Class 12th JEE

MRJM/12 Milestone Test-03 Phase-1

DATE: 07/07/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (2) 31. (4) 61. (2)
2. (1) 32. (1) 62. (4)
3. (4) 33. (4) 63. (4)
4. (2) 34. (3) 64. (3)
5. (1) 35. (2) 65. (4)
6. (3) 36. (2) 66. (1)
7. (2) 37. (2) 67. (2)
8. (2) 38. (2) 68. (2)
9. (1) 39. (3) 69. (2)
10. (3) 40. (3) 70. (2)
11. (1) 41. (4) 71. (1)
12. (1) 42. (2) 72. (2)
13. (2) 43. (4) 73. (1)
14. (2) 44. (4) 74. (3)
15. (4) 45. (2) 75. (2)
16. (2) 46. (3) 76. (2)
17. (3) 47. (1) 77. (1)
18. (4) 48. (1) 78. (2)
19. (4) 49. (2) 79. (2)
20. (1) 50. (2) 80. (1)
21. (5) 51. (32) 81. (1)
22. (3) 52. (4) 82. (4)
23. (4) 53. (5) 83. (7)
24. (4) 54. (51) 84. (20)
25. (15) 55. (3) 85. (0)
26. (7) 56. (24) 86. (17)
27. (32) 57. (1) 87. (47)
28. (10) 58. (3) 88. (8)
29. (24) 59. (3) 89. (2)
30. (2) 60. (25) 90. (9)
 SECTION-I (PHYSICS)
1. (2)

According to figure (ii) when charge Q is

displaced by small distance x then it’s potential
energy now
E.F. is constant
 1 1  2kqQa
σ U= kqQ  + = 
( )
…(ii)
E=  ( a + x ) ( a − x )  a 2 − x 2
… (1) f
2ε0
Let a small dipole of dq charge at r distance from Hence change in potential energy
O, so Torque  a 1
∆U = U f − U i = 2kqQ  2 − 
dτ = dPEsinθ a − x 2 a
dτ = dq(2r)Esinθ, dq = λdr
2kqQx 2
 =
( a2 − x2 ) a
  r2 
⇒τ= ∫ λ (2 r ) E sin θdr = 2λ E sin θ  
0  2  0
2kqQx 2
λσ sin θ 2 Since x << a so
= ∆U ⇒ ∆U ∝ x 2
=λE sin θ = 2 a3
2ε0
5. (1)
2. (1) On removing one plate, electric field will become
For the currents through galvanometer and shunt half; therefore, force will also become half.
resistance we have
IG S 6. (3)
=
IS G 1
E∝ (r < R)
I  r2
S = G G E=0 (r ≥ R)
 IS 
 2  G 7. (2)
=S = G
 98  49 If V is the voltage rating of the two bulbs then their
resistances are given as
3. (4) V2 V2 V2 V2
=R1 = and =
R 2 =
P1 200 P2 100
⇒ R2 = 2R1

3Q 8. (2)
∆V =
2C
2
1  3Q 
 
U= 
2 2 
C

4. (2)
Initially according to figure (i) potential energy of Let P1 = 2qd, where d << r
 
Q is U =− P ⋅ E
2kqQ −2kP2 P1 cos θ
Ui = …(i) =
a r3
9. (1) 15. (4)
By property of conductor, it provides Electrostatic Total flux coming out from unit charge
shielding inside the cavity in the conductor.   1
φ = E.ds = = ε0−1
ε0
10. (3)
When k is open equivalent resistance of the circuit 16. (2)
is given as Rnet=3R/2 Ceq =1+1=2µF
2E
= ( 3R / 2 )
⇒ i1 E / =
17. (3)
3R
When k is closed equivalent resistance of the circuit
is given as
 R × 2R  4
=Rnet 2=
 R + 2R  3 R
 
3E
⇒ i2 E / (=
= 4 R / 3)
4R
i1 8
⇒ =
i2 9 Let the side length of square be '' a '' then potential
at centre O is
K ( −8Q ) k ( − q ) k ( 3q ) k ( 4Q )
11. (1) V= + + + = 0
Given, q1 =
5µC, q2 =
10µC  a  a a a
 
 2 2 2 2
and r2 = 0.5 m, r1 = 1 m
2Q = q
1 1 1
W= q1q2  
4πε0  r2 r1  18. (4)
−6 −6
= 9 × 10 × 5 × 10
9
× 10 × 10 (2 − 1) Here we use
( R + R0 ) R
= 45 × 10−2 J R0= R +
( R + R0 ) + R
2 R 2 + RR0 + R 2 + RR0
12. (1) R0 =
2 R + R0
1
F∝ 3
In case of an electric dipole,   
r 2 RR0 + R02 = 3R 2 + 2 RR0
∴ new force = F/3 = F/27
3
3R 2 = R02
R0
R=
13. (2) 3
(a) EC and EF are cancelled. EE and ED at 60°
(b) EB and EE are cancelled. EF and ED at 120°. 19. (4)
(c) EB and EE are cancelled. Similar, EF and EC are As a voltmeter resistance is in general is very high
cancelled. so initially very low current flows in circuit and
(d) EF and ED at 120°. So, their resultant is in the potential difference across voltmeter is almost same
direction of EE Hence, net is 2E. as that cell voltage and current reading of ammeter
would be very low. When a resistance is connected
14. (2) in parallel to the voltmeter then overall resistance of
Just after the switch is closed C1 is short circuited circuit decreases which causes current to increase
and current passes through R1 and C1 only so it is and the potential difference across voltmeter will
given as E/R1. decrease.
20. (1) 200
4 × 50 + 2 × 100 = 6 × V ⇒ V = V
3
Total energy after connection
2
1  200  4
= × 6 × 10−6 ×  −2
 = × 10 J
2  3  3
Zero flux passes through the 3 surfaces which are
connected to the point charge, so by symmetry, 24. (4)
equal flux passes through the remaining three The equivalent of the circuit is
surfaces of the cube. Total flux through the cube is
th
1
 8  of the total flux(q/ ε0) through the point
 
charge. So, flux through one surface
1 q q 4R
= = For maximum power transfer, r = Req =
3 (8ε0 ) 24ε0 9

21. (5) 25. (15)

Tolerance of combination is also . 5%
ε0 A Cd 3 × 5 × 10−3
R = 100 ± 5 We have C = ⇒ A= =
d ε0 ε0
4R = 400 ± 20
Tolerance of combination is also 5% 15 × 10−3
=
ε0
22. (3)

26. (7)
Shorting the batteries and finding equivalent
resistance across the terminals of ‘C’ we get:

Now, 2 Ω and x are in parallel. So, their combined

2x
resistance is
2+ x 3R 7R
Req = +R=
2x 4 4
Or RAB = 1 +
2+ x Time constant = Req C.
But RAB is assumed as x. Therefore,
2x
x= 1 + 27. (32)
2+ x Dipole moment
Solving this equation, we get
p = 4 × 10−8 × 2 × 10−4 = 8 × 10−12 Cm
x=2Ω
Net resistance of circuit, R = 2Ω Maximum torque = pE = 8 × 10−12 × 4 × 108
12
Current through battery= i = 6A = 32 × 10−4 Nm
2
This current is equally distributed in 2Ω and 2Ω
resistances. 28. (10)
i Heat produced = Energy of charged capacitor
Therefore, the desired current is or 3A. 1
2 = CV 2
2
23. (4)
When connected in parallel
1
( )
= × 2 × 10−6 × (100 ) =10 mJ
2
2
29. (24) 12
=
V0 = V 2.4V
(2 L) ( L) 5
R1 =
ρ R2 =
ρ
A (2 A)
5 ρL 30. (2)
Req = R1 + R2 =
2 A
V 7 2 A 14 A
i= =× =
R 5 ρL 5 ρL

By mechanical energy conversation

Using KVL Ui + Ki = Uf + Kf
 2ρL   14 A  − kQ 1 2
8−  =V0 0 +=0 + mv
 A   5 ρL  R 2

V0 = 8 −
28 2kQ 2
⇒v=
5 mR

SECTION-II (CHEMISTRY)
31. (4) 1 1 1
= = [ x 1]
.               
Pº −Ps
=
n1 8 ( 2) ( 2)y
x

Pº n1 + n 2
1 1 1
= 1 . y
  8 ( 2) ( 2)
 1 
=
Pº −Ps   × 760
 1 + 1000  1 1
=
 18  8 2 × 2y

=
1
× 760 =
13.43 mm Hg 2y = 4
56.55 ∴Y = 2
Hence , differential rate equation is r ∝ [ A ] [ B]
1 2

32. (1)
dC
Let the order with respect to A and B is x and y or = kCA × C2B
respectively. dt
`Hence, [Where, CA and CB =concentrations of A and B]
Rate r = [ A ] [ B] …(i)
x y

33. (4)
On doubling the concentration of A, rate increases
1 1 1 1.8
2 times, k= × =
   × = 6.67 × 10–3 S cm–1
R a 50 5.4
4r = [ A ] [ B]
x y
… (ii)
And λ = k  V
× = 0.0104 ×10,000 = 104
From Eqs. (i) and (ii)
K × 1000 6.67 × 10−3 × 1000
1 1
x =
Λeq =
=  N 0.1
2 2
= 66.7 Ω–1 cm–1
∴   X = 1
∴ order with respect to A is 1 34. (3)
If concentration of A and B both are doubled,
Λ vs c curves are hyperbolic for weak
8r = [ 2A ] [ 2B] … (iii)
x y
electrolytes because on dilution their no. of ions as
From Eqs. (i) and (iii), we get well as ionic mobility both increase.
35. (2) X A YA
∴ <
Resonance structure with complete octet are more X B YB
stable.
41. (4)
36. (2)
For the given cell,
Zn + Cu+2 → Zn+2 + Cu(s)
H − C ≡ CH 
HgSO 4
→ CH
= 2 CH − OH  CH 3 − CHO
 Zn 2+ 
dil H SO 2 4

log  2+ 
0.0591
(X) (Y) E= E °cell −
Cu 
cell
2
CH 3 − CHO + 4HI 
→ CH 3CH 3 + 2I 2 + H 2 O
red P
 
0.0591 0.1 0.0591
E °cell −
1. E1 = log E °cell +
=
37. (2) 2 1 2
0.0591 1 0.0591
Z=
E E 2 E °cell −
2. = log = E °cell −   
96500 2 0.1 2
E 0.0591 1 0.0591
0.0006735 = E 3 E °cell −
3. = log = E °cell −    ×0
96500 2 1 2
E = 65 = E °cell   
∴ E1    
> E 3    
> E2
38. (2)
(C − Br) bond is weaker than (C − Cl) bond.
42. (2)
Grignard reagent is formed more predominantly
with (C − Br) An optically inactive compound forming optically
Br MgBr D active compound during a reaction always gives
Mg/ether D OD racemic mixture.
Cl
Cl Cl Cl
Wurtz +
Active D reaction
R with
Na 43. (4)
Cyclobutane, cyclopentane, and cyclohexane are
D D D D
more stable than cyclopropane and do not undergo
Cl + 2Na + Cl
catalytic hydrogenation at normal condition of
temperature
39. (3) (H2 + Pt) converts (C ≡ C) to (C − C)
     for glucose = ∆T for KCl + ∆T for urea Birch reduction gives anti-addition of H2 and
converts (C ≡ C) to (C=C). So the answer is (4).
1000 ×1.86 ×10 1000 ×1.86 ×1×2 1000 ×1.86 ×5
= + +
100 × 180 74.5 ×100 100 ×60 44. (4)
= 3.069 Given rate of formation of SO3
∴ f .p. =273 − 3.069 =269.93 K 100
= 100 gm min–1 = mole/min
80
40. (3) −1 SO 2 d(O 2 ) 1 d(SO3 ) 2 100 1
= = = ×
PAo X A YA 2 dt dt 2 dt 80 2
=
PBo X B YB −d(O 2 ) 5
= mole/min
dt 8
PAo
 >1 5
PBo = × 32 = 20 gm mol–1
8
45. (2) Me
CH O + O CH CH3
Fact.

Me H H
46. (3) * C C
CH3
(A)
(A) Has two geometrical centres. (along double
bond and along ring).
Number of G.I. = 22 = 4
47. (1)
This is Wurtz reaction. 2-chloropropane and 53. (5)
chloromethane reacts in presence of dry ether 1 2 5
Me H H
H 3 4
form 2-methyl propane.
Ether H H H CH 3
CH 3 Cl + 2Na + Cl CH CH 3 cis or (Z) trans or (E)
CH3 Pent-3-en-1-yne
CH 3 CH CH3 + 2 NaCl Minimum number of C atoms required to show
G.I. is five
CH3
54. (51)
48. (1) 3X 
→ X3
Aryl halides show resonance in their structure. 1− α α /3
α
49. (2) i = 1− α +
3
E °Fe2+ /Fe = −0.441 V 2α
0.66 = 1 −
E °Fe3+ /Fe = −0.771 V
3
2α
= 1 − 0.66
E °cell E °OP
= + E °RP (See redox 3
Fe/Fe2+ Fe3+ /Fe2+

α = 0.51
change)
= + 0.441 + 0.771 = 1.212 V
55. (3)
The cell reaction is
50. (2)
H 2 ( g ) + I 2 ( s )  2H + ( aq ) + 2I − ( aq )
CH 3 − CH = CH 2 + Cl2 
500ºC
∆
→ ClCH 2 − CH = CH 2 2 2
 H +   I− 
log    
Allyl Chloride 0.0591
= 0.535 −
0.7714
2 p H2
51. (32) ∴ pH =
3
Eq. of H2 = Eq. of Cu
1.608 W 56. (24)
∴ = K × w 2 × 1000
1 63.5/2 = f
M 2   
∴ WCu = 32 g Tf × w1
1.86 × 1.8 × 1000
or    M 2 = =180
0.465 × 40
52. (4)
180 180
Proceeding reverse, the structure of (A) is: n= = = 6
emp.formula mass 30
Molecular formula of the compound is C6 H12 O6
57. (1) the order, of reaction with respect to Br2(g) is 1.
Rate = k [ NOBr2 ][ NO ] …(i)
58. (3)
But NOBr2 is in equilibrium
Mixture of products obtained.
k eq =
[ NOBr2 ]
[ NO][ Br2 ] 59. (3)
[ NOBr2 ] = k eq [ NO][ Br2 ] …(ii) CH 3 NH 2 
CH3 I
− HI
→ ( CH3 )2 NH 
CH3 I
− HI
→ ( CH 3 )3 N
  
Putting the [ NOBr2 ] in ( i ) → ( CH 3 )4 N + I −
 CH3 I

rate = k.k eq [ NO ][ Br2 ][ NO ] Hence, three molecules of CH 3 I is used.

Hence, rate = k.k eq [ NO ] [ Br2 ]
2

60. (25)
rate = k '[ NO ] [ Br2 ]
2
100 
6 hr
→ 50 
6 hr
→ 25
where, k’.Keq
SECTION-III (MATHEMATICS)
61. (2) 65. (4)
aij =( i − j ) ⇒ a ji =( j − i ) =− ( i − j ) =−aij
3 3 3 Apply vertical line test
Vertical line test: Draw all possible lines parallel
∴ A is a skew-symmetric matrix to y-axis. If any line cuts the graph at two or more
than two points then it is not a function.
62. (4)
66. (1)
1 −3
=
α , =
β 4, =
γ tan −1 (1) + tan −1 ( 0 ) + tan −1 ( 2 ) + tan −1 ( 3)
4 2
π  2+3 
1 
log 5
( β2 + 4 γ 2 ) = + π + tan −1   (as 2 ⋅ 3>1)
⇒  + 1 =
625 4 1− 2⋅3 
α  5π 5π π
= + tan −1 ( −1) = − = π
4 4 4
63. (4)
Option (1), (2), (3) are not equivalence relation. 67. (2)
In option (4), We have f ( x) =( x − 1)( x − 2)( x − 3)
(a, a ) ∈ R for all a ∈ A ⇒ f (1) = f (2) = f (3) =0
Hence It is reflexive ⇒ f ( x) is not one-one
(1, 2) ∈ R and (2,1) ∈ R For each y ∈ R, there exists x ∈ R such that
f ( x) = y . Therefore f is onto.
Hence It is symmetric
(1, 2) ∈ R,(2,1) ∈ R and (1,1) ∈ R Hence, f : R → R is onto but not one-one.

Hence It is transitive. 68. (2)

Hence, it is an equivalence relation. 0 −1 2  −1 0 
=B = , B  0 −1
1 0   
64. (3)
1 0 
A is orthogonal matrix =
and B 4 =  I
0 1 
∴ ATA = I
B1027 = (B4)256.B3
2 x2 0 0  1 0 0  = (I)256.B3
 
 0 6 y2 0  = 0 1 0  = I.B3
  = B3
 0 0 3z 2  0 0 1 
= B.B2
1 1 1 0 −1  −1 0   0 1 
⇒ + 2 + 2 = 2 + 6 + 3 = 11 = =    
1 0   0 −1  −1 0 
2
x y z
 69. (2) 74. (3)
x −1 Statement I and statement II both are correct.
≥ 0,
x+2 −1 π 
tan= x 2  − cot −1 x 
+ – + 3 
–2 1 π π 
= 2  −  − tan −1 x  
⇒ x ∈ (−∞, – 2) ∪ [1, ∞) and 3 2 
2x − 5  −π  π
≤1 =2  + tan −1 x  ⇒ tan −1 x =
x−2  6  3
⇒ x ∈ (2, 3] ⇒ x =3
1 – x2 = 4x has 2 solution
70. (2)
For f(x) to be defined 75. (2)
3− | x | 1 + ax 1 + bx 1 + cx
≥0
| x | −7 Given that, 1 + a1 x 1 + b1 x 1 + c1 x
| x | −3 1 + a2 x 1 + b2 x 1 + c2 x
⇒ ≤0
| x | −7 =A0 + A1 x + A2 x 2 + A3 x3
⇒ 3≤| x|< 7 On putting x = 0 on both sides, we get
⇒ x ∈ [3, 7) ∪ (–7, − 3] 1 1 1
1 1 1 = A0
71. (1) 1 1 1
Only reflexive a = b ⇒ 3 is an irrational number ⇒ A0 =
0

( )
3,1 ∈ R but (1, 3 ) ∉ R not symmetric
76. (2)
( 3,1) , (1, 2 3 ) ∈ R but ( )
3, 2 3 ∉ R not Given, order of A is 3×4
Let order of B is m × n
transitive.
Now, if A'B is defined then
Number of columns of A' = Numbers of rows of B
72. (2)
∴3=m
Let tan −1 x = θ . Then, =
x tan θ Also, A' will be of 4×3 order
Also, Also, BA' is defined, so
π π Number of columns of B = Numbers of rows of A'
x ∈ (1, ∞ ) ⇒ 1 < x < ∞ ⇒ 1 < tan θ < ∞ ⇒ <θ<
4 2 ∴n=4
Now, ∴ Order of B is 3×4,
1  2x 
Order of B' is 4×3,
tan −=  2 
tan −1 ( tan 2θ ) Order of B'A is 4×4
1− x 
= tan −1 ( − tan ( π − 2θ ) ) 77. (1)
= tan −1
( tan ( 2θ − π ) ) Given, ( 3x + 1)2 < ( 2 − x )
= 2 tan −1 x − π ⇒
   3 x + 1 < 2 − x
3x + 1 ≥ 0
73. (1) 1
⇒
   3 x + 1 < 2 − x ⇒ x <
x −1 =0 4
⇒x=
1 Similarly, 3x + 1 < 0
78. (2) Taking log both side at base 2
 C = ABAT ⇒ C = A ⋅ B ⋅ AT 2+ x
f ( x) = log 2  
2
2− x
⇒C = A ⋅B
 8x 
f ( x ) = λf  
and =
X A C A ⇒=
T
X2
A C T 2
A  4 + x2 
⇒ X =
2 2  8x 
 2 + 4 + x2
A C
2+ x 
 = λ log 2  
(A ) =( A )
2 2 log 2 
∴ X = A 2− x
2 2 3
⋅B ⋅B  2 − 8x 
 4 + x2 
=
 A 1,=
and B 1
2 + x  x + 2
X = (13 ⋅ 1) 2 = 1 ⇒ log 2   =
2λ log 2 
2 − x  2 − x 
⇒ 2λ = 1
79. (2)
For infinite number of solutions
82. (4)
∆ = ∆1 = ∆ 2 = ∆ 3 = 0
2 − k 2 
Given, A = 
3 − k 
1 2 3
 1
=∆ 2=3 1 0
Since, the matrix A is non-invertible
4 3 α
∴ |A| = 0
⇒ (3α − 3) − 2 (2α – 4) + 3 (6 – 12) = 0 2−k 2
⇒ (3α − 3) − 4α + 8 − 18 =0 ⇒ = 0 ⇒ (2 − k ) (3 − k ) − 2 = 0
1 3− k
⇒ 3α − 3 − 4α − 10 =0
⇒ 6 – 5k + k2 – 2 = 0 ⇒ 4 – 5k + k2 = 0
⇒ α = −13
⇒ k2 – 5k = –4 ⇒ |k2 – 5k| = 4
5 2 3
=∆1 9 =
3 1 0
83. (7)
β 3 −13
  −7  
⇒ 5(−39 − 3) − 2(−117 − β) + 3(27 − 3β) = 0 (– 17)  tan tan −1    = 7
  17  
⇒ ∆1 = −210 + 234 + 2β + 81 − 9β = 0
⇒ β =15 84. (20)
and ∆ 2 =0 =∆ 3 2
a b  a b 
∴ α + β = – 13 + 15 = 2 c 1 − a = c 1 − a
   
80. (1) a b  a b  a b 
⇒    =
 
I → T, II → R, III → Q, IV → P c 1 − a c 1 − a c 1 − a
x2  a 2 + bc ab + b − ab   a
I. −1 ≤ ≤1 ⇒ −2 ≤ x 2 ≤ 2 b 
2 ⇒ =c 1 − a
 ac + c − ac bc + (1 − a )  
2

⇒− 2≤x≤ 2
II. x ∈ [−1, 1] − {0}  a 2 + bc b  a b 
⇒ =c 1 − a
1 3  c bc + (1 − a )  
2

III. Range is  , 
4 4
IV. Range is (0, 1) ⇒ a 2 + bc = a
1
a − a 2 = bc = (given)
81. (1) 4
2+ x f (a) =
1
2 f ( x) =
2− x 4
85. (0) 23n + 24
⇒ =
1
As we know that 24n − 23
π n = 47
| sin −1 x |≤
2
∴ Given relation 88. (8)
3π
sin −1 x + sin −1 y + sin −1 z =
2
is possible only when x ∈ ( −7, −3] ∪ ( 0, 4]
π
sin −1 x + sin −1 y = sin −1 z = integral values of x are
2 =−6, −5, −4, −3,1, 2,3, 4
⇒ x = y = z =1
9 89. (2)
∴ x100 + y100 + z100 − 101
x + y101 + z101 2[x] = x + {x}
9 ⇒ 2[x] = [x] + 2{x}
= 1+1+1−
1+1+1 ⇒ {x} =
[ x]
9 2
=3 − =0
3 1
⇒ [x] = 0 or 1 and {x} = 0 or
2
86. (17) 3
⇒ x = 0 or
Given |A| = 2, |B| = 3 and |C| = 5 2
∴ |A2BC–1| = |A2| |B| |C–1|
90. (9)
1
= | A |2 ⋅ | B | ⋅ adj (adj (adjA)) = 316
|C |
1 Let adjA =
B ⇒ adj (adjB ) =
316
= (2)2 ⋅ (3) ⋅
5 2
⇒ | B |( n −1) = 316
12
= 2 2
5 ⇒ | adjA |( n −1) =
316 ⇒ (| A |n −1 )( n −1) =
316
3
⇒ | A |( n −1) = 316
87. (47)
3 3
1 1 1 1
tan −1   + tan −1   + tan −1   + tan −1   ⇒ 9( n −1) =⇒
316 32( n −1) =
316
3 4 5 n ⇒ (n − 1)3 =
8
 23  1 π ⇒ n–1=2⇒n=3
⇒ tan −1   + tan −1   =
 24  n 4 ∴ Number of elements = n2 = 9

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