Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Identification of the substance Ortho-Phosphoric acid 85 % p.A.
Registration number (REACH) this information is not available
CAS number 7664-38-2
Article number LC-7313
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses General use
Uses advised against Do not use for squirting or spraying. Do not use
for products which come into direct contact with
the skin.

1.3 Details of the supplier of the safety data sheet

NeoFroxx GmbH
Marie-Curie-Str. 3
D-64683 Einhausen
Germany

Telephone: +49 (6251) 989 24 - 0

e-mail: [email protected]
Website: neofroxx.com
e-mail (competent person) [email protected] (neoFroxx GmbH)
1.4 Emergency telephone number

Poison centre

Country Name Postal code/city Telephone

United Kingdom National Poisons Information Service 111

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Section Hazard class Category Hazard class and cat- Hazard state-
egory ment

2.16 substance or mixture corrosive to metals 1 Met. Corr. 1 H290

3.1O acute toxicity (oral) 4 Acute Tox. 4 H302

3.2 skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 serious eye damage/eye irritation 1 Eye Dam. 1 H318

For full text of abbreviations: see SECTION 16.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epidermis and into
the dermis.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
- Signal word danger
- Pictograms
GHS05, GHS07

- Hazard statements
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

- Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protec-
tion.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or
shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P390 Absorb spillage to prevent material damage.
P501 Dispose of contents/container to industrial combustion plant.

2.3 Other hazards

Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance ortho-Phosphoric acid 85 % p.A.
Identifiers
CAS No 7664-38-2
EC No 231-633-2
Index No 015-011-00-6
Purity 85 %

Specific Conc. Limits M-Factors ATE Exposure route

Skin Corr. 1B; H314: C ≥ 25 % 588.2 mg/kg oral

Skin Irrit. 2; H315: 10 % ≤ C < 25 %
Eye Dam. 1; H318: C ≥ 25 %
Eye Irrit. 2; H319: 10 % ≤ C < 25 %

Molecular formula H3O4P

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Molar mass 97.99 g/mol

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still
and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek
medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.

Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respirat-
ory tract irritation, consult a physician. Provide fresh air.

Following skin contact

Wash with plenty of soap and water.

Following eye contact

Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at
least 10 minutes, holding the eyelids apart.

Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.

4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media
Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2)

Unsuitable extinguishing media

Water jet

5.2 Special hazards arising from the substance or mixture

Substance or mixture corrosive to metals.

Hazardous combustion products

Phosphorus oxides (PxOy)

5.3 Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do
not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately.
Fight fire with normal precautions from a reasonable distance.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel
Remove persons to safety.

For emergency responders

Wear breathing apparatus if exposed to vapours/dust/spray/gases.

6.2 Environmental precautions

Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.

6.3 Methods and material for containment and cleaning up

Advice on how to contain a spill
Covering of drains

Advice on how to clean up a spill

Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal
binder

Appropriate containment techniques

Neutralisation techniques. Use of adsorbent materials.

Other information relating to spills and releases

Place in appropriate containers for disposal. Ventilate affected area.

6.4 Reference to other sections

Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materi-
als: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Recommendations
- Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation. Use only in well-ventilated areas. Never add water to this product.

- Handling of incompatible substances or mixtures

Do not mix with alkali.

- Keep away from

Caustic solutions

Advice on general occupational hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective
equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals
in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

7.2 Conditions for safe storage, including any incompatibilities

Managing of associated risks
- Corrosive conditions
Store in corrosive resistant container with a resistant inner liner.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

- Packaging compatibilities
Only packagings which are approved (e.g. acc. to ADR) may be used.

7.3 Specific end use(s)

See section 16 for a general overview.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits)

Coun- Name of agent CAS No Identi- TWA TWA STEL STEL Ceiling-C Ceiling-C Nota- Source
try fier [ppm] [mg/m³] [ppm] [mg/m³] [ppm] [mg/m³] tion

EU orthophosphoric 7664-38-2 IOELV 1 2 2000/

acid 39/EC

GB orthophosphoric 7664-38-2 WEL 1 2 EH40/

acid 2005

Notation
Ceiling-C ceiling value is a limit value above which exposure should not occur
STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute peri-
od (unless otherwise specified)
TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours
time-weighted average (unless otherwise specified)

8.2 Exposure controls

Appropriate engineering controls
General ventilation.

Individual protection measures (personal protective equipment)

Eye/face protection
Wear eye/face protection.

Skin protection
- Hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-
tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off
and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective
gloves mentioned above together with the supplier of these gloves.

- Type of material
NBR: acrylonitrile-butadiene rubber

- Material thickness min. 0,11 mm

- Breakthrough times of the glove material
>480 minutes (permeation: level 6)

- Other protection measures

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.
Wash hands thoroughly after handling.

Respiratory protection
P2 (filters at least 94 % of airborne particles, colour code: White).

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Environmental exposure controls

Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state liquid

Colour colourless

Odour odourless

Melting point/freezing point not determined

Boiling point or initial boiling point and not determined

boiling range

Flammability non-combustible

Lower and upper explosion limit not determined

Flash point not determined

Auto-ignition temperature not determined

Decomposition temperature not relevant

pH (value) <0.5 (in aqueous solution: 100 g/l, 20 °C) (acid)

Kinematic viscosity 30.5 mm²/s at 20 °C

Solubility(ies)

Water solubility miscible in any proportion

Partition coefficient

Partition coefficient n-octanol/water (log value) not relevant (inorganic)

Vapour pressure 2 Pa at 20 °C

Density and/or relative density

Density 1.71 g/cm³ at 20 °C

Particle characteristics no data available

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

9.2 Other information

Information with regard to physical hazard there is no additional information

classes

Other safety characteristics

Miscibility Completely miscible with water.

SECTION 10: Stability and reactivity

10.1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". It's a reactive substance.
Substance or mixture corrosive to metals.

10.2 Chemical stability

See below "Conditions to avoid".

10.3 Possibility of hazardous reactions

Risk of ignition or formation of inflammable gases or vapors with:
Metals, metal alloys . It can arise:. Hydrogen. Strong reactions possible with:. Bases. Metal oxides.

10.4 Conditions to avoid

There are no specific conditions known which have to be avoided.

10.5 Incompatible materials

Bases, Aluminum, iron / ferrous compounds, steel , Hydrogen is released by reaction with metals

10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are
not known. Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Harmful if swallowed.

- Acute toxicity estimate (ATE)

Oral 588.2 mg/kg

Skin corrosion/irritation
Causes severe skin burns and eye damage.

Serious eye damage/eye irritation

Causes serious eye damage.

Respiratory or skin sensitisation

Shall not be classified as a respiratory or skin sensitiser.

Germ cell mutagenicity

Shall not be classified as germ cell mutagenic.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Carcinogenicity
Shall not be classified as carcinogenic.

Reproductive toxicity
Shall not be classified as a reproductive toxicant.

Specific target organ toxicity - single exposure

Shall not be classified as a specific target organ toxicant (single exposure).

Specific target organ toxicity - repeated exposure

Shall not be classified as a specific target organ toxicant (repeated exposure).

Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

11.2 Information on other hazards

There is no additional information.

SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.

12.2 Persistence and degradability

Data are not available.

12.3 Bioaccumulative potential

Data are not available.

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

Data are not available.

12.6 Endocrine disrupting properties

Not listed.

12.7 Other adverse effects

Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste treatment-relevant information
Recycling/reclamation of other inorganic materials. Regeneration of acids.

Sewage disposal-relevant information

Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Waste treatment of containers/packagings

It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Completely emptied
packages can be recycled. Handle contaminated packages in the same way as the substance itself.

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be
handled separately by the local or national waste management facilities.

SECTION 14: Transport information

14.1 UN number or ID number

ADR/RID/ADN UN 1805
IMDG-Code UN 1805
ICAO-TI UN 1805
14.2 UN proper shipping name
ADR/RID/ADN PHOSPHORIC ACID, SOLUTION
IMDG-Code PHOSPHORIC ACID, SOLUTION
ICAO-TI Phosphoric acid, solution
14.3 Transport hazard class(es)
ADR/RID/ADN 8
IMDG-Code 8
ICAO-TI 8
14.4 Packing group
ADR/RID/ADN III
IMDG-Code III
ICAO-TI III
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.

14.7 Maritime transport in bulk according to IMO instruments

The cargo is not intended to be carried in bulk.

Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Classification code C1
Danger label(s) 8

Excepted quantities (EQ) E1

Limited quantities (LQ) 5L
Transport category (TC) 3

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Tunnel restriction code (TRC) E

Hazard identification No 80
Emergency Action Code 2R
International Maritime Dangerous Goods Code (IMDG) - Additional information
Marine pollutant -
Danger label(s) 8

Special provisions (SP) 223

Excepted quantities (EQ) E1
Limited quantities (LQ) 5L
EmS F-A, S-B
Stowage category A
Segregation group 1 - Acids
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Danger label(s) 8

Special provisions (SP) A3

Excepted quantities (EQ) E1
Limited quantities (LQ) 1L

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction No

ortho-Phosphoric acid 85 % p.A. this product meets the criteria for classi- R3 3
fication in accordance with Regulation
No 1272/2008/EC

Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental
lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both,
if they:
- can be used as fuel in decorative oil lamps for supply to the general public, and,
- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN).

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Legend
5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and la-
belling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, that the following re-
quirements are met:
(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly marked as
follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December 2010, ‘Just a sip of lamp oil - or
even sucking the wick of lamps - may lead to life-threatening lung damage’;
(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by
1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lung damage’;
(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in black
opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, in accord-
ance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and fuel for decorative
lamps, labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with R65 or H304,
shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids labelled
R65 or H304 to the competent authority in the Member State concerned. Member States shall make those data available to
the Commission.

List of substances subject to authorisation (REACH, Annex XIV) / SVHC - candidate list
not listed

Deco-Paint Directive (2004/42/EC)

VOC content 0%

Directive on industrial emissions (VOCs, 2010/75/EU)

VOC content 0%

Water Framework Directive (WFD)

not listed

National inventories

Country Inventory Status

EU REACH Reg. substance is listed

US TSCA substance is listed

Legend
REACH Reg. REACH registered substances
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2000/39/EC Commission Directive establishing a first list of indicative occupational exposure limit values in imple-
mentation of Council Directive 98/24/EC

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)

ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Abbr. Descriptions of used abbreviations

ADR/RID/ADN European Agreements concerning the International Carriage of Dangerous Goods by Road/Rail/Inland
Waterways (ADR/RID/ADN)

ATE Acute Toxicity Estimate

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

DGR Dangerous Goods Regulations (see IATA/DGR)

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)

EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation
(EC) No 1272/2008

IOELV Indicative occupational exposure limit value

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

STEL Short-term exposure limit

SVHC Substance of Very High Concern

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

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 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Ortho-Phosphoric acid 85 % p.A.

Version number: GHS 1.0 Date of compilation: 2021-03-25

Abbr. Descriptions of used abbreviations

WEL Workplace exposure limit

Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures. Regulation (EC)
No. 1907/2006 (REACH), amended by 2020/878/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Maritime Dangerous
Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Code Text

H290 May be corrosive to metals.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely inten-
ded for this product. The information is intended to give you guidelines for the safe handling of the product men-
tioned in this safety data sheet during storage, processing, transport and disposal. The information is not transfer-
able to other products. Insofar as the product is mixed, blended or processed with other materials or is subjected to
processing, the information in this safety data sheet cannot be transferred to the new material produced in this way,
unless expressly stated otherwise.

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