Recycling Sugarcane By-Products
Recycling Sugarcane By-Products
ACKNOWLEDGEMENTS ...................................................................... 3
ABSTRACT ............................................................................................. 4
INTRODUCTION.................................................................................... 5
THE HISTORY OF SUGAR PRODUCTION IN EGYPT ................... 12
INDUSTRIAL PROCESS ...................................................................... 16
RECYCLING SUGARCANE BY-PRODUCTS ..................................... 30
BAGASSE ............................................................................................................ 32
Bagasse recycling ............................................................................................ 33
1.Source of energy .............................................................................. 33
2. Paper-making................................................................................... 37
3.Industrial woods .............................................................................. 41
4.cellulosic derivatives...................................................................... 44
5.Furfural................................................................................................ 47
6.ِ Animal feed ....................................................................................... 50
MUDS ................................................................................................................. 53
Filter Mud............................................................................................................ 53
Applications of Filter Mud: .............................................................. 54
Clarified Mud ..................................................................................................... 55
Applications of Clarified Mud: ........................................................ 56
MOLASSES ......................................................................................................... 58
Content of Molasses ........................................................................................ 58
Uses of Molasses ............................................................................................... 60
Food and Beverage Industry........................................................... 60
Pharmaceutical and Nutraceutical Applications..................... 66
Industrial Uses ..................................................................................... 69
1
CASE STUDY: SUGARCANE AND BY-PRODUCTS AT ARMANT SUGAR
FACTORY ............................................................................................................ 72
CONCLUSION ....................................................................................... 75
REFERENCES ....................................................................................... 76
List of figures
2
Acknowledgements
Finally, I would like to acknowledge Prof. Dr. Dina Mamdoh and all
stuff of our faculty for providing the resources and environment
necessary to conduct this research. This project would not have been
possible without the support of all these individuals and organizations.
3
Abstract
4
Introduction
The sugar industry is among the vital sectors globally. The aim of this
research is to analyze the by-products of sugar production, identifying
methods for their recycling while estimating the associated costs for each
approach.
Through data obtained from the Arment Sugar Factory, it was found that
every ton of sugar cane yields approximately 104,000 %cane units of
sugar as the primary product. Additionally, significant quantities of by-
products are generated, offering potential for recycling to mitigate
environmental impact and enhance sustainability.
1. Bagasse: refers to the residual fibers left after crushing the sugar
These cylinders crush the stalks and extract juice from the cane. The
left after the crushing and juice purification process are termed
Bagasse.
5
a. As fuel, many factories burn Bagasse to generate energy for
in addition to sheep.
7
comply with D-6868 standards[3]. Bagasse packaging used for
(Fahrenheit).
8
c. Sulfate Mud: Sulfates can be a major component of sugar
refining mud, especially if additives containing sulfur are used
during refining processes. Sulfates may form as a result of
reactions with the chemical substances used in clarification
and refining processes.
It has been discovered that the mud produced from sugar production
contains important nutrients, making it beneficial for use in
agriculture such as : -
1. Chemical manufacturing:-
● Alcohol Production: Molasses is used as a primary
source for alcohol production. The sugar present in
molasses is fermented using yeast to produce ethyl
alcohol, which can be utilized in the production of
biofuels, alcoholic beverages, and other chemical
substances[8].
2. Animal Feed[10] :-
● Improving Nutritional Value: Molasses can be added to
animal feed as a source of energy and simple sugars.
10
Molasses is considered a rich source of vitamins and
minerals such as potassium, calcium, and iron, which
help enhance the nutritional value for animals
11
The history of sugar production in Egypt
Throughout its more than a century and a half of history, the Egyptian
sugar industry has faced numerous risks and obstacles. However, it has
managed to overcome them and grow and flourish over the years.
Investments in sugar industry projects have reached nearly ten billion
pounds, and the value of its factories exceeds 25 billion Egyptian
pounds.
The sugar industry in Egypt is considered one of the oldest and most
important industries, with its establishment dating back to the eighteenth
century. It follows the cotton industry in terms of size and significance,
with investments in this sector exceeding 4 billion pounds.
12
According to (ESIIC) https://www.siicegypt.com/sugar-industry
The history of the sugar industry in Egypt dates back to 710 AD, with
Egyptians being the first to master the production of refined sugar,
exporting it to Europe. This industry declined during the Mamluk rule until
Muhammad Ali Pasha came to power in 1818, leading to the revival of
sugarcane cultivation and sugar production. In 1850, a sugar factory was
established in the Minya Governorate. In 1834, two more factories were
established in Minya, and in 1846, Muhammad Ali Pasha hired French
technicians to operate and manage these factories. In 1848, four
additional sugar factories were established in Giza, Minya, and Qena,
marking significant achievements credited to Muhammad Ali Pasha.
13
established, totaling 64 factories. One of these factories was the Armant
Sugar Factory, established in 1869 during the opening of the Suez
Canal. The Armant Factory is still operational today after undergoing
renovations and upgrades, contributing significantly to Egypt's sugarcane
production.
In 1892, all raw sugar factories were merged under the name Northern
Sugar Factories Company. In 1897, the Egyptian Refining Company and
the Northern Sugar Factories were merged under the name Egyptian
Sugar and Distillation Company.
The government contributed half of its capital, and in 1966, the company
was decided to establish the Nasr Sugar and Paper Industries Company,
and in 1997, it was merged with the Egyptian Sugar and Distillation
Company for Food Industries, and the name was changed to the Sugar
14
3. Naj-Hammadi Sugar Factories (Qena)
4. Dishna Sugar Factories (Qena)
5. Qus Sugar Factories (Qena)
6. Armant Sugar Factories (luxor)
7. Edfu Sugar Factories (Aswan)
8. Kom Ombo Sugar Factories (Aswan)
15
Industrial Process
16
to the bustling mills where it is transformed into crystalline sweetness, we
explore the intricacies of this age-old practice and its modern-day
implications. Along the way, we uncover the innovations driving
efficiency, the environmental considerations shaping practices, and the
socio-economic dynamics shaping the lives of those involved.
17
Simultaneously, preparatory measures are initiated to ready the cane for
subsequent processing steps. Cleaning stations equipped with
mechanical brushes and screening mechanisms effectively remove
extraneous matter such as leaves, soil, and other contaminants,
safeguarding the integrity of the incoming cane and enhancing the
efficiency of downstream operations.
After preparation, we begin with the first process, which is the sugar
cane milling.
18
Figure 2: sugar industrial process
19
1. Milling[11]
● Crushing:
The extracted juice flows out from the crushed cane and is
collected for further processing.
● Shredding:
20
The shredded bagasse is then typically sent to boilers for use
as fuel, while the extracted juice continues on to next stages of
process
2. juice extraction[12]
3. Clarification[13]
1. Objective of Clarification:
22
2. Clarification Methods:
3. Process Optimization:
23
4. Evaporation [14]
1. Purpose of Evaporation:
2. Evaporator Types:
3. Evaporation Process:
24
● Sugar cane juice is heated in the evaporator vessel, and
water is evaporated from the juice.
● The vapor generated during evaporation is typically
condensed and reused as heating media in the evaporator
system, contributing to energy efficiency.
● The concentrated juice, known as syrup or massecuite, is
continuously withdrawn from the evaporator, while excess
water is removed as vapor.
25
5. Crystallization [15]
3. Crystallization Equipment:
● Various types of crystallizers are used in industrial sugar
processing, including vacuum pans, batch crystallizers, and
continuous crystallizers.
26
● Vacuum pans are commonly used for batch crystallization,
where the sugar solution is boiled under vacuum to promote
crystallization and prevent caramelization.
● Continuous crystallizers operate continuously, with the sugar
solution flowing through a series of chambers or stages
where crystallization occurs.
27
Figure 3: Crystallization process
6. Centrifugation [16]
1. Purpose of Centrifugation:
● Centrifugation is used to separate sugar crystals from the
syrup or molasses produced during the sugar crystallization
process.
● By subjecting the sugar solution to centrifugal force, denser
sugar crystals are forced to the periphery of the centrifuge,
while the less dense syrup or molasses is expelled through
the center.
2. Types of Centrifugals:
28
● There are various types of centrifugals used in the sugar
industry, including basket centrifugals and continuous
centrifugals.
● Basket centrifuges are commonly used for batch processing,
where a batch of sugar crystals is loaded into the centrifuge
basket, spun at high speeds, and then discharged after
separation.
● Continuous centrifugals operate continuously, with sugar
solution continuously fed into the centrifuge, and separated
sugar crystals continuously discharged while the syrup or
molasses is recirculated.
29
Recycling sugarcane by-products
This search aims to explore the diverse range of sugar cane by-products
generated during the sugar production process and elucidate the various
methods and applications for their recycling and utilization. By delving
into the characteristics, composition, and potential uses of these by-
products, this chapter seeks to underscore the importance of adopting
sustainable practices in the sugar industry. Moreover, it endeavors to
highlight the economic, environmental, and social benefits associated
with the recycling and valorization of sugar cane by-products. Through a
comprehensive examination of current research, innovative
technologies, and practical applications, this chapter endeavors to
provide insights into the sustainable management of sugar cane by-
products and the potential avenues for their integration into circular
economy models.
30
Figure 4: sugarcane final products
31
Figure 5: Percentages of sugarcane by-products
Bagasse
Bagasse is the fibrous residue that remains after sugar cane stalks have
been crushed to extract their juice during the sugar production process.
It is a lignocellulosic material composed primarily of approximately[17]:
● Cellulose: 40-45%
● Hemicellulose: 25-30%
● Lignin: 20-25%
● Pectin and other organic compounds: 5-10%
● Sugar : 1-2%
32
Bagasse recycling
1.Source of energy
1. Boiler Fuel[18]:
● Combustion Process:
i. Bagasse is burned in a boiler furnace to generate heat
through combustion.
ii. The combustion process involves the oxidation of
bagasse in the presence of oxygen, resulting in the
release of heat energy.
iii. The heat generated by burning bagasse raises the
temperature of water in the boiler, producing steam.
● Steam Generation:
i. The steam produced by burning bagasse is used to
drive turbines connected to electricity generators or to
provide heat for various industrial processes in the
sugar mill.
ii. The steam may be used for juice evaporation, sugar
crystallization, distillation, or any other process
requiring heat energy within the sugar production
facility.
● Boiler Design and Efficiency:
i. Boilers used for burning bagasse are specifically
designed to accommodate the unique characteristics of
this biomass fuel.
ii. Specialized boiler designs incorporate features such as
grates for efficient fuel combustion, combustion air
preheating systems, and heat recovery mechanisms to
33
maximize boiler efficiency and steam generation
capacity.
iii. Advanced control systems are employed to optimize
boiler operation, ensuring stable combustion, efficient
fuel utilization, and minimal emissions.
● Environmental Benefits:
i. The utilization of bagasse as a boiler fuel offers
significant environmental benefits, including reduced
greenhouse gas emissions and decreased reliance on
fossil fuels.
ii. By utilizing a renewable biomass fuel like bagasse,
sugar mills contribute to the reduction of carbon dioxide
emissions and mitigate environmental impacts
associated with fossil fuel combustion.
1. Boiler Operation:
● Bagasse is burned in boilers to generate steam for both
electricity generation and thermal applications within the
sugar mill.
● The combustion of bagasse produces high-pressure steam,
which is used to drive turbines connected to electricity
generators.
2. Electricity Generation:
● The steam turbines in CHP systems convert the energy from
high-pressure steam into mechanical energy, which is then
used to drive electricity generators.
● The electricity generated by CHP systems can be used to
power various operations within the sugar mill, including
34
sugar processing equipment, lighting, and other electrical
loads.
● Excess electricity generated by the CHP system can be
exported to the grid for sale to external consumers, providing
an additional source of revenue for the sugar mill.
3. Heat Recovery:
● In addition to electricity generation, CHP systems utilize the
heat produced during electricity generation for various
thermal applications within the sugar mill.
● The heat recovered from the steam turbine's exhaust is used
for processes such as juice evaporation, sugar crystallization,
and drying operations.
● By capturing and utilizing this waste heat, CHP systems
achieve higher overall energy efficiency compared to
separate heat and power generation systems.
3. Biofuel Production[20]:
1. Bioethanol Production:
● Bagasse can be enzymatically hydrolyzed to break down the
cellulose and hemicellulose components into fermentable
sugars, primarily glucose and xylose.
35
● The enzymatic hydrolysis process involves treating bagasse
with enzymes such as cellulase and hemicellulase to convert
the complex carbohydrates into simple sugars.
● The resulting sugar-rich hydrolysate is then fermented by
yeast or other microorganisms to produce ethanol through a
process similar to traditional ethanol fermentation from sugar
cane juice.
● After fermentation, the ethanol is separated from the
fermentation broth and purified for use as a transportation
fuel or blending with gasoline.
2. Biogas Production:
● Bagasse can also be subjected to anaerobic digestion to
produce biogas, a mixture of methane and carbon dioxide.
● During anaerobic digestion, bagasse is placed in an oxygen-
free environment, where microorganisms break down the
organic matter in bagasse, primarily cellulose and
hemicellulose, to produce biogas.
● The biogas produced can be used directly as a fuel for
electricity generation or as a feedstock for upgrading into
biomethane, a renewable natural gas suitable for injection
into natural gas pipelines or use as a transportation fuel.
3. Process Optimization:
● Various factors, including pretreatment methods, enzymatic
hydrolysis conditions, fermentation parameters, and
anaerobic digestion process parameters, influence the
efficiency and economics of biofuel production from bagasse.
● Process optimization efforts aim to maximize sugar or biogas
yields, minimize energy and chemical inputs, and reduce
production costs to make biofuel production from bagasse
economically viable.
4. Environmental Benefits:
● Biofuel production from bagasse offers several environmental
benefits, including reduced greenhouse gas emissions,
decreased dependence on fossil fuels, and potential
36
mitigation of waste disposal issues associated with bagasse
disposal.
2. Paper-making
To turn bagasse into paper pulp, there are two main methods:
mechanical and chemical pulping.
Chemical pulping, on the other hand, involves using chemicals like those
in the Kraft process or sulfite pulping to break down the bagasse and
extract the cellulose fibers.
● Pulping Process:
a. The Kraft process involves treating the raw material,
such as bagasse, with a mixture of sodium
37
hydroxide (NaOH) and sodium sulfide (Na2S) under
high temperature and pressure.
b. The alkali (NaOH) breaks down the lignin in the
bagasse into soluble compounds, while the sulfide
(Na2S) prevents the formation of undesirable by-
products by reducing the lignin to a lower molecular
weight.
c. This process effectively dissolves lignin and
separates it from the cellulose fibers, producing a
pulp with high cellulose content.
● Cooking Phase:
a. The bagasse is first chipped or shredded into small
pieces and then mixed with the chemical solution in
a large vessel called a digester.
b. The mixture is heated to temperatures ranging from
150°C to 180°C under pressure for several hours,
typically 1 to 4 hours, to facilitate the breakdown of
lignin.
c. During this cooking phase, the NaOH and Na2S
penetrate the bagasse fibers, causing the lignin to
become solubilized and dissolved in the liquor.
38
a. While the Kraft process is highly effective in
producing strong, high-quality pulp, it generates
large amounts of black liquor, a by-product
containing lignin, spent chemicals, and dissolved
solids.
b. To minimize environmental impact, black liquor is
often processed in a recovery boiler to generate
steam and recover chemicals for reuse in the
pulping process, making the Kraft process more
sustainable.
1. Pulping Process:
● Sulfite pulping involves treating the raw material, such as
bagasse, with a solution of sulfurous acid (H2SO3) or bisulfites
(e.g., calcium bisulfite or sodium bisulfite) in the presence of an
alkali, typically sodium hydroxide (NaOH) or calcium hydroxide
(Ca(OH)2).
● The sulfite chemicals penetrate the bagasse fibers and break
down the lignin, which binds the cellulose fibers together.
● This process selectively dissolves lignin while preserving the
cellulose fibers, resulting in a high-quality pulp with excellent
strength properties.
2. Cooking Phase:
● The bagasse is chipped or shredded into small pieces and then
mixed with the sulfite solution in a digester.
39
● The mixture is heated to temperatures ranging from 140°C to
180°C under pressure for several hours, typically 4 to 10 hours,
to facilitate the breakdown of lignin.
● During this cooking phase, the sulfite chemicals react with the
lignin, causing it to become solubilized and dissolved in the
liquor.
3. Washing and Bleaching:
● After the cooking phase, the pulp is washed to remove the
spent liquor, residual chemicals, and dissolved lignin.
● The washed pulp is then bleached using chlorine dioxide,
oxygen, or hydrogen peroxide to further remove lignin and
brighten the pulp.
● Bleaching also improves the brightness and color of the pulp,
making it suitable for high-quality paper and paper products.
4. Environmental Considerations:
● Sulfite pulping generates less black liquor compared to the
Kraft process, making it more environmentally friendly in terms
of chemical recovery and waste management.
● However, sulfite pulping requires more stringent control of
process parameters and higher operational costs compared to
the Kraft process.
After getting the pulp from bagasse typically stored in large tanks or
chests after it has been washed and bleached. These storage tanks are
often made of stainless steel or fiberglass and are equipped with
agitators to prevent the pulp from settling and becoming unevenly
distributed. The pulp is stored in these tanks temporarily before being
further processed or transported to the paper machine for sheet
formation. During storage, the pulp may be treated with additives or
chemicals to maintain its consistency and prevent microbial growth.[23]
40
1. Writing and Printing Paper: Bagasse paper is commonly used for
writing and printing purposes, offering a smooth surface that is
suitable for high-quality printing and writing. It can be found in
notebooks, stationery, office papers, and other similar products [24].
2. Packaging Paper: Bagasse paper is also used in packaging
applications, such as for making corrugated cardboard boxes,
packaging materials, and disposable food containers. It provides
adequate strength and rigidity for packaging while being
biodegradable and eco-friendly [25].
3. Tissue Paper: Bagasse fibers can be processed into tissue paper,
which is used for various hygiene and sanitary products, including
facial tissues, toilet paper, and paper towels. Bagasse tissue paper
is soft, absorbent, and environmentally friendly [26].
4. Specialty Papers: Bagasse paper can be used to produce specialty
papers tailored for specific applications, such as fine art paper,
filter paper, and industrial papers. These specialty papers leverage
the unique properties of bagasse fibers to meet specific
requirements [27].
3.Industrial woods
41
Production process:
2. Composite Panels:
[35]
Manufacturing Process :
43
involve forcing the mixture through a die to form continuous
panels of varying shapes and sizes.
Applications [37]:
4.cellulosic derivatives
44
Cellulosic derivatives derived from bagasse offer a wide range of
applications in various industries due to their versatile properties.
1. Cellulose Extraction:
● Cellulose is extracted from pretreated bagasse using
chemical or enzymatic methods.
● Chemical methods involve treating bagasse with alkalis (e.g.,
sodium hydroxide) or acids (e.g., sulfuric acid) to dissolve
lignin and hemicellulose, leaving behind purified cellulose
fibers.
● Enzymatic methods utilize cellulase enzymes to selectively
hydrolyze lignin and hemicellulose, releasing cellulose fibers
[39]
.
2. Derivatization of Cellulose:
● Purified cellulose fibers obtained from bagasse are
chemically modified to produce various cellulosic derivatives
with tailored properties.
● Common cellulosic derivatives include cellulose acetate,
cellulose ethers (e.g., methyl cellulose, ethyl cellulose), and
cellulose esters (e.g., cellulose nitrate).
● Derivatization reactions involve functionalizing cellulose
hydroxyl groups with acetyl, alkyl, or ester groups through
[40]
esterification or etherification reactions .
Applications:
1. Pharmaceutical Applications:
● Cellulosic derivatives are extensively used in pharmaceutical
formulations as excipients, binders, and disintegrants.
45
● According to a study by Zhang et al. (2019), cellulose
derivatives are included in over 90% of oral solid dosage
forms, contributing to their mechanical properties and drug
release characteristics [41].
● Methyl cellulose, for example, is widely used in tablet
formulations, with an estimated annual production of over
50,000 metric tons globally [42].
2. Food Industry Applications:
● Cellulosic derivatives serve as essential additives in the food
industry, functioning as thickeners, stabilizers, and
emulsifiers.
● According to market research by Grand View Research, the
global market for food-grade cellulose derivatives was valued
at USD 5.47 billion in 2020 and is projected to reach USD
8.15 billion by 2027, with a compound annual growth rate
(CAGR) of 5.6% [43].
● Carboxymethyl cellulose (CMC) is one of the most commonly
used cellulose derivatives in food products, contributing to
improved texture and viscosity in a wide range of applications
[44]
.
3. Textile Industry Applications:
● Cellulosic derivatives find significant applications in the textile
industry as sizing agents, thickeners, and modifiers.
● According to a report by Textile Exchange, the global
consumption of cellulosic fibers, including those derived from
cellulose derivatives, reached 7.5 million metric tons in 2020,
with an expected annual growth rate of 4-5% [45].
● Hydroxyethyl cellulose (HEC) is widely used in textile printing
and dyeing processes, contributing to enhanced color
consistency and fabric quality [46].
4. Cosmetic and Personal Care Applications:
● Cellulosic derivatives play a crucial role in cosmetic and
personal care products as rheology modifiers, film-forming
agents, and binders.
● According to market research by Allied Market Research, the
global market for cellulose ethers, including derivatives such
46
as hydroxypropyl cellulose (HPC) and hydroxyethyl cellulose
(HEC), was valued at USD 4.2 billion in 2019 and is expected
to reach USD 6.2 billion by 2027, with a CAGR of 5.3% [47].
● Cellulose derivatives enhance the performance and stability
of cosmetic formulations, contributing to improved texture,
spreadability, and shelf life [48].
5.Furfural
Furfural is an organic compound derived from various agricultural by-
products, particularly lignocellulosic biomass such as corncobs,
sugarcane bagasse, and rice husks. It is a heterocyclic aldehyde with the
chemical formula C5H4O2.
1. Pretreatment of Bagasse:
● Bagasse undergoes pretreatment to break down
lignocellulosic components into simpler sugars, primarily
glucose and xylose.
● Pretreatment methods include steam explosion, acid
hydrolysis, or enzymatic hydrolysis, which can achieve sugar
yields ranging from 60% to 90% [49].
47
● For example, acid hydrolysis with dilute sulfuric acid at
optimized conditions can yield glucose and xylose
concentrations of 60-80 g/L and 20-40 g/L, respectively [50].
2. Hydrolysis of Pretreated Bagasse:
● The pretreated bagasse is further hydrolyzed to convert
glucose and xylose into furfural, primarily through
dehydration reactions.
● Acid-catalyzed hydrolysis at elevated temperatures (e.g.,
160-200°C) and pressures (e.g., 1-3 MPa) can achieve
furfural yields ranging from 40% to 70% [51].
● For instance, studies have reported furfural yields of up to
68% from glucose and 47% from xylose using sulfuric acid as
a catalyst under optimized conditions [52].
3. Furfural Recovery and Purification:
● Furfural is recovered from the hydrolysate through distillation
or extraction processes.
● Distillation methods, such as batch or continuous distillation,
can achieve furfural recoveries exceeding 90% with purities
ranging from 95% to 99% [53].
● Alternatively, furfural can be extracted using organic solvents
like methyl isobutyl ketone (MIBK) or ethyl acetate, with
[54]
extraction efficiencies typically ranging from 70% to 90% .
Applications of furfural:
48
1. Solvent Applications:
● Furfural serves as a solvent in various industrial processes,
including petrochemical refining, pharmaceuticals, and
flavorings.
● According to market research by Grand View Research, the
global furfural solvent market was valued at USD 500 million
in 2020 and is projected to reach USD 700 million by 2027,
with a compound annual growth rate (CAGR) of 5.2% [57].
● Furfural Is excellent solvent properties, such as high polarity
and low toxicity, make it suitable for extracting value-added
compounds from biomass, such as lignin and cellulose [58].
2. Chemical Intermediate:
● Furfural serves as a key chemical intermediate in the
synthesis of various derivatives, including furfuryl alcohol,
tetrahydrofurfuryl alcohol, and levulinic acid.
● The global furfural derivatives market was valued at USD 1.2
billion in 2020 and is expected to reach USD 1.7 billion by
2027, with a CAGR of 4.8% [59].
● Furfural derivatives find applications in resin production,
lubricants, plasticizers, and pharmaceuticals [60].
3. Biofuel Production:
● Furfural can be further processed into biofuels such as furan-
based biodiesel and gasoline additives.
● According to a study by Liu et al. (2019), furfural-derived
biofuels have shown promising performance in engine tests,
with comparable energy density and combustion
characteristics to petroleum-derived fuels [61].
● The global biofuels market, including furfural-based biofuels,
was valued at USD 140 billion in 2020 and is expected to
reach USD 220 billion by 2027, with a CAGR of 6.8% [62].
4. Biopolymer Synthesis:
● Furfural derivatives are utilized in the production of
biopolymers such as polyfurfuryl alcohol (PFA) and furan
resins.
● These biopolymers offer advantages such as
biodegradability, thermal stability, and mechanical strength,
49
making them suitable for applications in coatings, adhesives,
and composites [63].
● The global biopolymer market was valued at USD 10 billion
in 2020 and is projected to reach USD 20 billion by 2027,
with a CAGR of 9% [64].
5. Fine Chemicals Synthesis:
● Furfural serves as a precursor for the synthesis of various
fine chemicals, including pharmaceutical intermediates and
flavor compounds.
● According to a report by MarketsandMarkets, the global fine
chemicals market was valued at USD 200 billion in 2020 and
is expected to reach USD 300 billion by 2027, with a CAGR
of 6% [65].
● Furfural-derived fine chemicals find applications in
pharmaceuticals, agrochemicals, and specialty chemicals
industries [66].
50
● Studies have shown that bagasse can contribute to animal
nutrition by providing insoluble fiber, which promotes rumen
health and regulates digestion [67].
● According to research by González et al. (2017), direct
feeding of bagasse to ruminants can enhance rumen
fermentation and microbial activity, leading to improved feed
efficiency [68].
● However, direct feeding of bagasse may require
supplementation with additional nutrients to meet the dietary
requirements of animals, especially protein and minerals.
2. Ensiling Bagasse for Animal Feed:
● Bagasse can be ensiled to improve its digestibility and
palatability for livestock.
● Ensiling involves compacting and fermenting bagasse under
anaerobic conditions, typically with the addition of microbial
inoculants or fermentable carbohydrates.
● Research by Ogunade et al. (2018) demonstrated that
ensiling bagasse with additives such as molasses or urea
can enhance fermentation and nutrient preservation,
resulting in improved feed quality [69].
● Ensiled bagasse can serve as a cost-effective feed
ingredient, particularly in regions with abundant sugarcane
production and limited access to traditional forage resources.
3. Pelleting Bagasse for Animal Feed:
● Bagasse can be processed into pellets to improve handling,
storage, and feed efficiency.
● Pelleting involves grinding bagasse into smaller particles and
compressing them into pellets using heat and pressure.
● According to market research by Grand View Research, the
global animal feed pellet market was valued at USD 15.2
billion in 2020 and is projected to reach USD 22.9 billion by
2027, with a compound annual growth rate (CAGR) of 5.6%
[70]
.
● Bagasse pellets offer advantages such as reduced wastage,
improved feed intake, and enhanced nutrient availability for
animals.
4. Supplementation with Bagasse-Based Feed Additives:
51
● Bagasse can be supplemented with feed additives such as
protein sources, minerals, and vitamins to meet the
nutritional requirements of animals.
● Research by Dehghan-Banadaky et al. (2016) demonstrated
that supplementing bagasse-based diets with protein-rich
additives can improve animal growth, rumen health, and milk
production [71].
● The use of bagasse-based feed additives contributes to
balanced nutrition and optimized feed utilization in livestock
production systems.
52
Muds
Types of Mud:
Mud from sugarcane processing can be classified into two main types
based on its origin and composition:
Filter Mud
is the residue obtained from the filtration process during sugarcane juice
extraction. It consists of suspended solids, organic matter, cellulose,
lignin, and mineral components. Filter mud is separated from the juice
using filtration equipment such as rotary vacuum filters or filter presses.
This by-product is typically rich in nutrients and organic material, making
it suitable for various applications.
The composition of filter mud varies depending on factors such as the
quality of sugarcane, processing methods, and environmental conditions.
On average, filter mud contains:
53
nutrients contribute to the fertility and organic matter content of soils
when filter mud is used as a soil amendment or fertilizer.
● Biogas Production:
54
methane. Biogas generated from filter mud can be used for
electricity generation, heating, or as a renewable fuel source.
● Candle Production
Clarified Mud
is the sediment obtained from the clarification of sugarcane juice using
chemical agents or flocculants to separate impurities. It consists of finer
particles, including residual sugar, proteins, and mineral precipitates.
The composition of filter mud and clarified mud varies depending on the
sugarcane variety, processing methods, and environmental factors.
55
The composition of clarified mud varies depending on the clarification
process, sugarcane quality, and operational factors. However, on
average, clarified mud contains:
Clarified mud has a higher sugar content compared to filter mud, making
it suitable for certain applications that require a readily available energy
source.
● Biogas Production:
● Industrial Fermentation:
● Environmental Remediation:
57
Molasses
Content of Molasses
1. Sugars [76]
● Sucrose: Sucrose is the predominant sugar in molasses,
accounting for a significant portion of its sweetness. Sucrose
molecules are composed of glucose and fructose units linked
together.
● Glucose and Fructose: These monosaccharides are present
in smaller quantities in molasses, contributing to its overall
sweetness and flavor profile.
● Invert Sugars: During the processing of sugarcane or sugar
beet, sucrose may undergo hydrolysis to form invert sugars,
including glucose and fructose, which enhance the
sweetness and solubility of molasses.
2. Minerals [77]
○ Potassium (K): Essential for various physiological functions,
including muscle contraction, nerve transmission, and fluid
balance.
○ Calcium (Ca): Important for bone health, muscle function,
and blood clotting.
○ Magnesium (Mg): Involved in energy metabolism, muscle
function, and protein synthesis.
58
○ Phosphorus (P): Essential for bone and teeth formation,
energy metabolism, and cell signaling.
○ Iron (Fe): Required for oxygen transport, energy production,
and enzyme function.
4. Vitamins [79]
○ Lactic Acid: Produced during fermentation processes and
contributes to the tangy flavor of molasses.
○ Acetic Acid: Contributes to the sourness and aroma of
molasses.
○ Citric Acid: Adds a citrusy flavor and acts as a natural
preservative.
○ Malic Acid: Provides tartness and enhances the overall flavor
profile of molasses.
59
Uses of Molasses
Food and Beverage Industry
● Sweetener and Flavoring Agent:-
1. Sweetening Properties:
a. Molasses is valued for its high sweetness
intensity, attributed to its rich content of natural
sugars, primarily sucrose, glucose, and fructose.
b. The sweetness of molasses is often described as
complex and multi-dimensional, with undertones
of caramel, toffee, and earthiness, which
contribute to its unique flavor profile.
c. Studies have shown that molasses possesses a
higher sweetness potency compared to refined
sugar, allowing for the reduction of sugar content
in recipes without compromising sweetness
perception (Bakowska-Barczak, 2017) [81].
2. Flavor Enhancement:
a. Molasses adds depth of flavor and complexity to
food products, imparting a rich, robust taste with
notes of caramelization, bitterness, and acidity.
b. The distinctive flavor of molasses is derived from
Maillard reactions and caramelization processes
occurring during sugar extraction and
concentration, resulting in the formation of flavor
compounds such as furfurals, pyrazines, and
melanoidins.
c. These flavor compounds contribute to the overall
sensory profile of foods, enhancing aroma,
mouthfeel, and taste perception, particularly in
baked goods, sauces, and marinades (Bekedam
et al., 2018) [82].
3. Maillard Reactions:
a. Maillard reactions between reducing sugars (e.g.,
glucose, fructose) and amino acids occur during
heating or cooking processes, leading to the
60
formation of brown pigments, flavors, and
aromas.
b. Molasses provides a rich source of reducing
sugars and amino acids, facilitating Maillard
reactions and the development of desirable flavor
characteristics in food products.
c. The Maillard reaction products formed during the
caramelization of molasses contribute to the
browning, sweetness, and umami notes in foods,
enhancing their overall sensory appeal
(Mestdagh et al., 2018) [83].
4. Applications in Food Products:
a. Molasses is extensively used as a sweetener and
flavoring agent in a wide range of food products,
including:
i. Baked Goods: Bread, cookies, cakes,
muffins, and pastries benefit from the rich
flavor and moisture retention properties of
molasses, resulting in tender, flavorful
products.
ii. Sauces and Marinades: Molasses adds
complexity and depth to barbecue sauces,
glazes, and marinades, enhancing their
sweetness, tanginess, and caramelized
notes.
iii. Beverages: Molasses is used to sweeten
and flavor beverages such as teas, coffees,
smoothies, and cocktails, imparting
richness and depth to their taste profiles.
● Coloring Agent:
1. Natural Colorant Source:
61
a. Molasses serves as a natural coloring agent in
food products, imparting a deep, rich brown hue
due to its high content of non-enzymatic browning
compounds, such as melanoidins and
caramelization products.
b. Melanoidins are complex polymers formed
through the Maillard reaction between reducing
sugars and amino acids during the processing
and heating of molasses. These brown pigments
contribute to the characteristic color and flavor of
molasses (Gross et al., 2019) [84].
c. Caramelization reactions occur when sugars in
molasses are heated, resulting in the formation of
caramel-like compounds that enhance the color
intensity and visual appeal of foods.
2. Enhancement of Appearance:
a. The deep, rich brown color of molasses adds
visual appeal and aesthetic value to food
products, making them more attractive to
consumers.
b. In bakery products such as bread, cakes,
cookies, and muffins, molasses contributes to the
development of a golden-brown crust and a
moist, tender crumb, enhancing the overall
appearance and texture of the finished products.
c. Molasses is also used as a coloring agent in
savory dishes, sauces, marinades, and glazes,
where it imparts a dark, glossy sheen and a
caramelized flavor profile to meats, vegetables,
and side dishes.
3. Regulatory Considerations:
a. Molasses is generally recognized as safe (GRAS)
by regulatory agencies such as the U.S. Food
and Drug Administration (FDA) and the European
Food Safety Authority (EFSA) for use as a
coloring agent in food products.
62
b. Food manufacturers may use molasses as a
natural coloring agent in accordance with food
labeling regulations, which require the declaration
of ingredients on product labels to inform
consumers about the presence of molasses in
processed foods (EFSA, 2019) [85].
c. Molasses-derived colorants are preferred by
consumers seeking natural and clean-label food
products, as they offer an alternative to synthetic
food dyes and additives.
● Fermentation:
1. Definition and Process:
a. Fermentation is a metabolic process that
converts carbohydrates, such as sugars or
starches, into organic acids, gases, or alcohol in
the absence of oxygen. It is carried out by
microorganisms such as bacteria, yeast, or fungi.
b. During fermentation, microorganisms metabolize
carbohydrates through enzymatic reactions,
producing energy and metabolic byproducts. The
specific end products of fermentation depend on
the type of microorganism involved and the
environmental conditions.
c. In industrial settings, fermentation processes are
utilized for the production of a wide range of
products, including alcoholic beverages, biofuels,
organic acids, enzymes, antibiotics, and
probiotics.
2. Types of Fermentation:
a. Alcoholic Fermentation: Yeast species such as
Saccharomyces cerevisiae are commonly used in
alcoholic fermentation, where they convert sugars
63
into ethanol and carbon dioxide. This process is
utilized in the production of alcoholic beverages
such as beer, wine, and spirits [86].
b. Lactic Acid Fermentation: Lactic acid bacteria
such as Lactobacillus spp. convert sugars into
lactic acid through lactic acid fermentation. This
process is used in the production of fermented
dairy products (e.g., yogurt, cheese), sourdough
bread, sauerkraut, and kimchi [87].
c. Acetic Acid Fermentation: Acetic acid bacteria
such as Acetobacter spp. oxidize ethanol into
acetic acid in the presence of oxygen, leading to
the production of vinegar. This process is utilized
in vinegar production from alcoholic beverages or
fruit juices [88].
d. Ethanol Fermentation: Various microorganisms,
including yeast and bacteria, can ferment sugars
into ethanol. This process is used in biofuel
production, where ethanol is produced from
renewable feedstocks such as sugarcane, corn,
or cellulosic biomass [89].
64
c. In addition to sugars, molasses contains minerals
such as potassium, calcium, magnesium,
phosphorus, and trace elements, which play vital
roles in bone development, muscle function,
enzyme activation, and overall metabolic
processes in animals.
d. Molasses also contains organic acids, including
lactic acid, acetic acid, and citric acid, which
contribute to gut health, pH regulation, and
nutrient absorption in livestock (Schrama et al.,
2019) [90].
2. Palatability Enhancement:
a. Molasses serves as a palatability enhancer in
livestock feed formulations, improving the taste,
aroma, and texture of feeds, thereby increasing
feed intake and animal performance.
b. The sweet taste and aroma of molasses attract
animals to consume feed more readily,
particularly in situations where feed quality may
be suboptimal or during periods of low appetite.
c. Studies have shown that the addition of molasses
to feed increases voluntary feed intake, nutrient
utilization, and growth performance in various
livestock species, including cattle, sheep, goats,
and horses (Khorasani et al., 2016) [91].
3. Energy Source:
a. The carbohydrates present in molasses,
particularly fermentable sugars, serve as a
valuable energy source for livestock, providing
readily available calories for metabolic processes,
growth, and lactation.
b. Molasses is often included in ruminant diets as a
source of fermentable carbohydrates for rumen
microbial fermentation, resulting in the production
of volatile fatty acids (VFAs) such as acetate,
propionate, and butyrate, which serve as major
energy substrates for ruminants.
65
c. The energy density of molasses makes it
particularly suitable for supplementing low-quality
forages or roughages, enhancing their nutritional
value and digestibility for ruminant animals
(Zhang et al., 2017) [92].
4. Feed Processing and Formulation:
a. Molasses can be incorporated into various types
of animal feed, including pelleted feeds, liquid
supplements, blocks, and lick tubs, through a
process known as molasses blending or coating.
b. In feed processing facilities, molasses is mixed
with other feed ingredients, such as grains,
protein meals, and forages, to form a
homogeneous mixture that is palatable,
nutritious, and easy to handle.
c. The inclusion rate of molasses in animal feed
formulations varies depending on factors such as
species, age, weight, production stage, and
nutritional requirements of the animals, with
typical inclusion levels ranging from 2% to 10% of
the total diet (Enkvetchakul et al., 2018) [93].
66
throat and respiratory passages, providing relief
from coughs, sore throats, and respiratory
congestion.
b. The rich, viscous consistency of molasses allows
it to form a protective coating over irritated
mucous membranes, reducing irritation and
inflammation and promoting healing [95].
c. In addition to its soothing effects, molasses
provides a natural source of energy and nutrients,
making it suitable for individuals recovering from
illness or experiencing fatigue or weakness [96].
2. Traditional Uses:
a. In traditional medicine systems, molasses-based
syrups are often combined with medicinal herbs,
spices, and botanical extracts to create
formulations targeting specific health concerns[97].
b. For example, molasses may be combined with
ginger, lemon, and honey to create a soothing
cough syrup with expectorant properties, or with
herbs such as licorice, marshmallow, and slippery
elm for a demulcent throat syrup.
c. These traditional formulations are believed to
support respiratory health, boost immune
function, and alleviate symptoms of colds, flu,
and respiratory infections[98].
● Iron Supplements:
1. Iron Content in Molasses:
a. Molasses is a rich source of iron, containing
significant amounts of this essential mineral. The
iron content of molasses varies depending on
factors such as the type of molasses (e.g., light,
67
dark), processing method, and source of the raw
material (sugarcane or sugar beet).
b. Dark molasses, which undergoes less processing
and retains more of the original sugarcane or
sugar beet juice, typically has higher iron content
compared to light molasses [99].
c. Iron in molasses exists in the form of ferrous
(Fe^2+) and ferric (Fe^3+) ions, which are readily
absorbed by the body and utilized for various
physiological functions, including oxygen
transport, energy metabolism, and enzymatic
reactions (Zhang et al., 2019) [100].
2. Bioavailability of Iron:
a. The bioavailability of iron in molasses is
influenced by factors such as its chemical form
(e.g., heme vs. non-heme iron), presence of
enhancing or inhibiting factors, and individual's
iron status and dietary factors.
b. Non-heme iron, the predominant form of iron in
plant-based foods such as molasses, is less
readily absorbed compared to heme iron from
animal sources. However, the absorption of non-
heme iron can be enhanced by factors such as
vitamin C (ascorbic acid) and organic acids
present in molasses [101].
c. Studies have demonstrated that consuming iron-
rich foods or supplements along with vitamin C-
rich foods or beverages, such as citrus fruits or
juices, enhances the absorption of non-heme iron
from plant sources, including molasses (Layrisse
et al., 2000) [102].
3. Iron Supplementation:
a. Molasses is commonly used as a natural source
of iron supplementation in individuals with iron
deficiency or anemia, particularly in populations
where access to conventional iron supplements
or fortified foods is limited.
68
b. The inclusion of molasses in the diet or as an
ingredient in fortified foods, beverages, or
medicinal formulations provides a convenient and
cost-effective way to increase iron intake and
improve iron status[103].
c. Molasses-based iron supplements are often
recommended for pregnant women, children,
vegetarians, and individuals at risk of iron
deficiency or anemia due to factors such as poor
diet, gastrointestinal disorders, or chronic
diseases[104].
Industrial Uses
● Biofuel Production:
◄ The use of molasses as a feedstock for biofuel production
offers several advantages, including its abundance, low
cost, and potential to reduce greenhouse gas emissions
compared to fossil fuels (Basso et al., 2020) [105].
◄ Bioethanol production from molasses involves a
fermentation process where sugars in the molasses are
converted into ethanol and carbon dioxide by
microorganisms such as Saccharomyces cerevisiae
(brewer's yeast).
◄ The fermentation process typically occurs in large
fermentation tanks under controlled conditions of
temperature, pH, and nutrient availability.
◄ Yeast strains are selected for their ability to efficiently
convert sugars to ethanol and tolerate high
concentrations of ethanol, ensuring maximum ethanol
yields and productivity (da Silva et al., 2019) [106].
◄ Following fermentation, the ethanol-containing broth is
subjected to distillation to separate ethanol from water
and other fermentation by-products.
◄ Distillation involves heating the fermented broth to
vaporize ethanol, which is then condensed and collected
as a concentrated ethanol solution.
69
◄ Additional purification steps such as dehydration and
rectification may be employed to further purify ethanol to
[107]
meet fuel-grade specifications (Kumar et al., 2018) .
● Microbial Biotechnology:
1. Microbial Growth and Metabolism:
● Microorganisms such as bacteria, yeast, and
fungi can utilize the sugars present in molasses
as carbon and energy sources for their growth
and production of various metabolites.
● The composition of molasses, including its sugar
profile and nutrient content, influences the types
of microorganisms that can thrive and the
products they can produce through fermentation
(Singh et al., 2019) [108].
2. Bioethanol Production:
● Yeast species such as Saccharomyces
cerevisiae are commonly used for bioethanol
production from molasses through fermentation.
● During fermentation, yeast metabolizes the
sugars present in molasses, primarily sucrose,
glucose, and fructose, to produce ethanol and
carbon dioxide.
● Optimization of fermentation conditions, including
pH, temperature, agitation, and nutrient
supplementation, is essential for maximizing
ethanol yields and productivity (Basso et al.,
2020) [109]..
71
Case Study: Sugarcane and By-Products at
Armant Sugar Factory
Armant Sugar Factory, established 154 years ago in 1869 AD, stands as
a prominent player in the sugar production industry. Renowned for its
efficient processing of sugarcane, the factory not only yields high-quality
sugar but also maximizes the utilization of its by-products for diverse
applications, including energy generation and other industrial uses.
Objective:
This case study aims to analyze the sugarcane processing stages, the
production of sugar, and the utilization of by-products, including their
quantities and applications.
Methodology:
Data was collected from the Armant Sugar Factory's production records
and operational details to provide a comprehensive overview of its
processes.
72
● The factory processes 400 tons per hour (t/hr) of sugarcane, with
two mills: 250 t/hr for Kozakii and 150 t/hr for Skoda.
● Juice concentrations: mixed juice (118.76 kg%/h) and clarified juice
(121.29 kg%/h).
● Syrup concentration: 25.53%.
Boiler Utilization:
The feed consists of 11% protein from various sources, including press
mud, molasses, corn, wheat bran, beet pulp, limestone, salt, cottonseed
cake, soybean meal, urea, sulfur, bicarbonate, etc.
Conclusion:
73
Armant Sugar Factory demonstrates an efficient process of sugarcane
processing and utilizes its by-products effectively for energy generation
and other applications, contributing to sustainability and resource
optimization.
74
Conclusion
The analysis of data from the Armant Sugar Factory illustrates the
practical benefits of these recycling practices. Bagasse, when used as
boiler fuel, contributes to steam generation while reducing reliance on
non-renewable energy sources. Mud, repurposed as organic fertilizer,
supports agricultural practices and promotes soil health. Molasses, with
its diverse applications in the production of alcohol, yeast, and animal
feed, adds considerable value to the sugar production chain.
75
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