Sec:JR.

IIT_*CO-SC(MODEL-A) Date: 30-07-2023

Time: 3HRS WAT-13 Max. Marks: 186

30-07-2023_JR.STAR CO-SUPERCHAINA(MODEL-A)_JEE-ADV_WAT-13_SYLLABUS
MATHS PRESENT WEEK(80%):
MATRICES: Types of Matrices and their properties, Algebra of Matrices,
Transpose of Matrix, Symmetric & Skew-Symmetric Matrix, Determinant of a
square Matrix, Adjoint and Inverse of a matrix and its properties
PREVIOUS WEEK(20%): TRIGINOMETRIC EQUATIONS:
General Solution, Solution of Trigonometric equation using graph or otherwise,
Equations based on extreme values using graph or otherwise, Trigonometric
inequalities using graph or otherwise DETERMINANTS:
Introduction of Determinants & its Properties, Properties of Determinants
PHYSICS PRESENT WEEK(80%):
Power , Vertical Circular Motion
PREVIOUS WEEK(20%):
Work ,Power, Energy: Work, Kinetic energy, work - enegry theorem, conservative
and non conservative forces, potential energy, conservation of energy Elastic
Potential energy of Spring, Spring Block Problems, Stable and unstable
equilibrium
CHEMISTRY PRESENT WEEK(80%):
Chemical kinetics: Rates of chemical reactions; Order, Molecularity rate law
and Rate constant, Differential and integrated rate expressions for zero and first
order reactions, half-life; examples of 1st order KineticsTypes of problems based
on first order kinetics, Collision Theory, Arhenius equation effect of catalyst on
rate of reaction, Second order and nth order kinetics, parallel first order reaction
(Exclude: Steady state approximation, sequential, opposing reactions)
PREVIOUS WEEK(20%):
Ionic Equilibrium: Theories of acid & bases
– Arhenius, Bronsted-Lowry and Lewis theory (Exclude: Comparision of Acidic &
Basic strength), Ionic product of water and pH scalepH calculation involving strong
acid, Strong base and their mixtures, pH of weak acids and bases, Mixture of weak
acids, Levelling effect, Common ion effect, Dissociation of polyprotic acids, Salts
and their Hydrolysis, Buffer solution & Buffer capacity, Solubility of sparingly
soluble salts and solubility product, Indicator, Acid base titration curves
Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P

2019-P1_MODEL
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 5 – 12) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Total 18 62

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 22) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 23 – 30) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 40) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 41 – 48) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62

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MATHEMATICS Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
2i  j
1. If 'A' is a 3rd order square matrix whose general element a ij  and A  L  D  U ,
2
where L, D & U are Lower triangular, diagonal and upper triangle matrices
respectively,then, the sum of non-diagonal elements of the matrix 'L' is

( where L   rij  ; rij  0,  j  i , D   d ij  ; d ij  0,  i  j and U   u ij  ; u ij  0,  i  j )

A) 6 B) 6 C) 12 D)12

 1 1 1   4 2 2
2. Let A  2 1 3 and 10A 1   5 0   . Then  is
   
1 1 1   1 2 3 

A) -2 B) -1 C) 2 D) 5

3. If P,B and Q are 3rd order square matrices of unity determinant, then adj  Q 1BP 1  

A) PBQ B) PB1Q C) QBP D) QB1P

4. If A & B are any two different square matrices of same order with  A  B  is non-

singular. Also, A 3  B3 and A 2 B  B2 A , then

A) A 2  B 2  O B) A 2  B 2  I

C) A 3  B3  I D) A 3  B3  O

SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
5. If A is a 3  3 order matrix such that det(A) = 2, then (where det  A   A 
determinant value of matrix A)
1
A) 2adjA  32 B) adj2A 16  
C) adj A 1 
4
D) adj  2  adj2A    2 22

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
6. Let S be the set of real values of  such that 2 1  a 2   sin 2  2a  sin   cos  ,a   ;
then which of the following can be correct :
1
A) a  B) a  sin  for some  S
2

C) a  sin  for some  S D)  n  ; n 
4
7. Suppose A is 5 7 matrix, all of whose rows are identical. suppose B is an 7  5 matrix,
all of whose columns are identical. Then,

A) maximum number of distinct elements in 5th column of matrix AB is 5

B) maximum number of distinct elements in 5th row of matrix AB is 1

C) maximum number of distinct elements in matrix AB is 5

D) These exist such matrices A and B such that AB is non singular

a, ij

8. Let M n   a ij  be a n  n matrix such that a ij  1, i  j 1 .
0, otherwise

Let D n denotes the determinant value of matrix M n . Then ,

A) D n  D n 1  a D n 2 ,  n    1,2

B) D n  aD n 1  D n  2 ,  n    1,2
n
C) D r  D n 1 , when a  1, n    1
r 1

D) when a =1, D 2023 1

9. Let A 3 3 and b31 be given matrices and there exist two distinct matrices X1 and X 2
such that AX1  b  AX 2 then
A) A is a singular matrix

B) A  5X1  4X 2   b

C) These exist infinitely many matrices X such that AX  b

D) These exists a positive integer n such that A n is a null matrix

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 0 c b 
10. X  a b c  and A   c 0 a  , where a 2  b 2  c2 1. Then .

  b a 0 

A) A 2  I  X ' X

B) A 3  A

C) A 2  I is singular matrix

D) The least positive integer n   2  such that A n  A is 5.

11. Choose the correct statement(s) regarding 2  2 matrices A, B and C :-

(where tr  P  denotes sum of diagonal elements of square matrix P)

A) If tr  A   0 then A 2   det A  I  O

B) If tr  A   0 then A 4 B  BA 4

C) If tr  A   0 then A 3 B  BA 3

2 2
D)  AB  BA  C  C  AB  BA 

2 1 
12. If A & B are square matrices of order 2 such that A  adj BT     &
 1 2 

 0 1
A T  adj B     , then
 1 0

A) B is symmetric B) A n  A  n  N

C) A  A 2  A 3  A 4  A 5  0 D) B  B2  B3  B 4  B5  0

( Where X = determinant of matrix X )

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
SECTION – III
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
 bc b 2  bc c 2  bc
13. If a  cot 800 , b  cot 600 and c  cot 400 , then the value of a 2  ac ac c 2  ac
a 2  ab b 2  ab ab

is equal to

14. The maximum value of real parameter b for which the equation in x as
cos8 x  b cos 4 x  1 0 has a solution , is

1 1 1  10  2 5 5 1 
 , then tr  BA 2023 BT  is equal to
15. If A    and B  4
 0 1  1 5
 10  2 5 

(where tr  P  denotes sum of diagonal elements of square matrix P)

T T T T
16. If A is a square matrix such that A 1 0  1 1 & A 0 1   2 1 , then sum
T
of the elements of the matrix A  2 3 is

 3 2 sec 0 
17. Let A    and B   0  be two matrices . If A  adj A   5 B 2 ,
 1 1   sin   cos 

then number of values of  in 0,2  is____

 3 2 2
18. Let a matrix P   4 0 0  . A matrix Q of order 3  3 exists such that
 
 1 4 0 

QP 2  Q 3 .det  Q  . If PQ  QP and P  2Q , then det  P 2  2 PQ  is equal to ____

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
PHYSICS Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.

19. A particle of mass m slides on a frictionless surface ABCD, starting from rest as
shown in Fig. The part BCD is a circular arc. If it looses contact at point P, the
maximum height attained by the particle from point C is

 1   1   1   1 
A) R 2  B) 2R 1  C) 1.5R 1  D) R 1 
 2 2  
 2 2  2 2  
 2 2

20. A smooth circular tube of radius R is fixed in a vertical plane. A particle is projected
from its lowest point with a velocity just sufficient to carry it to the highest point. The
time taken by the particle to reach the end of the horizontal diameter is

  sec d  ln sec  tan  

R R g g
A)
g

ln 1  3  B)
g

ln 1  2  C)
R

ln 1  2  D)
R

ln 1  3 
21. A particle moving in a straight line is acted upon by a force which works at a constant
rate and changes its velocity from u and v over a distance x. The time taken in it is
3 u  v  x 2 u  v  x 3 u  v  x 2 u  v  x
A) B) C) D)
2 (u 2  v 2  uv ) 3 (u 2  v 2  uv ) 2 (u 2  v 2  uv ) 3 (u 2  v 2  uv )

22. A particle of mass m is moving in a circular path of constant radius r such that its

centripetal acceleration ac is varying with time t as ac  k 2 rt 2 , where k is a constant. The

power delivered to the particle by the force acting on it is
A) mkrt B) mk 2 r 2t 2 C) mk 2 rt 2 D) mk 2 r 2t

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.

23. Bob B of the pendulum AB is given an initial velocity 3Lg in horizontal direction. The
maximum height of the bob from the starting point is

3L 3L
A) Is if AB is a massless rod B) Is if AB is a massless string
2 2
40 L 40 L
C) Is if AB is a massless rod D) Is if AB is a massless string
7 27
24. A small sphere B of mass m is released from rest in the position shown and swings
freely in a vertical plane, first about O and then about the peg A after the cord comes
in contact with the peg. The tension in the cord

3mg
A) Just before the sphere comes in contact with the peg is
2
5mg
B) Just before the sphere comes in contact with the peg is
2
5mg
C) Just after it comes in contact with the peg
2
3mg
C) Just after it comes in contact with the peg
2

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
25. A ring of mass M hangs from a thread and two beads of mass m slides on it without
friction. The beads are released simultaneously from the top of the ring and slides down
in opposite sides.

3M
A) The ring will start to rise, if m 
2
3M
B) The ring will start to rise, if m 
2
1
C) The ring will start to rise, if tan  
3
1
D) The ring will start to rise, if sin  
3
26. A completely filled cylindrical tank of height H contains water of mass M. At a height h
above the top of the tank there is another wide container. The entire water from the tank
is to be transferred into the container in time t0 such that level of water in tank decreases
at a uniform rate. How will the power of the external agent vary with time t?

Mg  t  Mg  t 
A) P  h  H  B) P  h  H 
t0  t0  t0  t0 

Mg  t0  Mg  t0 
C) P  h  H  D) P  h  H 
t0  t  t0  t 

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
27. A particle starting form rest at the highest point slides down the outside of a smooth
vertical circular track of radius 0.3 m. When it leaves the track its vertical fall is h and
the linear velocity is v. The angle made by the radius at that position of the particle with
the vertical is  . Then

2 1
A) h  0.1m and cos   B) h  0.2m and cos   C) v  2 m / s
3 3
D) After leaving the circular track the particle will describe a parabolic path

28. Mechanical energy of a particle P moving on x-axis is given by E  Ax2  BV 2 , where x is

displacement of P from x=0 and V is the velocity of P at x. A and B are positive
constants. If it’s mechanical energy is conserved, then:

A) the x-coordinate of the particle can be 2E A

B) the particle is at equilibrium at x  0

E
C) maximum velocity of the particle during its motion is
B
Ax
D) acceleration of the particle as a function of x is ax  
B
29. In the system shown in the figure the mass m moves in a circular arc of angular
amplitude 600 . Mass 4m is stationary. Then: at A the block m is at rest to release and
length of hanging part is l.

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
A) The minimum value of coefficient of friction between the mass 4m and the surface of
the table is 0.50
B) The work done by gravitational force in the block m is positive when it moves from A
to B
C) The power delivered by the tension when m moves from A to B is zero
D) The kinetic energy of m in position B equals the work done by gravitational force on
the block when its moves from position A to B.

30. Block A has no relative motion with respect to wedge fixed to a box as shown in figure
during the displacement -1 or displacement -2 of the box

A) Work done by gravity on block A in displacement-2 is less than in displacement-1

B) Work done by normal reaction on block A in both the motions will be positive
C) Work done by force of friction on block A in displacement -1 may be positive
D) Work done by force of friction on block A in displacement -1 may be negative

SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.

31. A particle of mass m is suspended by a string of length l from a fixed rigid support. A
sufficient horizontal velocity v0  3gl is imparted to it suddenly. Calculate the angle
made by the string with the vertical when the acceleration of the particle is inclined to
the string by 45°. (In degree)

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
32. A small block slides with velocity 0.5 gr on the horizontal frictionless surface as shown
in the figure. The block leaves the surface at point C. The angle  in the figure
is   cos1 (n) . Find n?

33. A track (ACB) is in the shape of an arc of a circle. It is held fixed in vertical plane with
its radius OA horizontal. A small block is released on the inner surface of the track from
point A. It slides without friction and leaves the track at B. The value of tan  so that the
block travels the largest horizontal distance by the time it returns to the horizontal plane
passing through B is

34. As shown in the figure a person is pulling a mass 2kg from ground on fixed rough surface
upto the top of surface with the help of a light inextensible string. Find the work done in
joule by tension in the string if height of the surface is 1m from ground, length of base of
the surface is 2.5m and friction coefficient is 0.4. Assume that the block is pulled with
negligible velocity  g  10 m / s 2 

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35. Power of the only force acting on a particle of mass 1kg moving in straight line depends
on its velocity as P  2 where  is in ms1 and P is in Watt. If initial velocity of the
particle is 1ms1 , then the displacement (in m) of the particle in 'ln 2' seconds will be

36. A block of mass m = 5kg is pulled by external agent by means of string and multiple
pulleys as shown in the figure. At a certain instant the velocity and acceleration of point P
are 5ms 1 and 5ms 2 respectively. Surface is smooth, string and pulleys are ideal. The rate
of doing work at the instant by external agent (in wt) is

m
P

CHEMISTRY Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.

37. Some PH 3 is introduced into a flask at 600C containing an inert gas, PH 3 proceeds to
(g )

decompose into P4( g ) and H 2( g ) the reaction goes to completion as per first order kinetics.
The total pressure is given below as a function of time. The value of rate constant for the
reaction
4 PH 3( g )  P4( g )  6 H 2( g )

Time(sec) 0 60 120 
P(mm of Hg) 262.40 272.90 275.51 276.40

( log10 18.67  1.27;log10 4.67  0.67;log10 1.19  0.075)

A) 1.45 x 103 sec 1 B) 1.45 x 103 min 1

C)5.8 x 103 sec 1 D)2.32 x 10 2 sec 1

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Narayana IIT Academy 30-07-23_JR.IIT_*CO-SC(MODEL-A )_JEE-Adv_WAT-13_Q’P
38. What is the order of reaction, when concentration of the reactant ‘C’ varies with ‘t’ as
shown by the following graph.

A) First order B)Second order

C)Zero order D)Data insufficient to find order
39. Consider the reaction 2 H 2 ( g )  2 NO ( g )  N2 ( g )  2 H 2O ( g ) The rate law for this reaction is
rate  k[ H 2 ][ NO ]2 Under what conditions could these steps represents the mechanism?
Step: 1 2NO  N 2O2
Step: 2 N 2O2  H 2  N 2O  H 2O
Step: 3 N 2O  H 2  N 2  H 2O
A) These steps cannot be the mechanism under any circumstances
B) These steps could be the mechanism if step 1 is slow step
C) These steps could be the mechanism if step 2 is slow step
D) These steps could be the mechanism if step 3 is slow step
40) Iodide ion is oxidized to Hypoiodite ion (clo  ) in basic solution as
I  ( aq )  ClO  ( aq )  IO  ( aq )  Cl  ( aq )

The following initial rate experiments were run and for each the initial rate of formation
of IO  was determined
Exp. Initial concentration (mol/L) Initial rate
I ClO  OH  (mol L sec 1 )

1 0.010 0.020 0.010 12.2 102

2 0.020 0.010 0.010 12.2 102
3 0.010 0.010 0.010 6.1 10 2
4 0.010 0.010 0.020 3.0  102

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The correct rate law for the reaction is

A) r  K [ I  ][ C lO  ][ O H  ]

B) r  K [ I  ][ClO  ][OH  ]1

C) r  K [ I  ][ClO  ][OH  ]

D) r  K [ I  ][ClO  ][OH  ]1

SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.

41. Consider the following reactions

i) A  Product
TiTime(hr.) 0 1 2 3 4
Conc.(mole L) 100 90 81 72.9 65.61

ii) B  Product
Time(hr.) 0 1 2 3 4
Conc. (mole L) 100 90 80 70 60

Select the correct statement(s) on the basis of above information.

A) The unit of rate constant for the first reaction is hr 1
B) The unit of rate constant for the second reaction is mole L1 hr 1
0.693
C) Half-life for first reaction  [k=rate constant]
k
A
D) Half-life for second reaction  [A=Initial concentration, k= Rate constant]
2k
42. Which of the following is/are correct statements?
A) For elementary reactions, molecularity and order of reaction is same.
B) 50% of zero order reaction is completed in ‘t’ sec then time taken to complete
100% of same reaction is’2t’sec

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C) According to Maxwell Boltzmann distribution curve as the temperature increases
fraction of molecule which show most probable velocity decrease
D) Area under the curve in Maxwell Boltzmann distribution curve is constant with
decrease or increase in temperature
43. In a hypothetical A  B the activation energies for the forward and backward reaction
are 15 and 9kJ/mole respectively. The potential energy of A is 10kJ/mole, then which
is/are correct?
A) The threshold energy of the reaction is 25 kJ/mole
B) Potential energy of B is 16kJ/mole
C) Heat of reaction is 6kJ/mole
D) The reaction is endothermic
44. Select the correct statement(s) regarding phosphoric acid. Given that
H f ( H 3 PO4 ) aq =-1290 kJ/mole

H f ( H 2 PO4 )aq =-1302 kJ/mole

S ( H 3 PO4 ) aq =176 J mole 1K 1

S ( H 2 PO4 )aq =89 J mole 1K 1

Assume  f H ( H  )aq =0 and S ( H  )aq =0

Consider a standard temp at 298K.

R=8.314J. mole 1K 1 and ln x  2.303log x
A) P Ka of ( H 3 PO4 ) is nearly 2.44
1
B) P Ka of ( H 3 PO4 ) is less than P Ka
2 1

C) Ka1 of ( H 3 PO4 ) is exothermic D) Ka1 of ( H 3 PO4 ) is entropy driven

45. 100ml of 0.5 M Hydrazoic acid ( HN 3 , K a  3.6  104 ) and 400 ml of 0.1 M cyanic acid
( HOCN ),( K a  8  10 4 ) are mixed, which of the following is (are) true for the final

solution?
A) [ H  ]  102 M B) [ N 3 ]  3.6  103 M
C) [OCN ]  6.4 10 3 M D) [ H  ]  1.4 102 M

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46. Consider the following first order decomposition reaction : A4 ( g )  4 A( g ) . Which of the
following statement(s) is/are correct regarding the reaction?(log2=0.3)

A)At 30 mins, only 20% reaction is complete.

B) t1/2 of reaction is approximately 90 min.

C)Rate of reaction decrease linearly with time.
D)The time for intersection of two curves is independent of initial concentration of A4 .
47. According to the Arrhenius equation,
A) A high activation energy usually implies a fast reaction.
B) Rate constant increases with increase in temperature, this is due to a greater
number of collisions whose energy exceeds the activation energy.
C) Higher the magnitude of activation energy stronger is the temperature dependence
of the rate constant.
D) The pre-exponential factor is a measure of the rate at which collisions occur,
irrespective of their energy.
48. For a first order reaction A( g )  2 B( g )  C ( g ) at constant volume and 300K. the total
pressure at the beginning (t=0) and at time t are P0 and Pt respectively. Initially, only A is
present with concentration [ A]0 and t1/3 is the time required for the partial pressure of A to
reach 1/3rd of its initial value. The correct option(s) is (are)
(Assume that all these gases behave as ideal gases)

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SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values
comprising of positive or negative decimal numbers (place value ranging from
Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.

y
49. pH of Ba (OH )2 is12. If its K sp is x  10 y M 3 then the value of is
x
50. Consider the kinetic date given in the following table for the reaction A+B+C  Product

3. Experiment [A] [B] [C] RATE

No. ( mol.dm 3 ) ( mol.dm 3 ) ( mol.dm 3 ) ( mol.dm 3s 1 )
1 0.2 0.1 0.1 6.0  10 5

2 0.2 0.2 0.1 6.0  10 5

3 0.2 0.1 0.2 1.2  104

4 0.3 0.1 0.1 9.0  105

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The rate of the reaction for[A]=0.15 mole dm 3 ,[B]=0.25mol dm 3 and [C]=0.15mol dm 3 is
found to be Y  105 moldm 3s 1 .The value of Y is______

51. The plot of log k f , versus 1/T for a reversible reaction A( g )  P ( g ) is shown.

Pre-exponential factors for the forward and backward reactions are 1015 S 1 and 1011 S 1 ,
respectively. If the value of log K for the reaction at 500K is 6, the value of log kb at

250K is___.
[K=equilibrium constant of the reaction
k f =rate constant of forward reaction

kb =rate constant of backward reaction]

52. The inversion of cane sugar proceeds with constant half-life of 500min at p H  5 for any
concentration of sugar. However, if p H  6 , the half-life changes to 50min.For this
reaction rate equation is r  k[ sugar ]a [ H  ]b , then value of a + b is.(with respect to cane
sugar reaction is first order)

53. For a first order reaction, the ratio of time for 99.9% of the reaction to complete and half
x
of the reaction to complete is x, then is
2

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54. A substance undergoes first-order decomposition involving two parallel first –order
reaction as

k1  1.25  104 s 1 , k2  3.80  10 5 s 1

The mole percentage of B in the product is

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