12072024 Assignmet # 09 Target batch

ORGANIC CHEMISTRY
(Topic : OPTICAL ISOMERISM)
(for JEE-Mains & Advanced 2025)
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01. Number of POS present in CH4 :
(a) 3 (b) 4 (c) 5 (d) 6
02. How many stereoisomers of the following molecule are possible ?
HOOC.CH=C=CH.COOH
(a) Two optical isomers (b) Two geometrical isomers
(c) Two optical and two geometrical isomers (d) None
03. A pure simple of 2-chlorobutane shows rotation of PPL by 30º in standard condi-
tions. When above sample is made impure by mixing its opposite form, so that the
composition of the mixture become 87.5% dform and 12.5%-form, then what
will be the observed rotation for the mixture.
(a) –22.5º (b) +22.5º (c) +7.5º (d) –7.5º
04. When an optically active compound is placed in a 10 dm tube is present 20 gm in a
200 ml solution rotates the PPL by 30º. Calculate the angle of rotation & specific
angle of rotation if above solution diluted to 1 Litre.
(a) 16º & 36º (b) 6º & 30º (c) 3º & 30º (d) 6º & 36º
05. Identify % optical purity if 6 gm (+)-2-butanol is mixed with 2 gm (–)-2-butanol.
(a) 50 % (b) 66.6 % (c) 33.3 % (d) 75 %
06. A mixture of d and, 2-bromobutane contain 75% d-2-bromobutane. Calculate enan-
tiomeric excess.
(a) 75% (b) 25% (c) 50% (d) 100%
07. Which of the following is example of meso compound ?

(a) (b) (c) (d)

08. Configuration of I & II respectively will be :

(a) D , D (b) L , D (c) D , L (d) L , L

09.M Which of the following compounds are optically active ?
(a) CH3.CHOH.CH2.CH3 (b) H2C = CH.CH2.CH = CH2

(c) (d)

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10.M Among the following the non- resolvable compound is/are :

(a) (b) (c) (d)

11.M Which of the following statements is/are not correct for D-(+) glyceraldehyde :
(a) The symbol D indicates the dextrorotatory nature of the compound.
(b) The sign(+) indicates the dextrorotatory nature of the compound.
(c) The symbol D indicates that (–OH) group lies left to the chiral centre in the
conventionally correct Fischer projection diagram.
(d) The symbol D indicates that (–OH) group lies right to the chiral centre in the
conventionally correct Fischer projection diagram.
12. Which of the following are correct representation of L-amino acids :

(a) (b) (c) (d)

13. (X) (Y)

What would be the correct match to get (Y) as a diastereomers of (X)?

(a) M = – H Q = – Ph (b) M = – H Q = – H
N = – Br P = – H N = – Br P = – Ph
(c) M = – Br Q = – Ph (d) M = – Br Q = – H
N=–H P=–H N = – H P = – Ph
Comprehension For Q. 14 to 16
S(+) Mono sodium Glutamate (MSG) is a flavour enhancer used in many foods. Fast
foods often contain substantial amount of MSG and is widely used in Chinese food.
If one mole of above MSG was placed in 845 ml solution and passed through 200
mm tube, the observed rotation was found to be + 9.6°.

14. Find out the specific rotation of (–) MSG :

(a) +24° (b) +56.8° (c) –48° (d) None of these
15. Find out the approximate percentage composition of (–) MSG in a mixture contain-
ing (+) MSG and (–) MSG whose specific optical rotation is –20° :
(a) 83.3 % (b) 16.7 % (c) 91.6 % (d) 74 %

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16. If 33.8 g of (+) MSG was put in 338 ml solution and was mixed with 16.9g of (–)
MSG put in 169 ml solution and the final solution was passed through 400 mm tube.
Find out observed rotation of the final solution :
(a) +1.6° (b) +4.8° (c) +3.2° (d) None of these
17. Consider ther following compund .
CH3 — CH — CH — CH — CH — CH — CH — CH — CH3
Cl OH F OH F OH Cl

The % change in no. of optically active isomers when one Cl is replaced by Br is:
(a) 50 % (b) 100 % (c) 0 % (d) 130 %
18. Which of the following is correct :
(a) A meso isomer contains at least two chiral carbon and can rotate the plane of
plane polarized light (PPL).
(b) A racemic mixture is equimolar mixture of diastereomers and the mixture can
not rotate the plane of PPL.
(c) A meso isomer does not cannot rotate the plane of PPL.
(d) A meso isomer is a chiral due to plane of symmetry or centre of symmetry or both.
19. Identify % optical purity if 6 gm (+)-2-butanol is mixed with 2 gm (–)-2-butanol.
(a) 50 % (b) 66.6 % (c) 33.3 % (d) 75 %
20. The two projection formulae that represent a pair of enantiomers are :

(I) (II) (III) (IV)

(a) I and II (b) III and IV (c) I and III (d) II and IV
21. Which two of the following compounds represents a pair of enantiomers ?

(a) I & II (b) II & III (c) III & IV (d) II & IV
22. The number of optically active products obtained from the complete ozonolysis
of the given compound is ?

(a) 0 (b) 1 (c) 2 (d) 4

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23. (+) tartaric acid has a specific rotation of + 12 unit when measured in 12 cm
polarimeter tube and 2g/ml concentration at given temperature and light.
When it is diluted to half the concentration, length of tube and other
parameters being same, then the specific rotation will be :
(a) + 6 unit (b) + 12 unit (c) – 6 unit (d) + 24 unit
24. Which of the following can exhibit optical isomerism ?

(1) (2) (3) (4)

(a) 1 and 2 (b) 2 and 4 (c) 3 only (d) 2 only

25. How many of the given compounds are chiral .

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii)

(ix)

26 For the given compound X, the total number of optically active stereoisomers
is____ ?

This type of bond indicates that the configuration at the specific carbon and
the geometry of the double bond is fixed.
This type of bond indicates that the configuration at the specific carbon and
the geometry of the double bond is NOT fixed.

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