) 3 3) 2 4) 4 5) 4
6) 4 7) 2 8) 1 9) 4 10) 4
11) 3 12) 1 13) 4 14) 1 15) 4
16) 1 17) 1 18) 1 19) 1 20) 2
21) 4 22) 15 23) 5 24) 242 25) 79
26) 2 27) 4 28) 4 29) 30 30) 6
CHEMISTRY
31) 1 32) 3 33) 1 34) 1 35) 2
36) 1 37) 1 38) 1 39) 1 40) 1
41) 3 42) 4 43) 3 44) 1 45) 3
46) 2 47) 3 48) 1 49) 1 50) 2
51) 85 52) 382 53) 4 54) 6 55) 3412
56) 8 57) 5 58) 3 59) 6 60) 3
MATHEMATICS
61) 2 62) 2 63) 1 64) 1 65) 1
66) 2 67) 1 68) 3 69) 1 70) 1
71) 1 72) 1 73) 3 74) 2 75) 1
76) 3 77) 3 78) 2 79) 3 80) 4
81) 65 82) 6 83) 25 84) 74 85) 1
86) 5 87) 10 88) 3 89) 10 90) 324
SOLUTIONS
PHYSICS
1. Key: 4
Sol: d= 6 cm, f = 504, v = 336 m/s e = 0.3d
2. Key: 3
Sol:
23. Key: 5
Sol: J E
5 10 7 10 10 3 0.5 10 3
2
i EA
53 10 3 A 125 mA
24. Key: 242
Sol. Resonance, Z=R
V 220 11
I P I 2R
Z 200 10
25. Key: 79
N P 500, N S 50; A 0.02 0.02m2
0 4107 Hm1 ,1 50 cm 0.5 m
0 N P N S A 410 500 50 0.02
7 2
P P P
P 3Pi or Pi ; Pi 2x Pt x t i
3 2
2.303 Pi 2.303 2 P
As we know k log So k log
t Pi x t 3( P Pt )
33. 2KI HgI 2 K2 HgI 4
75 3000
34. Vm X , g 250litre
0.90 1000
By PV = nRT; PXo 74.78torr and PYo 23.37torr
88 8000
Vm Y , g 800litre P PXo X X PYo PY P PXo PXo PYo X Y 0.48
0.88 1000
1
35. E1 0.059 log 0.059 pH1
H
pK a
1 E1 E2 E E2
1
E 2 0.059 pH 2 ; pH 1 pH 2 2 pK a
2 0.059 0.118
1 60
36. 6.023 10 23 3.74 10 20
96500
37. Down the group E H bond length increases
38. NCERT (d block elements)
39. Fe can exhibit variable oxidation states.
40. From La to Lu ionic radii decreases
3
41. Cr NH 3 6 d 3 , t 21,1,1
g eg
0,0
CFSE 0.4 3 0 1.2 0
42. Q – shows cis – trans isomerism
R – shows fac and mer isomerism
43.
44. Intramolecular Sn 2 reactions
45. Intramolecular oxymercurisation demercurisation. Since 6 membered ring is more stable
then 5 membered ring c is the major product formed.
46. Cleavage of O-H bond takes place from alcohol.
Ph Ph Ph
+
H
CH 3 C CH 2 CH 3 C CH 2 CH3OH CH 3 C CH 2
+
47. O OH OCH3OH
CH3 CH3
SN 1
H3C Br + NaOH (First order)
H3C OH +NaBr
CH3 CH3
At time t = 0 P0 0
At time t P P0-P
48.
P0 0.693
rate = [ Br] ln kt ; t1/ 2
P k
ln
P
kt ;
Q P0 P 1 P 1 e kt
P0 P 0 P0 P0
Br CN COOH
Br2 / P HOH / H
CH 3 COOH CH 2 COOH
NaCN
CH 2 COOH
CH 2 COOH
49.
50. m – xylene does not show coupling
760 5.26
51. P 70
100
52. butyricacid
o
83 426 127 382
53. a,b,d
The reactions are
4 NaCl K 2Cr2O7 6 H 2 SO4 2CrO2Cl2 4 NaHSO4 2 KHSO4 3H 2O
(Re d vapours )
CrO2Cl2 4 NaOH Na2CrO4 2 NaCl 2 H 2O
chromyl yellow
chloride solution
54. H 2 S , FeSO4 , NaNO2 , Na 2 SO3 .PbS , Na2 S
55. 1) XeF2 , XeF4T 2
2) XeF2 , Z 1
3) XeF6 , X 3
4) XeO3 , Y 4
56. PH 5 , PbI 4 , NCl5 , OF4 , HFO4 , FeI 3 , Al2 F6 , B2 F6
CH3 CH3 CH2
Cl
C2H5ONa + +
C2H5OH C+T C+T
57. CH3
58. Compounds 1,5,7 will follows the reduction of LIAlH4 and aldol condensation and Iodo
form reaction.
x 100 100 x 20 68
59.
100
60. Vitamins A, D, E, and K are fat soluble. Whereas vitamins B and C are water soluble.
MATHEMATICS
(2,-1)
61.
We are given that directrix of the parabola is 4x 3y 21
and vertex of the parabola is 2, 1
8 3 21 10
Now a 2
5 5
latus rectum of the parabola = 4a 8
62. Equation of PN : x at 2
y c bisects PN
c at
Which cuts the parabola at Q
c2 c2 at 2
c 2 4ax x Q , c Q , at
4a 4a 4
at 0
Equation of NQ : y 0
at 2
x at 2 ;
at 2
4
2021 2021 2021
1 1 1 1 1 2020 a
63.
n 2 n 1 n 1
n 2 n n 1
n 2 n 1
1
n
2021 2021 b
b a 1
dx x 2 x
64. 1 0
dy y 2 y
x dx dt dt dt dy
Let t x ty y t y t t2 t 1 0 2
y dy dy dy t 1 y
x
tan 1 t ln y C 0 tan 1 ln y C 0
y
Tr A a b c 10
65. , a b c
Therefore it may be 1,3,6 , 1, 4,5 . 2,3,5
number of matrices = 3! 3 3 !
Arranging diagonal arranging non-diagonal elements = 3 3!
2
20
r
310 1/9
Tr 1 18Cr x
18 r
x
When r = 9
B T10 18C9 310
2m 1 4 2n 1
2
We have, x 2 2 2 x .
1 1
68.
x x
r
50 r 1
Tr 1 50
C r .x . 50
C r x 50 2r
x
For independent of x, we put
50 2r 0 r 25
T251 50C25
But in binomial expansion of x a , middle terms is independent of x, iff x . a 1.
n
69. D n n!
n
1 r 1 1 1
n!1 ......
1
n
r0 r! 1! 2! 3! n!
1 1 1 1 1
D5 5! 1
1! 2! 3! 4! 5!
1 1 1 1
120 6 20 5 1 65 21 =44
2 6 24 120
Hence, Statement-1 is true, statement-2 is true and statement-2 is a correct
explanation for statement-1
70. Circle: x 2 y2 6x 2y 0
Line: 2x y 5
Centre= 3, 1
Now, 2 3 1 5 , hence centre lies on the given line. Therefore line passes through the
centre. The given line is normal to the circle.
This statement-2 is true, but statement-1 is not true as there are infinite circle according to
the given conditions.
10 10 10
2x y 5
1.3.44
100 9 150 100 0.6 150 0.4
2 2 2
250
33.60 900 150 36 24
2
2 16 4
72. Given, n 100, x 40, 10 and x 40
x i
40
x 40 x i 4000
i
n 100
Now, corrected x i 4000 30 70 3 27 = 4030 100 3930
3930
Corrected mean = 39.3
100
Now,
2 x i2
40
2
100
x12
1600 x12 170000
n 100
Now, corrected
x 170000 30 70 32 27
2 2 2
2
1 =164939
164939
39.3
2
corrected
100
1649.39 39.3 39.3 1649.39 1544.49
104.9 10.24
73. x y 17; xy 60, To find x 2 y2
Now, x 2 y 2 x y 2xy
2
h 2 k 2 2h 4k 11
So, locus of (h,k) is x 2 y2 2x 4y 11
Aliter : x h y k 25 ....... 1
2 2
=
k
18x 27 x 1 K =9
ab a ab
2
77. 2b a a 2 and a 2 3
2a 3 a 2 a a 2a a 1 0
2
a 2a 1 a 1 0 a0
1 1
1 1
a , b 2 4
2 2 8
1 1 1
G.P. is , , , ...............
2 4 8
1
1
Sum 2
1 3
1
2
78.
1 1
Area bounded = 1 1 2 1 1 1 3
1 1 1
79. y log 2 x 1 2 3 ........ 2 log 2 x
2 2 2
5 9 13 ...... 4y 1
4 log 4 x
1 3 5 ........ 2y 1
2y 2 3y
2 log 2 x y y 2 2y 3
y2
y 3 y 1, rejected and x 23/2
x 2 y 24
80. We have C1 : arg z
4
y
tan 1
x 4
let z x iy
y
tan 1 yx
x 4
C1 : y x ..... i
3 y 3
C 2 :arg z
4
tan 1
x 4
Let z x iy
y 3
tan 1 y x
x 4
C2 : y x ..... ii
And C3 : arg z 5 5i
y 5
tan 1
x 5
letz x iy
y5
tan 0 y 5
x 5
C3 : y 5 .... iii
We get the following figure.
1 50 50
Area of the region bounded by C1 , C2 and C3 25
2 5 0 50
Statement-1 is false
Now, OA 5 2, OB 5 2 and AB 10
OA OB AB and OA OB
2 2 2
y ln x n2 x 2n x dx xn 2 x C
Put x = 1 get C = 0
y ln x x ln 2 x
y f x x ln x.
1 1
f ' x f ' e f " 1 ln e 4 24 6
x 4
83. A: Mr. A reaches late
B1 : A goes to school by walking
B2 : A takes bus to school.
E: A will be on time for atleast one out of 2 consecutive days.
P B1 3 / 4
P B2 1/ 4
P A / B1 1/ 3
P A / B2 2 / 3
3 1 1 2 5
P A P B1 A P B2 A
4 3 4 3 12
5 5 119 p
P E 1 P A A 1 q p 144 119 25
12 12 144 q
1
84. The probability of drawing one white balls and one green ball from the first urn is
5
1
The probability of drawing one white ball and one green ball from the second urn is
3
2
The probability of drawing one white ball and one green ball from the third urn is ,
11
2
11 15 a
Therefore, the probability that the third urn was chosen is
1 1 2 59 b
5 3 11
Hence 15 59 74
1 dx
cos x 2019 .cos x dx 2019
2
85. ec
II cos x 2019
1
1 sin x
. cot x 2019 .cot x dx
cos x 2019
cos x 2020
3
The point inside the quadrilateral ACBP which is equidistant from all the four vertices
is the centre M 6.8 of the circle described on PC as diameter.
Hence , distance from origin to the point M is 36 64 100 10
88.
cos120 o
1 r 1 R r R
2 2 2
1
2 1 r 1 R 2
3 3R 3r rR 0 Rr 3R 3r 3
89. f x f x ,g x ,g x g x 1
a a
f x
f x dx 10
0
I 1 g x dx
a
f xa a
g x f x dx
Using King I dx I
a
1 g x a
1 g x
Eqn. (1) +Eqn. (2
a a a
2I f x dx 2 f x dx I f x dx 10 )
a 0 0
5 b2 9
90. e PS1
4 a 4
16 1 9 9
Q , 0 A . . 80A 324
5 2 2 5