Nitrogen dioxide (Dinitrogen Tetroxide)

Safety Data Sheet LIND-P088

This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

SECTION: 1. Product and company identification

1.1. Product identifier
Product form : Substance
Substance name : Nitrogen dioxide (Dinitrogen Tetroxide)
CAS-No. : 10102-44-0
Formula : NO2
Other means of identification : Nitrogen Oxide; Nitrogen Peroxide; Dinitrogen Tetroxide
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial and professional use
1.3. Details of the supplier of the safety data sheet
Linde Inc.
10 Riverview Drive
Danbury, CT 06810-6268, USA
www.lindeus.com

Electronics gas products 1-800-932-0624 or 1-908-329-9700

Linde Inc. 1-844-44LINDE (1-844-445-4633)

For additional product information contact your local customer service.

1.4. Emergency telephone number
Emergency number : Onsite Emergency: 1-800-645-4633

CHEMTREC, 24 hr/day 7 days/week

— Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887
(collect calls accepted, Contract 17729)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
GHS-US classification
Ox. Gas 1 H270
Press. Gas (Liq.) H280
Acute Tox. 1 (Inhalation:gas) H330
Skin Corr. 1B H314
Eye Dam. 1 H318

2.2. Label elements

GHS US labelling
Hazard pictograms (GHS US) :

GHS03 GHS04 GHS05 GHS06

Signal word (GHS US) : Danger
Hazard statements (GHS US) : H270 - MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H330 - FATAL IF INHALED
CGA-HG01 - MAY CAUSE FROSTBITE.
CGA-HG11 - SYMPTOMS MAY BE DELAYED
CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT.
Precautionary statements (GHS US) : P202 - Do not handle until all safety precautions have been read and understood.
P220 - Keep/Store away from clothing and other combustible materials.
P244 - Keep reduction valves/valves and fittings free from oil and grease.

EN (English) SDS ID: LIND-P088 1/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

P260 - Do not breathe gas/vapours

P262 - Do not get in eyes, on skin, or on clothing.
P271+P403 - Use and store only outdoors or in a well-ventilated place.
P280+P284 - Wear protective gloves, protective clothing, eye protection, respiratory protection,
and/or face protection.
P370+P376 - IN CASE OF FIRE: Stop leak if safe to do so
P303, P361, P353, P363, P310 - IF ON SKIN OR (HAIR): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before
reuse. Immediately call a POISON CENTER/doctor.
P336 - Thaw frosted parts with lukewarm water. Do not rub affected area.
P332+P313 - IF SKIN IRRITATION OCCURS: Get medical advice/attention.
P304, P340, P310 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing.Immediately call a POISON CENTER/doctor.
P-305-351-338-313 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
P405 - Store locked up.
P501 - Dispose of contents/container in accordance with container Supplier/owner instructions
CGA-PG05 - Use a back flow preventive device in the piping.
CGA-PG06 - Close valve after each use and when empty.
CGA-PG10 - Use only with equipment rated for cylinder pressure.
CGA-PG12 - Do not open valve until connected to equipment prepared for use.
CGA-PG20 - Use only with equipment of compatible materials of construction and rated for
cylinder pressure.
CGA-PG21 - Open valve slowly.
CGA-PG22 - Use only with equipment cleaned for oxygen service.
CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F).
CGA-PG18 - When returning cylinder, install leak tight valve outlet cap or plug.

2.3. Other hazards

Other hazards which do not result in : None.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substances
Name : Nitrogen dioxide (Dinitrogen Tetroxide)
CAS-No. : 10102-44-0
Name Product identifier %
Nitrogen dioxide (CAS-No.) 10102-44-0 ≥ 99
Nitrogen tetroxide (CAS-No.) 10544-72-6 ≤1

3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing,
give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a
physician. . WARNING: To avoid possible chemical burns, the rescuer should avoid breathing
any exhaled air from the victim.
First-aid measures after skin contact : In case of contact, immediately flush affected areas with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Call a physician. Wash clothing before
reuse. Discard contaminated shoes. The liquid may cause frostbite. For exposure to liquid,
immediately warm frostbite area with warm water not to exceed 105°F (41°C). Water
temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes
or until normal coloring and sensation have returned to the affected area. In case of massive
exposure, remove clothing while showering with warm water. Seek medical evaluation and
treatment as soon as possible.

EN (English) SDS ID: LIND-P088 2/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
CONTACT WITH THIS PRODUCT REQUIRES IMMEDIATE MEDICAL ATTENTION! Symptoms may be delayed. Seek medical attention even if no
symptoms are present.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Oxidizing agent; vigorously accelerates combustion. Contact with flammable materials may
cause fire or explosion.
Explosion hazard : Heating may cause an explosion. PRESSURISED CONTAINER: MAY BURST IF HEATED.
Reactivity : Cylinders are NOT equipped with a pressure relief valve. MAY CAUSE OR INTENSIFY FIRE;
OXIDIZER.
5.3. Advice for firefighters
Firefighting instructions : DANGER: Toxic, oxidizing, corrosive liquid and gas under pressure.

Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
L—Fire Protection.
Special protective equipment for fire fighters : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters.
Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat
radiation may cause gas containers to rupture. Cool endangered containers with water spray jet
from a protected position. Prevent water used in emergency cases from entering sewers and
drainage systems.

Stop flow of product if safe to do so.

Use water spray or fog to knock down fire fumes if possible.

Other information : Cylinders are NOT equipped with a pressure relief valve.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : DANGER: Toxic, oxidizing, corrosive liquid and gas under pressure.. Immediately
evacuate all personnel from danger area. Do not approach area without self-contained
breathing apparatus and protective clothing. If cylinders are leaking, reduce toxic vapors with
water spray or fog. Reverse flow into cylinder may cause rupture. (See section 16.) Shut off
flow if without risk. Ventilate area or move cylinder to a well-ventilated area.

6.1.1. For non-emergency personnel

No additional information available
6.1.2. For emergency responders
No additional information available
6.2. Environmental precautions
Try to stop release. Reduce vapour with fog or fine water spray. Prevent waste from contaminating
the surrounding environment. Prevent soil and water pollution. Dispose of contents/container in
accordance with container supplier/owner instructions.

EN (English) SDS ID: LIND-P088 3/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

6.3. Methods and material for containment and cleaning up

No additional information available
6.4. Reference to other sections
See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Do not breathe gas/vapour. Avoid all contact with skin, eyes, or clothing. Emergency eye wash
fountains and safety showers should be available in the immediate vicinity of any potential
exposure.

Wear leather safety gloves and safety shoes when handling cylinders. Protect containers from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry
bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable
strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to
open, discontinue use and contact your supplier. Close the container valve after each use;
keep closed even when empty. Never apply flame or localized heat directly to any part of the
container. High temperatures may damage the container and could cause the pressure relief
device to fail prematurely, venting the container contents. For other precautions in using this
product, see section 16.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Avoid oil, grease and all other combustible materials.

Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open
Flames” signs in storage and use areas. There must be no sources of ignition. Separate
packages and protect against potential fire and/or explosion damage following appropriate
codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or
according to requirements determined by the Authority Having Jurisdiction (AHJ). Always
secure containers upright to keep them from falling or being knocked over. Install valve
protection cap, if provided, firmly in place by hand when the container is not in use. Store full
and empty containers separately. Use a first-in, first-out inventory system to prevent storing full
containers for long periods. For other precautions in using this product, see section 16.

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in the
piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with
adequate ventilation. If a leak occurs, close the container valve and blow down the system in a
safe and environmentally correct manner in compliance with all international, federal/national,
state/provincial, and local laws; then repair the leak. Never place a container where it may
become part of an electrical circuit.
7.3. Specific end use(s)
None.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)
ACGIH ACGIH OEL TWA [ppm] 0.2 ppm
USA OSHA OSHA PEL C 9 mg/m³
USA OSHA OSHA PEL C [ppm] 5 ppm
USA IDLH IDLH [ppm] 13 ppm
Nitrogen dioxide (10102-44-0)
ACGIH ACGIH OEL TWA [ppm] 0.2 ppm
USA OSHA OSHA PEL C 9 mg/m³

EN (English) SDS ID: LIND-P088 4/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

Nitrogen dioxide (10102-44-0)

USA OSHA OSHA PEL C [ppm] 5 ppm

8.2. Exposure controls

Appropriate engineering controls : Use only in a closed system. A corrosion-resistant, forced-draft fume hood is preferred.
LOCAL EXHAUST: A corrosion-resistant system is acceptable. Provide adequate general and
local exhaust ventilation. Ensure exposure is below occupational exposure limits (where
available).
Eye protection : Provide readily accessible eye wash stations and safety showers. Wear safety glasses when
handling cylinders; vapor-proof goggles and a face shield during cylinder changeout or
whenever contact with product is possible. Select eye protection in accordance with OSHA 29
CFR 1910.133.
Skin and body protection : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where
needed. Wear appropriate chemical gloves during cylinder changeout or wherever contact with
product is possible.
Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that
meets or exceeds the requirements of the appropriate Health and Safety Regulations. Use an
air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator
has the appropriate protection factor for the exposure level. If cartridge type respirators are
used, the cartridge must be appropriate for the chemical exposure. For emergencies or
instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).
Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.
Other information : Wear safety shoes while handling containers. Keep suitable chemically resistant protective
clothing readily available for emergency use. Consider the use of flame resistant safety
clothing.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Gas
Molecular mass : 46 g/mol
Colour : Brownish gas.
Odour : Poor warning properties at low concentrations. Pungent.
Odour threshold : No data available
pH : Not applicable.
Relative evaporation rate (butylacetate=1) : No data available
Relative evaporation rate (ether=1) : Not applicable.
Melting point : -11.2 °C
Freezing point : No data available
Boiling point : 21.2 °C
Flash point : Not applicable.
Critical temperature : 158.2 °C
Auto-ignition temperature : Not applicable.
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 100 kPa
Critical pressure : 10100 kPa
Relative vapour density at 20 °C : No data available
Relative density : 1.4
Relative gas density : 2.8
Solubility : Water: No data available
Partition coefficient n-octanol/water (Log Pow) : Not applicable.
Partition coefficient n-octanol/water (Log Kow) : Not applicable.
Viscosity, kinematic : Not applicable.
Viscosity, dynamic : Not applicable.

EN (English) SDS ID: LIND-P088 5/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

Explosive properties : Not applicable.

Oxidizing properties : Oxidizer.
Explosive limits : Non flammable.
9.2. Other information
Gas group : Press. Gas (Liq.)
Additional information : Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below
ground level.

SECTION 10: Stability and reactivity

10.1. Reactivity
Cylinders are NOT equipped with a pressure relief valve. MAY CAUSE OR INTENSIFY FIRE;
OXIDIZER.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
May explode on contact with:. Incompatible materials.
10.4. Conditions to avoid
High temperature.
10.5. Incompatible materials
Water. Reacts with water to form corrosive acids. Nitric acid. Nitric oxide. With water causes rapid
corrosion of some metals. Bases. Aluminium. May explode on contact with:. Ammonia. Boron
trichloride. Carbon disulfide. Cyclohexane. Fluorine. Formaldehyde. Nitrobenzene. Toluene.
Propylene. Alcohols. Ozone. incompletely halogenated hydrocarbons.
10.6. Hazardous decomposition products
At high temperatures : Above 160°C (320°F). Nitric oxide. Oxygen.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : FATAL IF INHALED.

Nitrogen dioxide (Dinitrogen Tetroxide) ( \f )10102-44-0

LC50 Inhalation - Rat [ppm] 57.5 ppm/4h
ATE US (gases) 57.5 ppmv/4h
Nitrogen dioxide (10102-44-0)
LC50 Inhalation - Rat [ppm] 57.5 ppm/4h
ATE US (gases) 57.5 ppmv/4h
Nitrogen tetroxide (10544-72-6)
LC50 Inhalation - Rat [ppm] 57.5 ppm/4h
ATE US (gases) 57.5 ppmv/4h
ATE US (vapours) 0.5 mg/l/4h
ATE US (dust,mist) 0.05 mg/l/4h

Skin corrosion/irritation : CAUSES SEVERE SKIN BURNS.

pH: Not applicable.

EN (English) SDS ID: LIND-P088 6/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

Serious eye damage/irritation : CAUSES SERIOUS EYE DAMAGE.

pH: Not applicable.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No data available. No known ecological damage caused by this product.

12.2. Persistence and degradability

Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)
Persistence and degradability Not applicable for inorganic products.
Nitrogen dioxide (10102-44-0)
Persistence and degradability Not applicable for inorganic products.
12.3. Bioaccumulative potential
Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)
Partition coefficient n-octanol/water (Log Pow) Not applicable.
Partition coefficient n-octanol/water (Log Kow) Not applicable.
Bioaccumulative potential No data available.
Nitrogen dioxide (10102-44-0)
Partition coefficient n-octanol/water (Log Pow) Not applicable for inorganic products.
Bioaccumulative potential No data available.
Nitrogen tetroxide (10544-72-6)
BCF - Fish [1] (no bioaccumulation)
12.4. Mobility in soil
Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)
Mobility in soil No data available.
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.
Nitrogen dioxide (10102-44-0)
Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.5. Other adverse effects

Other adverse effects : May cause pH changes in aqueous ecological systems.
Effect on the ozone layer : None.

Effect on global warming : No known effects from this product.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : U.S. - RCRA (Resource Conservation Recovery Act) - Hazardous Constituents - Appendix VIII
to 40 CFR 261. U.S. - RCRA (Resource Conservation Recovery Act) - P Series Wastes -
Acutely Toxic Wastes.
Product/Packaging disposal recommendations : Do not attempt to dispose of residual or unused quantities. Return container to supplier.

EN (English) SDS ID: LIND-P088 7/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

SECTION 14: Transport information

In accordance with DOT
Transport document description (DOT) : UN1067 Dinitrogen tetroxide, 2.3
UN-No.(DOT) : UN1067
Proper Shipping Name (DOT) : Dinitrogen tetroxide
Class (DOT) : 2.3 - Class 2.3 - Poisonous gas 49 CFR 173.115
Hazard labels (DOT) : 2.3 - Poison gas
5.1 - Oxidizer
8 - Corrosive

DOT Special Provisions (49 CFR 172.102) : 1 - This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone A
(see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation
hazard under the provisions of this subchapter.
B7 - Safety relief devices are not authorized on multi-unit tank car tanks. Openings for safety
relief devices on multi-unit tank car tanks shall be plugged or blank flanged.
B14 - Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated
with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more
than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per
square foot per degree Fahrenheit) temperature differential. Insulating materials must not
promote corrosion to steel when wet.
B45 - Each tank must have a reclosing combination pressure relief device equipped with
stainless steel or platinum rupture discs approved by the AAR Tank Car Committee.
B46 - The detachable protective housing for the loading and unloading valves of multi-unit tank
car tanks must withstand tank test pressure and must be approved by the Associate
Administrator.
B61 - Written procedures covering details of tank car appurtenances, dome fittings, safety
devices, and marking, loading, handling, inspection, and testing practices must be approved by
the Associate Administrator before any single unit tank car tank is offered for transportation.
B66 - Each tank must be equipped with gas tight valve protection caps. Outage must be
sufficient to prevent tanks from becoming liquid full at 55 C (130 F). Specification 110A500W
tanks must be stainless steel.
B67 - All valves and fittings must be protected by a securely attached cover made of metal not
subject to deterioration by the lading, and all valve openings, except safety valve, must be fitted
with screw plugs or caps to prevent leakage in the event of valve failure.
B77 - Other packaging are authorized when approved by the Associate Administrator.
T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the
applicable liquefied compressed gases are authorized to be transported in portable tanks in
accordance with the requirements of 173.313 of this subchapter.
TP21 - The wall thickness must not be less than 8 mm. Portable tanks must be hydraulically
tested and internally inspected at intervals not exceeding 2.5 years.
Additional information
Emergency Response Guide (ERG) Number : 124

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is
correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by sea
UN-No. (IMDG) : 1067
Proper Shipping Name (IMDG) : DINITROGEN TETROXIDE (NITROGEN DIOXIDE)
Class (IMDG) : 2.3 - Toxic gases
Division (IMDG) : 2.3 - Toxic gases

EN (English) SDS ID: LIND-P088 8/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

Subsidiary hazard (IMDG) : 5.1, 8

EmS-No. (1) : F-C
EmS-No. (2) : S-W

Air transport
UN-No. (IATA) : 1067
Proper Shipping Name (IATA) : Nitrogen dioxide
Class (IATA) : 2.3 - Gases : toxic
Subsidiary hazard (IATA) : 5.1, 8

SECTION 15: Regulatory information

15.1. US Federal regulations
Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

Listed on the United States SARA Section 302

CERCLA RQ 10 lb releases to the air in amounts <1000 pounds per 24 hours which are the
result of combustion and combustion-related activities are exempt from the
notification requirements per 40 CFR 302.6
SARA Section 302 Threshold Planning Quantity 100 lb
(TPQ)

All components of this product are listed, or excluded from listing, on the United
States Environmental Protection Agency Toxic Substances Control Act (TSCA)
inventory.

Nitrogen dioxide (10102-44-0)

Listed on the United States SARA Section 302
CERCLA RQ 10 lb releases to the air in amounts <1000 pounds per 24 hours which are the result of
combustion and combustion-related activities are exempt from the notification requirements
per 40 CFR 302.6
SARA Section 302 Threshold Planning Quantity 100 lb
(TPQ)
Nitrogen tetroxide (10544-72-6)
CERCLA RQ 10 lb listed under Nitrogen oxide NO2

15.2. International regulations

CANADA

Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)

Listed on the Canadian DSL (Domestic Substances List)
Nitrogen dioxide (10102-44-0)
Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Nitrogen dioxide (10102-44-0)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

EN (English) SDS ID: LIND-P088 9/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

15.2.2. National regulations

Nitrogen dioxide (Dinitrogen Tetroxide) (10102-44-0)
Listed introduction on Australian Industrial Chemicals Introduction Scheme (AICIS Inventory)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on KECL/KECI (Korean Existing Chemicals Inventory)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on the TCSI (Taiwan Chemical Substance Inventory)
Nitrogen dioxide (10102-44-0)
Listed introduction on Australian Industrial Chemicals Introduction Scheme (AICIS Inventory)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on KECL/KECI (Korean Existing Chemicals Inventory)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on the TCSI (Taiwan Chemical Substance Inventory)

15.3. US State regulations

Nitrogen dioxide (Dinitrogen Tetroxide)(10102-44-0)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental No
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

Nitrogen dioxide (10102-44-0)

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Male
Female
No No No No

Nitrogen tetroxide (10544-72-6)

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Male
Female
No No No No

Nitrogen dioxide (10102-44-0)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

Nitrogen tetroxide (10544-72-6)

U.S. - Massachusetts - Right To Know List

EN (English) SDS ID: LIND-P088 10/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

Nitrogen tetroxide (10544-72-6)

U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

EN (English) SDS ID: LIND-P088 11/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.
 Nitrogen dioxide (Dinitrogen Tetroxide)
Safety Data Sheet LIND-P088
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Issue date: 06/03/2015 Revision date: 03/25/2022 Supersedes: 02/15/2021 Version: 2.1

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end product.
Before using any plastics, confirm their compatibility with this product.

Linde asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify employees,
agents, and contractors of the information in this SDS and of any other known product hazards
and safety information, (2) furnish this information to each purchaser of the product, and (3) ask
each purchaser to notify its employees and customers of the product hazards and safety
information.

The opinions expressed herein are those of qualified experts within Linde Inc. We believe that
the information contained herein is current as of the date of this Safety Data Sheet. Since the
use of this information and the conditions of use are not within the control of Linde Inc, it is the
user's obligation to determine the conditions of safe use of the product.

Linde SDSs are furnished on sale or delivery by Linde or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products,
contact your sales representative, local distributor, or supplier, or download from
www.lindeus.com. If you have questions regarding Linde SDSs, would like the document
number and date of the latest SDS, or would like the names of the Linde suppliers in your area,
phone or write the Linde Call Center (Phone: 1-844-44-Linde (1-844-445-4633); Address: Linde
Call Center, Linde Inc, P.O. Box 44, Tonawanda, NY 14151-0044).

Linde and the Linde wordmark are trademarks or registered trademarks of Linde Inc. or its
affiliates. The information contained herein is offered for use by technically qualified personnel
at their discretion and risk without warranty of any kind.

Copyright © 2022, Linde Inc.

Revision date : 03/25/2022

NFPA health hazard : 3 - Materials that, under emergency conditions, can cause
serious or permanent injury.
NFPA fire hazard : 0 - Materials that will not burn under typical fire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA instability : 0 - Material that in themselves are normally stable, even
under fire conditions.
NFPA specific hazard : OX - Materials that posses oxidizing properties.

SDS US (GHS HazCom 2012) - Linde 2022

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

EN (English) SDS ID: LIND-P088 12/12

This document is only controlled while on the Linde US website and a copy of this controlled version is available for download. Linde cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.